Sec: XI_STU_IIT_IC/IR Date:11-09-2023

Time: 3 Hrs. CFTM – 1 Max.Marks:300

JEE MAIN 2022 Model
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
B B B B C C B D C C
11 12 13 14 15 16 17 18 19 20
D B C B A D D A C B
21 22 23 24 25 26 27 28 29 30
1 5 20 5 3 2 6 746 40 5

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
C C A C D A C B A D
41 42 43 44 45 46 47 48 49 50
B B B C C D D B A A
51 52 53 54 55 56 57 58 59 60
6 1 222 5 2 2 15 10 4 4
MATHEMATICS
61 62 63 64 65 66 67 68 69 70
C B C B C A A C C B
71 72 73 74 75 76 77 78 79 80
C A B B B D C D C D
81 82 83 84 85 86 87 88 89 90
55 7 1 1 0 0 1 2 25 17
 XI_IIT_IC/IR_CFTM–1_11-09-2023
Solutions
1. (B) m2g - T  m 2a;T - m1g sin   m1a

B
w  Ax   Pr inciple of hom ogenity  10. (C)
C  x 
2

11. (D)
2. (B) Maximum friction available to m2 is
From the third equation of motion
(fmax) =  m 2 g
v – u  2as
2 2

Therefore maximum acceleration which can

F F
But, a   v 2  u 2 – 2   S be provided to m2 by friction, (without the
m m
help of normal reaction from m1) is
 2.5 10 –2  20
 v 2  (1) 2 – (2)  –3 
f max
 20 10  100 amax = = g
m2
1 1 If a >  g , normal reaction from m1(on m2) is
 v 2  1– v m / s  0.7 m / s
2 2
non-zero.
3. (B)
12. (B)
h 2h
tan   , R  h    45 , u , v B cos 30  3
R g
V  u 2  2 gh vB  2 m / s

4. (B) 13. (C)

5. (C) mg sin    cos   2mg sin    cos 

Fnet  ma tan   3; tan   3 tan 

6. (C) 14. (B)

F mv 2
V  u  at, a F
m r
 F  v2
7. (B)
If V becomes double then F (tendency to
ma = T–mg
overturn) will become four times.
To move up with an acceleration a.The
15. (A)
monkey will push the rope downwards with a
force of ma. v= 𝑡2

8. (D) Now apply work-energy theorem

Null vector W= Δ(K.E)

9. (C) 16. (D)

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 XI_IIT_IC/IR_CFTM–1_11-09-2023
Vertical displacement will be zero when Plugging in the values and solving for x and
particle reaches the ground again. So work Kx gives the extension in the spring as x = 0.1
done by gravity will be also zero. m and the tension in the spring (which is the

17. (D) spring force) as Kx = 7.5 × 0.1 = 0.75 N.

1 Substituting the given values:

S  ut  at 2
2 7.5x = 0.1 × (52) × (0.2 + x),
1 Which simplifies to :
50  0   a 100
2
7.5x = 5 × (x + 0.2)
a 1 m / s 2

Solving for x gives x = 0.1 m. The tension in

F  mg  ma the spring is then kx = 7.5 . 0.1 = 0.75 N.

30    50  5  1 So, the correct answer is 0.75 N.

50  25
20. (B)
1

2

18. (A)

As the body is moving with constant velocity

so forces acting on the body must be
balanced.

contact force from incline should balance

  4ˆj(m / s)
weight of the body.
2 16
a   8m / s 2
 |Fcontact|= Mg R 2
ˆ
a  8(m / s 2 )(i)
19. (C)
21. (1)
In this problem, the spring is stretched due to
the circular motion of the block, so the 22. (5)
effective radius of the circular motion At 2 sec V = [5 – 4] = 1
becomes the natural length of the spring plus At 3 sec V = [5 – 9] = –4
the extension in the spring (r = 0.2 + x) aavg = V/T = –4–1 / 1 = –5/1

The spring force, which is also the centripetal 23. (20)

force, is given by Fc = Kx = m2r, where K is
2  2  sin 15 0
t
the spring constant, x is the extension of the g cos 30 0
spring, m is the mass of the block,  is the
1
angular velocity, and r is the radius of the S  2 cos150  t  g sin 30 0 t 2
2
circular path.

