-

Ealr , summary
a) k = A e

b) lmk =
In A -
Ea_
RT

e)
log k
log A
Ead
-
=

303 RT
'

E÷ ( ÷
d) ln be =
-

,
ki

P block C̲ i ̲r ̲c̲l ̲e̲

lm R2
¥ ( ÷ ttz )
-

j
=
,

Ti =
303 K Tz = 313 K

(%
lm 3. 55
±,
Eat
= -

.
" "

Ea-
(3%3-3%3)
'
268 =

8. 314

Ea = P block C̲ i ̲r ̲c̲l ̲e̲

 "
" state

A.
a

E- a
E F
p

&
↓ D H

[
F R
Enthalpy
DH
-

Ren
Endothermic
Exothermic Ren

P block C̲ i ̲r ̲c̲l ̲e̲

 Reversible Reaction

t
^
R # P

Ea, , , Ea, , >

tag ,

I
^

↓ DH -

Que . An exothermic Reaction ✗ → Y has an

'
activation moi
energy
30k ] .

If DH

during
the Rscn is -20k]
,
Then Ea
for
Reverse Ren P
is block
_
.
( mains 2021
C̲) i ̲r ̲c̲l ̲e̲
 E- a
,b = Ea
,f
+ / DH )

= 30 + 20

=
50 K] molt

Out -
For the
Equilibrium A FB , If DH = -40

'
K ] moi .

Then
If Ratio
of Eaf_ =
2-3
.

Eab

P block
↳
Ef=Z C̲ i ̲r ̲c̲l ̲e̲
?⃝
 a) Ea , Eaib
2
60 100
f
= =

b) Ea ,f = 30 Ea ,b =
70
M¥f
East =
80 Ea , b =
120

d) Ea ,b 30
Earf = 70 =

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 ¥
o -
045 = R( 0 -05 )k( 0.05 ) Y ①

(0^05) 't
^
0.090 = K (0-10) ②

0.72 = R ( O -20 )k (0-10) Y ③

P block C̲ i ̲r ̲c̲l ̲e̲

2 ÷ I

1z:
0 090

( °s )
"
.

Tous

2 = 2
✗ =

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 ME

0.8 % 0 .
y

tyz = 15 mins

0 .
I → 0 .
0 5 → 0 .
025

15min 15min

I 30 mins

P block C̲ i ̲r ̲c̲l ̲e̲

 '
rate = RCA ] = R( 0.01 )

€^PP°ᵈÉp=
0.034
k= =

2.3¥ log 0.025

0.691
2.301 4 20min
log
=

=
40

I 0.05 ᵗ 0.25

2.33g2
= 0 -

P block # ◦ min
C̲ i ̲r ̲c̲l ̲e̲
 A - P B - P

54min 18 mins
tyz tyz
= =

Ao = N Bo = R

At = 16 Bt

( Bg )
AI 16
=
, ①
gn

P block C̲ i ̲r ̲c̲l ̲e̲

 '
and tiles
of half
n n are no .

?
n=t_ =
totait.me#
t '
/a
half life

(
' •
=

In

2¥
1- =

In

'

2h = 162
n

P block C̲ i ̲r ̲c̲l ̲e̲

 ' "
2h = 24 2

'
n = 4 t n

I =
4 + ±

C- 42 ) the
'

tip ¥
4 +
=

1-
?
i◦8m①
=

P block C̲ i ̲r ̲c̲l ̲e̲

 2¥
☒ ,

2
r = R [ A) [ Bz ] ← Rate law

'
[
≥
r =
R [ 3A ] 3 Bz ]

= 27 times
=

P block C̲ i ̲r ̲c̲l ̲e̲

 [ A] and time

ero order =

At = Ao -
Rt
Kt
First order 8 At = A- ◦ e-
-
ln At =
ln Ao -

Rt
]
CA
In [ ]
•

A [ A ] k
slope
-
=

pv
A
time time

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
P block C̲ i ̲r ̲c̲l ̲e̲
 logk log É%3RT
= A-

slope =/ É÷zo3R
-4-10,000

500 k k 10-5 101000

2%-03,2
At ,
=
> =
&
T ? k= to
,

P block C̲ i ̲r ̲c̲l ̲e̲

 log # E÷◦sr( ÷ %)
-

log
II
(% ¥)
' ◦ ' ◦ ◦ ◦ -

=
-

s
,◦

Tz = 526 K
__

P block C̲ i ̲r ̲c̲l ̲e̲

Ahs = 32 times

25tim⊖

P block C̲ i ̲r ̲c̲l ̲e̲

 &
- Ea
/ Re
e- =
e

8◦•9✗
EAR
R =
=

T
8.31 ✗ 700

=
13.9
=

P block C̲ i ̲r ̲c̲l ̲e̲