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kr

Material Safety Data Sheet

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATON

A) Product name STARBOND 950

B) Recommendations and uses Adhesive
C) Supplier information

Company's name CHILSUNG POLYMER CO.,LTD

Company's address 140, Seotan-ro, Seotan-myeon, Pyeongtaek-si, Gyeonggi-do, Korea

Company's emergency phone
82-31-664-3849
number

2. HAZARDS IDENTIFICATION

A) Hazards identification classification

Flammable liquid CATEGORY 2

Skin corrosion/irritation CATEGORY 2

Serous eyes damage/eye irritation CATEGORY 2

Germ cell mutagenicity CATEGORY 1B

Reproductive toxicity CATEGORY 2

Specific target organ toxicity (Single exposure) CATEGORY 3(anesthesia action)

Specific target organ toxicity (Single exposure) CATEGORY 3(respiratory tract irritation)

Specific target organ toxicity (Repeated exposure) CATEGORY 2

Aspiration hazard CATEGORY 1

B) Label elements and precautionary statement

Pictograph(GHS)

A signal word Danger

Hazard statement H225 Highly flammable liquid and vapor.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

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H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H340 May cause genetic defects

H361 Suspected damagingfertility unbornchild.

H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P264 Wash hands thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response P301+P310 If swallowed : Immediately call a posion center or doctor/physician.

P302+P352 If on skin : Rinse skin with water.

P303+P361+P353 If on skin(or hair) : Remove/Take off immediately

all contaminated clothing. Rinse skin with water/shower.

P304+P340 If Inhaled : Remove victim to fresh air and keep at rest in

a position comfortable for breathing.

P305+P351+P338 If on eyes : Rinse eyes with water.

P308+P313 :If exposed or concerned: Get medical advice or attention.

P312 If you feel unwell : call a poison center or doctor/physician.

P314 Get medical advice/attention if you feel unwell.

P331 Do not induce vomiting.

P332+P313 If your skin unwell : Get medical advice/attention.

P337+P313 If your eye unwell : Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P370+P378 In case of fire : Use form extinction.

P391 Please collect spillage.

Storage P403+P233 Store in a well-ventilated place. Keep lock.

P403+P235 Store in a well-ventilated place. Keep cool.

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P405 Store locked up.

Disposal P501 Dispose of contents and container in accordance with local regulations.

C) Other Hazard-Risk which is not included in the classification criteria Chemical Name NFPA - No Data

3. COMPOSITION, INFORMATION ON INGREDIENTS

INGREDIENT COMMON NAME CAS No Content(%)

Toluene Toluol 108-88-3 32 ± 5

Methyl cyclopentane 96-37-7 15 ± 5

Naphtha (petroleum), light straight-run 64741-46-4 12 ± 3

n-Hexane 110-54-3 6±2

Cyclohexane 110-82-7 6±2

2-Methylhexane 591-76-4 3±1

Cyclopentane 287-92-3 3±1

2-Methylpentane 107-83-5 3±1

Neoprene 9010-98-4 20 ± 5

4. FIRST AID MEASURES

A) Eye contact If in eyes: Rinse cautiously with water for several minutes. If possible,

remove the contact lenses. Keep washing.

If eye irritation persists, get medical advice / attention.

B) Skin contact If on skin(or hair) : Remove/Take off immediately all contaminated clothing.

Rinse skin with water/shower.

If skin irritation occurs: Get medical advice / attention.

Remove contaminated clothing and shoes and isolate contaminated area.

At minimal skin contact, prevent the spread of contaminated area.

Wash skin with soap and water.

In case of contact with material, immediately flush skin with running water for

at least 20 minutes.

C) Inhalation If exposed or concerned: Get medical advice / attention.

Do not induce vomiting.

If exposed to excessive levels of dust or fumes, remove to fresh air and

get medical

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Call a POISON CENTER or doctor/physician if you feel unwell.

