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2 .Correlation Analysis.
2 .Correlation Analysis.
2 .Correlation Analysis.
Types of Correlation
I. Positive and Negative Correlation
(a) Positive Correlation: If two variables move in the same direction, then the correlation is called
positive. For example, price and supply are positively correlated. When
price goes up, supply goes up and vice versa.
Degree of Correlation
The degree of correlation is measured through the coefficient of correlation. The degree of correlation
for the given variables can be expressed in the following ways:
1. Perfect Correlation:
If the relationship between the two variables is in such a way that it varies in equal proportion (increase
or decrease) it is said to be perfectly correlated. This can be of two types:
Positive Correlation: When the proportional change in two variables is in the same direction, it is said to
be positively correlated. In this case, the Coefficient of Correlation is shown as +1.
Negative Correlation: When the proportional change in two variables is in the opposite direction, it is
said to be negatively correlated. In this case, the Coefficient of Correlation is shown as -1.
2. Zero Correlation:
If there is no relation between two series or variables, it is said to have zero or no correlation. It means
that if one variable changes and it does not have any impact on the other variable, then there is a lack of
correlation between them. In such cases, the Coefficient of Correlation will be 0.
3. Limited Degree of Correlation:
There is a situation with a limited degree of correlation between perfect and absence of correlation. In
real life, it was found that there is a limited degree of correlation.
The coefficient of correlation, in this case, lies between +1 and -1.
Correlation is limited negative when there are unequal changes in the opposite direction.
Correlation is limited and positive when there are unequal changes in the same direction.
The degree of correlation can be low (when the coefficient of correlation lies between 0 and 0.25),
moderate (when the coefficient of correlation lies between 0.25 and 0.75), or high (when the coefficient
of correlation lies between 0.75 and 1).
Zero order
Zeroth-Order Reactions
A zeroth-order reaction is one whose rate is independent of concentration; its differential rate law is
rate=k.
We refer to these reactions as zeroth order because we could also write their rate in a form such that the
exponent of the reactant in the rate law is 0:
rate=−Δ[A]
Δt=k[reactant]0=k(1)=k(1.6.1)
Because rate is independent of reactant concentration, a graph of the concentration of any reactant as a
function of time is a straight line with a slope of −k
. The value of k
is negative because the concentration of the reactant decreases with time. Conversely, a graph of the
concentration of any product as a function of time is a straight line with a slope of k
, a positive value.
First-Order Reactions
In a first-order reaction, the reaction rate is directly proportional to the concentration of one of the
reactants. First-order reactions often have the general form A → products. The differential rate for a first-
order reaction is as follows:
rate=−Δ[A]
Δt=k[A](1.6.5)
If the concentration of A is doubled, the reaction rate doubles; if the concentration of A is increased by a
factor of 10, the reaction rate increases by a factor of 10, and so forth. Because the units of the reaction
rate are always moles per liter per second, the units of a first-order rate constant are reciprocal seconds
(s−1).
The integrated rate law for a first-order reaction can be written in two different ways: one using
exponents and one using logarithms. The exponential form is as follows:
[A]=[A]0e−kt(1.6.6)
where [A]0
is the initial concentration of reactant A
at t=0
; k
is the rate constant; and e is the base of the natural logarithms, which has the value 2.718 to three
decimal places. Recall that an integrated rate law gives the relationship between reactant concentration
and time. Equation 1.6.6
Second-Order Reactions
The simplest kind of second-order reaction is one whose rate is proportional to the square of the
concentration of one reactant. These generally have the form
2A→products⋅
A second kind of second-order reaction has a reaction rate that is proportional to the product of the
concentrations of two reactants. Such reactions generally have the form A + B → products. An
example of the former is a dimerization reaction, in which two smaller molecules, each called a
monomer, combine to form a larger molecule (a dimer).
The differential rate law for the simplest second-order reaction in which 2A → products is as
follows:
rate=−Δ[A]2Δt=k[A]2(1.6.8)
Consequently, doubling the concentration of A quadruples the reaction rate. For the units of the
reaction rate to be moles per liter per second (M/s), the units of a second-order rate constant must
be the inverse (M−1·s−1). Because the units of molarity are expressed as mol/L, the unit of the rate
constant can also be written as L(mol·s).
For the reaction 2A → products, the following integrated rate law describes the concentration of the
reactant at a given time:
1[A]=1[A]0+kt(1.6.9)
Because Equation 1.6.9
has the form of an algebraic equation for a straight line, y = mx + b, with y = 1/[A] and b = 1/[A]0,
a plot of 1/[A] versus t for a simple second-order reaction is a straight line with a slope of k and an
intercept of 1/[A]0.
PARTIAL CORRELATION
When there are more than two variables and we study
the relationship between any two variables only, assuming
other variables as constant, it is called partial correlation. For
example, the study of the relationship between rainfall and
agricultural produce, without taking into consideration the
effects of other factors such as quality of seeds, quality of soil,
use of fertilizer, etc.
Partial correlation coefficient measures the relationship
between one variable and one of the other variables assuming
that the effect of the rest of the variables is eliminated.
If r12 = 0.98, r13 = 0.44 and r23 = 0.54, find (1) r12.3,
(2) r13.2 and (3) r23.1
Sol:
(1)
r12.3 = r12 – r13 r23
√1–r13sq √1–r23sq
= 0.98 – 0.2376
√1–0.1936 √1–0.2916
(2)
r13.2 = r13 – r12 r23
√1–r12sq √1–r23sq
= 0.44 – 0.5292
√1–0.9604 √1–0.2916
3)
r23.1 = r23 – r12 r13
√1–r12sq √1–r13sq
= 0.54 – 0.4312
√1–0.9604 √1–0.1936
MULTIPLE CORRELATION
When there are more than two variables and we study
the relationship between one variable and all the other
variables taken together, then it is the case of multiple
correlation. Suppose there are three variables, namely x, y and
z. The correlation between x and (y & z) taken together is
multiple correlation. Similarly, the relation between y and (x &
z) taken together is multiple correlation. Again, the relation
between z and (x & y) taken together is multiple correlation. In
all these cases, the correlation coefficient obtained will be
termed as coefficient of multiple correlation.
Qn: If r12 = 0.6, r23 = r13 = 0.8, find R1.23, R2.13 and R3.12 .
Sol:
R1.23 = √ [r12sq+ r13sq – 2 r12 r13 r23]÷ [1– r23sq]