KHALLAL-SHINDE CHEMISTRY CLASSES

WORK SHEET For pH concept

Answers

1) If [H+] = 3.24  10-8mol/dm3, 20) If pOH = 11.45,

pH = 7.4895 [OH-] = 3.548  10 -12 mol/dm3
2) If [H+] = 11.23  10-8mol/dm3, and pH = 2.55

pH = 6.9497

3) If [OH-] = 4.34  10-4mol/dm3, 21) If pOH = 8.67,

pH = 10.6375 [OH-] = 2.138  10-9 mol/dm3

4) If [OH-] = 8.913  10-2mol/dm3, and pH = 5.33

pH = 12.95 22) If pOH = 4.5,

[OH-] = 3.162  10-5 mol/dm3
5) If [H+] = 8.314  10-9mol/dm3,
pOH = 5.9198 and pH = 9.5

6) If [H+] = 9.234  10-5mol/dm3, 23) If pOH = 5.78,

pOH = 9.9654 [OH-] =1.66  10 -6 mol/dm3

7) If [OH-] = 9.34  10-11mol/dm3, and pH = 8.22

pH = 3.9703 24) For given [H+] (in mol/dm3) arrange with

8) If [H+] = 0.0023mol/dm3, increasing order of acidity.

a) 9.34  10-10 b) 3.45  10-12
pH = 2.6383
c) 1.23  10-4 d) 3.45  10-6
9) If [OH-] = 0.00034mol/dm3,
Ans: b < a < d < c
pOH = 3.4685

10) If [OH-] = 0.00034mol/dm3, 25) For given [OH-] (in mol/dm3) arrange with
pH = 10.5315 increasing order of basicity.
11) If [OH-] = 0.0002mol/dm3, a) 2.45 10-4 b) 8.99 10-9
pH = 10.301 c) 3.45 10-7 d) 6.7810-8

12) If pH =2.3,[H+]= 5.012  10 -3 mol/dm3 Ans: b < d < c < a

13) If pH = 3.45, [H+] = 3.548 10 -4 mol/dm3 26) From give [H+] (in mol/dm3), identify strongest
14) If pH = 8.33, [H+] = 4.677  10 -9 mol/dm3. acid.
15) If pH = 9.12, [H+] = 7.586  10 -10 mol/dm3 a) 9.78  10-4 b) 9.78  10-9
16) If pOH = 4.99, [H+] =9.772  10 -10 mol/dm3. c) 9.78  10-8 d) 9.78  10-7

17) If pH = 4.5, Ans: a)

[H+] = 3.162  10 -5mol/dm3 and 27) If Kw 1  10-12 , pH of water = 6

pOH = 9.5
28) If Kw 1  10-10 , pH of water = 5
18) If pH = 11.45,
29) If Kw 1  10-15, range of pH scale should be 0 to
[H+] = 3.548  10 -12 mol/dm3 and
15.
pOH = 2.55
30) Compare [H+] for the solutions whose pH is given
19) If pH = 3.99,
as:
[H+] = 1.023  10 -4 mol/dm3 a) 3 and 5:
and pOH = 10.01 100 times greater in pH 3 than pH 5
 b) 5 and 6: M M
g) 40 mL HCl + 60 mL NaOH
10 times greater in pH 5 than pH 6 10 10

c) 3 and 6: =12.301

1000 times greater in pH 3 than pH 6 34) Calculate pH of solution when equal quantity of

31) What would be pH if solution of following are mixed:

a) pH 1 is diluted by 10 times : 2 a) pH 1 + pH 2 = 1.3

b) pH 2 is diluted by 100 times: 4 b) pH 2 + pH 4 = 2.3

c) pH 6 is diluted by 100 times: 6.95 c) pH 2 + pH 5 = 2.3

d) pH 10 is diluted by 100 times: 8 d) pH 2 + pH 6 = 2.3

e) pH 8 is diluted by 100 times: 7.1 35) Calculate pH of solution when equal quantity of

f) pH 14 is diluted by 1000 times: 11 following are mixed:

32) Identify following solution is I) acidic, II) basic or a) pH 1 + pH 8 = 1.3

III) neutral. b) pH 6 + pH 8 = 7

a) 10 mL 0.1 N HCl + 20 mL 0.05 N NaOH c) pH 5 + pH 8 = 5.3

= neutral d) pH 6 + pH 10 = 9.7

b) 20 mL 0.1 N HCl + 20 mL 0.05 N NaOH 36) What happens with pH if,

= Acidic a) [H+] is increased = decreases

c) 50 mL 0.1 N HCl + 20 mL 0.1 N NaOH b) [OH-] is increased = increases

= Acidic c) Ka is large = decreases

d) 100 mL 0.1 N HCl + 50 mL 0.05 N NaOH d) Kb is large = increases

= Acidic e) pKa is large = increases

e) 10 mL 0.1 N HCl + 50 mL 0.1 N NaOH f) pkb is increased = decreases

= Basic g) water is added into strong acid = increases

33) Calculate pH of following solution. h) acid is added into water= decreases

M M i) water is added into base : decreases

a) 55mL HCl  45 mL NaOH
10 10 j) base is added into water= increases
=2 k) temperature of water is increased: decreases
M M 37) Which of the following undergoes hydrolysis?
b) 100 mL HCl + 100 mL NaOH
10 10 a) NaCl b) KCl c) CH3COONa
=7 d) HCOOK e) NH4Cl f) NaCN
M M = c) , d) , e) and f )
c) 60 mL HCl + 40 mL NaOH
10 10
38) Classify the following aq. solution into acidic,
= 1.6990
basic and neutral solution.
M M
d) 75 mL HCl + 25 mL NaOH a) NaCN: Basic
5 5
b) CH3COOK: Basic
=1
c) HCOOK: Basic
M M
e) 25mL HCl  75mL NaOH
d) NH4Cl: Acidic
5 5

=13 e) KNO3: Neutral

M M f) NaF: Basic
f) 45mL HCl + 55mL NaOH
10 10 g) Na2SO4: Neutral
= 12 h) HCOOLi : Basic
39) Write correct formula of pH for:
a) Salt of WASB:

b) Salt of SAWB:

c) Salt of WAWB:

40) Write Henderson’s Equation to calculate pH for:

a) Acidic buffer:

b) Basic buffer:

c) Neutral buffer: