Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr. Elite & Target(C-120, C-IPL & IPL-IC) JEE-ADVANCE-2022_P1 Date: 05-Nov-23
Time: 09.30AM to 12.30PM RPTA-11 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 10 2 20 3 3 4 3 5 3 6 0

7 7 8 42 9 AC 10 ABCD 11 AB 12 AC

13 AD 14 ABCD 15 B 16 A 17 B 18 C

PHYSICS
19 95 20 2 21 1 22 12 23 80 24 12

25 20 26 6 27 BCD 28 BC 29 AB 30 BD

31 BC 32 ABCD 33 B 34 C 35 C 36 A

CHEMISTRY
37 2 38 19 39 8 40 5 41 2 42 2

43 2 44 2 45 ABC 46 ABC 47 BC 48 ABC

49 BCD 50 ABD 51 A 52 C 53 A 54 A
 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's

SOLUTIONS
MATHS
x2 y2
1.  1
25 16
b2 16
e 1 2 1
2

a 25
3
e 
5
foci are   ae,0  or  3,0 
Hence the given points F1 and F2 are foci of the ellipse
 PF1  PF2  2a  2.5  10
In an ellipse the sum of focal distances of a point is equal to length of major axis.
2. Let point  a, a  1 as the point of intersection of line and ellipse so,
a 2  a  1
2

  1  a 2  2  a 2  2a  1  4
4 2
3a  4a  2  0
2

If the roots of this equation are  and 

So, P  ,   1 and Q  ,   1
PQ 2  4r 2            
2 2

9
 
9 1
9r 2  2             4   16  24  20
4
2

2
2
 2
1 
3. Solving 4 x 2  y 2  5 with the line y  3  2 x we get the point of intersection as P  , 2 
2 
and Q 1,1
1  1
Tangent at  ,2  is 4 x    y.2  5 , Slope is -1
2  2
Tangent at 1,1 is 4 x.1  y.1  5 slope is -4
Slopes of the normals are 1,1 / 4 . If  be the angle between the normals, then
m  m2 1  1 / 4 3
tan   1  
1  m1m2 1  1 / 4 5
4. Putting (3, 5) in the equation of the ellipse, we get S1  ive and S2  0 so that the point
(3, 5) lies outside S1  0 and hence two tangents can be drawn through the point (3, 5). The
point (3, 5) lies on S2  0 and only one tangent can be drawn. Thus the total no. of
tangents passing through (3, 5) to the two ellipses is 2  1  3
(B) (C) The equation of two perpendicular chords drawn through each of the foci be
1
y  m  x  ae  and y   x  ae  Locus of their point of intersection P is obtained by
m

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
eliminating the variable m. Multiplying the equations of chords, we have
y    x 2  a 2e2  or x 2  y 2  a 2  b 2 .
x2 y2
Above represents the director circle of hyperbola 2  2  1 which we know is the locus
a b
of the point of intersection of perpendicular tangents QP and QR.
Hence QPR   / 2
 c
5. Parametric co-ordinates of xy  c 2 are  ct , 
 t
 c  2
Here  ct ,    6,   t  3
 t   3
6.

The eccentricity of rectangular hyperbola xy  c 2 is 2 . It is independent of c 2

 e 1  e  6   2  2  0
7. a1e1  a2e2 or a12e12  a22e22
2 2
 12   9  225
16  a         9a  7
 5  5 25
x2 y 2
8. H : 2  1
a 1
2
Length of latus rectum 
a
2 2
x y
E:  1
4 3
6 2 2
Length of latus rectum   3  3  a 
2 a 3
 9   3 
12  eH2  eE2   12  1    1     42
 4   4 
9. x  y  a ------(1)
2 2 2

ax by
  a 2  b2
cos  sin 

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
ax sec   by cos ec
 1 -----(2)
a 2  b2
From 1 and 2
2
2  ax sec   by cos ec 
x  y a 
2 2

 a 2  b2
QOR  90
Coefficient of x 2 +coefficient of y 2 =0
10. p  ,   y  mx  a 2 m 2  b 2    m  16m 2  9
  m   16m 2  9  2   2 m 2  2 m  16m 2  9
   2  16  m 2  2 m   2  9  0
m1m2  1
 2  2  25
b 2 a 1  e 
2 2

