Uji XRD XRF Pasir Silika (Geoservice)

PT.
GEOSERVICES MINERALOGY LABORATORY

Jl Industri Selatan 2, Blok MM1, Jababeka 2, Cikarang Bekasi 17520, Indonesia
Technical Report
MLG.00058
"XRD & XRF Testwork on behalf of PT. Djabesmen"

Prepared for: Mrs. Josephine
External copy to: Mrs. Josephine
Company: PT. Djabesmen
Company Address: Jl. Lemah Abang KM.59
Cikarang Bekasi 17530
Project: Silica Sand
Mineralogist: Istiqomah
Author: Anita
Laboratory Job Number: MLG.00058
Client Submission Number: MLG_DJ_20180920
Receipt Date: October 01, 2018
Report Issue Date: October 15, 2018
Wayne Turner
Head of Mineral Division
Report No: MLG.00058 PT. Djabesmen Page | 1

PT. GEOSERVICES MINERALOGY LABORATORY
SUMMARY
XRD Bulk tabled in Paragraph 4.1 are summarized in bar graphs below for mineral identification and mineral
phase contribution.
MINERAL PHASE RIETVELD (WT%)

100.0
90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0
0.0
After BM 1 After BM 2 After BM 3 Pasir Belitung Pasir Belitung Pasir Belitung
Before BM 1 Before BM 2 Before BM 3
Quartz Cristobalite Ferrihydrite Gibbsite
Figure 1 – Summary Bar Graph of Mineral Identification
The minerals identified were classified by general mineral grouping and Reitveld% contribution summed and
tabled below:
Table 1 – Mineral General Grouping – Sum of Reitveld %

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DISCLAIMER
This report has been prepared for the Client by PT. Geoservices – Mineralogy Laboratory. Other parties, at
the discretion of the Client may be given access to the report or receive copies of the report, but only in full
including this page, the title page and appendices.
PT. Geoservices Ltd has performed the Mineralogy Services reported herein based on the
information provided by the Client to PT. Geoservices Ltd and PT. Geoservices Ltd understanding of the
Client’s requirements.
PT. Geoservices Ltd is not responsible for any loss or damage arising out of any inaccurate, incomplete or
misleading information that the Client gives to PT. Geoservices Ltd or any misunderstanding of the Client’s
requirements by PT. Geoservices Ltd.
PT. Geoservices Ltd is not responsible for any loss or damage arising out of the performance or non-
performance in connection with the Mineralogy Services by any third party that PT. Geoservices Ltd engages
to assist it in performing the Mineralogy Services.
PT. Geoservices Ltd has performed the Mineralogy Services and prepared this Report based only upon the
sample material that the Client provided to PT. Geoservices Ltd.
The results presented in this report pertain only to the samples as received.

TABLE OF CONTENTS
SUMMARY ............................................................................................................................................... 2
DISCLAIMER ............................................................................................................................................. 3
TABLE OF CONTENTS ................................................................................................................................ 4
LIST OF FIGURES ...............................................................................................................................................5
LIST OF TABLES .................................................................................................................................................6
1.0 INTRODUCTION ............................................................................................................................ 7
2.0 SAMPLE INFORMATION................................................................................................................. 8
3.0 TEST METHODOLOGY .................................................................................................................... 9
3.1 TESTWORK FLOWCHART .............................................................................................................................9
3.2 TESTWORK METHOD SUMMARY ..................................................................................................................9
3.2.1 Sample Preparation for XRD testing .............................................................................................9
3.2.3 XRD Equipment Settings ...............................................................................................................9
3.2.4 XRF Fusion Analysis for Silica Sand ............................................................................................ 10
4.0 TESTWORK RESULTS.................................................................................................................... 11
4.1 XRD BULK SCAN MINERAL IDENTIFICATION ................................................................................................ 11
4.2 XRF FUSION – SILICA SAND RESULTS ......................................................................................................... 12
APPENDICES .......................................................................................................................................... 13
APPENDIX – XRD BULK DIFFRACTOGRAMS ............................................................................................................ 14

LIST OF FIGURES
Figure 1 – Summary Bar Graph of Mineral Identification ....................................................................................2

Figure 2 – Sample “As Received” Photos..............................................................................................................8
Figure 3 – Testwork Flowchart .............................................................................................................................9
Figure 4 – XRD Bulk Diffractogram – After BM 1 ............................................................................................... 14
Figure 5 - XRD Bulk Diffractogram – After BM 2................................................................................................ 14
Figure 6 – XRD Bulk Diffractogram – After BM 3 ............................................................................................... 15
Figure 7 – XRD Bulk Diffractogram – Pasir Belitung Before BM 1 ..................................................................... 15
Figure 8 - XRD Bulk Diffractogram - Pasir Belitung Before BM 2 ....................................................................... 16
Figure 9 – XRD Bulk Diffractogram – Pasir Belitung Before BM 3 ..................................................................... 16
Figure 10 – XRD Bulk Diffractogram – After BM 1 REP...................................................................................... 17