D) Ingestion Immediately call a POISON CENTER or doctor/physician.

Do not induce vomiting.

E) Note to physician Ensure that medical personnel are aware of the material(s) involved and

take precautions to protect themselves.

5. FIRE-FIGHTING MEASURES

A) Suitable extinguishing media Use alcohol foam, carbon dioxide, or water spray when fighting fires involving

B) Specific hazards arising Highly Flammable Liquids and Vapors.

from the chemical Violent polymerization can cause fire and explosion.

During a fire, irritating and highly toxic gases may be generated

Vapors may be transferred to an ignition source and ignite.

Vapors can form explosive mixtures at temperatures at or above the flash point.

Container may explode when heated.

Highly flammable: Will be easily ignited by heat, sparks or flame.

A spill or leak can cause an immediate fire/explosion.

Vapor explosion hazard indoors, outdoors or in sewers.

C) Special protective equipment For a fire on tank, step back from the tank engulfed in flames.

and precautions for firefighters Keep a safe distance from the area and fight fire.

Fight fire with normal precautions from a reasonable distance

Move containers from fire area if you can do it without risk.

For a fire on tank, fight fire from maximum distance or use unmanned fire

extinguishing equipment

Many liquids are lighter than water.

For a fire on tank, cool containers with flooding quantities of water until well

after fire is out.

For a fire on tank, Withdraw immediately in case of rising sound from venting

6. ACCIDENTAL RELEASE MEASURES

A) Personal precautions, protective Avoid breathing dust/fume/gas/mist/vapors/spray.

equipment and emergency Very fine particles can cause a fire or explosion. Eliminate all ignition sources.

procedures Clean up spills immediately, observing precautions in the Protective Equipment section.

Isolate the contaminated area.

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Do not let people who do not need to enter or do not have protective equipment

go in and out.

Remove all ignition sources.

Ground all equipment containing material.

Stop leak if without risk.

Do not touch damaged containers or spilled material unless wearing appropriate

protective clothing.

B) Measures necessary to protect Do not discharge into the environment.

the environment Prevent entry into waterways, sewers, basements or confined areas.

C) Method for the purification or Dike and collect water used to fight fire.

removal Absorb spill with inert material, (e.g., dry sand or earth),

then place into a chemical waste container.

Absorb liquids and wash contaminated area with detergent and water.

For large spills, please be away from the spill and dig a ditch.

Use clean explosion proof tools to collect absorbed material.

7. HANDLING AND STORAGE

A) Precautions for safe handling Do not handle until all safety precautions have been read and understood.

Use explosion-proof electrical / ventilating / lighting / equipment.

Use only non-sparking tools.

Take precautionary measures against static discharges.

Avoid breathing dust/fume/gas/mist/vapours/spray.

Wash hands thoroughly after handling.

Use only outdoors or in a well-ventilated area.

Do not pressurize, cut, weld, braze solder, drill, grind, or expose containers to flames,

sparks, heat, or other potential ignition sources.

Follow all MSDS/label precautions even after container is emptied because it may retain

product residues.

Use care in handling/storage.

Pay attention to the materials and conditions to avoid.

Pay attention to high temperature.

B) Storage method Keep away from heat / sparks / open flames / hot surfaces.-No smoking.

Keep container tightly closed in a well-ventilated place.

Store in a well-ventilated place and keep cool.

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Empty drums should be completely drained, properly bunged and promptly returned to

a drum reconditioner, or properly disposed of them.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

