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Starbond B5 MSDS (E)
Starbond B5 MSDS (E)
kr
2. HAZARDS IDENTIFICATION
Specific target organ toxicity (Single exposure) CATEGORY 3(respiratory tract irritation)
Pictograph(GHS)
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H335 May cause respiratory irritation.
P202 Do not handle until all safety precautions have been read and understood.
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P405 Store locked up.
Disposal P501 Dispose of contents and container in accordance with local regulations.
C) Other Hazard-Risk which is not included in the classification criteria Chemical Name NFPA - No Data
A) Eye contact If in eyes: Rinse cautiously with water for several minutes. If possible,
B) Skin contact If on skin(or hair) : Remove/Take off immediately all contaminated clothing.
In case of contact with material, immediately flush skin with running water for
at least 20 minutes.
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C) Inhalation If exposed or concerned: Get medical advice / attention.
get medical
E) Note to physician Ensure that medical personnel are aware of the material(s) involved and
5. FIRE-FIGHTING MEASURES
A) Suitable extinguishing media Use alcohol foam, carbon dioxide, or water spray when fighting fires involving
from the chemical Violent polymerization can cause fire and explosion.
Vapors can form explosive mixtures at temperatures at or above the flash point.
C) Special protective equipment For a fire on tank, step back from the tank engulfed in flames.
and precautions for firefighters Keep a safe distance from the area and fight fire.
For a fire on tank, fight fire from maximum distance or use unmanned fire
extinguishing equipment
For a fire on tank, cool containers with flooding quantities of water until well
For a fire on tank, Withdraw immediately in case of rising sound from venting
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A) Personal precautions, protective Avoid breathing dust/fume/gas/mist/vapors/spray.
equipment and emergency Very fine particles can cause a fire or explosion. Eliminate all ignition sources.
procedures Clean up spills immediately, observing precautions in the Protective Equipment section.
Do not let people who do not need to enter or do not have protective equipment
go in and out.
protective clothing.
the environment Prevent entry into waterways, sewers, basements or confined areas.
C) Method for the purification or Dike and collect water used to fight fire.
removal Absorb spill with inert material, (e.g., dry sand or earth),
Absorb liquids and wash contaminated area with detergent and water.
For large spills, please be away from the spill and dig a ditch.
A) Precautions for safe handling Do not handle until all safety precautions have been read and understood.
Do not pressurize, cut, weld, braze solder, drill, grind, or expose containers to flames,
Follow all MSDS/label precautions even after container is emptied because it may retain
product residues.
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Pay attention to high temperature.
B) Storage method Keep away from heat / sparks / open flames / hot surfaces.-No smoking.
Empty drums should be completely drained, properly bunged and promptly returned to
A) Exposure limits of the chemical substance, biological exposure limits and etc
ACGIH Regulation
Toluene - TWA 20ppm
Cyclopentane - TWA 600ppm (1720 mg/m3)
Cyclohexane - TWA 100 ppm (350 mg/m3)
n-Hexane - 50ppm (176 mg/m3)
2-Methylpentane -TWA 500 ppm (1760 mg/m3) STEL 1000 ppm (3500 mg/m3)
2-Methylhexane - TWA 400 ppm (1640 mg/m3) STEL 500 ppm (2050 mg/m3)
3-Methylhexane : TWA, 400 ppm (1640 mg/m3) STEL, 500 ppm (2050 mg/m3)
3-Methylpentane : TWA, 500 ppm (1760 mg/m3) STEL, 1000 ppm (3500
mg/m3)
Biological Exposure Limit
0.02 mg/L Medium: blood Time: prior to last shift of workweek Parameter:
Toluene; 0.03mg/L Medium: urine Time: end of shift Parameter: Toluene; 0.3
Toluene
mg/g creatinine Medium: urine Time: end of shift Parameter: oCresol with
hydrolysis (background)
B) Appropriate engineering Use process enclosure, local exhaust ventilation, or other engineering
controls controls to control airborne levels below recommended exposure limits.
breathing apparatus.
Eye protection Wear protective glasses suitable for the physical and chemical
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properties of the material to be exposed.
1) Appearance
Color brown
2) Odor Aromatic
4) pH No data
or explosive range
coefficient
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the flash point.