LIST OF TABLES
Table 1 – Mineral General Grouping – Sum of Reitveld % ...................................................................................2

Table 2 – Sample Identification ............................................................................................................................8
Table 3 – XRD Operating Conditions – Bulk Scan .............................................................................................. 10
Table 4 – XRD Bulk Scan Mineral Identification ................................................................................................ 11

1.0 INTRODUCTION
The objective of this testing program was to provide data from XRD for Bulk Mineral Identification.
Six samples were received at Cikarang Mineralogy Laboratory on October 01, 2018.
Testing for the program is presented in flow diagrams in 3.1 Testwork Flowchart and included as follows:
Sample Preparation
XRD Bulk mineralogy
XRF Fusion – Silica Sand
Testing was concluded by 15/10/2018, after which this report was prepared.
This report summarizes key results from the test program, using data summaries and graphical
displays.
XRD Scan plots can be found in the Appendices as follows:
Appendix : XRD Bulk Diffractograms

2.0 SAMPLE INFORMATION

A total of 6 samples were submitted for XRF and XRD Bulk analysis with sample identification as per
following table:
Table 2 – Sample Identification
No Sample Identification Weight (g)

1 After BM 1 565.7
2 After BM 2 537.0
3 After BM 3 604.3
4 Pasir Belitung Before BM 1 1446.4
Figure 2 – Sample “As Received” Photos

3.0 TEST METHODOLOGY
3.1 Testwork Flowchart
Sample received from Client were prepared and analyzed as per flowchart below:
Figure 3 – Testwork Flowchart
3.2 Testwork Method Summary
3.2.1 Sample Preparation for XRD testing
MLG_PREP_XRD – The dried sample is ground in a tungsten carbide bowl/mortar bar to achieve fineness of
P100<53 microns.
3.2.3 XRD Equipment Settings
XRD - The XRD technique is non-destructive and involves placing a powdered sample in a holder, then
illuminate with x-rays of a fixed wave-length. X-ray diffraction relies on the dual wave/particle nature of X-
rays to obtain information about the structure of crystalline materials.

Phase ID/Qualitative Analysis is performed using Diffrac EVA software with the ICDD PDF-4 database.
Quantitative Phase Analysis (QPA) is performed using Diffrac TOPAS software based on Rietveld
refinement, a technique devised by Hugo Rietveld for use in the characterization of crystalline materials.
The x-ray diffraction of powder samples results in a pattern characterized by reflections (peaks in intensity)
at certain positions. The height, width and position of these reflections can be used to determine many
aspects of the material's structure. The Rietveld method uses a least squares approach to refine a theoretical
line profile until it matches the measured profile. The introduction of this technique was a significant step
forward in the diffraction analysis of powder samples as it is able to deal reliably with strongly overlapping
reflections. The Rietveld Refinement does not take into account any amorphous or poorly crystalline phases
that may be present and do not contribute to diffraction peaks
The XRD equipment is operated under for following conditions for standard bulk scans.
Table 3 – XRD Operating Conditions – Bulk Scan
XRD OPERATING CONDITIONS - BULK SCAN

Info XRD Equipment Bruker XRD D8 Advance Davinci Drives Thets- Drive Number 1
Software TOPAS Diffrac Suite, ICDD PDF4 Theta - Encoder used No
Xray Tube Cobalt Theta - Position 0.5000(°)
Generator Voltage 30 Kv Theta - Oscillation No
Generator Current 50 mA 2Theta- Drive Number 2
Measurement Time 1:27:18 (h:mm:ss) 2Theta - Encoder used No
Ranges Scan Mode Continuous Scan 2Theta - Position 1.0000(°)
Start Position 1 2Theta - Oscillation No
Stop Position 100 Phi- Drive Number 3
Increment 0.0194603 Phi - Encoder used No
# Steps 5088 Phi - Position 0.0(°)
Time per Step 1 (s) Phi - Oscillation no
Motorized Slit Changer INSTALLED LYNXEYE Electronic Window 2.95 (deg)
Synchronous Rotation INSTALLED
Spinner Rotation 10 (rpm) 10(rpm)
3.2.4 XRF Fusion Analysis for Silica Sand
XRFFSI - A calcined or ignited sample is added to Lithium Borate Flux, mixed well and fused between 1050 -
1100°C. A flat molten glass disc is prepared from the resulting melt. The fused-glass disk specimen is
irradiated by a high-energy X-ray beam. Concentrations of the elements are determined by relating the
measured radiation of unknown specimens to analytical curves prepared from reference materials of known
composition.
Silica Sand - XRF 14 Element Suite - Al2O3, BaO, CaO, Cr2O3, Fe2O3, K2O, MgO, MnO, Na2O, P2O5, SiO2,
SO3, SrO, TiO2 + LOI

4.0 TESTWORK RESULTS
4.1 XRD Bulk Scan Mineral Identification
XRD Bulk scan mineral identification on received samples tabled below.
Table 4 – XRD Bulk Scan Mineral Identification
RIETVELD REFINEMENT WT%