A) Exposure limits of the chemical substance, biological exposure limits and etc

ACGIH Regulation
Toluene - TWA 20ppm
Cyclopentane - TWA 600ppm (1720 mg/m3)
Cyclohexane - TWA 100 ppm (350 mg/m3)
n-Hexane - 50ppm (176 mg/m3)
2-Methylpentane -TWA 500 ppm (1760 mg/m3) STEL 1000 ppm (3500 mg/m3)
2-Methylhexane - TWA 400 ppm (1640 mg/m3) STEL 500 ppm (2050 mg/m3)
Biological Exposure Limit
0.02 mg/L Medium: blood Time: prior to last shift of workweek Parameter:
Toluene; 0.03mg/L Medium: urine Time: end of shift Parameter: Toluene; 0.3
Toluene
mg/g creatinine Medium: urine Time: end of shift Parameter: oCresol with
hydrolysis (background)

n-Hexane 2,5-Hexanedione (without hydrolysis) in urine: 0.4 mg/L (after work)

Other Exposure Limit No data

B) Appropriate engineering Use process enclosure, local exhaust ventilation, or other engineering
controls controls to control airborne levels below recommended exposure limits.

If user operations generate dust, fume or mist, use ventilation to keep

exposure to air borne contaminants below the exposure limit.

Facilities storing or utilizing this material should be equipped with a

face wash facility and a safety shower

C) Personal protective equipment

Respiratory protection If oxygen is insufficient(<19.6%), wear a respirator or self-contained

breathing apparatus.

wear a halfface-piece respirator withappropriate filter or purification

Eye protection Wear protective glasses suitable for the physical and chemical

properties of the material to be exposed.

Hand protection Wear chemical resistant protective gloves

9. PHYSICAL AND CHEMICAL PROPERTIES

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1) Appearance

Physical state Liquid

Color Yellowish brown

2) Odor Aromatic

3) Odor thershold No data

4) pH No data

5) Melting/Freezing point No data

6)Initial boiling point and boiling point 65℃

7) Flash point -20℃

8) Evaporation rate 5.8

9) Flammability (solid, gas) No data

10) Upper / lower limit of flammable 7.6 / 1.1%

or explosive range

11) Vapor pressure 28.4mmHg at 25℃ (HSBD)

12) Water solubility No data

13) Vapor density 3.1 (HSBD)

14) Specific gravity 0.83

15) n-octanol / water partition 2.73

coefficient

16) Spontaneous ignition temperature >250℃

17) Decomposition temperature No data

18) Viscosity 9000 ± 1000 Cps

19) Molecular weight No data

10. STABILITY AND REACTIVITY

1) Chemical stability and Highly flammable liquid and vapor.

possibility ofhazardous Chemically stable at room temperature and pressure

reactions Vapors can form explosive mixtures at temperatures at or above

the flash point.

Container may explode when heated.

Highly flammable: Will be easily ignited by heat, sparks or flame

A spill or leak can cause an immediate fire/explosion.

Vapor explosion hazard indoors, outdoors or in sewers.

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Vapors may form explosive mixtures with air.

Vapors can travel to a source of ignition and flash back

Vapors may cause dizziness or asphyxiation without consciousness

Inhalation or contact with material may irritate or burn skin and eyes

May be toxic by ingestion, inhalation and skin absorption

2) Conditions to avoid Keep away from heat/sparks/open flames/hot surfaces - No smoking

3) Incompatible materials No data

4) Hazardous decomposition During a fire, irritating and highly toxic gases may be generated

products by thermal decomposition or combustion

11. TOXICOLOGICAL INFORMATION

1) Information on the likely May cause irritation with short-term exposure

routes of exposure

2) Health hazard information

Acute toxicity

Oral LD50 > 2000mg/kg Rat

Skin LD50 > 2000mg/kg Rabbit

Inhalation LC50(vapor) > 20mg/ℓ Rat (OECD TG 403)

Skin corrosion or irritation

As a result of the skin irritation test using rabbits, erythema and edema
Toluene irritation were observed in all 7 animals, and moderate irritation was observed.
EU Method B4. (ECHA)
Methyl cyclopentane Non-irritating in rabbits (OSHRI Risk Assessment, 2010)

Naphtha (petroleum) Irritating in rabbits (GLP, ECHA)

