where:
fnear form:
fnear form:
C. Temkin Adsorption Equation
of an ot tho ecu use of SLU.
mectarical, photocopy
y- weigh! or volume of gas adsorbed per unit area or unit mass of adsorbent
P - equilibrium pressure
K.n - empirical constants dependent on the nature of solid and gas and on the
temperature
Iny =Ink+ \ny sloyem = 4
yin = Ime Al
yma
WP
B. Langmulr Adsorption Equation
> A much belter equation for Type | isotherm was d
leduced by Irving Langmuir from
theorefical considerations. Langmriur posiviated tha! gases are being absorbed by
a sold surface cannot form a layer more than a single molecule in depth. Further,
he visualized the adsorption process as consisting of two opposing actions,
condensation of molecules from the gas phase onto the surface and on
evaporation of molecules from the surface back into the body of the gos.
Isodmevn
wee,
ot a
Standard Fort:
t
am: adsorbate -¥ ’
and b- Langmuir constants
is isotherm contains a factor that expicilly taking into the cccount of
Pr ‘oring the extremely low and large value
t-adsorbate interactions. By ian
es that heal of adsorption (function of
‘concentrations, the model assumes
i ecules in the layer would decrease Ineary rather than
temperature) of all mo!
logarithmic with coverage.
y=kinPn
y= kin +kinn
k and n-Temkin constants
reer noah a overs sorb, os
Ragen, er ra se ae oP HTS
ol SLU, 1s by rcs
ing enn, ortransmning aay Frm oY gpQQ
8. Langmuir — Msorpyinn Fan +e
5) 90: Langmue cotatts ath mae te
BI z @ 5
Sa Se fh tpiag gs
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2.quy (19) | 4
4-ayy CBD) Wee
ye x sane Z
| Ta
Cacu- Fong a a ata e
gs oe gS Thus, Langmuir Comstams are
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C-_Temvin —_Adsowpiom Equation!
Sendra Form: yy = kn Pn
jimear bor: oy Elis + lnm.
eee
Kin = Temncin Constants.
|
|
t
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