Q1: The number of chiral carbons in chloramphenicol is:

Q1: The number of chiral carbons in chloramphenicol is:

2.00

Solution:
Q2: The number of chiral centres in Penicillin is .
Q2: The number of chiral centres in Penicillin is .
3.00

Solution:

The structure of penicillin is shown below:

So, the number of chiral centers = 3

Q3: The number of chiral carbons present in the molecule given below is ……….. .
Q3: The number of chiral carbons present in the molecule given below is ……….. .

5.00
Solution:

Total chiral carbon = 5

Q4:
The number of chiral carbon(s) present in peptide, Ile-Arg-Pro, is ……….. .
Q4:
The number of chiral carbon(s) present in peptide, Ile-Arg-Pro, is ……….. .

4.00

Solution:
Q5: The total number of C–C sigma bond/s in mesityl oxide is ............... (Round
off to the Nearest Integer).
Q5: The total number of C–C sigma bond/s in mesityl oxide is ............... (Round
off to the Nearest Integer).
5.00

Solution:
Q6: The number of acyclic structural isomers (including geometrical isomers) for pentene are
______
Q6: The number of acyclic structural isomers (including geometrical isomers) for pentene are
______
6.00

Solution:
Q7: The number of sigma bonds in
is ____________.
Q7: The number of sigma bonds in
is ____________.
10.00

Solution:

Number of sigmabonds are 10 in given compound

Q8: The dihedral angle in staggered form of Newman projection of 1, 1, 1-Trichloro ethane is
......... degree. (Round off to the nearest integer)
Q8: The dihedral angle in staggered form of Newman projection of 1, 1, 1-Trichloro ethane is
......... degree. (Round off to the nearest integer)
60.00

Solution:
Q9: An organic compound is subjected to chlorination to get compound A using 5.0 g of
chlorine. When 0.5 g of compound A is reacted with AgNO3 [Carius method], the percentage
of compound A is _______ when it forms0.3849 g of AgCl. (Round off to the nearest integer
(Atomic masses of Ag and Cl are 107.87 and 35.5 respectively)
Q9: An organic compound is subjected to chlorination to get compound A using 5.0 g of
chlorine. When 0.5 g of compound A is reacted with AgNO3 [Carius method], the percentage
of compound A is _______ when it forms0.3849 g of AgCl. (Round off to the nearest integer
(Atomic masses of Ag and Cl are 107.87 and 35.5 respectively)
19.00

Solution:

Mass of organic compound = 0.5 gm.

Mass of formed AgCl = 0.3849 gm

= 19.06
= 19
Q10: In Carius method for estimation of halogens, 0.2 g of an organic compound gave 0.188
g of AgBr. The percentage of bromine in the compound is ________ . (Nearest integer)
[Atomic mass : Ag = 108, Br = 80]
Q10: In Carius method for estimation of halogens, 0.2 g of an organic compound gave 0.188
g of AgBr. The percentage of bromine in the compound is ________ . (Nearest integer)
[Atomic mass : Ag = 108, Br = 80]
40.00

Solution:
Q11: The number of moles of CuO, that will be utilized in Dumas method for estimation
nitrogen in a sample of 57.5 g of N, N-dimethylaminopentane is ________ × 10–2. (Nearest
integer):
Q11: The number of moles of CuO, that will be utilized in Dumas method for estimation
nitrogen in a sample of 57.5 g of N, N-dimethylaminopentane is ________ × 10–2. (Nearest
integer):
1125.00

Solution:

Moles of N in N,N - dimethylaminopentane

Q12: When 0.15 g of an organic compound was analyzed using Carius method for estimation
of bromine, 0.2397 g of AgBr was obtained. The percentage of bromine in the organic
compound is ___. (Nearest integer)
[Atomic mass: Silver = 108, Bromine = 80]
Q12: When 0.15 g of an organic compound was analyzed using Carius method for estimation
of bromine, 0.2397 g of AgBr was obtained. The percentage of bromine in the organic
compound is ___. (Nearest integer)
[Atomic mass: Silver = 108, Bromine = 80]
68.00

Solution:

188 g of AgBr contains 80 g Br.

