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Ethanol Ahyd Histo 4l
Ethanol Ahyd Histo 4l
Ethanol Ahyd Histo 4l
Company
Fisher Scientific Company
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Classification
This chemical is considered hazardous by the 20122. Hazard(s)
OSHA identification
Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word
Danger
Hazard Statements
Highly flammable liquid and vapor
Causes serious eye irritation
Suspected of causing cancer
Suspected of damaging fertility or the unborn child
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Ethanol, Anhydrous Revision Date 07-Jan-
Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood Use
personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling Wear
eye/face protection
Do not breathe dust/fume/gas/mist/vapors/spray Do not
eat, drink or smoke when using this product
Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep
container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting equipment Use
only non-sparking tools
Take precautionary measures against static discharge
Response
IF exposed or concerned: Get medical attention/advice
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye
irritation persists: Get medical advice/attention
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep cool
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Repeated
exposure may cause skin dryness or cracking Other
hazards
Poison, may be fatal or cause blindness if swallowed. Vapor harmful. CANNOT BE MADE NON-POISONOUS. WARNING.
Cancer and Reproductive Harm - https://www.p65warnings.ca.gov/.
Component3. Composition/Information
CAS No on Ingredients Weight %
Ethyl alcohol 64-17-5 90-95
Methyl alcohol 67-56-1 3-5
Methylisobutyl ketone 108-10-1 1-3
Ethyl acetate 141-78-6 1-2
Solvent naphtha (petroleum), light aliphatic 64742-89-8 1
4. First-aid measures
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Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,
call a physician.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Unsuitable Extinguishing Media Water may be ineffective, Do not use a solid water stream as it may scatter and spread fire
Method - Estimated
Explosion Limits
Upper 18.0 vol %
Lower 3.3 vol %
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
NFPA
Health Flammability Instability Physical hazards
3 3 0 N/A
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Up
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Ethanol, Anhydrous Revision Date 07-Jan-
Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in
eyes, on skin, or on clothing. Avoid ingestion and inhalation.
Storage. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat,
sparks and flame. Incompatible Materials. Strong oxidizing agents. Acids. Acid anhydrides.
Acid chlorides. Peroxides. Alkali metals.
Exposure Guidelines
8. Exposure controls / personal protection
Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Ethyl alcohol STEL: 1000 ppm (Vacated) TWA: 1000 ppm IDLH: 3300 ppm STEL: 1000 ppm
(Vacated) TWA: 1900 mg/m3 TWA: 1000 ppm
TWA: 1000 ppm TWA: 1900 mg/m3
TWA: 1900 mg/m3
Methyl alcohol TWA: 200 ppm (Vacated) TWA: 200 ppm IDLH: 6000 ppm TWA: 200 ppm
STEL: 250 ppm (Vacated) TWA: 260 mg/m3 TWA: 200 ppm STEL: 250 ppm
Skin (Vacated) STEL: 250 ppm TWA: 260 mg/m3
(Vacated) STEL: 325 mg/m3 STEL: 250 ppm
Skin STEL: 325 mg/m3
TWA: 200 ppm
TWA: 260 mg/m3
Methylisobutyl ketone TWA: 20 ppm (Vacated) TWA: 50 ppm IDLH: 500 ppm TWA: 20 ppm
STEL: 75 ppm (Vacated) TWA: 205 mg/m3 TWA: 50 ppm STEL: 75 ppm
(Vacated) STEL: 75 ppm TWA: 205 mg/m3
(Vacated) STEL: 300 mg/m3 STEL: 75 ppm
TWA: 100 ppm STEL: 300 mg/m3
TWA: 410 mg/m3
Ethyl acetate TWA: 400 ppm (Vacated) TWA: 400 ppm IDLH: 2000 ppm TWA: 400 ppm
(Vacated) TWA: 1400 mg/m3 TWA: 400 ppm
TWA: 400 ppm TWA: 1400 mg/m3
TWA: 1400 mg/m3
Legend
Engineering Measures Ensure adequate ventilation, especially in confined areas. Use explosion-proof
electrical/ventilating/lighting equipment. Ensure that eyewash stations and safety showers are close
to the workstation location.
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye
and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Physical State Liquid
Appearance 9. Physical and chemical
Clear properties
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Odor Alcohol-like
Odor Threshold No information available
pH Not applicable
Melting Point/Range < -90 °C / -130 °F
Boiling Point/Range 77.1 °C / 170.8 °F
Flash Point 13.9 °C / 57 °F
Method - Estimated
Evaporation Rate 3.6 (Butyl acetate = 1.0)
Flammability (solid,gas) Not applicable
Flammability or explosive limits
Upper 18.0 vol %
Lower 3.3 vol %
Vapor Pressure 48 mmHg
Vapor Density 1.5
Specific Gravity 0.785 - 0.792
Solubility Soluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature 362.8 °C / 685 °F
Decomposition Temperature No information available
Viscosity No information available
VOC Content(%) 100
Conditions to Avoid Incompatible products. Excess heat. Keep away from open flames, hot surfaces and
sources of ignition.