Container may explode when heated.
Inhalation or contact with material may irritate or burn skin and eyes
4) Hazardous decomposition During a fire, irritating and highly toxic gases may be generated
routes of exposure
Acute toxicity
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As a result of skin corrosion/irritation test using rabbits, mild irritation was
Methylcyclohexane
observed that was completely recovered within 72 hours (erythema: 0.5) (ECHA)
As a result of the skin corrosion irritation test using rabbits, the primary skin
Cyclopentane
irritation index was 0.67 (similar substance 109-66-0) (OEC TG 404, ECHA)
3-Methylhexane irritant
As a result of the skin corrosion/irritation test using rabbits, there is irritation
n-Heptane that does not recover within 72 hours. pepper. Erythema index = 1, edema
index = 0, OECD TG404, analogue CAS No. 540-84-1 (ECHA)
3-Methylpentane Causes skin irritation (KOSHA)
Serious eye damage or irritation
As a result of the eye irritation test using rabbits, weak irritation was observed
Toluene
and no other effects were observed (ECHA)
Methyl cyclopentane Irritant in rabbits (OSHRI Risk Assessment, 2010)
As a result of severe eye damage/irritation test using rabbits, corneal and iris
Cyclopentane
effects were not observed (similar substance 109-66-0) (OECD TG 405, ECHA)
3-Methylhexane irritant
As a result of severe eye damage/irritation test using rabbits, there is irritation
n-Heptane that is completely recovered within 48 hours. non-irritating. Conjunctival index
= 0.67, corneal index = 0, iris index = 0, conjunctival edema index = 0, OECD
3-Methylpentane mild to moderate irritation (HSDB)
Skin sensitization
As a result of the maximization test using guinea pigs, no skin sensitization was
Toluene
observed. EU Method B.6, GLP (ECHA)
As a result of skin sensitization test using mice, it did not cause hypersensitivity
n-Hexane
(OECD TG 429) (ECHA)
Skin sensitization test results using male and female guinea pigs, non-
Cyclohexane
sensitization, EU Method B.6, GLP (ECHA)
As a result of skin sensitization test using guinea pig (female), no
Cyclopentane hypersensitivity (similar substance CAS No.78-78-4) (OECD Guideline 406 ,GLP,
ECHA)
Skin sensitization test results using guinea pigs, non-sensitization, OECD TG
n-Heptane
406, similar substances: SBP 100/140 (ECHA)
Carcinogenic
IARC Toluene 3
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Neoprene 3
OSHA No data
ACGIH Toluene A4
NTP No data
EU CLP No data
2-Methylpentane Microbial reverse mutation test negative (OSHIRI Risk Assessment, 2010)
As a result of inhalation exposure for 6 hours per day, 6-19 days after
Naphtha (petroleum) conception, no maternal and developmental toxicity was observed up to a
concentration of 9000 ppm (IUCLID)
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As a result of an acute inhalation toxicity test on rats, testicular tubule atrophy
was observed at 5000 ppm in rats, a wide range of testicular lesions that did
not recover within the recovery period were observed, and weight gain and
food intake were reduced, which was an early neurological disorder.