2
 XI_IIT_IC/IR_CFTM–1_11-09-2023
Put values and solve Differentiating w.r.to time,
v1  v 2  2v3  0
S  20 cm
Again differentiating w.r.to time,
24. (5) a1  a 2  2a 3  0
a1  a 2  2a1  0; 3a1  a 2  0
a 2  3a1 ; a B  3a A

26. (2)

1
K  E f  K  Ei
4

1 11 
mv 2   mv02 
(MB + mBC) a = TC – MAg 2 42 

Given = a = 0.2 m/s2, mBC = ½ × 0.2 = 0.1 kg, v0

v
for wire BC. 2

TC = (1.9 + 0.1) (0.2 + 9.8) = 20N Now applying, v  u  at

For tension at D. v0
 v0  (g)t o
2
(MA + MB + mAB)a = TD – (MA + MB + mw)g
V0
Given :mAB = 0.2 kg for wire AB. 
2gto
TD = (2.9 + 1.9 + 0.2) (0.2 + 9.8) = 50 N
N = 2.
 TC = 20 N and TD = 50 N.
27. (6)
25. (3)
The minimum velocity that should be
imparted to the bob so that it completes
vertical circle is

v  5gl

mv2
At lowest position, T  mg 
l

m(5gl)
T  mg 
x1  x 3  1
l
Differentiating with respect to time, T = 6mg
We get v1  v3  0
x=6
Again differentiating w.r.to to time,
a 1  a 3  0  a 1   a 3 , a 3  a 1 28. (746)
(x1  x 3 )  (x 2  x 3 )  2

x1  x 2  2x 3  2

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 XI_IIT_IC/IR_CFTM–1_11-09-2023
Normal force is given by N = mg + F sin  = P  t  K.E.
1
F 3 0.5  5  (0.2)v 2  0
100 + 2
2
2.5  0.1 v 2
Thus maximum static friction, fS,max = N = v  5m / s

 F 3 F 3 31. K.E. = hv – hv0

0.5 100    50 
 2  4
 Where, v = frequency of incident radiation
v 0 =Threshold frequency
This friction force is equal to the horizontal
component of applied force at the time motion K.E. is independent of intensity but it depends
starts. on frequency of light. Intensity is directly
proportional to the no. of electrons emitted.
F 3 F
Thus, 50   Fcos 60  n2
4 2 32. r  0.529 A
Z
1 3
F     50
2 4 
50
F  746N
0.067

29. (40)

From energy conservation

1  1 1 
33.  RH  2  2 
  n1 n 2 

34. The kinetic energy of the ejected electron is

K i  Ui  k f  U f given by the equation

 1  3
0   110    k f   3 10  
 2  2
5  k f  45
k f  40J

30. (5)
35. (a), (b) and (c) are according to quantum
As power is constant
theory but (d) is statement of kinetic theory of
gases
36. Given that
Mass % of 0, W0 %  61.4%

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 XI_IIT_IC/IR_CFTM–1_11-09-2023
Mass % of 0, WC %  22.9% 42. Ar  g   e  Ar   g  endothermic 


Mass % of 0, WH %  10% H  g   e   H   g  exothermic 

Mass % of 0, WN %  2.6% O   g   e   O 2  g  endothermic 
Mass of the person, W = 75 kg Electron gaining enthalpy (EGE) of H(g) is
 Mass of H , WH  10% of 75kg
1
negative while that of Ar(g) is positive due to
10 ns2np6 configuration.
  75kg  7.5
100 Second EGE is always positive for an atom.
Since, 1 H 2 so double mass of 1 H1 Ionization potential of an atom is positive.

 Mass of H 2 WH2  15kg 43.

