Sec: XI_IIT_IC & IR Date:21-08-2023

Time: 3 Hrs. CTA – 01 Max.Marks:180

JEE ADV _2018-PAPER-1_MODEL
ANSWER KEY

PHYSICS
1 ABCD 2 ABC 3 ACD 4 BC 5 BD

6 AD 7 360 8 15 9 3 10 2

11 3 12 0.5 13 30 14 4 15 D

16 C 17 B 18 D

CHEMISTRY
19 ACD 20 ABD 21 ABCD 22 ABC 23 AC

24 ACD 25 8.00 26 8.00 27 5.00 28 0.00

29 30.00 30 6.00 31 4.00 32 4.00 33 B

34 C 35 B 36 C

MATHS
37 BC 38 BCD 39 ABC 40 AD 41 BC

42 ABD 43 3 44 6 45 1 46 1

47 8 48 0 49 0 50 1 51 A
52 B 53 B 54 B
 XI_IIT_IC_& IR_CTA-1_23-08-2023
HINTS & SOLUTIONS
1. (ABCD)
v   LT 1  , a   LT 2  , F   MLT 2 
v
 T
a
5m / s 1
 Unit of time = 2
 s
20 m / s 4
F
As F = ma so m 
a
Mg
10 N 1 On solving N B  3N A ; N A 
 Unit of mass = 2
 kg 2
20 m / s 2
Length L = vt 5. (BD)
1  5 Applying NLM on 40 kg block
 Unit of length =  5 m / s   s   m
4  4
F
Pressure = 2
L
10 N 32
 Unit of pressure =  Pa
5 5 2 5
 m
4 4
2. (ABC)
T 3T
At t  and t  , the stone is at same
4 4 400  4T  40a
height.
Hence average velocity in this time interval For 10 kg block T = 10.4 a
is zero. Solving a = 2 m/s2
Change in velocity in same time interval is T = 80 N
same for a particle moving with constant
acceleration. 6. (AD)
Let H be maximum height attained by stone, Friction on the ring = its weight = Mg
T
then distance travelled from t = 0 to t  is Tension in string = mg = Normal force
4 between the pole and ring.
3 T 3T
H and from t  to t  distance f  mg
4 4 4
H But f  N
travelled is .
4
M
T  Mg  mg  m
From t  to t = T see distance travelled is 
2
T 3T 7. (360)
H and from t  to t  distance travelled n 
2 4 n1u1  n2u2  n2   1  u1
H
is .  n2 
4 1 2
 M   L  T 
2

3. (ACD)   1   1   1  u1
1  M 2   L2   T2 
R1  v cos T  g sin T 2 1 2 2
2  1kg   1 m   1 s 
      1
1  10 kg   1 km   1min 
R2  v cos T  g sin T 2
2 1
4. (BC)   106  60  60  360  106
10
For equilibrium N A cos 60  N B cos30  Mg 8. (15)
and N A sin 60  N B sin 30 . Let the separation between A and C become
3d after time t.
 XI_IIT_IC_& IR_CTA-1_23-08-2023
Displacement of C – displacement of A = d 900  300  m  20 
d  m  30 kg
 10t  5t  d  t  …………(1)
5 14. (4)
In the same time t, we have Considering A + B together
Displacement of B – displacement of C = d 20.a  20.g sin37 0.510 g cos37 0.410g cos37
 ut  10t  d  a  6  2  1.6
 ut  10t  5t [using (1)]
 a  2.4 ms 2
 u  15m / s [using (1)]
Considering only A:
9. (3) T  10  g  sin 37  0.5  10 g cos37  10  2.4
 T  60  40  24
10. (2)  T  4N
From A to C, vx  2 m / s
15. (D)
vy  4 m / s The free body diagram of cart is
 l  2x
x 1
tan   
l 2
To move along CB, the boat is steered in a
direction making angle  with CB.
Resultant velocity of boat

v b  4sin      iˆ  4cos      ˆj  2iˆ Hence net horizontal force on cart is zero.
 acceleration of cart is zero.
 4sin       2  iˆ  4cos      ˆj
 16. (C)
vb is along CB The acceleration of each block is equal to
4sin       2 F
.
 tan  
4cos      3m
 tension in required string can be found by
1 4sin       2 applying Newton’s second law to block C.
 