Mineral Mineral Mineral Chemical Mineral Pasir Belitung Pasir Belitung Pasir Belitung
After BM 1 After BM 2 After BM 3
Classification Group Formula Identification Before BM 1 Before BM 2 Before BM 3
Silicates Quartz Si O2 Quartz 97.5 97.1 97.6 99.1 98.8 98.9
Silicates Quartz Si O2 Cristobalite 0.3 0.3 0.3 0.3 0.3 0.3
Oxides/Hydroxides No Group 5 Fe2 O3. 9 H2 O Ferrihydrite 1.7 1.9 1.4 0.4 0.6 0.7
Oxides/Hydroxides No Group Al (O H)3 Gibbsite 0.5 0.7 0.7 0.2 0.2 0.2
Total 100.0 100.0 100.0 100.0 100.0 100.0

4.2 XRF Fusion – Silica Sand Results
Major analytes determined by XRF fusion tabled below:
Table 6 - XRF Silica Sand Major Analytes

APPENDICES

Appendix – XRD Bulk Diffractograms
Figure 4 – XRD Bulk Diffractogram – After BM 1
Figure 5 - XRD Bulk Diffractogram – After BM 2

Figure 6 – XRD Bulk Diffractogram – After BM 3
Figure 7 – XRD Bulk Diffractogram – Pasir Belitung Before BM 1

Figure 8 - XRD Bulk Diffractogram - Pasir Belitung Before BM 2
Figure 9 – XRD Bulk Diffractogram – Pasir Belitung Before BM 3

Figure 10 – XRD Bulk Diffractogram – After BM 1 REP


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PT.

GEOSERVICES MINERALOGY LABORATORY

"XRD & XRF Testwork on behalf of PT. Djabesmen"

Report No: MLG.00058 PT. Djabesmen Page | 1

MINERAL PHASE RIETVELD (WT%)

Quartz Cristobalite Ferrihydrite Gibbsite

Figure 1 – Summary Bar Graph of Mineral Identification

Report No: MLG.00058 PT. Djabesmen Page | 2

Report No: MLG.00058 PT. Djabesmen Page | 3

Report No: MLG.00058 PT. Djabesmen Page | 4

Figure 1 – Summary Bar Graph of Mineral Identification ....................................................................................2

Report No: MLG.00058 PT. Djabesmen Page | 5

Table 1 – Mineral General Grouping – Sum of Reitveld % ...................................................................................2

Report No: MLG.00058 PT. Djabesmen Page | 6

XRD Scan plots can be found in the Appendices as follows:

Appendix : XRD Bulk Diffractograms

Report No: MLG.00058 PT. Djabesmen Page | 7

2.0 SAMPLE INFORMATION

Table 2 – Sample Identification

No Sample Identification Weight (g)

Figure 2 – Sample “As Received” Photos

Report No: MLG.00058 PT. Djabesmen Page | 8

3.0 TEST METHODOLOGY

3.1 Testwork Flowchart

Figure 3 – Testwork Flowchart

3.2 Testwork Method Summary

3.2.1 Sample Preparation for XRD testing

3.2.3 XRD Equipment Settings

Report No: MLG.00058 PT. Djabesmen Page | 9

Table 3 – XRD Operating Conditions – Bulk Scan

XRD OPERATING CONDITIONS - BULK SCAN

3.2.4 XRF Fusion Analysis for Silica Sand

Report No: MLG.00058 PT. Djabesmen Page | 10

4.0 TESTWORK RESULTS

4.1 XRD Bulk Scan Mineral Identification

XRD Bulk scan mineral identification on received samples tabled below.

Table 4 – XRD Bulk Scan Mineral Identification

RIETVELD REFINEMENT WT%

Report No: MLG.00058 PT. Djabesmen Page | 11

4.2 XRF Fusion – Silica Sand Results

Major analytes determined by XRF fusion tabled below:

Table 6 - XRF Silica Sand Major Analytes

Report No: MLG.00058 PT. Djabesmen Page | 12

Report No: MLG.00058 PT. Djabesmen Page | 13

Appendix – XRD Bulk Diffractograms

Figure 4 – XRD Bulk Diffractogram – After BM 1

Figure 5 - XRD Bulk Diffractogram – After BM 2

Report No: MLG.00058 PT. Djabesmen Page | 14

Figure 6 – XRD Bulk Diffractogram – After BM 3

Figure 7 – XRD Bulk Diffractogram – Pasir Belitung Before BM 1

Report No: MLG.00058 PT. Djabesmen Page | 15

Figure 8 - XRD Bulk Diffractogram - Pasir Belitung Before BM 2

Figure 9 – XRD Bulk Diffractogram – Pasir Belitung Before BM 3

Report No: MLG.00058 PT. Djabesmen Page | 16

Figure 10 – XRD Bulk Diffractogram – After BM 1 REP

Report No: MLG.00058 PT. Djabesmen Page | 17

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