11. h  ac, k     a 1  e2 
a a

 h2 
k   a 1  ac 2     ac  
 a 
h  aa  k   x  a a  y
2 2

x2 y2
12.   1 Perpendicular to 2 x  y  0 m  2
4 3
1
x  2 y  k  0 m1 
2
1 1  1 1
y  mx  a 2 m 2  b 2  y  x  4   3   y  x  4  y  x  2
2 4  2 2
2y  x  4  x  2y  4  0  x  2y  4  0
1 1 1 1 1 1 e2  1
13.  1 2  1 1 2  2
f e f e
2 2
e12 e22 e e e
e2 e2
f e  2
2
 f  e  2
e 1 e 1

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's

1 e2
 e2  e2  1  e
f  f e  f   
 e 2  1  e2
 1
e2  1
3
3 3 3
 e2  9 1 8
1 F  e de  1 f  f  e   de  1 ede   2   2  2  2  4
3
e
 
3
f f  f e   de   e 2  1   9  1  0  8  2 2
1 e2  1  1
c2
14. x  y  a ; xy  c  y 
2 2 2 2

x
2
 c2 
Substitute in equation x     a 2  x 2  c 4  a 2 x 2  x 4  a 2 x 2  c 4  0
2

 x
x1 , x2 , x3 , x4 are roots a  s1  0
15. e1  e2  a, e1e2  2
A) b 2  4ac  0  a 2  4  2   0  a 2  8
16. A)

ae 1
sin 30   e
a 2
2 2
x y
B)  1
25 16

25  16 3
e 
25 5

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
2ac  6
3
2 a  6
5
a5
2a  2  5  10
17. Conceptual
18. P  3cos ,2sin     0, 2
No of rational  
Conceptual
PHYSICS
n  n  1
19. No of lines obtained 
2
n  n  1
  10  n  5
2
1 1  1  13.6  24
E  13.6  2  2   13.6 1  2  
 n1 n2   5  25
hc 12400  25
    95nm
E 13.6  24
20. let ground state energy be E1
E2 n  E1  204eV
E1
 E1  204eV  1
4n 2
E1 E1
  40.8eV   2 
4n 2 n 2
From (1) & (2) , n=2
1 1 
21. E photon  13.6    eV  3eV
 4 36 
E
 mv  momentum conserved 
c
E  3 1.6  1019 
v   1m / s
mc 1.67  1027   3 108 
1
22. We know that 
m
For ordinary hydrogen atom,
1  1 1  5R
 R 2  2   with hypothetical particle, required wavelength
  2 3  36
1 36 12
'   
3 5R 5 R

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
23. Path difference between rays reflected from upper and lower faces of layer  2t (for
normal incidence)
Path difference due to reflection from denser(upper) surface is  / 2
Condition of constructive interference (or maxima) is
  1.8
  1.5

2t   n
2
1   2n  1 
t  2n  1  , n  1,2,...
2 2 4
For least thickness n=1
 576
 tmin   nm  80nm
4 4  1.8
24. d sin   n
n  0.5 n
sin   
1.5 3
For n  0;  will have 2 values
For n  1;  will have 4 values
For n  2;  will have 4 values
For n  3;  will have 2 values
Total maximum observed =12

25. Let l be the distance between the two slits, at any instant, then
dl
It is given that v  ……….(i)
dt
l
The path difference reaching the point P from the slits is evidently x  y
D
d x y dl yv
Differentiating both sides with respect to time t, we get  .  ……….(ii)
dt D dt D
Since, a change in optical path difference of  , corresponds to one fringe, the number of
fringes crossing point P per unit time will be
3 3
 d x  1 yv 10  10  1  10
     20
 dt   D 5  107  1
I
26. 3 0  I 0Cos 2   / 2 
4


3
 
.x 
 3

x 
6

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's

d sin  
6
 
  sin 1  
 6d 

27. Any transition causing a photon to be emitted in the Balmer series must end at n  2 .
This must be followed by the transition from n  2 to n  1 , emitting a photon of energy
10.2eV , which correspond to a wavelength of about 122nm. This belongs to the Lyman
series
1 1
28. v , E 2 and r n 2
n n
29. rn  n r1
2

A   n 2 
ln  n   ln  n2   ln n 4  4ln  n 
 A1   r1 
4ln(n)

ln  An / A1 
n
30. Minima will be formed at O, if  SS1  S1O    SS2  S 2O   , n  1,2.....
2
For minimum value of d, n  1