 Incase is mass W  WH  WH1

2

 15kg  7.5kg  7.5

37. Rb and Cs have nearly same electron gain B – Si, Be – Al and Li – Mg exhibit diagonal
1
enthalpy H eg  46kJ mol . relationship, whereas Li – Na belongs to same
Ar and Kr have same eq H eg  96 kJ mol1 group.
44. Ionization energy generally increase moving
38. At the time of D.I. Mendeleev, structure of
from left to right across the period So, the
atom was not known.
order is Na < Mg < …. Cl < Ar
39. For the isoelectronic species the ionic radius
45. On moving down in a group atomic radii
increase with increase of negative charged
increases.
and ionic radius decrease with increase of
46. C
positive charged.
N3  O 2  F  Na   Mg 2  Radii 

40. 13 Ga is in group 13 with e configuration

[Ar]
3d10 4s 2 4p1 whereas 30 Zn has e

configuration as [Ar]
3d10 4s 2 . Re moval of e from 4p orbital is
easier than that from 4s orbital.
41.
Group Number

3 4 5 6 7  18 47. 2, bent T-shape.

21 Sc 25 Mn 36 Kr

39 Y 42 Mo 54 Xe

57 La 72 Hf
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 XI_IIT_IC/IR_CFTM–1_11-09-2023

Steric no. = 5 (sp3d), lone pair = 2 Bent T

shape
  2.96 1.6 1019 
48. A – III, B – IV, C – I, D – II
 (10.74 1019  4.74 1019 )J
 6.0 1019 J
52. Bohr’s radius of H-atom in ground state = a 0

49. 1p – 1p > lp> bp > bp – bp

Due to Dp – 1p repulsion in PF3, F – P – F
cmgle will be less than that of BF3
 BF3  PF3
But it is (n = 2) is nth excited state
BF3  NH3 , as the geometry of BF3 is
Thus, first excited n = 1
triagonal planar while that NH3 is tetrahedral
53. By photoelectric effect
As the Fluorine atom pulls the lone pair of
electron on P atom, 1p – bp repulsion is more
pre dominant. Thus NH3> PF3 thus, BF3>
NH3> PF3
I3 ion linear. This bond angle is 180°.

 is I3  BF3  NH3  PF3

50. According to VSEPR, hybridization of
54. If n = 5, total waves = n
[XeF5]– : 5 Bond pair + 2 Lone pairs = 7
2r  circumference = total waves
hybrid orbitals, sp3d3 hydridization and shape
n=5
is pentagonal planer and XeO3F2 : 5 Bond
55. This is the case of ionisation
pairs + O Lone pairs = 5 hydrid orbitals, sp3d
hybridation and structure is tringonal
bipyramidal.
1
51. hv  hv0  mv2
2

6
 XI_IIT_IC/IR_CFTM–1_11-09-2023
56. In dxy orbital, electron density is distributed in mv
n
4 lobes which are oriented between X and Y h
2rn mv n
axis. Therefore, it has minimum electron 
h
density along X-Y axis from where we can
pass two nodal planes XZ and YZ.
 3.94
4
60. Concept base
9 r r
3   1 
61. Tr 1  Cr  x 2 
9
 
2   3x 
9 r r
3  1  183r
 Cr  
9
  x
2  3

For term independent of x , we set 18-3r= 0 or

r = 6. Thus, term independent of x in the
c 3 108 m s 1
57. v   15 106 s 1

9
20 m 3 1 
expansion of   x 2   is
 15 MHz 2 3x 
58. 2n 2  3n 1  18 ......  i  3
96
 1
6
7
  
9
Cr  
2n 2  3n 1  6 ......  ii  2  3  18
Add equations (i) and (ii)
2n 2  24
n2  6 ......  iii  (1  x)9 (1  x)92  1
62. E
Substitute value of (iii) in (ii) 1 x 1
2n2−3n1=6 9
(1  x)101  (1  x)
2(6)−3n1=6 
3n1=6
x
n1=2 Coefficient of x 9 in E
Hence, the transition is from 6→2
The total number of photons emitted  coeffcient of x10 in (1  x)101  (1  x)9 
101 C10

42  k
22 r k 1 k
59. Radius of fourth orbit =0.529 .
12
A 63. 
r 0 7
k
( Cr )  k
7
( C 4 )
r 0
k
r
r