As a result of skin irritation test using rabbit, mild irritation primary irritation
n-hexane
index 1.92 (OECD TG 404) (ECHA)
Skin corrosion/irritation test results for rabbits, non-irritation, erythema index =
Cyclohexane
1.93, EU Method B.4 (ECHA)

2-Methylpentane Non-irritating in rabbits (OSHRI Risk Assessment, 2010)

As a result of skin corrosion/irritation test using rabbits, mild irritation was
Methylcyclohexane
observed that was completely recovered within 72 hours (erythema: 0.5) (ECHA)
As a result of the skin corrosion irritation test using rabbits, the primary skin
Cyclopentane
irritation index was 0.67 (similar substance 109-66-0) (OEC TG 404, ECHA)

Serious eye damage or irritation

As a result of the eye irritation test using rabbits, weak irritation was observed
Toluene
and no other effects were observed (ECHA)

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Methyl cyclopentane Irritant in rabbits (OSHRI Risk Assessment, 2010)

Naphtha (petroleum) Non-Irritant in rabbits (GLP, ECHA)

n-Hexane As a result of severe eye damage/irritation test on rabbits, no irritation (ECHA)

As a result of severe eye damage/irritation test using rabbits, there is irritation
Cyclohexane that is completely recovered within 24 hours. slightly irritating. Overall irritation
index = 1.3, (OECD TG 405)
2-Methylpentane Non-irritating in rabbits (OSHIRI Risk Assessment, 2010)

As a result of severe eye damage/irritation test using rabbits, corneal and iris
Cyclopentane
effects were not observed (similar substance 109-66-0) (OECD TG 405, ECHA)

Respiratory sensitization No data

Skin sensitization
As a result of the maximization test using guinea pigs, no skin sensitization was
Toluene
observed. EU Method B.6, GLP (ECHA)
As a result of skin sensitization test using mice, it did not cause hypersensitivity
n-Hexane
(OECD TG 429) (ECHA)
Skin sensitization test results using male and female guinea pigs, non-
Cyclohexane
sensitization, EU Method B.6, GLP (ECHA)
As a result of skin sensitization test using guinea pig (female), no
Cyclopentane hypersensitivity (similar substance CAS No.78-78-4) (OECD Guideline 406 ,GLP,
ECHA)
Carcinogenic

IARC Toluene 3

Neoprene 3

OSHA No data

ACGIH Toluene A4

NTP No data

EU CLP No data

Germ cell mutagenicity

Gene mutation test results using in vitro mammalian cultured cells OECD TG
476, reverse mutation test results using microorganisms EU Method B.13/14,
Toluene
Negative regardless of presence or absence of metabolic activation system,
negative in vivo chromosomal abnormality test result (ECHA)
In vivo mammalian bone marrow micronucleus test negative (OSHRI Risk
Methyl cyclopentane
Assessment, 2010)
Naphtha (petroleum) Muta. 1B (Note P)(EU CLP)

Bacterial reverse mutation test using in vitro microorganisms, negative

n-Hexane regardless of metabolic activation system GLP, OECD Guideline 471 in vivo
chromosomal aberration test result, negative (ECHA)

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In vitro mammalian cell gene mutation test, reverse mutation using
microorganisms OECD TG 471, gene mutation test result using mammalian
Cyclohexane cultured cells OECD TG 476, negative regardless of the presence or absence of
metabolic activation system, chromosomal abnormality test result using
mammalian bone marrow cells in vivo OECD TG 475, GLP, Negative (ECHA)

2-Methylpentane Microbial reverse mutation test negative (OSHIRI Risk Assessment, 2010)

Cyclopentane Negative in vitro mammalian chromosomal abnormality test (OSHIRI, 2009)

Reproductive toxicity
As a result of the reproductive toxicity test using rats, sperm count and
Toluene epididymis decreased at 2000ppm (7537 mg/m3), NOAEC (P) 600ppm
(2261mg/m3)

