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Z AWEHYDE AND KETONES | Neon clateee: (aldehydes) Beir names axé detfved ei acd from comesoo He wn Formaldehyde -» Forenie acid “Noman ctature (Ketones) _ & yl cu; ‘Acetone Dietiyh Ketone ” Ls ketones are least rractve due fo Le Sherhit: hindrance 2 boky groups au Eledran donating emer! of allyf group 26 Alkyl qroyp decxeases polartty %} carbonyl dig ~ tH Gir cise tH aim amc chy dy © Bay3e -TetromeMnyl hexanal ok i H whith of the folowing tr the TEAC mame of above given stouttore ————____ Bitopionardery de “© peetalderyde | @Metranone —— @eetmara ——_ ese Ff | > Methane Sat ected (uae of poral wp) Be : Stn whith Class of orgente carpourds past tyon + Alcehydee 4 forcHtonal. group i nat mentioned while + Carborylic acid lorfing name accarding 40) UPAC . © Acid: Amide @Ateobels © Keloner Acid hatides- Oy roirde OAldehydes "GENERAL Fo@MoLA + aldehyde ba. on ie atasoys at pociton 4 1 4 Bidchydes and Ketones have some geneval fowrnuls tf mumber ap tarbon atom are $0 oe @ rere than tnvee Ca atch Eat G tan te ~ Because ketone tert from 9 BS Tatmeiyyl-a- hepfanore "Womertimn [or woe Aldehydes and_kelones axe t =e liomex*sms af each ather- if move than © aemethyl-2- penlanone ot Sere i fea SPIE IRERE aue |e Peay t crn ee am a 1+ wwhith of the Pllewing is ketone Oty-o-cuty © enCoet-eoot! Ot, co ay-0m, on, Xx / Fer dey ketones having Acetaldehyde t ketone ‘ets Carbon are move seaurve © cy-l cay, Oey neo by Cth co CH ~ CH TWO ign ap he Plowing B hele Wen llor © cy Lnny i Om-ca Shidergses ord ketones hove general formula: Seapeeeewn 20 Aldehyde act as a seducing agent @O Gtino OMtsn0 ny a) Oentinnd GO Catan | adn + co (ous, *wooH —ay ear 5 : ae U Ketones are lets reactive than aldehydes. ber S wbionn «G0 10 ae v ovdned — bytiened Boh alk mint re elecon donate than gi a thot oy atdehydet © Bm igh qooups produte, more stevie hiedioree 5 Both Ag? groups devseaies-polonty oy coxbonyt Pup ap Ketones % pC & NaBHy —» R-ch, OF 1p! ave election wird oe IF een png | Prepsatton ® seegr g Lhy Tk te alvo a identifitation teit for aldenydes s Aldehydes att os oridatron agent Reduction Primary alcohol -» @ch.-oH 1 a stot tah EIEN 4g eH + [ery PSS ss eazOR Ns“: wfebe Mo ten MAS eee (ee A ve” i Porites 4 Rormaldehy de oe A thedent mixed ety? alcohol-o:lth |, A bate catolyzed veaston fh car oorgh Small amount of sodium dichworrate and | ~tempound—tncreates————~ Added it to the hot! solution *h ditute Sulphurte oof 2A wigrout weactron took Place - He distilled the product ‘ormedh @ Aechophie chavacter of, the atlacktng seapentonly @Novesphite ehonacter of the Casbany? carbon only © Etnanoie acid © Ctranot sy oat trmedsately aittled corbaryl te aud wtih fore » l 1 ‘mnmedfately «what 05 The product © Ehehophite thorocter of the elettraphile ® Propanane ©knory ethane Dnoleophiie chosacter 9p, locking seagertt ‘meeuy Additeon of Satem Prauiprite Ss atdelydes and timallmety? ketone! yen with saturated aqueout soluffon of tadtum