Concomitant (LC50(count)>5000ppm) (OECD Guideline403) As a result of fetal
n-Hexane toxicity/teratogenicity test on mice, a decrease in the weight of the uterus of
conceived individuals was observed in the 200 and 5000ppm concentration
groups, and the number of implantation decreased in the 5000ppm
concentration group, and the 200ppm concentration group decreased. At
concentrations of , the incidence of intrauterine mortality is greatly increased
(NOAECmaternal toxicity=1000ppm) (ECHA)
As a result of the reproductive toxicity test using rats (male/female), salivation,
female weight loss, and reduction in offspring survival were found at high
doses (similar substance CASNo.110-82-7) (OECD Guideline 416, GLP)
Cyclopentane
Development using rats As a result of toxicity/teratogenicity test, no specific
symptoms were found (similar substance CAS No.109-66-0) (OECD Guideline
414 ,GLP)
Rat (male/female) 2nd generation reproductive toxicity test results (OECD TG
476, GLP), no reproductive toxicity effect (NOAEC(P)=500-2,000ppm (=1,720-
24,080mg/m3), NOAEC(F1)=7,000 ppm(=24,080 mg/m3),
NOAEC(F2)=7,000ppm(=24,080 mg/m3)), fetal development toxicity test results
using rats (OECD TG 414, GLP), no effects other than weight loss found
(NOAEC (maternal toxicity) = 500-2,000ppm, NOAEC (developmental toxicity) =
7,000ppm, NOAEC (teratogenicity) = 7,000ppm) - As a result of the 2nd
Cyclohexane generation reproduction toxicity test using rats, the weight loss of F1 and F2 is
unique (NOEL( Systemic toxicity) = 500ppm, NOEL (reproductive toxicity) =
2,000ppm), as a result of developmental toxicity test using rats and rabbits,
overall maternal weight loss and food consumption reduction were observed as
maternal toxicity only in rats. At 2,000ppm, there is a transient weakening or
disappearance of auditory stimulation. No effect on rabbits (NOEL (rat) =
500ppm, NOEL (rabbit) = 7,000ppm) - 2-year-old test results using rats (OECD
TG 416), no effect, developmental impact test results on rats and rabbits (OECD
As a result of inhalation 2nd generation reproductive toxicity test using rats
(female/female) (OECD TG 416, GLP), food consumption during breastfeeding
was significantly reduced. Reduced food consumption during gestation. Hyaline
droplet nephropathy and tubular basophilia in males. The number of dead
pups increased in the high concentration group. (NOAEL (reproductive
toxicity)=31,680mg/m³ air (nominal), NOAEL (other: F1, F2,
n-Heptane
female/male)=10,560 mg/m³ air (nominal),LOAEL (other: F1, F2, female/male)
=31,680 mg/m³ air (nominal)) (similar material: commercial hexane) - Results of
inhalation fetal developmental toxicity test for rats (OECD TG 414, GLP),
maternal weight loss. No other effects (NOAEC (maternal toxicity) = ca. 2,000
ppm, NOAEC (developmental toxicity) > 7 000 ppm) (Similar substance:
Cyclohexane) (ECHA)
Specific target organ toxicity (Single exposure)
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Effects on the central nervous system in humans, causing fatigue, drowsiness,
dizziness, respiratory irritation, excitement, vomiting, central nervous system
Toluene depression, confusion, gait abnormalities, etc. Causes eye, nose and throat
irritation. Causes an anesthetic effect in laboratory animals. Target organ:
central nervous system
Methyl cyclopentane Irritating to airways if inhaled (KOSHA)
In humans, acute inhalation toxicity may cause dizziness or central nervous
n-Hexane system depression. Airway stimulation appears Target organ: Central nervous
system (HSDB)
Results of acute inhalation test using male/female rats OECD TG 403, tremors,
hyperactivity, rapid breathing, inability to control body Decreased
Cyclohexane immunoreactivity in immunohistological studies, convulsions in rabbits at high
concentrations, severe diarrhea, circulatory collapse and death Target organ:
central nervous system (ECHA, HSDB)
Lungs, chest, respiratory, gastrointestinal, central nervous system (NLM, RTECS,
2-Methylhexane
ICSC)
As a result of acute oral toxicity test using rats (female/female), no special
symptoms were found (similar substance CAS No.109-66-0) (OECD TG401,GLP)
Acute inhalation toxicity test using rats (female/female) Result, death of one
Cyclopentane
male (14 days), hyperactivity disorder found (first 2 hours of exposure), lung
cancer, kidney abnormality found (OECD TG 403) Not applicable for
classification in this section due to effects of acute toxicity (ECHA)
As a result of repeated administration oral toxicity test for rats, 2 animals in the
13.2 mmol/kg and 46.2 mmol/kg concentration groups died immediately after
administration, the weight gain rate decreased as the food consumption
n-Hexane
decreased, testicular epithelial atrophy was observed, Axonal edema, axonal
myelin invagination were observed, and neurohabitrological toxicity such as
atrophy of nodal myelin was observed.