As a result of inhalation exposure for 6 hours per day, 6-19 days after
Naphtha (petroleum) conception, no maternal and developmental toxicity was observed up to a
concentration of 9000 ppm (IUCLID)
As a result of an acute inhalation toxicity test on rats, testicular tubule atrophy
was observed at 5000 ppm in rats, a wide range of testicular lesions that did
not recover within the recovery period were observed, and weight gain and
food intake were reduced, which was an early neurological disorder.
Concomitant (LC50(count)>5000ppm) (OECD Guideline403) As a result of fetal
n-Hexane toxicity/teratogenicity test on mice, a decrease in the weight of the uterus of
conceived individuals was observed in the 200 and 5000ppm concentration
groups, and the number of implantation decreased in the 5000ppm
concentration group, and the 200ppm concentration group decreased. At
concentrations of , the incidence of intrauterine mortality is greatly increased
(NOAECmaternal toxicity=1000ppm) (ECHA)
As a result of the reproductive toxicity test using rats (male/female), salivation,
female weight loss, and reduction in offspring survival were found at high
doses (similar substance CASNo.110-82-7) (OECD Guideline 416, GLP)
Cyclopentane
Development using rats As a result of toxicity/teratogenicity test, no specific
symptoms were found (similar substance CAS No.109-66-0) (OECD Guideline
414 ,GLP)

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Rat (male/female) 2nd generation reproductive toxicity test results (OECD TG
476, GLP), no reproductive toxicity effect (NOAEC(P)=500-2,000ppm (=1,720-
24,080mg/m3), NOAEC(F1)=7,000 ppm(=24,080 mg/m3),
NOAEC(F2)=7,000ppm(=24,080 mg/m3)), fetal development toxicity test results
using rats (OECD TG 414, GLP), no effects other than weight loss found
(NOAEC (maternal toxicity) = 500-2,000ppm, NOAEC (developmental toxicity) =
7,000ppm, NOAEC (teratogenicity) = 7,000ppm) - As a result of the 2nd
Cyclohexane generation reproduction toxicity test using rats, the weight loss of F1 and F2 is
unique (NOEL( Systemic toxicity) = 500ppm, NOEL (reproductive toxicity) =
2,000ppm), as a result of developmental toxicity test using rats and rabbits,
overall maternal weight loss and food consumption reduction were observed as
maternal toxicity only in rats. At 2,000ppm, there is a transient weakening or
disappearance of auditory stimulation. No effect on rabbits (NOEL (rat) =
500ppm, NOEL (rabbit) = 7,000ppm) - 2-year-old test results using rats (OECD
TG 416), no effect, developmental impact test results on rats and rabbits (OECD
Specific target organ toxicity (Single exposure)
Effects on the central nervous system in humans, causing fatigue, drowsiness,
dizziness, respiratory irritation, excitement, vomiting, central nervous system
Toluene depression, confusion, gait abnormalities, etc. Causes eye, nose and throat
irritation. Causes an anesthetic effect in laboratory animals. Target organ:
central nervous system
Methyl cyclopentane Irritating to airways if inhaled (KOSHA)
In humans, acute inhalation toxicity may cause dizziness or central nervous
n-Hexane system depression. Airway stimulation appears Target organ: Central nervous
system (HSDB)
Results of acute inhalation test using male/female rats OECD TG 403, tremors,
hyperactivity, rapid breathing, inability to control body Decreased
Cyclohexane immunoreactivity in immunohistological studies, convulsions in rabbits at high
concentrations, severe diarrhea, circulatory collapse and death Target organ:
central nervous system (ECHA, HSDB)
Lungs, chest, respiratory, gastrointestinal, central nervous system (NLM, RTECS,
2-Methylhexane
ICSC)
As a result of acute oral toxicity test using rats (female/female), no special
symptoms were found (similar substance CAS No.109-66-0) (OECD TG401,GLP)
Acute inhalation toxicity test using rats (female/female) Result, death of one
Cyclopentane
male (14 days), hyperactivity disorder found (first 2 hours of exposure), lung
cancer, kidney abnormality found (OECD TG 403) Not applicable for
classification in this section due to effects of acute toxicity (ECHA)