Thus, mass of Br present in 0.2397 g AgBr =
Thus, percentage of Br in organic compound =
Q13: 0.8 g of an organic compound was analysed by Kjeldahl's method for the estimation of
nitrogen. If the percentage of nitrogen in the compound was found to be 42%, then
__________ mL of 1 M H2SO4 would have been neutralized by the ammonia evolved during
the analysis.
Q13: 0.8 g of an organic compound was analysed by Kjeldahl's method for the estimation of
nitrogen. If the percentage of nitrogen in the compound was found to be 42%, then
__________ mL of 1 M H2SO4 would have been neutralized by the ammonia evolved during
the analysis.
12.00

Solution:
Q14: Number of electrophillic centres in the given compound is_____.
Q14: Number of electrophillic centres in the given compound is_____.

3.00

Solution:

This compound has 3 electrophilic centers.

Q15: Total number of possible stereoisomers of dimethyl cyclopentane is _____.
Q15: Total number of possible stereoisomers of dimethyl cyclopentane is _____.
6.00
Solution:

This will not show stereoisomer

This will show stereoisomers

Total stereoisomers possible = 6
Q16: Observe structures of the following compounds

The total number of structures/compounds which posses asymmetric carbon atoms is ____.
Q16: Observe structures of the following compounds

The total number of structures/compounds which posses asymmetric carbon atoms is ____.
3.00

Solution:

All these compound possess asymmetric carbon atoms.

Q17: The number of chiral alcohol(s) with molecular formula C4H10O is_____.
Q17: The number of chiral alcohol(s) with molecular formula C4H10O is_____.
1.00

Solution:

Possible structure of alcohols with molecular formula C4H10O are

Only 1 isomer is chiral in nature.

Q18: The number of sp3 hybridised carbons in an acyclic neutral compound with molecular
formula C4H5N is :
Q18: The number of sp3 hybridised carbons in an acyclic neutral compound with molecular
formula C4H5N is :
1

Solution:

Answer is 1
Q19: Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of (+)
isomer is +30°. The optical purity is____%
Q19: Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of (+)
isomer is +30°. The optical purity is____%
42

Solution:

Optical purity
Q20: The number of stereoisomers formed in a reaction of (±) Ph(C=O) C(OH)(CN)Ph with
HCN is_____.
Q20: The number of stereoisomers formed in a reaction of (±) Ph(C=O) C(OH)(CN)Ph with
HCN is_____.
3.00

Solution:
Q21: Number of sp2 hybrid carbon atoms present in aspartame is ____.
Q21: Number of sp2 hybrid carbon atoms present in aspartame is ____.
9.00

Solution:

The marked carbons are sp2 hybridised.

Q22: Using the provided information in the following paper chromatogram:

Fig: Paper chromatography for compounds A and B.

The calculated Rf value of A _______ × 10-1.
Q22: Using the provided information in the following paper chromatogram:

Fig: Paper chromatography for compounds A and B.

The calculated Rf value of A _______ × 10-1.
4.00

Solution:

Retardation factor
Q23: In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium
sulphate. The percentage of sulphur in the compound is _____%. (Nearest integer)
(Atomic Mass of Ba = 137 u)
Q23: In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium
sulphate. The percentage of sulphur in the compound is _____%. (Nearest integer)
(Atomic Mass of Ba = 137 u)
42.00

Solution:

Molecular mass of BaSO4 = 233 g

∴ 233 BaSO4 contain → 32 g sulphur
∴ 1.44 g BaSO4 contain → × 1.44 g sulphur
Given: 0.471 g of organic compound
Q24: The transformation occurring in Duma’s method is given below:

The value of y is ________. (Integer answer)

Q24: The transformation occurring in Duma’s method is given below:

The value of y is ________. (Integer answer)

7.00

Solution:

On balancing

On comparing y = 7
Q25: For the following reactions,

ks and ke, are, respectively, the rate constants for substitution and elimination, and ,
the correct option is ______.
(A) and

(B) and

(C) and

(D) and
Q25: For the following reactions,

ks and ke, are, respectively, the rate constants for substitution and elimination, and ,
the correct option is ______.
(A) and

(B) and

(C) and

(D) and
Solution:

The base favours substitution reaction over elimination reaction and thus . Since the bulkier
base tertiary butoxide (B) favours elimination reaction over substitution reaction,
is higher. Since , μA will be greater as it is having lower ke value.
Q26: The correct order of stability for the following alkoxides is:

(A) (C) > (A) > (B)

(B) (B) > (A) > (C)

(C) (C) > (B) > (A)

(D) (B) > (C) > (A)

Q26: The correct order of stability for the following alkoxides is:

(A) (C) > (A) > (B)

(B) (B) > (A) > (C)

(C) (C) > (B) > (A)

(D) (B) > (C) > (A)

Solution:

Higher the delocalization of the negative charge, more will be the stability of the anion.

