Sec: XI_STU_IC_IIT Date: 06-11-2023

Time: 3 Hrs. CFTM – 04 Max. Marks: 300

JEE MAIN 2022 Model
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
B C B C A C B D C D
11 12 13 14 15 16 17 18 19 20
A C B C C B A D C D
21 22 23 24 25 26 27 28 29 30
1 2 6 2 7 0 6 7 2 4
CHEMISTRY
31 32 33 34 35 36 37 38 39 40
B C A A D B D B B C
41 42 43 44 45 46 47 48 49 50
C D B C A A D A C C
51 52 53 54 55 56 57 58 59 60
4 0 101 2 0 22 200 6 186 3
MATHEMATICS
61 62 63 64 65 66 67 68 69 70
D D C D C D B A A D
71 72 73 74 75 76 77 78 79 80
A B A D A C A C D C

81 82 83 84 85 86 87 88 89 90

1 1 1 2 2 2 4 3 3 3
 XI-IIT-IC & IR_CFTM-04_6-11-2022
Solutions
1. (B) 7. (B)
L1  2 L2  2.02  2  1.02  4.06
L1  2L2  0.01  2  0.01  0.03 1
I
2. (C) 2 c 2 Ic V 2 I
x  2 2
 c2  K
dx dy 1 2 mV r mr
vx  , v y  ; v  vx2  v y2 mv
dt dt 2
3. (B)
Moment of inertia of rectangular sheet about x  k  1(k is radius of gyration)
an axis passing through O ,
8. (D)

M 2 M 2 2
IO 
12
 a  b2  
12 
 80    60  y 

From the parallel axis theorem, moment of
inertia about O ' ,
2
I O '  I O  M  50  About instantaneous axis of rotation the rod
M
IO 12
 802  602 
1
is considered to have pure rotation
  Let instantaneous axis of rotation be located
IO ' M 802  602  M 50 2 4
12
    at a distance x from the colliding end (fig. b)
4. (C)
The tension in both string will be same due l l
v v
to symmetry. 2  2
lx x
6V 2l
⟹  and x 
l 3
9. (C)
For sphere,
For equilibrium 1 2 1
mv  I  2  mgh
2 mg  T cos   T cos   2T cos  2 2
or
 2 mg  2  mg  cos  2
1 2 12 v 7v 2
1 mv   mR 2  2  mgh or h 
 cos      45o 2 2 5 R 10 g
2
For cylinder
5. (A)
1 2 1  mR 2  3v 2
mv     mgh ' or h ' 
Conceptual 2 2 2  4g
6. (C) h 7v 2 /10 g 14
  
h ' 3v 2 / 4 g 15
2  2r r
AC  2Vt  2v  4v
g g
2
 XI-IIT-IC & IR_CFTM-04_6-11-2022
10. (D) In pure rolling, combined rotation and
F  f r  ma ...  i  translation motion may be assumed to be a
pure rotational motion about an axis passing
mR 2 through bottommost point (with same ω ) or
f r R  I   ...  ii 
2 instantaneous axis of rotation
for pure rolling  
a  R ...  iii  VP   OP   , where OP  2 R sin  
2
from  i  ,  ii  and  iii 
   
Therefore, VP  2 R sin     2v sin  
mR 3 2F 2 2
F  m R  F  mR   
2 2 3mR
15. (C)
 
11. (A) V12  V1  V2  Vo iˆ  2Vo iˆ  3V0
Using conservation of angular momentum
 2 2ml 2    3V0 / 2R
mvl   ml  
 3 
16. (B)
5 3v
 mvl  ml 2   
3 5l The net gravitational force on any particle,
18
Or,   rad / s provides the necessary centripetal force.
5
Now using energy conservation, after From that force, we can estimate the speed
collision of the particle.
1 2 l
I   2mg 1  cos    mgl 1  cos  
2 2 17. (A)
3
 mv 2  2mgl 1  cos   Inside uniform Spherical shell field is Zero
10
23 and hence potential is same everywhere
cos      63o
50 from centre to surface.
12. (C)
18. (D)
P is the IAOR.
dm   dv

  r2    r3 r5 
M    o  1   2    4 r 2 dr  4 o   2 
  R   3 5R 

Gravitational field,
Since, vP = 0
 r3 r5 
G  4o   2 
vA  3 5R 
 BP   AP     l  AP  Eg 
PA r2
 r r3 
PA  l cos   G  4 o   2 
 3 5R 
v

l cos  dEg
0
dr
13. (B)
14. (C)