broulphate to foorn Caystalfne while ppt and sodiom bliuiphare adduct. +> The aeathion f wsed for the purtprcation ard Sparasvon of cavbony? compounds @ Getrophilte addition reactor ts ketones i which ohh alkyl groups © Etectrophiltt. sobehtiton seattion are bnger than mettyl donot give | -S-aoresphitte—acttthior—veactton—————"|]_weaelfan_ ft _bitufphite sf, 1 Arthur leparm beame ine frst fnvestfgate 0. deashion mechortim ‘Re ttaitin to be Tayethigated wat jar of Yeotion of HEA sth propane ne othe! da Ne call the methonitm ef tht: reavkon > hi tubiifHetion Yeadon: 2 ae © Nuueophilie s te, meee 1 ie ss | Hen adds fo carbony? compounds ~The 3 Wren eee fale Showt the relakve wales 2f Yeadon ae ‘ a Avnder different eondittons 4 ong poninax S tartonyfeompourdl when track wtih 7 ig Tiga erences: Godiuey bisuiphve soluttan, anes nerdte-solwttan | °° Vishualy: Zo¥0 Geysbilime dtm bftulphale ada/on Attaltoe colvton Vang soptd product fi formed: which 2{ the flosiny uchth of the following fs Meely to be totyed | at mat form the campers? to sale. delermicing “step @newo @ HO @n Or Ou-00-% © Hee wGtis + -©04-——Ouen—_____ The prodect of the restton betsean propanane and hydrogen Gponide ti hydotyzed undes . oud condtHon whas te te fororala ah wo C-hydoagen’ 1h necetiony for Mockton fhe pha product Ps : oH ches tytn vel Bh ty en @ chew Coudro © CicH re, CoH Aldol 7 Ochemcnenseot (Blew ee) “Canmznne Racrow: Me Went of, Ub _oW Goitey Sxtdaton “vedueaiton” Seaton tuyonml ac sagh Seu cn eee ete ere g 9 an-len 4 soxnash —s Un~o# ee ne a ee acl ecee Hi tH ‘eH aana TTI ay ro Sh ma, Gwhin $000 gs © Yells pnt ot rao Memane when warmed wfin alkaline Solution of, aqueaus fodine © cts ny, © cite fain, © cheemcnoy | © mong ketone ey, = \: “A, ay me footy 1 en, carry Ley ee Th oans ae Na Ne <= 49¢,Hsol#—3_N/ 7 A, 17 Sans ‘Hd taolyced weston tacveases act © Cle phaphie Taracker of cerbongfiton c : mes i =. Lraddttton op alcohol tn canton’ gives & An oid Catolyerd Yeachon in tarbony i feachon in a romety of otetal ti compounds trfeases af ba "4% Bevechophivic character of fhe atnehrng ® Uncoy ©etighedsal Reagent 3 ® Teppral prota! @) plnox O weorspbthe towsoer oe mor citaned resepedy Qetetcepri. caver 44 woksoyf weton saly | @ mecteephile eroracte 24, atbdtng seogert fer eel Both formaldehyde and acetal dely de — % fate in pretence op AiI-H any, p i NE OE, aS eat ——Sirinaton * to ive. % Meta Formaldehyde & Poraldehy de © ao q at Ho, Cf te 3y-4y —— ue 4 was trek forrralcely cle i as Bed — CHL at oy oy way Rhy 2 Sg t che Porotderyde eomrron name tube ey dl lsopsopyl metry? Ketone wl aiphobetical order ‘a Melamertim in Ketones ster! from penlanone | Hyloridteation Hybeidtzation> Mop or band + Lene pats aN A 6 Ue ; a e ie 3s Clechonegahvity = 8-S-1S =4 diperence ea Aldal Condensation } fi |-Nao| u > tly aN oy, dene tow pe Atde/ i % cc cy, dy, We to cre ener t} Carnizarol + Dtuproportionatfon ¥eaction ae 4 S0% Nach ow con-NooW:

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