(A) The negative charge is stabilized only through –I effect exhibited by the –NO2 group.
(B) The negative charge is stabilized by the delocalization of the double bond and the –I effect exhibited by the –NO2 group.
(C) The negative charge is stabilized by extended conjugation.
Q27: A flask contains a mixture of isohexane and 3-methylpentane. One of the liquids boils at
63°C while the other boils at 60°C. What is the best way to separate the two liquids and which
one will be distilled out first?
(A) Fractional distillation, isohexane

(B) Simple distillation, 3-methylpentane

(C) Fractional distillation, 3-methylpentane

(D) Simple distillation, isohexane

Q27: A flask contains a mixture of isohexane and 3-methylpentane. One of the liquids boils at
63°C while the other boils at 60°C. What is the best way to separate the two liquids and which
one will be distilled out first?
(A) Fractional distillation, isohexane

(B) Simple distillation, 3-methylpentane

(C) Fractional distillation, 3-methylpentane

(D) Simple distillation, isohexane

Solution:

When the difference between the B.P. of the two liquids is less than around 40oC, fractional distillation is more efficient. The
difference between the boiling points of isohexane and 3-methylpentane is only 3 degrees. So, fractional distillation is the best
suitable method. Since, isohexane has a lower boiling point, it comes out first.
Q28: Arrange the following compounds in increasing order of C—OH bond length: methanol,
phenol, p-ethoxyphenol
(A) Phenol < methanol < p-ethoxyphenol

(B) methanol < p-ethoxyphenol < phenol

(C) Phenol < p-ethoxyphenol < methanol

(D) methanol < phenol < p-ethoxyphenol

Q28: Arrange the following compounds in increasing order of C—OH bond length: methanol,
phenol, p-ethoxyphenol
(A) Phenol < methanol < p-ethoxyphenol

(B) methanol < p-ethoxyphenol < phenol

(C) Phenol < p-ethoxyphenol < methanol

(D) methanol < phenol < p-ethoxyphenol

Solution:

In methanol, there is no resonance. In phenol, there is resonance. In p-Ethoxyphenol, there is resonance involved but the
involvement of lone pair of oxygen in OH group is poor as compared with phenol due to the presence of lone pair oxygen in
OCH3 group which are also involved in resonance.
So, partial double bond character develops in C—OH bond of phenol and p-ethoxyphenol but in case of p-ethoxyphenol,
resonance is poor as compared to phenol. So, bond length follows the order: methanol > p-ethoxyphenol > phenol
Q29: The correct order of heat of combustion for following alkadienes is:

(A) C>B>A

(B) B>A>C

(C) A>B>C

(D) C>A>B
Q29: The correct order of heat of combustion for following alkadienes is:

(A) C>B>A

(B) B>A>C

(C) A>B>C

(D) C>A>B

Solution:

Heat of combustion
The trans-isomer is more stable than the cis-isomer. More the number of trans forms in a structure, higher the stability and
smaller will be heat of combustion
Q30: The number of sp2 hybrid orbitals in molecule of benzene is:
(A) 18

(B) 24

(C) 6

(D) 12
Q30: The number of sp2 hybrid orbitals in molecule of benzene is:
(A) 18

(B) 24

(C) 6

(D) 12

Solution:

Benzene (C6H6) has 6 sp2 hybridized carbons. Each carbon has 3 σ-bonds and 1 π-bond. 3 σ-bonds means that there are 3
sp2 hybrid orbitals for each carbon. Hence, the total number of sp2 hybrid orbitals is 18.
Q31: Which of the following has the shortest C–Cl bond?
(A) Cl − CH = CH2

(B) Cl − CH = CH − CH3

(C) Cl − CH = CH − OCH3

(D) Cl − CH = CH − NO2
Q31: Which of the following has the shortest C–Cl bond?
(A) Cl − CH = CH2

(B) Cl − CH = CH − CH3

(C) Cl − CH = CH − OCH3

(D) Cl − CH = CH − NO2

Solution:

There is extended conjugation present in option (d), which will reduce the length of C-Cl bond to the greatest extent which can
be represented as follows:
Q32: The decreasing order of basicity of the following amines is:

(A) I > II > III > IV

(B) IV > III > I > II

(C) II > I > III > IV

(D) IV > I > II > III

Q32: The decreasing order of basicity of the following amines is:

(A) I > II > III > IV

(B) IV > III > I > II

(C) II > I > III > IV

(D) IV > I > II > III

Solution:

The basicity of the compound depends on the availability of the lone pairs.
In compound IV, Nitrogen is sp3 hybridized.
In compound III, Nitrogen is sp2 hybridized and the lone pairs are not involved in resonance.
In compound I, Nitrogen is sp2 hybridized and the lone pairs are involved in resonance.
In compound II, Nitrogen is sp2 hybridized and the lone pairs are involved in resonance such that, they are contributing to the
aromaticity of the ring.
From the above points we can conclude that the basicity order should be IV > III > I > II.
Q33: The increasing order of the following compounds towards HCN addition is :

(A) (iii) < (i) < (iv) < (ii)

(B) (iii) < (iv) < (i) < (ii)

(C) (i) < (iii) < (iv) < (ii)

(D) (iii) < (iv) < (ii) < (i)

Q33: The increasing order of the following compounds towards HCN addition is :

(A) (iii) < (i) < (iv) < (ii)

(B) (iii) < (iv) < (i) < (ii)

(C) (i) < (iii) < (iv) < (ii)

(D) (iii) < (iv) < (ii) < (i)

Solution:

Increasing the order of reactivity towards HCN addition

Greater than electrophilicity on

group greater the reactivity in nucleophilic addition

(iii) < (i) < (iv) < (ii)

Q34: The IUPAC name for the following compound is :

(A) 2,5-dimethyl-5-carboxy-hex-3-enal

(B) 2,5-dimethyl-6-oxo-hex-3-enoic acid

(C) 6-formyl-2-methyl-hex-3-enoic acid

(D) 2,5-dimethyl-6-carboxy-hex-3-enal
Q34: The IUPAC name for the following compound is :

(A) 2,5-dimethyl-5-carboxy-hex-3-enal

(B) 2,5-dimethyl-6-oxo-hex-3-enoic acid

(C) 6-formyl-2-methyl-hex-3-enoic acid

(D) 2,5-dimethyl-6-carboxy-hex-3-enal

Solution:

2,5-Dimethyl-6-oxo-hex-3-enoic acid
Q35: The major product in the following reaction is :

(A)

(B)

(C)
(D)
Q35: The major product in the following reaction is :

(A)

(B)

(C)
(D)

Solution:

Option (c) is correct answer.

Q36: Arrange the following labelled hydrogens in decreasing order of acidity :

(A) b>a>c>d

(B) b>c>d>a

(C) c>b>d>a

(D) c>b>a>d
Q36: Arrange the following labelled hydrogens in decreasing order of acidity :

(A) b>a>c>d

(B) b>c>d>a

(C) c>b>d>a

(D) c>b>a>d
Solution:

So, the answer is b > c > d > a

Hence, option (b) is correct

Q37: Which one of the following compounds possesses the most acidic hydrogen ?
(A)

(B)

(C)

(D)
Q37: Which one of the following compounds possesses the most acidic hydrogen ?
(A)

(B)

(C)

(D)
Solution:

Due to the presence of 3 (–R) groups

Q38: Among the following compounds, which one has the shortest C – Cl bond?
(A)

(B)

(C)

(D)
Q38: Among the following compounds, which one has the shortest C – Cl bond?
(A)

(B)

(C)

(D)
Solution:
Q39: The increasing order of the acidity of the hydrogen of the following compounds is :

(A) (D) < (C) < (A) < (B)

(B) (A) < (C) < (D) < (B)

(C) (C) < (A) < (B) < (D)

(D) (B) < (C) < (A) < (D)

Q39: The increasing order of the acidity of the hydrogen of the following compounds is :

(A) (D) < (C) < (A) < (B)

(B) (A) < (C) < (D) < (B)

(C) (C) < (A) < (B) < (D)

(D) (B) < (C) < (A) < (D)