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 XI-IIT-IC & IR_CFTM-04_6-11-2022
2 2
1 3r 34  32  V  VB  2
B
 
3 5R2 1 1
KEB  mvB2   0.1 2
2 2
5 1
 r R  0.1 J  J  x 1
9 10
22. (2)
19. (C)
v 2v v
  ;  x  2 R;  
Let mass of the removed part be ‘m’ & x x  2R 2R
23. (6)
radius R/2.
2 gl sin 
v 2
 m  M /8 K2
1 2
R
7M 24. (2)
Mass of left over part  M  M / 8 
8 g sin  2
a2   g sin 
I
 Field due to left over part 1 2 3
mr
1
 GM  S  ut  at 2
GM 2
  2  2
 x 8( x  R) 2   S g  sin   t12 g  sin   t22
1
S 2 3
20. (D) t2 3
 
a   R (pure rolling) t1 2
25. (7)
K.E.total of a rolling disc K.E.trans +
K.E.rotational
2
1 2 1 2 1 2 11 2  v 
 mv  I  mv   mR   2 
2 2 2 22  R 
F- f = ma 3 2
K .E.Total  mv
4
mR 2 a
( F  f ) R  mR 2   For surface AB,
R R 3 2 3
m  3  mg  30   mVB2
4 4
a
2F  ma  mR 2 2
For surface CD,
R 3 2 3
m  v2   mg  27   mVD2
4 4
F  ma  VB  VD
V2 = 7 m/s
So now
26. (0)
ma  f  ma Velocity at bottom point is zero as it is the
point of no slipping
f 0 27. (6)
Gravitational field at the surface
21. (1) Gm
E= 2
For elastic collision KEi = KE f r
1 1 1 1 E1 2
m  25   m  9  m  32  mvB2 
2 2 2 2 E2 3

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 XI-IIT-IC & IR_CFTM-04_6-11-2022
2
E1  r2   m1 
2
2  2   m1  Temperature changes the values of
        equilibrium constant.  
E2  r1   m2  3  1   m2  35. In case of thermodynamic process,
28. (7) H = nC p T
Gm2 Gm 2 Gm 2
F    ....  Proccess is isothermal, T = 0  H = 0
1 4 16
 
 1  4 36. N2O4  g   2 NO2  g 
Gm 2   Gm 2
1 3 100
 1  mol 0 at t = 0
 4 92
29. (2) 80 20
mol mol at equilibrium
dF 92 46
For maximum value of force 0
dx (  At equilibrium 20%
d  GM 2 x  NO2 is formed by mass,
  2 1  X   0  80% N2O4 is remained by mass)
dx  r  At t = 0 (initially)
1 p0V  n0 RT0
 X
2 100
 1 V   0.0821 300
30. (4) 92
or V  26.77 L
At equilibrium
GMm
F p2V  n2 RT2
r2
GM   m  3m  4GMm  80 20 
p2  26.77      0.0821 600
F'   4F  92 46 
r2 r2
or
31. Reverse direction because Q > Kc p2  26.77  1.3  0.0821 600
p2  2.4 atm
Given, ΔG∘= 2494.2 J
Hence, the resulting pressure = 2.4
1
2
[ B ][C ] 2 4 37. Equilibrium constant of a given reversible
Q 2
 2
[ A] 1 reaction depends only on temperature.
 