=8.464R
k
The velocity of electron in fourth orbit 1 5
 k (1  4) k   
1 7 7
V4  2.16 106  m / s
4
 5.4 10 m / s
5 Thus,
nh 
 k
22 r k
mv 
k 1

r 0 7
k
( Cr )

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 XI_IIT_IC/IR_CFTM–1_11-09-2023

 1  (1  x)
 k n
5
2n
5/7
   
k 1  7  1 5 / 7
 2.5 (1  x) 1   
n

 x xn

64. Sum of the coefficients in the expansion of  1

n
1
 Coefficient of x in (1  x) 1   n

( x  y)n is 2n . Therefore,  x
n 1
 Coefficient of x in (1+x) 2 n
2n  2048  211  n  11.
 2 nCn 1
n n
As n is odd, the greatest value of Cr is Ck
68. We have
where 100

1 1  100
Cm ( x  5)100m (4) m  ( x  5  4)100  ( x  1)100
k (n  1) or k  (n  1). m 0
2 2
Coefficient of x53 is 100C53 (1)47  100 C53.
Here n= 11, therefore k = 5 or 6.
Tr 1
11 69. Here, 1
Thus, greatest coefficient is C6 . Tr

8  r 1 4 
   1
65. We have r 3

C0 x  C1 x2  C2 x3  ...  Cn xn1  x(1  x)n  (9  r )4  3r  36  7 r

1
 r 5
Differentiating both the sides, we get 7
C0  2C1 x  3C2 x2  ...  (n  1)Cn x n 6th term is the greatest term.
n 1
 (1  x)  nx(1  x)
n
2 6 10 14
70. Let S  1   2  3  4  ...
(1)Putting x  1 , we get 3 3 3 3

C0  2C1  3C2 x  ...  (n  1)Cn 1 1 2 6 10

S   2  3  4  ...
3 3 3 3 3
 2n  n(1)2n1  (n  2)nn1
Subtracting (ii) from (i), we get
66. Middle term in the expansion of (1   x) is
4

 1 1 4 4 4
S 1    1   2  3  4  ...
4
C2 ( x)  6 x and the middle term in the
2 2 2
 3 3 3 3 3

expansion of (1   x)6 is 2 4 4 1 1 
 S   2 1   2  ... 
3 3 3  3 3 
6
C3 ( x)3  20 3 x3 .
2 4 4  1 
We are given  S  2 1  (1/ 3) 
3 3 3  
3
6 2  20  3    0or   
10 4 4 3 4 2 6
    
3 32 2 3 3 3
67. We have
2 6
 S  S  3
3 3
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 XI_IIT_IC/IR_CFTM–1_11-09-2023
1 1 If AC is the new position of the line AB then
71. We have x  
1  cos  sin 2 
2
CAX  450  150  600.

1 and thus its equation is

and y 
cos 2 
y  tan 600 ( x  2)
1 1 xy
Also z  
1  cos  sin  1  1 xy  1
2 2
 y  3( x  2)  3x  y  2 3
xy
75. Let the slope of L be m
 xyz  z  xy or xyz  xy  z
m 3
1 1
 1  x  y  xy then  tan 600  3
But
x y 1  3m

 xyz  x  y  z  
m  3  3 1 3 m 
3 1  3 m
72.
 3 1  sin    3 1  cos  1
or m 3  

2 2 2 2 2  m  0 or m  3

   But m  0 as L intersects x -axis

 sin sin   cos cos   cos
12 12 4
Hence equation of L is
    
cos      cos ,   2n 
 12  4 12 4 y  2  3( x  3)

  Or y  3 x23 3  0
  2n  
4 12
1 4
1 76. cosec180    5 1
73. | a(b  2)  0(2  0)  (0  b) | 0 sin180
5 1
2

 ab  2a  2b  0 Let cosec180  x  5  1
 2a  2b  ab
1 1 1
    x 1  5
a b 2
Squaring both sides, we get
1 0
74. Slope of AB  1
3 2 x2  2 x  1  5