Solution:
Q40: The increasing order of basicity of the following compounds is :

(A) (D) < (A) < (B) < (C)

(B) (A) < (B) < (C) < (D)

(C) (B) < (A) < (D) < (C)

(D) (B) < (A) < (C) < (D)

Q40: The increasing order of basicity of the following compounds is :

(A) (D) < (A) < (B) < (C)

(B) (A) < (B) < (C) < (D)

(C) (B) < (A) < (D) < (C)

(D) (B) < (A) < (C) < (D)

Solution:
Q41: Among the following compounds, geometrical isomerism is exhibited by :
(A)

(B)

(C)
(D)
Q41: Among the following compounds, geometrical isomerism is exhibited by :
(A)

(B)

(C)
(D)

Solution:

are Geometrical isomer

Q42: Which of the following compounds shows geometrical isomerism?
(A) 2-methylpent-1-ene

(B) 4-methylpent-2-ene

(C) 2-methylpent-2-ene

(D) 4-methylpent-1-ene
Q42: Which of the following compounds shows geometrical isomerism?
(A) 2-methylpent-1-ene

(B) 4-methylpent-2-ene

(C) 2-methylpent-2-ene

(D) 4-methylpent-1-ene

Solution:
Q43: The increasing order of pKb values of the following compounds is :

(A) I < II < III < IV

(B) II < IV < III < I

(C) I < II < IV < III

(D) II < I < III < IV

Q43: The increasing order of pKb values of the following compounds is :

(A) I < II < III < IV

(B) II < IV < III < I

(C) I < II < IV < III

(D) II < I < III < IV

Solution:
Q44: Which one of the following compounds is non-aromatic?
(A)

(B)

(C)

(D)
Q44: Which one of the following compounds is non-aromatic?
(A)

(B)

(C)

(D)
Solution:

contains atom. So it is non-planar & hence non aromatic.

All other options follow Huckel’s rule i.e. electrons. So all are aromatic compounds.
Q45: The correct order of acid character of the following compounds is:

(A) IV > III > II > I

(B) II > III > IV > I

(C) III > II > I > IV

(D) I > II > III > IV

Q45: The correct order of acid character of the following compounds is:

(A) IV > III > II > I

(B) II > III > IV > I

(C) III > II > I > IV

(D) I > II > III > IV

Solution:

Stability of conjugate bases :

Hence, acidic strength order will be

Ka : (ii) > (iii) > (iv) > (i)
Q46: Which of the following compound is added to the sodium extract before addition of silver
nitrate for testing of halogens?
(A) Ammonia

(B) Hydrochloric acid

(C) Nitric acid

(D) Sodium hydroxide

Q46: Which of the following compound is added to the sodium extract before addition of silver
nitrate for testing of halogens?
(A) Ammonia

(B) Hydrochloric acid

(C) Nitric acid

(D) Sodium hydroxide

Solution:

Sodium carbonate extract is acidified with HNO3 only in identification of halide.

Q47: Which of the following is 'a' FALSE statement?
(A) Kjeldahl's method is used for the estimation of nitrogen in an organic compound

(B) Carius tube is used in the estimation of sulphur in an organic compound

(C) Carius method is used for the estimation of nitrogen in an organic compound

(D) Phosphoric acid produced on oxidation of phosphorus present in an organic compound is precipitated as Mg2P2O7
by adding magnesia mixture
Q47: Which of the following is 'a' FALSE statement?
(A) Kjeldahl's method is used for the estimation of nitrogen in an organic compound

(B) Carius tube is used in the estimation of sulphur in an organic compound

(C) Carius method is used for the estimation of nitrogen in an organic compound

(D) Phosphoric acid produced on oxidation of phosphorus present in an organic compound is precipitated as Mg2P2O7
by adding magnesia mixture

Solution:

Carius method is used for estimation of S & halogens.