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Neurotoxicity such as hind limb paralysis was observed after administration in
the 46.2 mmol/kg concentration group. NOAEL number = 6.6 mmol/kg bw,
NOAEL neurological effect number = 13.2 mmol/kg bw Subchronic inhalation
toxicity in mice: 90-day test results, The body weight of male objects in the
n-Hexane
1000 and 10000ppm concentration groups decreased, and the weight of
female objects in the 10000ppm concentration group also decreased. Nose
damage NOAEL number = 500 ppm (OECD TG 413) Target organ: nervous
system (ECHA)
EPA OPPTS 870.3465 EPA OPPTS 870.3465, adverse effects on GLP, body
weight, hematology, clinical chemistry, and histopathology of tissue, as a result
of 90-day inhalation repeated toxicity test for male/female rats. Increased liver
weight and hypertrophy of hepatocytes in the middle lobules were found.
Acute and transient effects on the central nervous system NOAEC acute,
temporary effects = 500ppm, NOAEC subchronic toxicity = 7,000ppm, 90-day
inhalation repeated toxicity test using male and female mice EPA OPPTS
Cyclohexane 870.3465, red blood cell mass circulation, plasma protein concentration slightly
increased. Acute and temporary effects on the central nervous system NOAEC
acute, temporary effects = 500ppm, NOAEC subchronic toxicity = 2,000ppm
Target organ: central nerve - result of percutaneous repeated test, irritation
lesions caused by defatting effect, 90-day inhalation test result OECD TG 413, A
temporary sedative effect was observed, but this was considered an acute
effect NOAEL=500 ppm Slight hepatotoxicity at high concentration
NOAEL=2,000 ppm (EHCA, OECD SIDS)
NOAEL 1 mg/ℓ, steam (Rat, male) - As a result of repeated inhalation exposure
for 13 weeks in experimental animals (male), kidney abnormalities appeared
2-Methylpentane
(inflammatory cell infiltration in interstitial tissue, regenerative tubule, cystic
change) observation) (OSHIRI Risk Assessment, 2010)
As a result of a combination test of reproductive/developmental toxicity
screening and repeated toxicity tests using rats, no harmful effects were
Methylcyclohexane
observed other than salivation (LOAEL=250 mg/kg bw/day) (OECD TG 422,
GLP) (SIDS)
As a result of repeated inhalation toxicity test using rats (male/female), no
special symptoms were found (OECD Guideline 413) Specific target organ
Cyclopentane toxicity (repeated exposure): NOAEL 15.49 ㎎/ℓ (Rat) 13 weeks of repeated
inhalation exposure in experimental animals Results No significant toxicological
symptoms were observed (ECHA, OSHIRI, 2009)
Effects on the liver, causing dysfunction. (NITE(2006)). - Results of subchronic
inhalation repeated toxicity test using rats, no effect NOAEL neurotoxicity =
12,470 mg/m³ air nominal, NOAEC systemic = 12,470 mg/m³ air nominal - 26-
week subchronic inhalation repeated toxicity test using male/female rats
n-Heptane
ResultOECDTG 413, acute central nervous system depression acute CNS
depression NOAEL systemic toxicity=12,350 mg/m³ air analytical, LOAEL=1,650
mg/m³ airanalytical High concentration test result, not applicable for
classification (ECHA)
Aspiration hazard
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Naphtha (petroleum) Concern for lung damage if swallowed (EU CLP)
n-Hexane Hydrocarbon, kinematic viscosity less than 20.5 mm2/s (40 ℃) (EU CLP)
Risk of chemical pneumonitis by aspiration if liquid is swallowed. (ICSC)
Cyclohexane
