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where: fnear form: fnear form: C. Temkin Adsorption Equation of an ot tho ecu use of SLU. mectarical, photocopy y- weigh! or volume of gas adsorbed per unit area or unit mass of adsorbent P - equilibrium pressure K.n - empirical constants dependent on the nature of solid and gas and on the temperature Iny =Ink+ \ny sloyem = 4 yin = Ime Al yma WP B. Langmulr Adsorption Equation > A much belter equation for Type | isotherm was d leduced by Irving Langmuir from theorefical considerations. Langmriur posiviated tha! gases are being absorbed by a sold surface cannot form a layer more than a single molecule in depth. Further, he visualized the adsorption process as consisting of two opposing actions, condensation of molecules from the gas phase onto the surface and on evaporation of molecules from the surface back into the body of the gos. Isodmevn wee, ot a Standard Fort: t am: adsorbate -¥ ’ and b- Langmuir constants is isotherm contains a factor that expicilly taking into the cccount of Pr ‘oring the extremely low and large value t-adsorbate interactions. By ian es that heal of adsorption (function of ‘concentrations, the model assumes i ecules in the layer would decrease Ineary rather than temperature) of all mo! logarithmic with coverage. y=kinPn y= kin +kinn k and n-Temkin constants reer noah a overs sorb, os Ragen, er ra se ae oP HTS ol SLU, 1s by rcs ing enn, ortransmning aay Frm oY gp QQ 8. Langmuir — Msorpyinn Fan +e 5) 90: Langmue cotatts ath mae te BI z @ 5 Sa Se fh tpiag gs if 0 mma, x Mads om? oe i x if 2.quy (19) | 4 4-ayy CBD) Wee ye x sane Z | Ta Cacu- Fong a a ata e gs oe gS Thus, Langmuir Comstams are v w Pea Be OF tp mz 1h i ye ge70gl od os gH 21-4019. 989) YMA 01579 04958 cee § 49 GN TI C-_Temvin —_Adsowpiom Equation! Sendra Form: yy = kn Pn jimear bor: oy Elis + lnm. eee Kin = Temncin Constants. | | t TEETH THKLH LEKLKE LET ELT TTLTTEVWWWAVAAVE lerrer 4 FoWW Up probiem: a) Wing the data OF propte _v) SmnmnaTl te Natyes From. atl _c\ Whidh OF Me othetms woud oder PEL PEL uy ies x nb = ys Wao tage i * 36 [¥ 9.44 In 43 " los [2-4uy inte veal ST asa fa In 704 > 3g mde) in 40 E> M3 523 [2.400 In 942. = yet x (alia Formula [. Stina 2 24. 5uG53079 sto 0474548 Saou alee 4 % 00055 n= 60% v c Sutmary Sait m Freudiion kK «0 044d \ Isotherm he |. 23qu re 0-949 3090993 Lang mute 4a 0.030) ‘ : Ta he 4 Pog x10 pooh. ce 8 49h 4A te ~somy KU OOSS Ss - i FT Wen, Wee OWA ks a ee 2 ; (70.4949 498204 models tne adeorphon dato ANSP TON mopeL FOR BEF Isosherm ¢ Brunduer, Emmett, Tele) J 1 For Types gd at ttherm Ceormaaw of many. moleuular ‘Taye HMA HTTHTTAKATUTUTAAAAVANG f le a Cie VGr-# Ve Wing) Pe ti ii 5

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