K.V. No. 1 Kankarbagh, Patna (S.

S)

Autumn Break Home Work

Session: 2023-24
Class -12th ‘B’ Subject: Chemistry

SECTION A

1. Write the chemical equations for the following name reactions:

i. Sandmayer’s reaction

ii. Wurtz- Fitting reaction

iii. Gatterman’s reaction

iv. Kolbe’s reaction

v. Raimer-Tiemann reaction

vi. Williamson synthesis

vii. Rosenmund reduction

viii. Stephen reaction

ix. Etard reaction

x. Gatterman-Koch reaction

xi. Friedel Craft’s acylation

xii. Clemmensen reduction

xiii. Wolff- Kishner reduction

xiv. Aldol condensation

xv. Cross aldol condensation

xvi. Cannizzaro reaction

xvii. Hell –Volhard- Zelinsky reaction

xviii. Gabriel Phthalimide synthesis

xix. Hoffmann bromamide reaction

xx . Carbylamine reaction

SECTION B

2. Give reasons for the following:

i. Haloalkanes easily dissolve in organic solvents.

ii. Halogen compounds used in industry as solvents are alkyl chlorides rather than bromides and
iodides.

iii. Ethyl iodide undergoes SN2 reaction faster than ethyl bromide.

iv. Alcohols are more soluble in water than the hydrocarbons of comparable molecular masses.

v. O-nitrophenol is more acidic than O-methoxyphenol.

vi. Ethanoic acid is a weaker acid than benzoic acid.

vii. Aldehydes are more reactive than ketones towards nucleophiles.

viii. The boiling points of aldehydes and ketones are lower than those of the corresponding
acids.

ix. The aldehydes and ketones undergo a number of addition reactions.

x. Aniline gets coloured on standing in air for a long time.

SECTION C

3. Give one chemical test to distinguish between the following pairs of compounds:

i. Methylamine and dimethylamine.

ii. Secondary and tertiary amines.

iii. Aniline and Benzylamine.

iv. Benzoic acid and Ethyl benzoate.

v. Ethanal and propanal.

vi. Phenol and benzyl alcohol.

vii. Butan-2-ol and 2-Methylpropan-2-ol

viii. Benzaldehyde and acetophenone.

Rashmi Bala

PGT (Chemistry)

K.V. No.1 (S.S), Patna