Incompatible Materials Strong oxidizing agents, Acids, Acid anhydrides, Acid chlorides, Peroxides, Alkali metals
Ethyl acetate 10,200 mg/kg ( Rat ) > 20 mL/kg ( Rabbit ) 58 mg/l (rat; 8 h)
> 18000 mg/kg ( Rabbit )
Solvent naphtha (petroleum), light Not listed LD50 = 3000 mg/kg ( Rabbit ) Not listed
aliphatic
Toxicologically Synergistic No information available
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Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
STOT - single exposure Central nervous system (CNS) Optic nerve Respiratory system
STOT - repeated exposure None known
Other Adverse Effects The toxicological properties have not been fully investigated.
Ecotoxicity
12. Ecological
Contains a substance which is:. Toxic to aquatic organisms. information
The product contains following substances which are hazardous for the
environment.
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Ethyl acetate EC50 = 3300 mg/L/48h Fathead minnow: LC50: 230 EC50 = 1180 mg/L 5 min EC50 = 717 mg/L/48h
mg/l/ 96h EC50 = 1500 mg/L 15 min
Gold orfe: LC50: 270 EC50 = 5870 mg/L 15 min
mg/L/48h EC50 = 7400 mg/L 2 h
Solvent naphtha EC50: = 4700 mg/L, 72h Not listed Not listed Not listed
(petroleum), light aliphatic (Pseudokirchneriella
subcapitata)
Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
13. waste.
hazardous Disposal considerations
Chemical waste generators must also consult local, regional, and national
hazardous waste regulations to ensure complete and accurate classification.
DOT
UN-No 14. Transport
UN1170 information
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group II
TDG
UN-No UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group II
IATA
UN-No UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group II
IMDG/IMO
UN-No UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
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Packing Group II
Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed
International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea (KECL).
Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Ethyl alcohol 64-17-5 X - 200-578-6 X X X X X KE-13217
Methyl alcohol 67-56-1 X - 200-659-6 X X X X X KE-23193
Methylisobutyl ketone 108-10-1 X - 203-550-1 X X X X X KE-24725
Ethyl acetate 141-78-6 X - 205-500-4 X X X X X KE-00047
Solvent naphtha (petroleum), light 64742-89-8 X - 265-192-2 X - X X KE-31661
aliphatic
SARA 313
Component CAS No Weight % SARA 313 - Threshold
Values %
Methyl alcohol 67-56-1 3-5 1.0
Methylisobutyl ketone 108-10-1 1-3 0.1
CERCLA
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California Proposition 65 Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is
ingested as an alcoholic beverage. This product contains the following Proposition 65 chemicals.
Component REACH (1907/2006) - Annex XIV - REACH (1907/2006) - Annex XVII - REACH Regulation (EC
Substances Subject to Restrictions on Certain 1907/2006) article 59 - Candidate
Authorization Dangerous Substances List of Substances of Very High
Concern (SVHC)
Methyl alcohol - Use restricted. See item 69. -
(see link for restriction details)
Methylisobutyl ketone - Use restricted. See item 75. -
(see link for restriction details)
Ethyl acetate - Use restricted. See item 75. -
(see link for restriction details)
Solvent naphtha (petroleum), - Use restricted. See item 28. (see -
light aliphatic link for restriction details) Use
restricted. See item 29. (see link
for restriction details) Use
restricted. See item 75. (see link
for restriction details)
https://echa.europa.eu/substances-restricted-under-reach
Safety, health and environmental regulations/legislation specific for the substance or mixture
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Methylisobutyl ketone 108-10-1 Listed Not applicable Not applicable Not applicable
Ethyl acetate 141-78-6 Listed Not applicable Not applicable Not applicable
Solvent naphtha (petroleum), 64742-89-8 Listed Not applicable Not applicable Not applicable
light aliphatic
Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
Ethyl alcohol 64-17-5 Not applicable Not applicable Not applicable Annex I - Y42
Methyl alcohol 67-56-1 500 tonne 5000 tonne Not applicable Not applicable
Methylisobutyl ketone 108-10-1 Not applicable Not applicable Not applicable Annex I - Y42
Ethyl acetate 141-78-6 Not applicable Not applicable Not applicable Annex I - Y42
Solvent naphtha (petroleum), 64742-89-8 Not applicable Not applicable Not applicable Not applicable
light aliphatic
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
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