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INTERCOM S.R.L. Revision nr.

5
Dated 06/04/2023
Printed on 30/10/2023
Page n. 12 / /12
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Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 16.
2. Physical
4.
7.
8.
9.
11.
12.
14.Hazards
First
Handling
Exposure
Toxicological
Ecological
Transport
Otheraidinformation ...
identification
measures
and
and ... //properties
controls/personal
information
information
chemical
storage
information ...
>>
...
>>...
/...
/ >>
>>
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...
>>/ >> ... / >> ... / >>
protection
14.2.
4.2.
7.2.
Hazard
Auto-ignition
Information
REPRODUCTIVE
mixture
21. Most
Conditions
UN proper
Delegated
Skin important
pictograms:
of temperature
for
shippingsafe
symptoms
5-chloro-2-methyl-1,2-thiazol-3
Corr. not Regulation
1C available
TOXICITY storage,
name
(UE)and
mixture Skin
including
ofeffects,
2021/849 Safety Data Sheet
corrosion,
(XVIIany
(2H)both incompatibilities
Atp.
-onecategory
acute
--5-chloro-2-methyl-1,2-thiazol-3 notand
CLP)
and available
1C delayed (2H) -one(2H)
2-methyl-1,2-thiazol-3 and-one 2-methyl-1,2-thiazol-3 (2H) -one
Predicted
Decomposition
LC50 Eye - forDam. no-effect
Fish 1 temperature concentration Serious - PNEC eye damage,not category
0,19 available
mg/l/96h 1
According to Annex II to REACH - Regulation 2020/878 and to Annex II to UK REACH
Signal
pH
-not
Specific
Store
Delayed
Does
EC50 The Normal
applicable
Skin -words:
Merck
not
onlyfor
Sens. value
information
and
meet
in
Crustacea
Index.
the
immediate
the
1A inclassification
-fresh
originalon10th water
symptoms
effects
container.
Editionas Skin
criteria
and
well sensitization,
Store
-- effects
as
forthe
chronic
thiscontainers
caused
hazard category
7
effects
0,16
byclass
sealed,
the
from 1Ashort
mg/l/48h
product in aandare
welllong-term
unknown.
ventilatedexposure place, away from direct 0,00339
sunlight. Store mg/l in a cool and well
Kinematic
ventilated
-EC50 Normal
Handling
Aquatic viscosity
- for place,value
Algae
Chemical
Acute /inAquatic
keep 1marine
Safety
far away waterfrom
Plants Hazardous sources toofthe heat,aquatic
not
0,0273
naked available
environment,
flames and acute
mg/l/72h sparkstoxicity,
and other category
sources 1 of ignition.0,00339 mg/l
Keep containers away from any
4.3.-Chronic
14.3.Hazard
Dynamic
incompatible
Information
Adverse Indication
INRSTransport
Normal
Aquatic -statements:
viscosity
NOEC
Fiche value
effectsnotofhazard
any
materials,for
Toxicologique
Chronic for
available
on immediate
Fish fresh
sexual1class(es)
seewater
function
section medical
Hazardous
sediment
(toxicologicaland10 for attention
fertility to the aquatic
details.
sheet) and1000
0,02 special
environment,
mPas treatment
mg/l chronic
needed toxicity, category 1 0,027 mg/kg/d
SECTION
Solubility
-Chronic PattyNormal
EUH208
H310 - Industrial
NOEC 1. for
value Identification
for
Hygiene
Algae marine Contains:
water
/ Aquatic
and Fatal
Toxicology ofinthe
sediment
Plants contact substance/mixture
with 0,0035
mixture not
skin. ofavailable and of the company/undertaking
5-chloro-2-methyl-1,2-thiazol-3
mg/l (2H) -one and 0,027 2-methyl-1,2-thiazol-3mg/kg/d (2H) -one
7.3.-not
Partition
Interactive
Information Specific
N.I. Normal
applicable
H330 Saxcoefficient:
end
value
- effects
Dangerous use(s)
not available for n-octanol/water
water,
propertiesintermittentFatal if release
of Industrial inhaled. Materials-7, not available
1,2-Benzisothiazol-3 1989 Edition (2H) -one 0,00339 mg/l
1.1.-polyurethane
Vapour Product
IFA Normal
H301GESTIS identifier
pressure
value dispersion
website of STP microorganisms May produce Toxic if swallowed. an allergic reaction. 23 hPa at 20°C 0,23 mg/l
14.4. Density
Information
Adverse
-LC50 ECHAPacking
Normal
H314 - for and/or
websitevalue
effects
Fish group
not relative
fordevelopment
available
on thedensity
terrestrial Causes
ofcompartment severe skin burns
the offspring 1 100 and
> g/cm3
mg/l/96h eye damage. 0,01 mg/kg/d
SECTIONProduct
Relative
-EC50
Health Database
H318 - -forname
vapour 5.SDS
Crustacea
Derivedof Firefighting
density models for
no-effect level measures
Causes
- DNELserious
chemicals -/ Ministry
DMEL Ecostick®
eyeofdamage.
not
>Health
100 and1816B
available
mg/l/48h ISS (Istituto Superiore di Sanità) - Italy
5.1. Precautionary
Particle
not
ACUTE
Information applicable
H317
Extinguishing characteristics
TOXICITY notstatements:
available
media Effects May on-- cause
consumers an allergic not skin applicable
reaction. Effects on workers
SECTION
1.2.
12.2. Relevant
Route ofidentified
Persistence
H400 8.
exposureExposure usesAcute
and degradability of controls/personal
theVery substance
toxic Acute or mixture
to aquatic life. protection
and uses advised
Chronic Chronic against Acute local Acute Chronic Chronic
9.2.
14.5.
8.1.Effects
ATE
SUITABLE Other
Environmental
H410
Control information
(Inhalation
on or via-lactation
parameters
EXTINGUISHING hazardsof
vapours) local the Very
mixture:
EQUIPMENT toxic systemic
to aquatic life with local >long lastingsystemic
20 mg/l effects. systemic local systemic
Intended
ATE
Note Oral(Oral)
for use
users:of the mixture: 0,110 Adhesive >2000 mg/kg 0,090
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
2.3.The not
9.2.1.
ATE
Information
BENZYL
UNSUITABLE
Regulatory Other applicable hazards
information
(Dermal)
Information
ALCOHOLnotof
References:available
contained
the with
EXTINGUISHING mixture:
regard in the presentmg/kg
to physical
EQUIPMENT sheet bw/d
hazard areclasses
based on >2000 our own mg/kg mg/kg bw/d
knowledge on the date of the last version. Users must verify the
Identified
Rapidly
LEGEND:
suitability Inhalation Uses
degradable
and thoroughness 0,040
of provided information Industrial
according 0,020 to each specific use Professional
of the 0,040
product. Consumer
0,020
None in particular.
14.6. Adhesive
Information Special precautions
not available for mg/m3
user mg/m3 -
On
-STOT
This
DEU ADR: thedocument
-European
basis
SINGLE of must EXPOSURE
Agreementnot be
data,
Deutschland regarded
concerning
the product as athe guarantee
does
carriage
Technischennot contain
on
of Dangerous
any
Regeln any
specific PBT
für goods
product
or vPvB by property.
Gefahrstoffe Road (TRGSmg/m3
in percentage 900)≥ -thanListe0,1%.der Arbeitsplatzgrenzwerte mg/m3 und
mixture
-
The ATE: use
5.2. Special hazards arising from the substance Acute
BENZYL
ofof 5-chloro-2-methyl-1,2-thiazol-3
this
Toxicityproduct
ALCOHOL Estimate
is not subject to our(2H) direct
-one control;
and
or mixture
Kurzzeitwerte. 2-methyl-1,2-thiazol-3
MAK- und BAT-Werte-Liste 2020, Ständige Senatskommission zurthe
therefore, users must, (2H) under
-one their own responsibility, comply with current health
Prüfung
1.3.and -not
The
Legend:
9.2.2.
Does
Entirely Details
CAS: applicable
safety
product
not
Other oflaws
Chemical
LD50
degradable
meet the
safety
does supplier
(Dermal):
theand
Abstract
not
classification
characteristics
regulations.
contain of the
Service safety
substances
criteria
TheNumber data
producer
for with
thissheet
endocrine
is
hazardrelieved class disrupting
from 2000 any mg/kg
liability
properties Rabbit
arisingin concentration
from improper
gesundheitsschädlicher Arbeitsstoffe, Mitteilung 56 ≥ uses.
0.1%.
-(C)
Provide
HAZARDS CE50: = CEILING LD50
Effective
appointed
CAUSED (Oral):; concentration
staff
INHALBYwith = adequate
EXPOSURE Inhalable
(required Fraction
training
IN to induce
THE on; how
EVENT RESP
a 50% to use
OF =effect)
FIRERespirable
chemical
1230 mg/kg products.
Fraction
Rat ; THORA = Thoracic Fraction.
14.7. Name
VOC
VND
Target
-polyurethane CE: Maritime
(Directive
=Identifier
organs
hazard
LC50 transport
2010/75/EU)
dispersion
(Inhalation
identified
in ESIS in bulk
(European
but
vapours):no according
DNEL/PNEC
archive ofto IMO
existing
available INTERCOM
instruments
2,89
substances)
; %NEA > -4,1
= S.R.L.
28,92
nomg/l/4h
exposure Rat g/litre
expected ; NPI = no hazard identified ; LOW = low hazard
SECTION Do not breathe
Full
;Threshold
-NOT
CALCULATION CLP:
MED address
rapidly
Regulation
STA
= medium 3. Composition/information
combustion
degradable
(Inhalation
METHODS
(EC)
hazard 1272/2008
vapours):
products.
;FOR HIGH = high hazard. via
CLASSIFICATION ondella ingredients
BENZYL ALCOHOL
11Gora, 13
mg/l estimate from table 3.1.2 of Annex I of the CLP
SECTION Limit
10. Value
Stability and reactivity 50025 from Montespertoli
District
-Information and Country relevant (Florence)
3.1.Chemical
5.3. DNEL:Type Derived
Advice
Substances and
for not physical
available
No
firefighters Effect hazards:
Country Level Product
TWA/8hclassification derives(figure STEL/15min criteria
used forestablished
calculationby of the
the CLP
Remarks acute / Regulation,
toxicity
Observations estimate
AnnexofI,the Partmixture)
2. The data for
8.2.
12.3. -
evaluation Exposure
EmS:Bioaccumulative
Emergency
of controls
chemical-physical potential
Schedule properties are reported in section 9. Italy
10.1. Reactivity mg/m3 ppm mg/m3 ppm
-Route
Health GHS: ofhazards:
Globally
1,2-Benzisothiazol-3
exposure Harmonized
Product Tel. labeling +39 as 0571per671096
SECTION Information
GENERAL AGW not relevant
15.
INFORMATION RegulatoryDEUclassification System
(2H) -one 22ofisclassification
information
based on 5 calculation
and methods
44 of chemicals 10 Annex I ofSKIN CLP, Part 3, unless 11 determined otherwise in Section
-As
11. IATA the DGR:
use
LD50 ofInternational
(Dermal):
adequate technical
Air Transport equipment Association must Fax take
always
Dangerous 2000Goods
priority+39
mg/kg 0571
Regulation
over 671151protective equipment, make sure that the workplace is
personal
Predicted
Use jets
There areofno no-effect
waterparticular to cool concentration
risks
the of containers
reaction - PNEC with
to preventother substances
product decomposition in normal conditions and the development
of use. of substances potentially hazardous for
e-mail address of the competent person
3.2.Environmentalwell
Information
-BENZYL
health. IC50: aired
Mixtures
Normal Immobilization
LD50
ALCOHOL
Alwaysthrough
not(Oral):
value hazards:
available
wear ineffective
fresh
fullConcentration
Product
water
fire local
prevention aspiration.
classification
50% gear. Collect is based on calculation
extinguishing 1150 water mg/kg methods
to prevent as per Annex
it from I of CLP,
draining into Part
1,01
the 4, unless
sewer determined
mg/l
system. Disposeotherwise
of in
responsible
When
Partition
-
Section IMDG: choosing
12. for the
International
coefficient: personalSafety DataCode
n-octanol/water
Maritimeprotective Sheet equipment,
forregulations/legislation
dangerous askgoods sds@intercomsas.it
your
1,1
15.1. contaminated
BENZYL Safety,
Normal health
value
ALCOHOL water inand marine
used environmental
for water
extinction and the remains ofchemical
the fire substance
specific
according for to supplier
the substance
applicable for advice. or mixture 0,101
regulations. mg/l
Personal
-STOT
Changes
Contains:
SPECIAL IMO: Normal -International
Decomposes REPEATED
mixture
protective
to previous
value
PROTECTIVE ofat
for5-chloro-2-methyl-1,2-thiazol-3
Maritime
equipment
EXPOSURE
review:
fresh
temperatures water
EQUIPMENT Organization
must
sediment
above beFOR CE marked, (2H)
870°C/1598°F.Possibility
FIRE-FIGHTERS showing
-one and that2-methyl-1,2-thiazol-3
it complies
of explosion.with applicable (2H) -one standards. 5,27 mg/kg/d
1.4.The HAND
-mixture Emergency
INDEX: following
PROTECTION
LD50
of Identifier telephone
5-chloro-2-methyl-1,2-thiazol-3
sections
(Dermal): number
10.2. Seveso
Normal Chemical
Normal Category
fire value stability
fighting -inDirective
for Annex
were
marine
clothing VI
modified:
water offire
2012/18/EU:
i.e. CLP kit (BS(2H)
sediment EN -one469),and gloves 2-methyl-1,2-thiazol-3
(BS660
None EN mg/kg
659) and boots (2H) -one (HO specification A29 0,527
and A30) inmg/kg/d combination with
Protect
Does
-Partition
02
Identification
self-contained LC50:
/Normal
03not /hands
STA
Lethal
04
coefficient:
meet / (Dermal):
value07with
Concentration
the
open/ for
08classification
category
n-octanol/water
/water,
11 / x12
circuit =III/50%
16.
work
intermittent
positiveConc. criteria gloves for this
% release
pressure (see hazard
standard
compressed 0,75class EN
Classification Log
air 50,001
374).
Kow (EC)
breathing mg/kg estimate
1272/2008
apparatus (BS from
(CLP)
EN 137).table 3.1.2 of Annex 2,3 I of the mg/l CLP
For
-The LD50: urgent
followingLethal inquiries
should
dose refer
50% be to
considered AUSTRIA Vergiftunginformationszentrale acute+43 1 406 43and 43 permeability.
Restrictions
The Normal
product value
relating
is stable of STP toin the microorganisms
normal product conditionsorwhencontained choosing
of andwork
use substances storage. glove (figure
material:
pursuant used compatibility,
for calculation
to Annex XVII todegradation,
ECof theRegulation failure
toxicity
39timeestimate
1907/2006 of
mg/lthe mixture)
12.4. The
-Target OEL:Mobility
work organs
Occupational
LD50 in
gloves' soil
(Oral): resistance
Exposure to Level
chemical agents should BELGIUM
be checked
457 Centre
mg/kg
before Antipoisons-Antigifcentrum
use, as it can be unpredictable. +32The 30245245
gloves'
BENZYL Product
NormalALCOHOL value for the terrestrial compartment 0,456 mg/kg/dtime depends on
wear
SECTION
10.3. -the
CAS
Health PBT: durationPersistent
Possibility
Point - Derived 6.
and ofAccidental
type
bioaccumulative
hazardous
100-51-6
no-effect of use.40 release
reactions
level -and
DNEL 1 toxic
≤ x /<DMEL measures
as5 REACH BULGARIA
Regulation National Toxicology Centre at National Clinical Toxicology Centre +359
Acute Tox. 4 H302, Acute Tox. 4 H332, Eye Irrit. 2 H319
SKIN
-Information PEC: PROTECTION
Predicted
polyurethane
not available
environmental
dispersion Concentration 2 9154 233
6.1.EC -Wear
Contained
Personal
PEL: category
Predicted
LD50
substance202-859-9
precautions,
(Oral):
I603-057-00-5
professional
exposure
Effects
protective on equipment
consumers and emergency
CROTIA Poison
Oral: 1230 mg/kg, Effects
LD50 procedures
Control Centre Zagreb
on workers
STA Inhalation vapours: 11 mg/l
+385 1 2348342EN ISO 20344). Wash body
INDEX
No Route
Point
hazardous of exposure reactions arelevel
Acute
75 long-sleeved
foreseeable Acute overallsconditions
in normal and safety >
Chronicoffootwear
2000
use and mg/kg (see
Chronic
storage.Regulation 2016/425
Acute local and standardAcute Chronic Chronic
with
-Route PNEC: soap ofLC50Predicted
exposure
and (Inhalation
water noafter effectmists/powders):
removing
concentration protective clothing. CECH REPUBLIC > 2,676 mg/l/4h Toxicological Information Centre + 420224919 293
REACH
Block Reg.
the leakage 01-2119492630-38
if and
there local
is1907/2006
noassessment
hazard. systemic local systemic systemic local systemic
12.5. -EYE Results
REACH: PROTECTION of PBT
Regulation (EC) vPvB DENMARK Poison Information Centre n +45 82 12 12 12
Regulation
BENZYL Oral
1,2-Benzisothiazol-3
Wear suitable (EU)
ALCOHOL 2019/1148
protective (2H) - on
-one
equipment the marketing 20
(including and use of
personal explosives
protective precursors
equipment 4 referred to under Section 8 of the safety data sheet) to prevent
Wear
SKIN
-Information
RID: CORROSION
airtight
Regulation not protective
available
concerning
/ IRRITATION
goggles thehydrobromic
(see
international ESTONIA Estonian Poison Information centre +372 626 93 90
CAS
not
any applicable
May react
contamination dangerously
2634-33-5
of skin, with:
eyesthe and 0standard
≤ mg/kg
personal x < 0,05 transport
EN
bw/d
clothing.
166).
acid,iron,oxidising of dangerous
These Acute
indications
goods
agents,sulphuric
Tox. mg/kg by train
4apply
H302, bw/d
foracid.Risk
Eye
bothDam. of1explosion
processing H318,staff on
Skinand contact
Irrit. with:
2 H315, phosphorus
SkininSens. 1 H317,
RESPIRATORY
-On TLV: the Threshold
basis of available
PROTECTION
Limit Value data, product does not FINLAND
contain any Finnish
PBT or Poison
vPvB in Information
percentage ≥ Centre
than 0,1%.+358 9those
471977 involved emergency
procedures. Inhalation
trichloride. 27 Aquatic Acute 5,4 1 H400 M=1, Aquatic Chronic 110 2 H411 22
10.4. If
Does
-ASPIRATION
EC TLV
the
Substances threshold
not
CEILING:
Conditions meet inHAZARD
the
value
Concentration
Candidate
to classification
avoid
220-120-9 (e.g.List TLV-TWA) that
criteria
(Art. should
59 isforexceeded
REACH)
mg/m3not
thisbe hazard forFRANCE
exceeded the
class substance
during Centre
Skin Sens. any Antipoison
ortime
one
mg/m3 of occupational
1 H317:
et de Toxicovigilance
the ≥substances
0,05% exposure. present inmg/m3 thedeproduct,
Angersuse +33 a2 41 35
mask 33a30
with
mg/m3 type
12.6. -ATWA: Endocrine
filter whose
Time-weighted disrupting
class (1, average
2 or properties
3) must exposure be chosen limit according HUNGARY to the Health
limit of use Toxicology
concentration. Information
(see Service
standard EN+36 80 20In11