 2
38. Le- Chatelier’s Principle

We know, G  G  RT ln Q 39. N2O4  2NO2
=2494.2+8.314×300 In 4
t=0 a
=28747.27 J (+ve value)
Q t = equlbm
Also, we have ΔG= RT ln
K a – aα 2 aα
If ΔG is positive, Q > Kc 2
Therefore, reaction shifts in reverse direction.
Kp =
P 
NO2

2
4 .P
32. In a reversible themodynamic process, system PN2O4 1
2

always remains in equilibrium surroundings.

1
Hvap 30000 Hence  
33. T   400K P
Svap 75
40. NH4HS  s  NH3  g  H2S  g 
34. Both temperature and pressure will change
the equilibrium amount of X3Y (g). t = 00.1 mole

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 XI-IIT-IC & IR_CFTM-04_6-11-2022
for max. pressure - 0.1 0.1 43.
= 0.2 gaseous mole    3
G  H  T S  54.07  10 J  298  10 J
P × 16.4 = 0.2 × 0.082 × 500
3
 P = 0.5.  57.05  10 J
41. pH of HCl solution = 5 
Also, G  2.303RT log K
[H+]intial = 10-5 G

 log K 
[H+]intial × V1 = [H+]intial × V2 2.303RT
3
[H+]final = 10-8 
57.05  10
 10
5705
Let the H+ from water be x.
44. BeCl2 exist in polymeric forms and has no
H2O ⇌ H+ + OH-
electron deficiency, not a Lewis acid.
X + 10-8 X
X (X + 10-8) = 10-14
X2 + 10-8-10-14 = 0.
8 16 14 - -
X=
10  10  4  10 45. NH2 +
H2O ⇌ NH3 + OH
2 Base Conjugate acid
8 8
46. N2 + 3H2 ⇌ 2NH3 ( Δn<0 )
10  10 401 1 mol 3 mol 0
X
2 (1-x) (3 – 3x) 2x
8 8 Peq = 1atm, T = 400K
 19  10  9.5  10 2 2

KC 
[ NH3 ]

2X  
4
[H+]Total = [H+]HCl + [H+]water 3 3
[ N2 ][ H2 ]  3  3   1  X  27
-8
= 10 + 10-8 × 9.5 2 2
X
pH = 8 – log 10.5 1 X 
4
 1  X  1 X    X  3X 1 0
2

Slightily less then 7 3 9 4 3 5

X  X
42. 2 2
3  2.24 3  2.24
X or X 
2 2
5.24 0.76
X  2.62 or , X 
2 2
 X  0.38 (Since X cannot be greater than 1)
 [NH3] = 0.38 × 2 = 0.76
47. A t equilibrium
rf  rb , k f  kb
G  0

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 XI-IIT-IC & IR_CFTM-04_6-11-2022
48. 55.
2
In O , 18 electrons are present
2
Configuration is given by

2 2 2 2 2 2 2
1s ,  1s , 2s ,  2s , 2 pz ,  2 px   2 py ,

2 2 0
  2 px    2 py , 2 pz
So number of unpairrd electrons in O22- = 0.

56. The vapour pressure of water is 0.4 atm.

So, intial pressure of gas = moist gas -
vapour pressure of water
= 4 – 0.4 = 3.6 atm
Final pressure of gas = ?
H S From Boyle’s law
49. log K  
2.303RT 2.303R P1V1= P2V2
Positive Slope . ×
50. When Q > K, reaction will favour backward P2 = = 1.8 atm.
direction and when Q < K, it will favour Final pressure of gas which is moist
forward direction. = 1.8 + 0.4 = 2.2 atm = 22
51. Molar mass of glucose (C6H12O6)   
= 12 × 6 + 12 ×1 + 16 × 6 = 180 g mol-1 57. r H    f H Product    f H Reatant
 Molarity (M) 0 
 { f H Al2O3  3 f H Ca }
=
W .
 
