altemative from the

(b) Complete the following statements by selecting the correct

given choices: 14x1

(0) The synthesis of Alkyl fluorides is best accomplished by:

Reaction
(1) Free radical fluorination (2) Sandmeyer's
Finkelstein's Reaction Swartz Reaction.
(3)
of diamagnetic nickel complex [Ni(CN).1 is
i) The structure
(atomic number Ni = 28):
4211
(1) trigonal bipyramidal square planar
(3) tetrahedral (4) octahedral

(ii) Which of the following aqueous solution will exhibit highest boiling point?
0.01 M Na,SO4 (2) 0.01 M KNO
(3) 0.015 Murea (4) 0.015 M Glucose
(iv) Phenol when first reacts with conc. H,SO4 and then conc. HNO; gives:

2,4,6-trinitrophenol (2) p-nitrophenol

(3) o-nitrophenol (4) nitrobenzene.
(c) Match the following: 4x1]
,
() Ethanol and watersolution (1) Lucas Test C)
i) EDTA )Azeotropic Mixture 234
(ii) Freon 4 (3) Hexadentate ligand(c
(Giv) Alcohols O4) Refrigerant D
Ar 2463a
=11:78ak
(d) Answer the following questions: 4x2]
T CxsTx
3
l12-3/5 Q
(i) Calculate the difference in osmotic pressure of 0.2 M NazSOs and 0.5 M X 3

glucose solution at 27°C, assuming complete dissociation of Na,SO4 o2xo-082)x3A(=

(ii) Write balanced chemical equation for: dh-2.4
ateme 1 xo-og21

(0) Finkelstein reaction R-B I RI N a .

O - 5

(2) Sandmeyer Reaction7*2 C +e

QuE
Gii) When a coordination compound CiCl.6H;0 is mixed with AgNO;, 2 moles
of AgCl are precipitated per mole of compound. Write the:
(1) Structural formula of the complex Cr(h)s Hh®
(2) IUPAC name ofthe complex
penlaognehlowchvmunJehlonck bmdra

Q-4 (2)
 Q
dlest. 21
- Ie t
Question 7
o-methoxyphenol
acidic than
0-nitrophenol is
dryness.-form ex pla*
more
(a) )
are n e v e r
evaporated to xde,
(11) Old samples ofcthers
OR
of ethanol to yield ethene. CaHs Or
(b) Write the mechanism ofacid dehydration
Mzo.
(2
Question 8 The
high pressure gives |B].
heating with NH;
at
An aromatic compound [A] on

and HCI gives [C], which on

A- treatment with ice cold NaNO2
compound [B] on
the compounds [A], [B
heating with Cu/HCl gives compound [A] again. Identify
to [C].
of the reaction for conversion [B]
of
and [C]. Write the name

Digotdto
e

Question 9
131
found to be 0.4022C.
The depression in freezing point of a sugar solution was

solution at 27°C. [R 0.0821 lit atm/ mol/K,

Calculate the osmotic pressure of =

o2161KO.oB21 x
K 1.86 Kkg/ mol] t AT mdahki xkfx*
ou02 mdalk & t86x 5 32au
Question 10( omm o-216 (C)
of in a dilute aqueous solution containing
(a) Thedegrec of dissociation Ca(NO;)>
pressure of water
7g of salt per100 g of water at 100"C is 70%. If the vapour
t1(3-1o7]-24 at 100°Cis 760 mm Hg, calculate the vapour pressure of solution. [Atomic
weight: Ca =40, N 14, 0=16] CalnJ 164
=

GH
Phenol foms dimer in Benzene. A solution of 2 g of Phenol in 100 g
Benzene
b) Calculate the degree of association of
has its freezing point lowered by 0.72 K.
76-P 20 o195 AT4O00 K a
phenol. (Kr for benzene 5.12 Kkg mol")
=

Ps-7o-20o5 am
72-10 K512 a c6.
73990 Question 11 G 6 [ n o-5-1)] Bi
Mention the type of isomerism exhibited by the following pairs of coordination
compounds:
() (CrNH;)s (SCN)J and [CrNHs)s (NCS)}* Linr
Iomsatiom
() [PMCh(NH3)4] Br and [Pt Br(NH:)4]Ch
i) [CuNH) [PHCI] and P(NH;)A] [CuCk] Covodiadn

Q-4 (4)
 Cuo
a
Question 16
5
(a) ) What is
HoHa
meant by negative deviation from Raoult's Law? Give an

example. What is the sign of AH or negative deviation? ) - ve

i) Methanol and Ethanol form nearly an ideal solution at 300 K. A solution
So is made by mixing 32 g Methanol and 23 g Ethanol at 300 K. Calculate PaHun51105
19
the partial pressures of the constituents and the total pressure of solution.

(at 300 K p° CHOH -90 mm of Hg. p° C;H,OH -

51 mm
of Hg).
OR

b) Henry's law corelating the pressure of gas and solubility in a

State

solvent and mention two applications ofthe law. Be-d, tra

(i) An aqueous solution containing 12.48 g of BaClh in 1000g of water , : o o8 32
boils at 100.0832°C. Calculate the degree of
dissociation of BaCl T 10 AKgai
[Given Ka for water 0.52 K kg mol , molar mass mil
of BaClh 208.34 g
mol i-264 O,0B32looTo 52% 12. 4
Question 17 2-6414-1) ,4 2 224 <
(a) i) Using the Valence bond theory, answer the following
questions for O
[CoF6 complex [Atomic number of Co =27]
State:
()Hybridisation (2) Geometry D r e t a d

(3) Magnetic behavior. 4) Number ofunpaired electrons.

(ii) How does Ka[Pt ClL] get ionized when dissolved
in water? Will it form
ppt when AgNO, solution is added to it? Give reason.
2LPrn)2 2 (eCk]
OR
(6) 6) DrawStereoisomers of the following complexes: No Pet Ce
1) Geometrical isomers of [Pt(NH,);Cl]
(2) Optical and Geometrical
isomers of [Co(en),Cl:]'. 2
(i) Discuss briefly giving an example in each case the role of coordination
compounds in:
0) Biologicalsystem C{lero tlaneyleb
(2) Qualitative analysis
Qnalyst ""/"/2.r
Q-4
(6)