 BAX  450 (Ref.Fig)  x2  2 x  4  0

77. We know that the equation of the line is

y  m1 x  c1 or  
m1  2  3 and the line is


y  m2 x  c2 or m2  2  3 . 
We also know that

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 XI_IIT_IC/IR_CFTM–1_11-09-2023

 m  m1 
tan     2 
  
2 3  2 3  n  n 7   n8 
C7  2 7  = nC8  2 8 
n
C7 2n 8 37
 n  8 . n 7

    3   3  C8 3 2
 1  m1m2  1  2  3 2  3
n ! 8!(n  8)! 1
   8 1

2 3

2 3
 3 7!(n  7) n! 6 n7 6
1 4  3 2
 48 = n -7  n =55
or 
  tan 1  3  82. Using (a+b)5 + (a-b)5

78. L1 (1, 1)  3(1)  8(1)  7  0 = 2[ a5+5C2 a3b2 + 5C4 ab4] ,

L2 (3,7)  3  3  8  7  0    
5 5
We get x  x3  1 + x  x3  1 = 2 [ x5

Hence (-1, -1) and (3, 7) lie on the same side + 10x3(x3-1) + 5x (x3-1)2]
of the line. which is a polynomial of degree 7.
79. D  2 83. We have 24 =16 = 17-1

 3  3 2
2000
= (24)500 = (17 =1 )500
 D  4  4  a 2   a 4
2 2

 4  4 =500
C0 17 500 – 500C1 17499+ 500C2 17498-500C3
17497+ ….. – 500C499 (17) + (-1 )500
 3  3
 D2  4 2  4  a 2   a 4 =
17m + 1
 4  4
r
80. OAB form a right angled triangle at 0 1
84. Tr 1  11
Cr(x )2 11-r
 
 bx 

1
Tr 1 11 Cr . x 223r .
br

For coefficient of x 7

22  3r  7 r 5

r
 1 
and 11cr  x 
11 r
 2
 bx 

81. Tr 1 , the (r +1) the term in the expansion of

 1 
r
113 r
 11cr  x  
 x
n  b 
 2   is given by
 3
For coefficient of x 7 ,
r
Tr 1 = nCr2n-r  x  =nCr  2 r  r 11  3r  7  r  6
nr

x
3  3 
1 11 1
11
C5  5
 C6  6
According to the given condition b b

10
 XI_IIT_IC/IR_CFTM–1_11-09-2023
since b  0 b  1 88. Since the line passing through (3,4) and (x,5)
makes an angle of 135°with x-axis ; therefore
 1  2   1 
85. 3  x    2   2  x    5  0 , its slope is
 x   x
tan135   1 .
Put

1 But, the slope of the line is also equal to

x   t  t   , 2]  [2,  
x 54
3t  2t  1  0
2
x3
3t 2  3t  t  1  0
54
1  1 
 3t (t  1)  1(t  1)  0  t  1,   x 3
3
1   x 3 1
 t  1, 
3
 x2
t  (, 2]  [2, )

No real value of t  no real value of x . 89. 

1
2
x1  y2  y3   x2  y3  y1   x3  y1  y2 
 1 3 
86.   tan 1    15 
1
38 12  1112  2  8  2  8
 1  3  2

1
87. The equation of the line joining the points  12  110  48
2
(2,3) and(4,1) is
25sq.units
1 3
y 3   x  2
42 90. Let m be the slope of the required line.
 y  3  x  2
Since the required line is perpendicular to the
 x y 5  0 ……… (i)
line joining A(2,-3) and B(4,2). Therefore ,
Suppose the line joining (2,3) and (4,1)
m  slope of AB = -1
divides the segment joining (1,2) and (4,3) at
23
point P in the ratio K :1  m  1
42
Then the coordinates of P are 2
 m 
5
 4k  1 3k  2 
 , 
 k 1 k 1  The required line cuts -off an intercept 4 on y-
axis , so c=4. Hence, the equation of the
Clearly , P lies on (i)
required line is
4k  1 3k  2
  5  0 2
k 1 k 1 y x4
 k 1 5

 2 x  5 y  20  0

11