= B = = 0.004 {3 f H  2 f H Al}
CaO
MB
 
= 4 × 10-3 M.  r H f  Al2O3   3r H f (CaO)
52. Orbital angular momentum (L)

L  l  l  1  h / 2  We know,  f H for elemental state = 0
For 3s orbital  
 f H Ca  0,  f H Al
[l= s = 0]
Putting the value,
So, b  0  0  1  h / 2

Or b = 0 r H = {1675 + 0} – {3(-625) + 0}
Thus, the value of x is 0. = - 1675 +1875 = 200 kJ
53. Unnilunium IUPAC
Atomic number (Z) = 101
Digit Number Abbreviation 58.
1 un u Since, equilibrium constant can be
0 nil n calculated as
1 un u Kf
Keq 
54. AB3 is a T- shaped molecule.Hence , it can Kb
3
be ClF3 with 2 pairs of lone pair. 10
Keq  2
 10
10

Again the relation between G and Keq
can be calculated from the formula

G = - RT In K

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 XI-IIT-IC & IR_CFTM-04_6-11-2022
 z2 = z1e i/3
So G = -8.3 × 300 × In (10)

Or G = - 5.7 Kj / mol
 -6 Kj/mol
 3 3  
2 2 

z2 = z1 cos   isin   z1  1  i 3 

59. Total milimoles of

H+ = (600 × 0.01) + ( 400 × 0.01 × 2) (2z2 − z1)2 = 3iz1
= 14 (2z2−z1)2=−3z12
+
H = = 14 × 10-3
Hence, z12 + z22 =z1z2
pH = 3- log14 So, a2 − 2b = b
= 3 – 1.14
= 1.86 = 186 × 10-2 a2 = 3b
60. (3) Statements given in A, D and E are 64. (D)
correct while ,B and C are incorrect. Let z = r(cos+ i sin ) = r ei
For 2 s orbital, the probability density first
decreases and then increase . So= 1[cos    / 2)  isin(   / 2)]
r
At any distance from the nucleus,the 1
probability density of finding an electron is  ei(/2)
r
never zero.It always have some finite values.
So z   rei 1 ei(/2)  ei  /2
r
=–i
61. (D) 65. (C)
(1 + )7 = A + B 66. (D)
(– 2)7 = A + B
– 2 = A + B Since  is the imaginary cube root of unity
1 +  = A + B 3 = 1 and
A=1
B = 1 (1, 1) 1 +  + 2 = 0 — (i)
62. (D) Hence, (1 +  − 2)7
z1/3 = p + iq
= ((1 + ) − 2)7
or, z = (p + iq)3
3 2 2 3
= (− 2 − 2)7 from (i)
or, x – iy = (p − 3pq ) + i(3p q − q )
= (− 22)7
Comparing both sides we get,
3 2 2 3
= − 12814
x = p − 3pq and y = − 3p q + q .
= −12812.2
Now,
= − 128(3)4.2
xy.
p q = − 1282 ...since 3 = 1.

= p2 − 3q2 − 3p2 + q2 67. (B)

= −2(p2 + q2) —(1). According to the problem,
z2 – z − (5 − 5i) = 0
Now,
a = 1; b = − 1 ; c = 5i − 5
xy So, the roots are
p q D = b2 − 4ac
.
p2  q2 = (−1)2 − 4(−5 + 5i)
= − 2. = 1 + 20 − 20i
=21 − 20i
63. (C)
We have z1 + z2= − a, z1z2= b