Specific target organ toxicity (Repeated exposure)

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90-day repeated oral toxicity test using rats EU method B.26 result
NOAEL625mg/kg, bw/day for increase in absolute or relative liver weight 103-
week inhalation carcinogenicity test using rats OECD TG453, GLP result NOAEC
600 for local toxicity of nasal epithelium 90-day inhalation repeated toxicity
Toluene
test using ppm2250mg/m3 rat EU method B.29, GLP result Clinical symptoms,
body weight change, organ weight brain, heart, lung, male relative testis weight
and hematological changes Leukocyte reduction, Plasma chollinesterase acitivity
decreased NOAEC 625 ppm2355 mg/m3
NOAEL 4.47 ㎎ / ℓ (Rat) - As a result of repeated inhalation exposure for 13
weeks in experimental animals, no significant toxicological symptoms were
Methyl cyclopentane
observed except for tender reactions observed in the highest concentration
group (20.21 ㎎ / ℓ) (OSHRI Risk Assessment, 2010 )

As a result of repeated administration oral toxicity test for rats, 2 animals in the
13.2 mmol/kg and 46.2 mmol/kg concentration groups died immediately after
administration, the weight gain rate decreased as the food consumption
n-Hexane
decreased, testicular epithelial atrophy was observed, Axonal edema, axonal
myelin invagination were observed, and neurohabitrological toxicity such as
atrophy of nodal myelin was observed.
Neurotoxicity such as hind limb paralysis was observed after administration in
the 46.2 mmol/kg concentration group. NOAEL number = 6.6 mmol/kg bw,
NOAEL neurological effect number = 13.2 mmol/kg bw Subchronic inhalation
toxicity in mice: 90-day test results, The body weight of male objects in the
n-Hexane
1000 and 10000ppm concentration groups decreased, and the weight of
female objects in the 10000ppm concentration group also decreased. Nose
damage NOAEL number = 500 ppm (OECD TG 413) Target organ: nervous
system (ECHA)
EPA OPPTS 870.3465 EPA OPPTS 870.3465, adverse effects on GLP, body
weight, hematology, clinical chemistry, and histopathology of tissue, as a result
of 90-day inhalation repeated toxicity test for male/female rats. Increased liver
weight and hypertrophy of hepatocytes in the middle lobules were found.
Acute and transient effects on the central nervous system NOAEC acute,
temporary effects = 500ppm, NOAEC subchronic toxicity = 7,000ppm, 90-day
inhalation repeated toxicity test using male and female mice EPA OPPTS
Cyclohexane 870.3465, red blood cell mass circulation, plasma protein concentration slightly
increased. Acute and temporary effects on the central nervous system NOAEC
acute, temporary effects = 500ppm, NOAEC subchronic toxicity = 2,000ppm
Target organ: central nerve - result of percutaneous repeated test, irritation
lesions caused by defatting effect, 90-day inhalation test result OECD TG 413, A
temporary sedative effect was observed, but this was considered an acute
effect NOAEL=500 ppm Slight hepatotoxicity at high concentration
NOAEL=2,000 ppm (EHCA, OECD SIDS)
NOAEL 1 mg/ℓ, steam (Rat, male) - As a result of repeated inhalation exposure
for 13 weeks in experimental animals (male), kidney abnormalities appeared
2-Methylpentane
(inflammatory cell infiltration in interstitial tissue, regenerative tubule, cystic
change) observation) (OSHIRI Risk Assessment, 2010)

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As a result of a combination test of reproductive/developmental toxicity
screening and repeated toxicity tests using rats, no harmful effects were
Methylcyclohexane
observed other than salivation (LOAEL=250 mg/kg bw/day) (OECD TG 422,
GLP) (SIDS)
As a result of repeated inhalation toxicity test using rats (male/female), no
special symptoms were found (OECD Guideline 413) Specific target organ
Cyclopentane toxicity (repeated exposure): NOAEL 15.49 ㎎/ℓ (Rat) 13 weeks of repeated
inhalation exposure in experimental animals Results No significant toxicological
symptoms were observed (ECHA, OSHIRI, 2009)
Aspiration hazard

Toluene It is a hydrocarbon and has a kinematic viscosity of 20.5 mm2 / s or less at 40 ° C.