14387). the99presence of gases
6.2.-Does INDEX
On Skin
the
Environmental basis of available
613-088-00-6
precautions data, the product 20 does not contain any
LD50 SVHCOral: in
4 percentage
1150 ≥ than 0,1%. 40 8
or
SERIOUS
TWAvapours not IRELAND Poison Information Centrefumes, of Ireland +353
etc.) 1 809 2166filters are required.
None
mixture inSTEL: meet
EYEof
particular.
of Short-term
various
the
DAMAGE classification
However kinds
5-chloro-2-methyl-1,2-thiazol-3 exposure
/ IRRITATION
and/or
the usual criteria
limit
gases for orthis
mg/kg
precautions vapours
(2H)hazard
bw/d used
-one containing
class
for chemical
and particulate (aerosol
mg/kg
products
2-methyl-1,2-thiazol-3 bw/dsprays,
should be respected.
(2H) -one mists,mg/kg combined mg/kg
Respiratory
-BasedVOC: on Volatile
the protection
available
organic devices
Compounds
data, themust product be useddoes if not
the LATVIA
contain
technical Valsts Toksikologijas
substances
measures listed
adopted in the
are main centres
not suitable
European + for
371 67042473
lists
restricting
of potential
CAS
Substances
The product subject
must 55965-84-9
not to authorisation
penetrate into (Annex
0
the ≤ x
sewer< XIV
0,0015 REACH)
system or come Acute into Tox. 2 H310,
contact with Acute water
surface Tox. 2orH330,ground bw/d
Acute
water. Tox.worker's
the 3orH301,
suspectedexposure endocrine
Skin Corr. to 1C
bw/d the
11.2. Information
threshold
Does
-disruptors
vPvB: not Verymeet
values
with on
Persistent other
environmental
the considered.
classification
and hazards
veryThe
effects
criteria
Bioaccumulative
protection
under for thisevaluation.
provided
hazard as forLITHUANIA
byclass
REACH
masks Lithuania
isRegulation
in casePoison
any Dam. limited. Control and Information Bureau +370 5 236 20 52
None
BENZYL ALCOHOL H314, Eye 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=10,
-If WGK:
the substance
Water hazard
considered NORGE Giftinformasjonen : corresponding
22 59 13 00 (døgnåpen)
6.3. Avoid
Methods exposure
and materialto: classes
air,sources
for
is (German).
odourless
containmentof heat,naked or its olfactoryflames. threshold
andbreathing
cleaning up Aquatic is higher
Chronic than1the H410 M=10 TLV-TWA and in the case of an
12.7. Other
emergency,
RESPIRATORY
Based on adverse
the wearavailable
OR effects
open-circuit
SKIN data, SENSITISATION
the
compressed
product doesair not PORTUGAL
contain apparatus
substances CIAV
(in Centro
compliance
listed in thedewithInformacao
main standard
European Antivelenos
ENlists137)of or +351or808
potential
external 250 143
air-intake
suspected breathing
endocrine
10.5. ECIncompatible
Substances subject materials
611-341-5 to exportation reporting pursuant to 1,2-Benzisothiazol-3 RegulationSkin Sens. (EU) 649/2012:
1A H317: (2H) ≥-one 0,0015%
apparatus
disruptors
GENERAL with
(in
BIBLIOGRAPHY
compliance
human health with effects
standard under EN evaluation.
138). For SLOVAKIA
a correct National
choice of Toxicological
respiratory protection Information
device, Center
see standard+421EN 2 54 529.774 166
INDEX the no-effect
Predicted
None
Collect leaked concentration
product into a CONTROLS suitable- PNEC STA Oral: 100 mg/kg, of the STA Dermal: 50,001 mg/kg, STA section
Inhalation
ENVIRONMENTAL
May
Information
1. Regulation
produce
Normal not
value an
(EC) available
allergic
in1907/2006
EXPOSURE
fresh reaction.
water(REACH) ofcontainer.
the European Evaluate
POLAND ParliamenttheInformacja
compatibility toksykogiczna container to be
w Polsce used,
+48by
403
42checking
631 47 24
mg/l
(czynna 10. 7:00-15:00)
Absorb the
SECTION BENZYL
remainder
The
Contains:
2. Regulation
emissions
ALCOHOL
with12. (EC)inertEcological
generated absorbent information
material. SPAIN
mists/powders: 0,051 mg/l
Istituto Nacional de Toxicologia +34 156 20420
Substances
Make Normal
Incompatible
sure value
thesubject in1272/2008
with:
leakage marine
tosulphuric
the by
siteRotterdam
manufacturing
water (CLP)
is(IIwellacid,oxidising
aired.
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the European
processes, Parliament
substances,aluminium.
Contaminated
including those generated by ventilation equipment,
material should be disposed of in compliance
should bemg/l
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checked to ensure
setin forth in point 08454
13.
compliance
mixture
3. Regulation of 5-chloro-2-methyl-1,2-thiazol-3
with (EU) environmental
2020/878 standards.
Annex of REACH
(2H) -one ENGLAND
Regulation)
and NHS Direct
2-methyl-1,2-thiazol-3 in(2H)England
-one or Wales 0845 46 or NHS 24 Scotland
10.6.
SECTION The
None
Use Hazardous
Normal
full
this wordingvalue
product13. decomposition
offor hazard
Disposal
according fresh water
(H)to phrases
products
sediment
considerations
good working is given in
practices. section Avoid 16 of the
littering. sheet.
Inform the competent authorities, 0,0499
should the mg/kg/d
product reach waterways or
1,2-Benzisothiazol-3
4. Regulation (EC) 24 24 24 (UK only)
6.4.contaminate Normal value
Reference soil
to orfor790/2009
other
(2H) -one
marine
vegetation.
sections
(I Atp.sediment
water CLP) of the European Parliament 0,00499 mg/kg/d
5. Regulation (EU) THAILAND Ramathibodi Poison Center Hotline: 1367 Line ID: @rpc1367
13.1. Substances
Waste
Normaltreatment
Information value
subject
not for286/2011
available to
water,
methods
the Stockholm (II Atp. CLP)
intermittent of the European
Convention:
release Parliament 0,0011 mg/l
12.1. Respiratory
6. Regulation
Contains:
None Toxicity
Normal sensitization
(EU)
polyurethane
value of 618/2012
STP dispersion (III Atp.
microorganisms in CLP)
water of the European Parliament 0,00103 mg/l
