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Poll
CHEMISTRY (C-O1)
Syllabus: Organic Chemistry-Some Basic Principles and Techniques
Choose the correct option. 4. The sodium fusion extract of an organic
1
Heterocyclic aromatic compound among the compound is boiled with FeSO4 and then
following is acidified with concentrated H2SO4. The
formation of prussian blue colour confirms the
presence of which element in the compound?
(1) (2) (1) Sulphur (2) Nitrogen
(3) Bromine (4) lodine
OH
5. In Carius method of estimation of halogen, 1.0 g
of an organic compound gave 0.94 g of AgBr.
The percentage of bromine in the compound is
(Molar mass AgBr = 188g mo-1)
(3) (4) (1) 32% (2) 40%
(3) 48% (4) 24%
6. Given below are the two statements.
2 Consider the following species
ÇH,
Statement 1: H, is trigonal planar in shape.
CH, Statement I: Carbon of H, is sp² hybridized.
In light of the above statements choose the
(i) (i) (iü) (iv) correct answer.
The species which show hyperconjugation (1) Statement I is correct but statement Il is
effect are incorrect
(1) ()and () only (2) (i) and (i) only (2) Both statement Iand statement ll are corect
(3) () and (ii) only (4) (0). (Ö1), (i) and (iv) (3) Both statement | and statement l are
3. incorrect
Most stable carbanion among the following is
(4) Statement Iis incorrect but statement Il is
Correct
7. IUPACname of the given compound is
(1) (2) NO,
OCH,
OCH,
H,c:
ÇH. ÇH,
(1) 4-Ethyl-1-fluoro-2-nitrobenzene
(3)| (4) (2) 1-Ethyl-4-fluoro-3-nitrobenzene
(3) 5-Ethyl-2-fluoro-1-nitrobenzene
NO, (4) 4-Ethy-1-fluoro-6-nitrobenzene
[Page 1]
Poll-01 Chemistry
8 Consider the following compounds 13. In sulphur estimation 1.6 g of an organic
CH3CH2COOH (CH3)sCCOOH (CHs)2CHCOOH compound gave 1.864 g of barium sulphate.
() (i) (ii) The percentage of sulphur in the compound is
(Molar mass of BaSO4 = 233 g mol-)
Correct order of acidic strength is
(1) 32%
(1) (i) > (0) > (1) (2) 24 %
(2) (i) > (i) > (i) (3) 56%
(3) () > (i) > (ii)
(4) 16%
(4) () > (i) > ()
9 14. Consider the following statements
Correct order of priority sequence of the given
functional groups is (a) Mixture of chloroform and aniline are easily
separated by distillation
(1) -CN>-CONH2 > -HC=0 >-COCI
(2) -COC|> -CONH2 >-CN>-HC =0 (b) Glycerol can be separated from spent-lye in
soap industry by using distillation under
(3) -CONH2 > -CN>-COCI > -HC=0 reduced pressure
(4) -CONH2 >-COC| >-HC=0>-CN (c) Fractional distillation is used to separate
10. Consider the following statements: different fractions of crude oil in petroleum
(a) Methoxypropane and ethoxyethane are industry
metamers The correct statements are
(b) Pentane, Isopentane and neopentane are (1) (b) and (c) only
chain isomers
(2) (a) and (c) only
(c) The compounds that have the same (3) (a). (b) and (c)
constitution and sequence of covalent
bonds but differ in relative positions of their (4) (a) and (b) only
atoms or groups in space are called 15. Correct order of stabiliy of given free radicals is
stereoisomers. "CH.
The correct statements are CH
CH,
(1) (a) and (b) only CH-C"
(2) (b) and (c) only CH,-CH CH,
(3) (a). (b) and (c) (i) (ii) (ii)
(4) (a) and (c) only (1) (0) >(iüi) >()
11. Colour of [Fe(SCN)J2* complex is (2) (i) > (ii) > ()
(1) Green (2) Yellow (3) (i1) > (ii) > (0
(3) Blood red (4) violet (4) (0) > (i) > (i)
12. The pair of compounds to which Kjeldahl 16. Which among the following elements is
method is not applicable is estimated by Dumas method?
CN (1) Nitrogen
NH, (2) Sulphur
(1) and
(3) Chlorine
(4) Bromine
NO, 17. IUPAC name of the given compound is
arnd
(2)

(3) NH, CN
and (1) 1-Ethy-3,3-dimethylcyclopentane
(2) 3-Ethyl-1,1-dimethylcyclopentane
(4) NH, and (3) 1-Ethy-4,4-dimethylcyclopentane
(4) 4-Ethyl-1, 1-dimethylcyclopentane
[Page 2]
Pol-01
18. During estimatlon of nltrogen present In an
organic compound by Kjeldahl's method, the
ammonla evolved from 2 g of an organic
Compound was neutralised by 20 mL of 0.8 M
HaSO4 solution. The percentage of nitrogen
present in the compound is
(1) 14.6%
(2) 38.2%
(3) 47.19%
(4) 22.4%
19. Given below are two statements
Statement l: Agl is insoluble in NHOH solution.
Statement Il: AgCi is soluble in NH4OH
solution.
In light of the above statements, choose the
correct answer
(1) Both statement Iand statement ll are correct
(2) Both statement | and statement I| are
incorrect
(Page 3]
Chemistry
(3) Statement I Is correct but statement I| is
incorrect
(4) Statement I Is incorrect but statement Il Is
correct
20. Consider the following statements
(a) Adsorption chromatography is based on the
fact that different Compounds are adsorbed
on an adsorbent to different degrees.
(b) Thin layer chromatography is a type of
partition chromatography.
(c) Partition chromatography is based on
continuous differential partitioning of
components of a mixture between stationary
and mobile phases.
The correct statements are
(1) (a) and (b) only
(2) (a) and (c) only
(3) (b) and (c) only
(4) (a), (b) and (c)