Naphtha (petroleum) Concern for lung damage if swallowed (EU CLP)
n-Hexane Hydrocarbon, kinematic viscosity less than 20.5 mm2/s (40 ℃) (EU CLP)
Risk of chemical pneumonitis by aspiration if liquid is swallowed. (ICSC)
Cyclohexane
Kinematic viscosity 0.894 mPa sat 25℃
Other adverse effects No data

12. ECOLOGICAL INFORMATION

1) Ecotoxicity

Fish

- [Toluene] : LC50 5.5 ㎎/ℓ 96 hr Oncorhynchus kistutch (ECHA)

- [Methyl cyclopentane] : LC50 2.25 ㎎/ℓ 96 hr (Estimate)
- [n-Hexane] : LC50 >1 ㎎/ℓ 48 hr Oryzias latipes (no guideline followed, ECHA)
- [Cyclohexane] : LC50 4.53 ㎎/ℓ 96 hr Pimephales promelas(OECD Guideline 203) (ECHA)
- [2-Methylhexane] : LC50 = 2.438 ㎎/ℓ 96 hr (Estimate)
- [Cyclopentane] : LC50 29.3 ㎎/ℓ 96 hr (EHCA)
- [2-Methylpentane] : LC50 4.656 ㎎/ℓ 96 hr (Estimate)
Crustacea

- [Toluene] : EC50 3.78mg/L 48hr (ECHA)

- [Methyl cyclopentane] : LC50 6.67 ㎎/ℓ 48 hr (Estimate)
- [n-Hexane] : LC50 30 ㎎/ℓ 48 hr Daphnia magna (ECHA)
- [Cyclohexane] : EC50 0.9 ㎎/ℓ 48 hr Daphnia magna(OECD TG 202)
- [2-Methylhexane] : LC50 = 1.769 ㎎/ℓ 48 hr (Estimate)
- [Cyclopentane] : EL50 51.15 ㎎/ℓ 48 hr (ECHA)
- [2-Methylpentane] : LC50 5.424 ㎎/ℓ 48 hr (Estimate)
Algae

- [Methyl cyclopentane] : EC50 4.44 ㎎/ℓ 96 hr (Estimate)

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- [Naphtha (petroleum), light straight-run] : EC50 6.5 ㎎/ℓ 72 hr Selenastrum capricornutum (IUCLID)
- [n-Hexane] : EL50 9.285 mg/L (ECHA)
- [Cyclohexane] : ErC50 9.317 ㎎/ℓ 72 hr Selenastrum capricornutum(OECD TG 201, GLP) (ECHA)
- [2-Methylhexane] : EC50 = 1.761 ㎎/ℓ 96 hr (Estimate)
- [Cyclopentane] : EC50 21.58 ㎎/ℓ 48 hr (ECHA)
- [2-Methylpentane] : EC50 3.635 ㎎/ℓ 96 hr (Estimate)
2) Persistence and Degradability

Persistence

- [Toluene] : 2.73 log Kow (20 °C) (ECHA)

- [Methyl cyclopentane] : log Kow 3.37 (UAKRON)
- [Naphtha (petroleum), light straight-run] : log Kow 2.1 ~ 6 (Estimate)
- [n-Hexane] : 4 log Kow (20°C, pH=7) (ECHA)
- [Cyclohexane] : 3.44 log Kow (25 °C, pH 7)
- [2-Methylhexane] : log Kow = 3.71 (Estimate)
- [Cyclopentane] : log Kow 3 (KOSHA)