SECTION Any
7. information
Regulation 9. (EU)Physical
on 487/2013
personal protection and
(IV Atp. chemical
CLP) andof disposal
the properties
is givenParliament
European in sections 8 and 13.
SECTION
SECTION
Reuse, Normal
Information
8. Regulation
when 2.
value
11.
not (EU)
Hazards
possible.for theNeat
Toxicological
available944/2013level
identification
terrestrialproduct
(V Atp.
compartment
residues
information
CLP)
should be considered special non-hazardous waste. 3 mg/kg/d
Healthcare
Disposal
Health must
- Derived controlsbe performed
no-effect through - DNEL an /ofDMEL
the European
authorised waste management Parliament firm, in compliance with national and local regulations.
SECTION
SECTION
2.1.
9.1. 9. Regulation
Classification
Information
Information
BENZYL
CONTAMINATED ALCOHOL4.
7.
not (EU)
onFirst
Handling
ofbasic
available theaid
605/2014
PACKAGING substance
physical measures
(VI
Effectsand Atp. and
on or CLP)
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chemical
consumers of the European
properties Parliament
In
Skin
10. the absence
Regulation
sensitization of
(EU) experimental
2015/1221 data
(VII for
Atp. the
CLP) product
of the itself,
European health hazards are evaluatedEffects
Parliament according on workers
to the properties of the substances it
4.1. LC50 Route
Contaminated
Description
contains, - for of
Fish
using exposure
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of the firstcriteriaaid must Acute
measures
specified be recovered
in theAcute or
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mg/l/96h
in compliance
for Chronic
with
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waste local
management Acute regulations. Chronic Chronic
7.1.The
15.2. 11. Regulation
Precautions
Properties
EC50 product
Chemical- for Crustacea (EU)
for safe
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as hazardous Atp. CLP) of the
pursuant to
systemic European
Value
230 the Parliament
provisions setsystemic
local
mg/l/48h forth in EC RegulationInformation 1272/2008 (CLP). local
systemic systemic
It is therefore
Information
12. Regulation necessary
not (EU) available 2016/1179 to take into
(IX Atp. account
CLP) the concentration of the individual hazardous substances indicated in section 3, to evaluate the
However,
Appearance
EC50 Inhalation
- for since
Algae the
/ product
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liquid
650 mg/l/72hin concentrations 1,2 such as to be declared in section no. 3, it requires 6,81 a safety data
SECTION EYES:
toxicological
13.
Keep
sheet
Colour
A Regulation
chemical away Remove 14.effects
(EU)
from heat,
with appropriate
safety Transport
contact
of
assessment
exposure
2017/776
sparks lenses,
information, (X
and information
to
hasnaked
if
Atp.the present.
product.
CLP)
compliant
not been flames; Wash
to (EU)
performed do not immediately
smoke
Regulation
white for
with
or2020/878.
use matches
the preparation/for
plenty
mg/m3 the
of water
or substances for
lighters. Without at least
indicated
30-60
adequate minutes,
in sectionventilation,
3.
opening the
vapours may eyelids
mg/m3
fully. Get
medical
GERM
14. Regulation
accumulate advice/attention.
CELL at MUTAGENICITY
(EU)
ground 2018/669
level and, (XI ifAtp.
ignited, CLP) catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
11.1. Odour
SKIN:
The Skin
1,2-Benzisothiazol-3
Information
product
Remove is not ontransfer
contaminated (2H) -one
hazard
dangerous classesclothing.
under as defined
current
Rinse inwith
provisions
skin characteristic
Regulation
aofshower
the Code (EC) ofNo
immediately. 0,345Get medical
1272/2008
International Carriage advice/attention.
of Dangerous Goods by Road (ADR) 0,966
and stirring
by Rail
15.
When
Hazard
Melting
LC50 Regulation
-ofperforming
classification
point
for Fish (EU)
/ freezing 2019/521
and point operations
indication: (XII Atp. CLP)
involving large
-- 0,74 containers,
not available
mg/l/96h connect to an earthing
mg/kg bw/d system and wear antistatic footwear. Vigorousmg/kg
SECTION INGESTION:
(RID),
Does
16.
and
Initial
EC50 Delegated
flownot
boiling
the
meet
through16.
- for Crustacea Other
International
Have
Regulation
pointthe the the
classification
tubes information
subject
Maritime
(UE)and drink
2018/1480
criteria
equipmentDangerous as
for much
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this
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risk explicitly
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17. Regulation by toxicokinetics,
a doctor.
(EU) 2019/1148
fires and explosions, never use compressed air whennot mechanism of action and other
handling. informationOpen containers with caution as they may be pressurised. Do not eat, drink or
14.1. Flammability
UN
INHALATION:
Text ofnumber
hazarduse. (H)or indications
Get ID number
medical advice/attention
mentioned in section
immediately.
2-3 available
ofenvironment.
theRemove
sheet: victim to fresh air, away from the accident scene. If the subject stops
2.2.18. CARCINOGENICITY
smoke
Label
Lower Delegatedduring
elements
explosive Regulation
limit Avoid (UE)
leakage 2020/217
of the product (XIV Atp. intoCLP)the
not available
breathing,
Information
19. Delegated administer
notRegulation
available artificial
(UE)respiration.
2020/1182Take (XV Atp. suitable CLP) precautions for rescue workers.
Upper
not explosive
applicable
Acute Tox.Regulation2 limit Acute toxicity, category not 2available
Does
20.
Flash Delegated
not meet
pointTox. the classification (UE) 2021/643
criteria for(XVIthis Atp.
hazard CLP) class
not 3applicable
Information
Acute on likely3 routes of exposure Acute toxicity, category

