Hira Girls School & College Matta Swat

1st Assessment Class First Year

Chemistry

SECTION A
Max marks: 18 Time: 20 min

Class No:____________________ Name:___________________________________

Note: Attempt all Mcqs. Cutting, overwriting is not allowed. Return the paper in given time.

1. An atom has four unpaired electrons. The total spin of this atom will be_______
(A) 1 (B) 1.5 (C) 2 (D) 4
2. Electromagnetic radiation (Photon) with least wavelength result when an electron in the hydrogen atom
falls from n = 5 to________
(A) n = 1 (B) n = 2 (C) n = 3 (D) n = 4
3. 80 g of NaOH contain _____________moles.
(A) 2 (B) 3 (C) 4 (D) 1
4. n + l value of 6p is _______________
(A) 6 (B) 7 (C) 5 (D) 8
5. The reactant which is used up first in a reaction is called_________________ reactant.
(A) Excess (B) Limiting (C) Activated (D) Minor
6. Planck proposed that energy travels in________________
(A) discontinuous manner (B) continuous manner (C)Slow Manner (D) General Manner
7. Volume of gas ______________________with increase in pressure.
(A) Decreases (B) increases (C) does not change (D) first increases and then decreases
8. Properties of solid that depends on direction are called_____________ properties.
(A) isotropic (B) Additive (C) Colligative (D) Anisotropic
th 0
9. The radius of 5 shell of an excited hydrogen atom is __________________A .
(A) 13.225 (B) 14.338 (C) 15.98 (D) 17.67
10. For heavier gases in positive rays production e\m ratio is_______________
(A) High (B) Small (C) Moderate (D) Very Minute
11. Sub shell which is not sub-divided into any other orbital is termed as_______________
(A) P subshell (B) S Subshell (C) D subshell (D) F subshell
12. An element has 18 electrons, and 20 neutrons. Its charge is —2. What is its mass number?________
(A) 38 (B) 39 (C) 40 (D) 41
13. When 6d orbital is complete, the entering electron goes into_____________
(A) 7P (B) 8S (C) 6f (D) 5f
14. Quantum number value for 2p sub shell are____________________
(A) n = 1,L = 0 (B) n = 1, L = 1 (C) n = 2, L = 0 (D) n = 2, L = 1
15. Which of the following statement Is wrong about electron______________
(A) It has wave like property (B) It is a particle (C) It emits energy while moving in orbit.
(D) Its motion is affected by magnetic field
16. Bond order of oxygen molecule is__________
(a) 2 (b) 3 (c) 1 (d) 0
17. The mass of 2 moles of CO2 is______________________
(a) 44g (b) 88g (c) 22g (d) 11g
18. D orbital can accumodate a maximum of ____________________________electrons.
(a) 2 (b) 6 (c) 10 (d) 14
 Hira Girls School & College Matta Swat
1st Assessment Class First Year
Chemistry
SECTION B
Time: 2 hr 40 min Marks: 40

Note: Attempt any 10 of the following.

I. Why actual yield is always less than theoretical yield?

II. What is the mass of 0.5 moles of NaCl?
III. Calculate the density of CH4 at 0 oC and 1 atm pressure.
IV. Why ice floats on the surface of water?
V. Which bond is stronger? A sigma or pi, why?
VI. Calculate the wavelength of electron moving with the speed of light.
VII. Define Hunds rule.
VIII. Explain Bond energy and bond length with examples.
IX. Differentiate between anisotropic and isotropic properties.
X. What are the different types of solids? Explain each shortly.
XI. What is viscosity? On which factors it depends.
XII. Discuss London dispersion forces and show that how it can effect properties of molecules.

SECTION C

Note: Attempt any three of the following questions. Marks: 27

I. (a) What are the main points of Valence Bond Theory?

(b) What is Orbital hybridization? Discuss its different types by giving examples.

II. Discuss the different types of quantum numbers in detail.

III. (a) What are limiting and Excess reactants?

(b) Differentiate between polymorphism, isomorphism and Allotropy.

IV. Write notes on

(a) Liquid Crystals
(b) Hydrogen Bonding
(c) Absolute Zero Temperature.