2 4cos      F
T2  ma 
 cos       2sin       1 3
 2sin       cos       1 17. (B)
Normal reaction N R  mg cos   ma sin 
 2sincos cossin coscossinsin 1
sin 2 
 2 1  2 1 N R  mg cos   mg  mg sec 
 2 sin   cos    cos   sin    1 cos 
 5 5  5 5 18. (D)
1 1 a  g tan 
 5sin   5  sin    tan  
5 2 F
 g tan 
11. (3) m  M 
F   m  M  g tan 
12. (0.5)
For A: F1  2 F2  ma 19. (ACD)
4Ag  8KCN  O 2  2H 2 O  4K  Ag  CN  2   4KOH
 20  16  1a  a  4ms 2   
 4  108g of Ag reacts with 8  65g of
For B: ma  F2  a  8ms 2   
KCN
Acceleration of B relative to A is 4ms 2    65
100g of Ag reacts with  100  120
 Required time can be calculated as 4  108
1 2 1 Hence to dissolve 100g of Ag, the amount
x at  0.5   4  t 2
2 2 of KCN required = 120g
 t  0.5 s Hence, statement A is correct
13. (30)  4  108g of Ag require 32g of O2
g eff  g  a  20 m / s 2  100g of Ag require
 F1  F2  mg eff
 XI_IIT_IC_& IR_CTA-1_23-08-2023
32  100 200
=   7.14g   0.4  36.5  0.08  36.5g
4  108 1000
Hence, choice C is correct  0.365g HCl is present in 1.0 mL
Hence, volume of O2 required stock solution.
7.4 0.08  36.5g HCl will be present in
  22.7  5.20  litre
32 0.08  36.5
 8.0 mL
Hence, (A), (C) and (D) are correct. 0.365
20. (ABD) 27. (5.00)
(A) Molarity of second solution is Na 2S4O6 is a salt of H2S4 O6 which has the
10  d  x following structure
 1M
M O O
(B) Volume = 100 + 100 = 200ml | |  0  | | (v)
(D Mass of H 2SO4  200  1  98  19.6gm HO  S  S  S  OH
1000 || ||
21. (ABCD) O O
Factual  Difference in oxidation number of
22. (ABC) two types of sulphur = 5
Orbital Concept and Electronic 28. (0.00)
configuration concept Given, n = 4, m  3, so   3
23. (AC) Possible value of   0,1, 2,3
Mole of H-atoms in glucose As m  3 is possible only for   3
0.9 For   3, m  3, 2, 1,0,1, 2,3
=  12  0.06
180 So, this is 4 f-orbital.
Mole of H-atoms in hydrazine Number of radial nodes
0.48 = n    1  4  3 1  0
=  4  0.06
32 So, there is no radial node in 4f orbital.
Mole of H-atoms in ammonia 29. (30.00)
0.17 Wavelength of photon absorbed,
=  3  0.03
17   330nm  330  10 m 9

Mole of H-atoms in ethane Planck’s constant, h  6.6  1034 Js

0.30 Molar mass of He, M
=  6  0.06
30 = 4g mol 1  4  10 3 kg mol 1
Mole of H-atoms in hydrogen
Avogadro number, N A  6  1023 mol 1
0.03
=  0.03 M
1 Mass of one atom of He, m 
24. (ACD) NA
1 4  103 2
n     1026 kg
n2 6  1023 3
25. (8.00) Velocity, = V cm/s.
Molarity = 3.2 M Using de-Broglie equation,
Let volume of solution = 1000 mL h

= Volume of solvent mv
Mass of solvent = 1000  0.4 = 400 g h 6.6  1034
Since, molarity of solution is 3.2 molar  v 
m 2 / 3  1026  330  109
 n solute  3.2mol 6.6  3  1034  1035
3.2   0.03  10  0.3 m/ s
Molality (m) = 8 2  330
400 / 1000 = 30 cm/s
Hence, correct integer is 8 30. (6.00)
26. (8.00) Count the all possible electrons having
Mass of HCl in 1.0 mL stock solution given set of quantum numbers
29.2 For n = 4, the total number of possible
 1.25   0.365g
100 orbitals are
Mass of HCl required for 200 mL 0.4M HCl
 XI_IIT_IC_& IR_CTA-1_23-08-2023
n 1
 1 
 an  10  
According to question | m  |  1, i.e., there are  2
2
two possible values f m , i.e., +1 and -1 and   an  1  100  2 n 1.
one orbital can contain maximum two
1
electrons one having s   and other 39. (A, B, C)
2  an 2  an  an 1
having s  1 / 2.
 a1  a2  a3  ...  an  an 2  1
So, total number of orbitals having

| m |  1  6 an 10 10
 10 n
 
10   10    89
Total number of electrons having n 1
 
 1 bn  an 1  an 1  12
| m  |  1 and m s     6
 2  10
n 1
n
  
n 1  10n

 89
31. (4.00) bn  an1  an1
Energy of photon
 n       n     
hc hc 6.625 1034  3 108  .
 J  eV     
 e 300 109 1.602  1019
6.6  3 1034 1035 40. (A, D)
 4.14e  Sn   32 12   42  22    72 52   82  62  ......
2  330
 0.03  10  0.3 eV  4n  4n  1 .
For photoelectric effect to occur, energy of 41. (B, C)
incident photons must be greater than work 1 cos 1 cos   31 cos 1 cos 
function of metal. Hence, only Li, Na, K and
 
Mg have work functions less than 4.14 V.  tan 2  3tan 2 .
32. (4.00) 2 2
56.x 42. (A, B, D)
0.33   100
68000   3a 3
 x  4.00  Number of integral values of a = –1, 0, 1
33. (B) For a = 1
34. (C)  1
y y z
x   2n  , where cos  
33.&34. Cx H y N z   x   O 2  CO 2  H 2 O  N 2 6 3
 4 2 2
 For a = 1, two solutions in  0, 2 .
 y Vy Vz
V ml V  x   mL Vx mL mL mL 43. (3)
 4 2 2
tan 2 x  tan 2 x+ tan 3x   1  tan 2 x tan 3x
 18  V  mL  8mL  12mL  4mL
 x  2, y  6, z  2 and V  4  tan 2 x tan 5 x  1  cos 7 x  0.
44. (6)
Now, C2 H6 N 2  H2  C2 H8 N 2
sin x sin 3x sin 9 x
4 mL 4 mL   0
cos3 x cos 9 x cos 27 x
35.
(B)
S1  2s 1  sin 2 x sin 6 x sin18 x 
   0
36. (C) 2  cos x cos x cos 3 x cos9 x cos 9 x cos 27 x 
32 1
ES1  13.6   E H  2.25  tan3x  tan x  tan9x  tan3x  tan27x  tan9x  0
22 2
37. (B, C) tan 27 x  tan x  0
Tn = T1 + a1 + a2 + …… + an – 1 sin 27 x.cos x  sin x cos 27 x  0
 Tn = 4n2 – 5n + 4. sin  27 x  x   0 ; sin 26 x  0
n  2 3 4 5 6
38. (B, C, D) x x , , , , ,
26 26 26 26 26 26 26
 an  2  an 1  Number of solutions : 6.
 XI_IIT_IC_& IR_CTA-1_23-08-2023
45. (1)  1
2
1
2

sin 3 x  1 and cos 2 x  1  2

 2
n 
 1   c 1 1   c 1
 x  n   1 , n  Z . 2 2
2

 1

 1
46. (1) 2 2

1
 1   11 1 11
If cot x  0 then  0  No solution.  1  1
sin x    1.
2    
If cot x  0  x   Only one solution. 51. (A)
3
47. (8) b c
x1  x2   , x1 x2  ,
Let the number of terms be ‘n’, where n is a a
even q r
x3  x4   , x3 x4  ,
Let the terms are p p
a, a  d , a  2d ....a   n  1 d 1 1
x2  x1  
21 x4 x3
By data a   n  1 d  a 
2 2
2 x  x 
  n  1 d 
21
…………..(1)
 x2  x1   3 4 2
2  x4 x3 
2
Given  x2  x1  1
a   a  2d    a  4d   ....   a   n  2 d   24  2
 2
 x4  x3   x3 x4 
…………..(2) 2
and 
 x2  x1   4 x1 x2

1
2 2
 a  d    a  3d    a  5d  ....   a   n 1 d   30  x3  x4   4 x3 x4  x3 x4 
…………..(3) On putting values we get
(3) – (2)  d  d  d  .....  d  6 b 2  4ac a 2
n  .
q 2  4 pr r 2…………..(4)
 d  6
2
2  n  1 21 52. (B)
   n  8. b c
n 12 x1  x2   , x1 x2  ,
a a
48. (0) q r
x3  x4   , x3 x4  ,
Let D be the common difference of the A.P. p p
Then, x2 x4 x x x x
a  4b  6c  4d  e   2 1 4 3
x1 x3 x1 x3
 a 4 a  D 6 a  2D  4 a 3D   a  4D  0. 2
 x1  x2  
x12 x1 x2

2
49. (0)  x3  x4  x32 x3 x4
Let
On putting value, we get q 2  pr.
f  x   x 2  7 x  6, x   , 5   6,  
53. (B)
f min  f  6   0. 2
      2  36  4 .
2

50. (1)
   4
54. (B)
x 2  px   P  C    x    x   
10  69  28  0
Put x = –1
10  69  28  0
 1  P  P  C  1   1     1  C
 a10  6a9  2a8  0.