EPY 11.2.0 - SDS 1004.14


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Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 2. Hazards identification ... / >>


Hazard pictograms: --

Signal words: --

Hazard statements:
EUH208 Contains: mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one
1,2-Benzisothiazol-3 (2H) -one
May produce an allergic reaction.

Precautionary statements: --

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.

SECTION 3. Composition/information on ingredients


3.1. Substances

Information not relevant

3.2. Mixtures

Contains:

Identification x = Conc. % Classification (EC) 1272/2008 (CLP)

BENZYL ALCOHOL
CAS 100-51-6 1≤x< 5 Acute Tox. 4 H302, Acute Tox. 4 H332, Eye Irrit. 2 H319
EC 202-859-9 LD50 Oral: 1230 mg/kg, STA Inhalation vapours: 11 mg/l
INDEX 603-057-00-5
REACH Reg. 01-2119492630-38
1,2-Benzisothiazol-3 (2H) -one
CAS 2634-33-5 0 ≤ x < 0,05 Acute Tox. 4 H302, Eye Dam. 1 H318, Skin Irrit. 2 H315, Skin Sens. 1 H317,
Aquatic Acute 1 H400 M=1, Aquatic Chronic 2 H411
EC 220-120-9 Skin Sens. 1 H317: ≥ 0,05%
INDEX 613-088-00-6 LD50 Oral: 1150
mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one
CAS 55965-84-9 0 ≤ x < 0,0015 Acute Tox. 2 H310, Acute Tox. 2 H330, Acute Tox. 3 H301, Skin Corr. 1C
H314, Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=10,
Aquatic Chronic 1 H410 M=10
EC 611-341-5 Skin Sens. 1A H317: ≥ 0,0015%
INDEX STA Oral: 100 mg/kg, STA Dermal: 50,001 mg/kg, STA Inhalation
mists/powders: 0,051 mg/l

The full wording of hazard (H) phrases is given in section 16 of the sheet.

Contains: polyurethane dispersion in water

SECTION 4. First aid measures


4.1. Description of first aid measures

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

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SECTION 4. First aid measures ... / >>


4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

SECTION 5. Firefighting measures


5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT


The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE


Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

SECTION 6. Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.


Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent
any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the
remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage


7.1. Precautions for safe handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous stirring
and flow through the tubes and equipment may cause the formation and accumulation of electrostatic charges. In order to avoid the risk of
fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised. Do not eat, drink or
smoke during use. Avoid leakage of the product into the environment.