  D2  d 2  D
4
 D 2  d 2   D  4
1/2

1/2
 d2  
D 1  2   D 
 D  4
1 d2 
D  D  D 
2 D2 4
d2 

2D 4
D
d  
2
D 2
   2 
d 

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
2 D 
31. 2  2 1D
d d

1  1 D
d
Nth order maxima of  2 coincides with 2nth order maxima of 1 . nth order minima of
 2 does not coincide with 2nth order maxima
32. x at O=d
7h 5
So, if d  , O will be a minima. If d  , O will be a maxima. If d  , O will be
2 2
minima and hence intensity is minimum. If d  4.8 then total 10 minima can be
observed on the screen, 5 above O and 5 below O, which correspond to
 3 5 7 9
x   ,  ,  ,  , 
2 2 2 2 2
13.6 2
33. E 2 z
n
34. A-PR, B-QS, C-QS, D-QR
mZ 2e 4 Z2
a) f  2 3 3  f  3
4 0 h n n
nh
b) L   Ln
2
e e
c) Magnetic moment: M  IA  vr 2  L
2r 2m
e  nh 
M    M n
2m  2 
ev e  mZe 2  Ze 2 Zh 2
d) I    2 2   I 3
2r 2  n h 0  20 nh n

35. The optical path difference the two waves arriving at P is

   SS2  S2 P    SS1  S1P    SS2  SS1    S2 P  S1P 

dy dy
 d sin 0  d sin   0 
D1 D2
d  20mm y0  2mm D2  2m , D1  1m , y  10m

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
20  2 20  10
   0.14mm
1000 2000
dy
For a bright fringe,   0  0.04mm
D1
' 0.04
n'    80
 0.5  103
Due to transparent paper, the change in optical path
    1 t  1.45  1 0.02  mm  0.009mm
 H  0.14mm  0.009mm  0.131mm
0.131
n  262
0.5  103
Due to transparent paper, the path difference at O
 H  1     1 t   0.04  0.009  mm  0.0131m
0.131
n  62
0.5  103
36. A-QRS, B-PQRS, C-QRS, D-PQRS
Intensity at a distance x from central maxima on screen is
2x
I  I 0  4 I 0  2 I 0 4 I 0 Cos

D
Where  
d
I max  9 I 0 and I min  I 0
a) At points where intensity is 1 / 9  th of maximum intensity, minima is formed.
Therefore, distance between such points is , 2, , 4,....
2x 1
b) At points where intensity is  3 / 9  th of maximum intensity cos 
 2
Hence distance between such points is
 2  2
, , ,   ,   ,2,.....
3 3 3 3
2x
c) cos 0

 
Hence distance between such points is , ,   ,2,.....
2 2
2x 1
d) cos 
 2
 2  2
Hence distance between such points is , , ,   ,   ,2,.....
3 3 3 3

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's

CHEMISTRY
Vf
37. w  2.303nRT log
Vi
25
w  2.303  0.5  8.314  300l og
5
w  2  103 J  2 KJ
v 10v
38. S  2.303nR log 2  2.303  1  8.314  log  19.15JK 1
v1 v
39. V  nCvT
V 5000 5000
Cv     8.33
nT 3  200 600
40. A  O2  H1  10 KCal
B  O2  H 2  15 KCal
3 A  xB  105
3  10  x  15  105
x5
NHCOCHCl2
O2 N CHOH CH
CH 2OH
41.
OH

CH 3
H 3C
42. Cl
43. In Kjeldahl method nitrogen is estimated in the form of ammonia. Compounds which
fails to liberate ammonia fails to give Kjeldahl method.
44. Oxygen, Carbon
45. Temperature remains constant in isothermal process.
For an ideal gas during an isothermal expansion internal energy as well as enthalpy
remains same.
46. IUPAC sign convention
Work done by the system = -ve
Work done on the system = +ve
Heat absorbed by the system = +ve
Heat released from the system = -ve
47. H  U  nRT
n  2  4  2
H  U  2  RT  2  8.314  300J  2  R  300  600 R

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 Sri Chaitanya IIT Academy 05-11-23_Sr.Elite (C-120, C-IPL, IPL-IC)_Jee Adv(2022-P1)_RPTA-11_Paper-1_Key & Sol's
48. Non – narcotic analgesic
49. Penicillin is a bactericidal antibiotic.
50. Non-narcotic drug
51.
List I(Reaction) List II(Representation)

A) Q) Enthalpy of formation

B) S) Enthalpy of hydration

C) R) Enthalpy of solution

D) P) Enthalpy of combustion
52.
A B C D
PRS RS T PQT
53. Lucas – alcohols
FeCl3 - phenols
Tollens – Aldehydes
Hinsberg - Amines
54. A-R, B-P, C-S, D-Q

Sec : Sr. Elite(C-120, C-IPL, IPL-IC) Page 12