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b  D b  D 4 4 4 4
z , |z| = z    z  
2 2 z z z |z|
1  21  20i 1  21  20i 4
z ,  2
2 2 |z|
The roots of 21 − 20i are  | z |2  2| z | + 4
Let assume z1 = 21 − 20i  (| z | – 1)2  5
Re(z1) = 21  | z | 1  5
 | z | 5 1
z1  (21) 2  (20) 2  441  400
Therefore, the greatest value of |z| is
 841  29 5 1
 |z |  Re(z1 ) | z1 |  Re(z1 )  71. (A)
21  20i    1 i  We have,
 2 2  zi x  i(y  1)
1  1
 29  21 29  21  zi x  i(y  1)
  i  2
 2 2  x  i(y  1)
 2
1
= ± (5 − 2i) x  i(y  1)
1  5  2i 1  5  2i  x2 + (y – 1)2 = x2 + (y + 1)2
z or z 
2 2  4y = 0; y = 0
z = 3 – i or z = i − 2 Which is x-axis
72. (B)
Hence product of real parts are
−2×3=−6 | a + b + c2 |
68. (A) We know 1 +  + 2 = 0
S = i + 2i2 + 3i3 +.....+ 100i100
2 = − (1 + )
iS = i2 + 2i3 + .... + 100 i101
a + b+ c2 = | a + b + c (– (1 + )) |
S(1 – i) = i + i2 + i3 + .... + i100 – 100i101
= | (a – c) + (b – c) |  | a – c | + | (b –
100i 100i(1  i)
S  c)  |
1 i 2
–50( i – 1) = 50(1 – i)  | | = 1
69. (A) |a–c|+ |b–c|
cos 2 i sin 2
  Let a – c = 0, b – c = 0 for minimum.
3 3
cos 2 i sin 2 a = c b = c which is contradictory for
 
3 3 question.
n n
 +
n n  for a = c = 0, |b–c|=1
 cos 2 i sin 2   cos 2 i sin 2 
=       b = 1 or (− 1)
 3 3   3 3 
 Minimum value is = 1.
73. (A)
 cos 2n isin 2n   cos 2n  2n  
    isin   z 1
 3 3   3  3  Since | z | = 1 and  
z 1
 2n  1 
 2 cos    z – 1 = z +   z
 3  1 
70. (D) |1   |
We have  | z | |1   |  |1   | (|z| = 1)
|1   |
Squaring both sides

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2 2 79. (D)
1 + |  | – 2|  | Re () = 1 + |  | + 2| w |
Re () 4sin .cos   2cos   2 3 sin   3  0
 2 cos (2sin   1)  3(2sin   1)  0
[ | z1 ± z2 |2 = | z1 |2 + | z2 |2 ± 2| z1 | | z2 |
 (2sin   1)(2 cos   3)  0
Re(z1z 2 ) ] 1 3
 sin   ,cos  
2 2
 4 |  | Re |  | = 0  Re () = 0  5 11
  , ,
74. (D) 6 6 6
z1  80. (C)
arg  2, 5, 8 .........
z2 2
a = 2, d = 3
z  
 1  cos  i sin  i  S2n = n[4 + (2n – 1) 3] = n(6n + 1)
z2 2 2  57, 59, 61, …………
( | z2 | = | z1 | = 1) Sn = [2 × 57 + (n – 1) 2]
n = n[57 + n – 1]
z = n (56 + n)
  (i) n
1
n
z 2 n(6n + 1) = n (56 + n)
Hence in = 1  5n = 55
 n = 4k  n = 11 
75. (A) 81. (1)
Let z = r(cos  + i sin )
Let z = x + iy
arg(z) =  < 0 (x  1) 2  y 2
| z – 1 | = | x + iy – 1| =
− z = – r(cos  + i sin )
(x  1) 2  y 2
| z + 1 | = | x + iy + 1| =
= r(cos( + ) + i sin ( + ))
x 2  (y  1) 2
arg(− z) =  +  | z – i | = | x + iy – i | =

 arg(– z) – arg(z) =  +  –  =  Given,

| z – 1 | = | z + 1| =| z – i
76. (C)
Image of A(1, 2) in line mirror y = x is (2, 1)
 (x  1) 2  y 2  (x  1) 2  y 2  x 2  (y  1) 2
; image of B(2, 1) in
y = 0 (x – axes) is 2, – 1) = Hence,  = 2,  = – 1
x – 1 = ± (x + 1)
77. (A)
n 1 n
Cr  x=0
 n n
r  0 C r  C r 1 (x + 1)2 + y2 = x2 + (y − 1)2
n 1
r 1 1 substituting x = 0 we get,
r0 n  1

n 1
[1  2  ........  n]
y=0  z=0
1 n(n  1) n
   Therefore there is only one complex number
n 1 2 2
78. (C)
82. (1)
Let roots are , –, ,  then  +  = 2 and 6 6 5 5
– 2 ( + ) = – 8 1  i 3 1 i 3 1  i 3  1 i 3
 2 = 4 ±2  2   2   2   2 
       
4 3 2
 2 – 2(2 ) + a(2) + 8(2) + b = 0  + ( ) +  + (2)5
6 2 6 5
— (1)
 4a + b = – 16
Where  is cube root of unity.
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3 2 86. (2)
i.e  = 1 and 1 +  +  = 0
from (1) x2 y2
   1
PB2 PA 2
6 + (2)6 + 5 + (2)5
PA  4  4  2 2
= 1 + 1 + 2 +  = 1 PA  2 2
83. (1) Put value of PA & PB in given equ.
1 + z + z2….. + z17 = (1 + z + z2…..+ z13) + 4 4
  1
z14 (1 + z + z2 + z3) 8 8
=0 +=2
87. (4)
Put 1 + z +……..+ z13 = 0 1
z14(1 + z + z2 + z3) = 0 n 1/13 (n 1)  a  5/ 2
T2 = C1 (a )    14a
 z14(1 + z)(1 + z2) = 0  a 1 
n 1
n a .a 3/2  14a 5/2
13

 z = 0, i, −1 Comparing both sides

n 1 3 5
But at z = 0, i, 1 + z + z2 + …. + z13  0  
13 2 2
n 1
 1  n  1  13
 z = −1 is the only possible value. 13
84. (2) n = 14
| z1 | = 1, | z2 | = 2, | z3 | = 3 n!
n
| 9z1z2 + 4z1z3 + z2z3 | = 12 C3 3!(n  3)! 2!(n  2)!n!
n
 
 | |z3|2 z1 z2 + | z2 |2 z1 z3 + |z1 |2z2 z3 | C2 n! n!3!(n  3)!
= 12 2!(n  2)!
 | z1z 2 z 3 z3  z1z 2 z 3 z2  z1z 2 z 3 z1 | 12  2!12! 12
 4
3!11! 3
  | z1z 2 z 3 || z1  z2  z3 |  12  88. (3)
 | z1 || z 2 || z 3 || z1  z 2  z 3 |  12  C1 (2, 3) r1 = 5
 | z1 + z2 + z3 | = 2 C2 (– 3, – 9) r2 = 8
85. (2) C1C2 = 25  144  13
z  2z 2 C1C2 = r1 + r2
Here 1 1
2  z1 z2  externally touch
 | z1  2z 2 |  | 2  z1 z2 |  3 Common tangents
89. (3)
 | z1  2z 2 |2  | 2  z1 z2 |2
4x2 –16x +  = 0
 (z1  2z 2 )(z1  2z 2 )  (2  z1z2 )(2  z1z2 ) f(1) > 0 and f(2) < 0 and f(3) > 0
 (z1  2z 2 )(z1  2z2 )  (2  z1z2 )(2  z1 z 2 ) 
  z1 z1  2z1 z2  2z 2 z1  4z 2 z2 
   4  2z1z 2  2z1 z2  z1 z1z 2 z2 
  | z1 |2  4 | z 2 |2  4  | z1 |2 | z 2 |2 
  | z1 |2  | z1 |2 | z 2 |2  4 | z 2 |2  4  0 
  | z1 |2 4 1 | z 2 |2   0 
 But | z2 |  1 (given) f(1) = 4 – 16 +  > 0
 | z1 |2 = 4   > 12 —(i)
Hence, | z1 | = 2.
f(2) = 16 – 32 + < 0

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  < 16 —(ii)
f(3) = 36 – 48 + > 0
  > 12 —(iii)
By (i) (ii)  (iii)
12 < l < 16.
So  = 13, 14, 15 has 3 integral solutions.
90. (3)
sin 7x + sin 4x + sin x = 0
 2 sin 4x cos 3x + sin 4x = 0
1
 sin 4x = 0 or cos 3x = 
2
2
 4x = n or 3x = 2n 
3
n 2n 2   2 4
x ,   0, , , , .
4 3 9 4 2 9 9

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