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SECTION 7. Handling and storage ... / >>


7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a cool and well
ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any
incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

SECTION 8. Exposure controls/personal protection


8.1. Control parameters

Regulatory References:

DEU Deutschland Technischen Regeln für Gefahrstoffe (TRGS 900) - Liste der Arbeitsplatzgrenzwerte und
Kurzzeitwerte. MAK- und BAT-Werte-Liste 2020, Ständige Senatskommission zur Prüfung
gesundheitsschädlicher Arbeitsstoffe, Mitteilung 56

BENZYL ALCOHOL
Threshold Limit Value
Type Country TWA/8h STEL/15min Remarks / Observations
mg/m3 ppm mg/m3 ppm
AGW DEU 22 5 44 10 SKIN 11
Predicted no-effect concentration - PNEC
Normal value in fresh water 1,01 mg/l
Normal value in marine water 0,101 mg/l
Normal value for fresh water sediment 5,27 mg/kg/d
Normal value for marine water sediment 0,527 mg/kg/d
Normal value for water, intermittent release 2,3 mg/l
Normal value of STP microorganisms 39 mg/l
Normal value for the terrestrial compartment 0,456 mg/kg/d
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acute Acute Chronic Chronic Acute local Acute Chronic Chronic
local systemic local systemic systemic local systemic
Oral 20 4
mg/kg bw/d mg/kg bw/d
Inhalation 27 5,4 110 22
mg/m3 mg/m3 mg/m3 mg/m3
Skin 20 4 40 8
mg/kg bw/d mg/kg bw/d mg/kg mg/kg
bw/d bw/d

1,2-Benzisothiazol-3 (2H) -one


Predicted no-effect concentration - PNEC
Normal value in fresh water 403 mg/l
Normal value in marine water 0,000403 mg/l
Normal value for fresh water sediment 0,0499 mg/kg/d
Normal value for marine water sediment 0,00499 mg/kg/d
Normal value for water, intermittent release 0,0011 mg/l
Normal value of STP microorganisms 0,00103 mg/l
Normal value for the terrestrial compartment 3 mg/kg/d
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acute Acute Chronic Chronic Acute local Acute Chronic Chronic
local systemic local systemic systemic local systemic
Inhalation 1,2 6,81
mg/m3 mg/m3
Skin 0,345 0,966
mg/kg bw/d mg/kg
bw/d

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SECTION 8. Exposure controls/personal protection ... / >>


mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one
Predicted no-effect concentration - PNEC
Normal value in fresh water 0,00339 mg/l
Normal value in marine water 0,00339 mg/l
Normal value for fresh water sediment 0,027 mg/kg/d
Normal value for marine water sediment 0,027 mg/kg/d
Normal value for water, intermittent release 0,00339 mg/l
Normal value of STP microorganisms 0,23 mg/l
Normal value for the terrestrial compartment 0,01 mg/kg/d
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acute Acute Chronic Chronic Acute local Acute Chronic Chronic
local systemic local systemic systemic local systemic
Oral 0,110 0,090
mg/kg bw/d mg/kg bw/d
Inhalation 0,040 0,020 0,040 0,020
mg/m3 mg/m3 mg/m3 mg/m3

Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.
VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified ; LOW = low hazard
; MED = medium hazard ; HIGH = high hazard.

8.2. Exposure controls

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on
the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type
A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases
or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing
apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

SECTION 9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Information


Appearance liquid
Colour white
Odour characteristic
Melting point / freezing point not available
Initial boiling point 100 °C
Flammability not available
Lower explosive limit not available
Upper explosive limit not available
Flash point not applicable

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SECTION 9. Physical and chemical properties ... / >>


Auto-ignition temperature not available
Decomposition temperature not available
pH 7
Kinematic viscosity not available
Dynamic viscosity 1000 mPas
Solubility not available
Partition coefficient: n-octanol/water not available
Vapour pressure 23 hPa at 20°C
Density and/or relative density 1 g/cm3
Relative vapour density not available
Particle characteristics not applicable

9.2. Other information

9.2.1. Information with regard to physical hazard classes

Information not available

9.2.2. Other safety characteristics

VOC (Directive 2010/75/EU) 2,89 % - 28,92 g/litre

SECTION 10. Stability and reactivity


10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

BENZYL ALCOHOL
Decomposes at temperatures above 870°C/1598°F.Possibility of explosion.
10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

BENZYL ALCOHOL
May react dangerously with: hydrobromic acid,iron,oxidising agents,sulphuric acid.Risk of explosion on contact with: phosphorus
trichloride.
10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

BENZYL ALCOHOL
Avoid exposure to: air,sources of heat,naked flames.
10.5. Incompatible materials

BENZYL ALCOHOL
Incompatible with: sulphuric acid,oxidising substances,aluminium.
10.6. Hazardous decomposition products

Information not available

SECTION 11. Toxicological information


In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

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SECTION 11. Toxicological information ... / >>


Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

ATE (Inhalation - vapours) of the mixture: > 20 mg/l


ATE (Oral) of the mixture: >2000 mg/kg
ATE (Dermal) of the mixture: >2000 mg/kg

BENZYL ALCOHOL
LD50 (Dermal): 2000 mg/kg Rabbit
LD50 (Oral): 1230 mg/kg Rat
LC50 (Inhalation vapours): > 4,1 mg/l/4h Rat
STA (Inhalation vapours): 11 mg/l estimate from table 3.1.2 of Annex I of the CLP
(figure used for calculation of the acute toxicity estimate of the mixture)

1,2-Benzisothiazol-3 (2H) -one


LD50 (Dermal): 2000 mg/kg
LD50 (Oral): 1150 mg/kg

mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one


LD50 (Dermal): 660 mg/kg
STA (Dermal): 50,001 mg/kg estimate from table 3.1.2 of Annex I of the CLP
(figure used for calculation of the acute toxicity estimate of the mixture)
LD50 (Oral): 457 mg/kg

polyurethane dispersion
LD50 (Oral): > 2000 mg/kg
LC50 (Inhalation mists/powders): > 2,676 mg/l/4h

SKIN CORROSION / IRRITATION

Does not meet the classification criteria for this hazard class

SERIOUS EYE DAMAGE / IRRITATION

Does not meet the classification criteria for this hazard class

RESPIRATORY OR SKIN SENSITISATION

May produce an allergic reaction.


