Alcohol and Phenol

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Alcohols F PHenols of Aleahols re ¢ niphabic lebots aaa ssipical woroydve faye nck Bhat Glycerol) fina 3 hot ices Terese atcond tend y IMMEDI CHES orcs MERAY are deriuatver 4 “OWA, econ So 5 ANGIE ond Etiayie hove Same general forrila” 9 (MBO) GAleokal and Chers are c as sty oH LA PH Or Ar oe x , ‘Tob alisha = MOKPTE alcakls contain anes on grup Per ae Polghydsie. alcohols ‘con: oi, Aeon OH groups {ea aha wth conten "Mc in Tg are ng abil BLO grOGp oH prcient but cattonct et te Uipdeababal thet ape a + ae ee #/alcahal ehith confoine tite OH groups on | nt corbons IMohe 6 che euy-the | C—O ey Gptanncdy-d wa Na du dy du I fgealer oe) Shire Po whit Hh oritalns SOM bo tar goorretny fo tab valor Ovs.o* © or” cent M095 Alcohol malecule hi and Tt hat bond angle ®rwase O wre Grmnswer —> 10S: 0" ss Because geornehyy of land anfe of lols? saiey it bend shape wT Aeepation. af atcohots yalamam ce oreo A buoy Dr cy aay + k0y Hydirolysit/ Mbeleaphite aul tetion reaction of Allgh halide > preserce of aqekatty cig eh «(Bayo —> oH + Ker > Reduction / Addrton of hydqgen > aldlehycks OF Retort oF of ee Shieh of the following method nol used to produce alcohels- 8 hydration of alkenes by hydrolyse of ally! boltdes 84 the melon fedex fateh det are Keloes polit of akan Ba cre ho pee? By ockd-4 arauses 36) Becawe RCN hy! acid Physical josmer! and taste es of Alcohols: rene org tat cove gps while aE. RP om & e a utlirg wd bofting Rains of altahols ave ‘hegher ten Cotiepanin akaas because Irexeove of cartoon, mee Land hile dust peas aleonelt shength of iydaygen bonaiy deeseases: Reactivity of Alcohols when (CO) Bard Breaks woniginatcs Spiga teh ary, giny polarized! 0 bond They are becaute {gang bond dont break -BHibond brealy and releotes @D They a Bhrongly basic 8 why in tert breaks whtle oH bond byeakc? Gece are MERIGIOP' ore Weakly etechar ae eee donate elechent to the which axe Atfrauted by the aikygen-atom frus Joe ard of hystiegen sail (Hs —C 0 Reactivity order of (=O) bond breaking alcohol o- *bend ‘dan Electrophitte:: (0-H) Brealey 1 FB ch trsflavouring due to thefy eo ame cetate os Gates abies fey 07 taste cry-O Nae te Ls rci-cn-on roma —> 2¢Hs-c- dedumbeneride tees wee pe eugaeices Fea > OM Mas CHyCOOH + cpt HOH cagcooqus +20 rr i! rtaly st Se Agee ree Seer, NE) i forwsing will at as 0 cotaly. char beow De caycne youn oy | i abete Fe oes t I" * astium dichroma! ge ota ® unos Oncidgred pet aa Sng Rd | @nssry — @ So se e artes tone i €—0H bond Sean tho > De nygtrating agent / onoaTion aoe |oondation of Primary alcohol, f : | . ks theor —etecgcott C8, ay, Cage on ae) +o MS rg L Hh ee ate a S04 dehyde oy ' Sag ssortdatton_of Setorelary alcohe| > Reactive to ClBCHOpHE so elertrophitit. Yeoottons ic Staleity oF Metmoxide tory ety FB Ray-5 PP RycH-0 Deco"! Because teoitary aleahels are Mave! baste track-ow) will breale and thethoxtde fon wil_rot be formed Hatin i GigE See sn eaten, js oxidation doesnt occur: by tevttiny aleohal ony detydeaton e€cors, because they don't bave any at Wypdragen and alkene: Produced fa HH ay EEO Coe oe td ge PH] 5804 i dtu Alcoha lg Pence fon) breaks trctg—cyeon rcp BOO cae cH,-+ Bo! ae cep + tgif a Ss ial du eth 04 tA —s Hyp cF BP + POO2, ve chy-eyon py BOB cc -nng +W? | Mags Ketors ave prepared by ine oxidation of | @_Lrimay aeorols © Secondary atohols © Peavy’ aleshote™* Onova of these Ancuses (Ale) Dtecondory alcorals Dehydration of alcchel In pretence of Con-thioy and at I7o-l90% delydrotion wil octoy and alkene ti pradved canson Leotthien aor hay +0 In presente ef Con.HiS0y ard a? 0% and th presente of excess alcchel . ether Pro kuced ae Bons ASE Gro -ty Hho a exes Wucag Teer wa tha fey te vied 40 differenciate between Prtmarystetondory ard textaly, alcchels Been news ee 2 Royo ity layer Cnmed tel) aly tayer(emtastes) ofty yer (2630 minted) (on best) Tororo Se Alcohols wht have me nyl poup abached 4° the carton sofil give ‘afer the HEA uted fo dittingotth | betseen Wlethanol and Ethane! bet Secondary alehols atio give tots tert Uhahol —> ives veactton © mteriaro =F no easkion eal enig ou +45, FON 20% NALS Sito Tig a acorn wE ond (reco Jur ci eoecty +H + Galo ——> Hs * ob Sho +SNot 4 ied Censcoona) 4 Uh Uia~Hy-og +, + baao —3 no vector & Uy-oW FMT, + baat 9 Me Feacton Je —} mos which of the falls hetseen methanal and etharcl @ Woform test @ twcos test @ eager: ts! O Feng Answer GO Moja fest meas = wht one of Oe falaihy Wan Gpaiprare ‘tation of postive Tdofrm, fits @ Foxmaners of 0) © Orth red pevcipoe © Yeu expels cysels *f (om) @ Retase of gas Mr yee Phenol 7 A alto called Bornercl > Caxbait. acid OTE wat fost obboined from phono! > ethanol >wates ig hep endl 3 Corbaryte.acid > ethana! > water Phovplacetare 1 Phenol 3 corbony! © costoryte acid > phorol Suuater > ethane! ® wotewd ethanol s phenol tarbatyl ack Answey GS Contanytte ac'd > phenel > woles > ether! Reaction due 0 (6-H oe ae ‘6 Weis YAQqueces pherol decoloriter: bromine }_ snare “sConfrimatory test for phendle SU wearHfon |of phenole, wlth, Oromne who form a white poe Py ae Oi OC Shane ety a “Pare octd behores Fee on acrd but if tha Sa ®Phenol © Costonytic acid © trowpant ocid © Aerol Acidity order Bs enh 4 @-phenol + Carbonic Act Phenol Methural Ho. Ehrare} Par é 2 ehyon > MO dCHren-oH at 1% 2,496-Tenitrophenol e ee S wshen phenol #s reduced in the presence Of Zine dest we get sins’ Nc. Soke value of phenol % ® tydoherane © Genrene @ tare © "7x16" © cerey? alechol © tyohowene @© 20x10? @® bax fo? eo Dect : SO eenzene le) B® 3 152 an = O19 ano ei whieh o und wil) have the maxtmun water (Ih) 9 Nepulifon wth Oak Othencnon © cyoctg. Answer ' 4@) onze ett) have miasimem vepulsion wth water betawse waler A poly and benrene OGnsoH Us nonpolar Campartion bekacen alcohal § Phenol nee Aeohol Ms Te ponte soa to hy Th ts Fey colulte th water voter 37/495 chavacteat shies lo hay peter od Phenotte smell SD soled at sdorntenpend| WT A More ab aot of te fusing Pda oblaned by the Yextion 9 th BRE foloed 4 os em hoens sfeigiyes aa fe, ‘ ie a a © which of Phe follesin 6 Wed to _—— oor, pia \) fron sty oD es | cee 4 mote stoble thors QMRitaatnaE on ee 6 —_——- Reacting ct (PRIORY ROR pucr 97+ allehysiey | (ontattorhy ADT EOE RPE oes to prope CRB GHyou + Na —> Gucondl + Hy | CH ON! + Gisy —» Giy~0-Gile + NaBs | Chery ethane % Ceoctng (CRBS ERG ay BB ars US CMAIDY Fs caliod ard vied to prepare (BHGRBIy |. ay WRNAREN 1 vestry = a a au qo sii 5 ob = ella gio u fi lied covets, } pg — — into GORE on fBaae 3 GIDE is converted into (BHBBBP withe "re help fe) GES 28 CER RTEAINSRBER 5 ws ne are broken dawn Info the prestence o

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