- [2-Methylpentane] : log Kow 3.21 (Estimate)

Degradability No data

3) Bioaccumulative

Concentration

- [Toluene] : BCF 90(ECHA)

- [Methyl cyclopentane] : BCF 210 (NLM/HSDB)
- [n-Hexane] : BCF 501.187 (Estimate) (ECHA)
- [2-Methylhexane] : BCF = 129.4 (Estimate)
- [2-Methylpentane] : BCF 100 ~ 408 (HSDB)
Biodegradable

- [Toluene] : 80 % 20 day (Readily biodegradable) (ECHA)

- [n-Hexane] : 98 % 28 day (Read-across CAS No.64742-49-0 OECD TG 301 F, GLP) (ECHA)
- [Cyclohexane] : 77 % 28 day (O2 consumption, OECD TG 301F, GLP)
- [2-Methylhexane] : (Cut-off value = 0.7068 ; rapidly biodegradable(BIOWIN 6)) (Estimate)

- [Cyclopentane] : 0 %, 28 day (CO2 emit, Non-degradable in the measurement environment (OECD

TG301F, GLP) (ECHA)

4) Mobility soil
- [Methyl cyclopentane] : Koc 1600 (HSDB)
- [n-Hexane] : 2187.76 Koc (Estimate)
- [Cyclohexane] : Koc 770 (ECHA)
- [2-Methylhexane] : Koc = 1658 (Can be adsorbed in the soil)(Estimate)

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5) Other adverse effects
Fish - Oncorhynchus kisutch : NOEC40 d=1.39 mg/L
- [Toluene]
Crustacea - Ceriodaphnia dubia : NOEC7 d=0.74 mg/L
- [n-Hexane] : Chronic aquatic toxicity Category 2 (Harmonized classification ECHA)
- [Cyclohexane] : Algae Selenastrum capricornutum: NOEC72hr=0.94 mg/L growth rate (OECD TG 201,
GLP)
- [Methylcyclohexane] : Algae(Pseudokirchneriella subcapitata): NOErC(72h) 0.022mg/L (Static) (ECHA)

13. DISPOSAL CONSIDERATIONS

1) Disposal method Dispose of contents and container in accordance with all applicable

regulations.

2) Disposal considerations If specified in the Waste Management Act, consider the precautions

specified in the regulations.

14. TRANSPORT INFORMATION

1) UN number 1133

2) Proper shipping name ADHESIVES

3) Transportation hazard class 3

4) Container grade Ⅱ

5) Marine pollutant No data

6) Special safeguards you need or need to knowabout transportation or transportation

Fire fighting measures in case of fire : F-E

Emergency measures in case of spill : S-D

15. REGULATORY INFORMATION

1) Foreign regulation

USA(CERCLA 103)

- [Toluene] : 453.599 kg 1000 lb

- [n-Hexane] : 2267.995 kg 5000 lb

- [Cyclohexane] : 453.599 kg 1000 lb

USA(EPCRA 313)

- [Toluene] : Applicable.

- [n-Hexane] : Applicable.

- [Cyclohexane] : Applicable.

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EU (Classification)

- [Toluene] : H225, H361d, H304, H373, H315, H336

- [2-Methylpentane] : H225,H304,H315,H336,H411

- [2-Methylhexane] : H225,H304,H315,H336,H410

- [Cyclohexane] : H225,H304,H315,H336,H410

- [Cyclopentane] : H225,H412

- [n-Hexane] : H225,H361f,H304,H373,H315,H336,H411

- [Naphtha (petroleum), light straight-run] : H350,H340,H304

16. OTHER INFORMATION

1) Source of data

Korea Occupational Safety and Health Agency

2) Date of initial publication 2013-06-27

3) Revision number and date of the last modification

Revision number 5

Date of the last modification 23.01.03

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