Contains:
mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one
1,2-Benzisothiazol-3 (2H) -one

Respiratory sensitization

Information not available

Skin sensitization

Information not available

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

Does not meet the classification criteria for this hazard class

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SECTION 11. Toxicological information ... / >>


REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

Adverse effects on sexual function and fertility

Information not available

Adverse effects on development of the offspring

Information not available

Effects on or via lactation

Information not available

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

Target organs

Information not available

Route of exposure

Information not available

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

Target organs

Information not available

Route of exposure

Information not available

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

11.2. Information on other hazards

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine
disruptors with human health effects under evaluation.

SECTION 12. Ecological information


Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or
contaminate soil or vegetation.

12.1. Toxicity

BENZYL ALCOHOL
LC50 - for Fish 460 mg/l/96h
EC50 - for Crustacea 230 mg/l/48h
EC50 - for Algae / Aquatic Plants 650 mg/l/72h

1,2-Benzisothiazol-3 (2H) -one


LC50 - for Fish 0,74 mg/l/96h
EC50 - for Crustacea 2,44 mg/l/48h

EPY 11.2.0 - SDS 1004.14


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Printed on 30/10/2023
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Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 12. Ecological information ... / >>


mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one
LC50 - for Fish 0,19 mg/l/96h
EC50 - for Crustacea 0,16 mg/l/48h
EC50 - for Algae / Aquatic Plants 0,0273 mg/l/72h
Chronic NOEC for Fish 0,02 mg/l
Chronic NOEC for Algae / Aquatic Plants 0,0035 mg/l

polyurethane dispersion
LC50 - for Fish > 100 mg/l/96h
EC50 - for Crustacea > 100 mg/l/48h

12.2. Persistence and degradability

BENZYL ALCOHOL
Rapidly degradable

mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one


Entirely degradable

polyurethane dispersion
NOT rapidly degradable

12.3. Bioaccumulative potential

BENZYL ALCOHOL
Partition coefficient: n-octanol/water 1,1

mixture of 5-chloro-2-methyl-1,2-thiazol-3 (2H) -one and 2-methyl-1,2-thiazol-3 (2H) -one


Partition coefficient: n-octanol/water 0,75 Log Kow

12.4. Mobility in soil

Information not available

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

12.6. Endocrine disrupting properties

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine
disruptors with environmental effects under evaluation.

12.7. Other adverse effects

Information not available

SECTION 13. Disposal considerations


13.1. Waste treatment methods

Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information


The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail
(RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

14.1. UN number or ID number

not applicable

EPY 11.2.0 - SDS 1004.14


INTERCOM S.R.L. Revision nr.5
Dated 06/04/2023
Printed on 30/10/2023
Page n. 10 / 12

Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 14. Transport information ... / >>


14.2. UN proper shipping name

not applicable

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

not applicable

14.6. Special precautions for user

not applicable

14.7. Maritime transport in bulk according to IMO instruments

Information not relevant

SECTION 15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Seveso Category - Directive 2012/18/EU: None

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006
Product
Point 40
Contained substance
Point 75

Regulation (EU) 2019/1148 - on the marketing and use of explosives precursors


not applicable

Substances in Candidate List (Art. 59 REACH)


On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%.

Substances subject to authorisation (Annex XIV REACH)


None

Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:


None

Substances subject to the Rotterdam Convention:


None

Substances subject to the Stockholm Convention:


None

Healthcare controls
Information not available

15.2. Chemical safety assessment

A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3.

SECTION 16. Other information


Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Acute Tox. 2 Acute toxicity, category 2


Acute Tox. 3 Acute toxicity, category 3

EPY 11.2.0 - SDS 1004.14


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Printed on 30/10/2023
Page n. 11 / 12

Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 16. Other information ... / >>


Skin Corr. 1C Skin corrosion, category 1C
Eye Dam. 1 Serious eye damage, category 1
Skin Sens. 1A Skin sensitization, category 1A
Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1
Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1
H310 Fatal in contact with skin.
H330 Fatal if inhaled.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- ATE: Acute Toxicity Estimate
- CAS: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE: Identifier in ESIS (European archive of existing substances)
- CLP: Regulation (EC) 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: Regulation (EC) 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA: Time-weighted average exposure limit
- TWA STEL: Short-term exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 2020/878 (II Annex of REACH Regulation)
4. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)
14. Regulation (EU) 2018/669 (XI Atp. CLP)
15. Regulation (EU) 2019/521 (XII Atp. CLP)
16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP)
17. Regulation (EU) 2019/1148
18. Delegated Regulation (UE) 2020/217 (XIV Atp. CLP)
19. Delegated Regulation (UE) 2020/1182 (XV Atp. CLP)
20. Delegated Regulation (UE) 2021/643 (XVI Atp. CLP)

EPY 11.2.0 - SDS 1004.14


INTERCOM S.R.L. Revision nr.5
Dated 06/04/2023
Printed on 30/10/2023
Page n. 12 / 12

Ecostick® 1816B Replaced revision:4 (Dated 12/12/2022)

SECTION 16. Other information ... / >>


21. Delegated Regulation (UE) 2021/849 (XVII Atp. CLP)

- The Merck Index. - 10th Edition


- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

Note for users:


The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

CALCULATION METHODS FOR CLASSIFICATION


Chemical and physical hazards: Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for
evaluation of chemical-physical properties are reported in section 9.
Health hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section
11.
Environmental hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in
Section 12.
Changes to previous review:
The following sections were modified:
02 / 03 / 04 / 07 / 08 / 11 / 12 / 16.

EPY 11.2.0 - SDS 1004.14

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