Kinematic viscosity 0.894 mPa sat 25℃
n-Heptane Hydrocarbon, kinematic viscosity 0.61 mm2/s (20℃) (KOSHA)
Other adverse effects No data
1) Ecotoxicity
Fish
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- [n-Hexane] : EL50 9.285 mg/L (ECHA)
- [Cyclohexane] : ErC50 9.317 ㎎/ℓ 72 hr Selenastrum capricornutum(OECD TG 201, GLP) (ECHA)
- [2-Methylhexane] : EC50 = 1.761 ㎎/ℓ 96 hr (Estimate)
- [Cyclopentane] : EC50 21.58 ㎎/ℓ 48 hr (ECHA)
- [2-Methylpentane] : EC50 3.635 ㎎/ℓ 96 hr (Estimate)
- [Methylcyclohexane] : ErC50 0.134 ㎎/ℓ 72 hr Other(Pseudokirchneriella subcapitata, Static) (ECHA)
- [n-Heptane] : EL50 4.338 ㎎/ℓ 72 hr (Estimate)
- [3-Methylhexane] : EC50 1.750 ㎎/ℓ 96 hr (Estimate)
- [3-Methylpentane] : EC50 3.635 ㎎/ℓ 96 hr (Estimate)
2) Persistence and Degradability
Persistence
- [Toluene] : 2.73 log Kow (20 °C) (ECHA)
- [Methyl cyclopentane] : log Kow 3.37 (UAKRON)
- [Naphtha (petroleum), light straight-run] : log Kow 2.1 ~ 6 (Estimate)
- [n-Hexane] : 4 log Kow (20°C, pH=7) (ECHA)
- [Cyclohexane] : 3.44 log Kow (25 °C, pH 7)
- [2-Methylhexane] : log Kow = 3.71 (Estimate)
- [Cyclopentane] : log Kow 3 (KOSHA)
- [2-Methylpentane] : log Kow 3.21 (Estimate)
- [Methylcyclohexane] : log Kow 3.88 (ECHA)
- [n-Heptane] : log Kow 4.5 (ICSC)
- [3-Methylhexane] : log Kow 3.71 (NLM;ChemIDPlus)
- [3-Methylpentane] : log Kow 3.6 (The Chemical Database/UAKRON)
Degradability No data
3) Bioaccumulative
Concentration
Biodegradable
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- [3-Methylhexane] : Non-degradable; not degraded and has a high potential to accumulate in vivo
(estimate)
- [n-Heptane] : 70 % 10 day (O2 Consumption)
4) Mobility soil
- [Methyl cyclopentane] : Koc 1600 (HSDB)
- [n-Hexane] : 2187.76 Koc (Estimate)
- [Cyclohexane] : Koc 770 (ECHA)
- [2-Methylhexane] : Koc = 1658 (Can be adsorbed in the soil)(Estimate)
- [n-Heptane] : Koc 239.7 (calculated) (ECHA)
- [3-Methylhexane] : Koc 211 (Estimates)
5) Other adverse effects
Fish - Oncorhynchus kisutch : NOEC40 d=1.39 mg/L
- [Toluene]
Crustacea - Ceriodaphnia dubia : NOEC7 d=0.74 mg/L
- [n-Hexane] : Chronic aquatic toxicity Category 2 (Harmonized classification ECHA)
- [Cyclohexane] : Algae Selenastrum capricornutum: NOEC72hr=0.94 mg/L growth rate (OECD TG 201,
GLP)
- [Methylcyclohexane] : Algae(Pseudokirchneriella subcapitata): NOErC(72h) 0.022mg/L (Static) (ECHA)
- [n-Heptane] : Fish(Oncorhynchus mykiss); 28d-NOELR 1.284 mg/L, Crustaceans(Daphnia magna); 21d-
NOEC 0.17 mg/L ,algae(Selenastrum capricornutum); 72h-NOELR 0.97 mg/L (biomass QSAR) (ECHA)
1) Disposal method Dispose of contents and container in accordance with all applicable
regulations.
2) Disposal considerations If specified in the Waste Management Act, consider the precautions
1) UN number 1133
4) Container grade Ⅱ
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15. REGULATORY INFORMATION
1) Foreign regulation
USA(CERCLA 103)
USA(EPCRA 313)
- [Toluene] : Applicable.
- [n-Hexane] : Applicable.
- [Cyclohexane] : Applicable.
EU (Classification)
- [2-Methylpentane] : H225,H304,H315,H336,H411
- [2-Methylhexane] : H225,H304,H315,H336,H410
- [Cyclohexane] : H225,H304,H315,H336,H410
- [Cyclopentane] : H225,H412
- [n-Hexane] : H225,H361f,H304,H373,H315,H336,H411
- [3-Methylpentane] : H225,H304,H315,H336,H411
- [n-Heptane] : H225,H304,H315,H336,H410
- [Methylcyclohexane] : H225,H304,H315,H336,H411
Revision number 5
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