Kjeldhal's and Dumas method is used for nitrogen estimation
Phosphoric acid produced on oxidation of phosphorus present in an organic compound is precipitated as Mg2P2O7 by adding
magnesia mixture.
Q48: In molecule, the hybridization of carbon 1, 2, 3 and 4
respectively, are:
(A) sp2, sp, sp2, sp3

(B) sp3, sp, sp3, sp3

(C) sp2, sp3, sp2, sp3

(D) sp2, sp2, sp2, sp3

Q48: In molecule, the hybridization of carbon 1, 2, 3 and 4
respectively, are:
(A) sp2, sp, sp2, sp3

(B) sp3, sp, sp3, sp3

(C) sp2, sp3, sp2, sp3

(D) sp2, sp2, sp2, sp3

Solution:
Q49: In chromatography technique, the purification of compound is independent of
(A) Length of the column or TLC plate

(B) Solubility of the compound

(C) Mobility or flow of solvent system

(D) Physical state of the pure compound

Q49: In chromatography technique, the purification of compound is independent of
(A) Length of the column or TLC plate

(B) Solubility of the compound

(C) Mobility or flow of solvent system

(D) Physical state of the pure compound

Solution:

In Chromatography, for purification, there will be no need of the physical state of pure compound.
Q50: Among the following, the aromatic compounds are:

Choose the correct answer from the following options

(A) (A) and (B) only

(B) (B) and (C) only

(C) (A), (B) and (C) only

(D) (B), (C) and (D) only

Q50: Among the following, the aromatic compounds are:

Choose the correct answer from the following options

(A) (A) and (B) only

(B) (B) and (C) only

(C) (A), (B) and (C) only

(D) (B), (C) and (D) only

Solution:

6 π electron

6 π electron
Q51: Assertion A: Enol form of acetone [CH3COCH3] exists in < 0.1% quantity. However, the
enol form of acetyl acetone [CH3COCH2OCCH3] exists in approximately 15% quantity.
Reason R: Enol form of acetyl acetone is stabilized by intramolecular hydrogen bonding,
which is not possible in enol form of acetone.
Choose the correct statement:
(A) Both A and R are true but R is not the correct explanation of A

(B) Both A and R are true and R is the correct explanation of A

(C) A is true but R is false

(D) A is false but R is true

Q51: Assertion A: Enol form of acetone [CH3COCH3] exists in < 0.1% quantity. However, the
enol form of acetyl acetone [CH3COCH2OCCH3] exists in approximately 15% quantity.
Reason R: Enol form of acetyl acetone is stabilized by intramolecular hydrogen bonding,
which is not possible in enol form of acetone.
Choose the correct statement:
(A) Both A and R are true but R is not the correct explanation of A

(B) Both A and R are true and R is the correct explanation of A

(C) A is true but R is false

(D) A is false but R is true

Solution:

stable due to intramolecular H-bonding

Q52: Statement I: Sodium hydride can be used as an oxidising agent.
Statement II: The lone pair of electrons on nitrogen in pyridine makes it basic.
Choose the correct answer from the options given below:
(A) Statement I is true but statement II is false

(B) Both statement I and statement II are false

(C) Statement I is false but statement II is true

(D) Both statement I and statement II are true

Q52: Statement I: Sodium hydride can be used as an oxidising agent.
Statement II: The lone pair of electrons on nitrogen in pyridine makes it basic.
Choose the correct answer from the options given below:
(A) Statement I is true but statement II is false

(B) Both statement I and statement II are false

(C) Statement I is false but statement II is true

(D) Both statement I and statement II are true

Solution:

⇒ NaH is used as reducing agent.

⇒ The lp on nitrogen in pyridine makes it basic
Q53: Given below are two statements:
Statement I: Retardation factor (Rf) can be measured in meter/centimetre.
Statement II: Rf value of a compound remains constant in all solvents.
Choose the most appropriate answer from the options given below :
(A) Statement I is true but statement II is false

(B) Statement I is false but statement II is true

(C) Both statement I and statement II are true

(D) Both statement I and statement II are false

Q53: Given below are two statements:
Statement I: Retardation factor (Rf) can be measured in meter/centimetre.
Statement II: Rf value of a compound remains constant in all solvents.
Choose the most appropriate answer from the options given below :
(A) Statement I is true but statement II is false

(B) Statement I is false but statement II is true

(C) Both statement I and statement II are true

(D) Both statement I and statement II are false

Solution:

Rf (Retardation factor is dimension less) and lengths should be measured in the same units.
Rf value changes with the solvent due to different degree of adsorption.
Q54: Given below are two statements:
Statement I: and AgCN both can generate nucleophile.
Statement II: KCN and AgCN both will generate nitrile nucleophile with all
reaction conditions.
Choose the most appropriate option
(A) Both statement I and statement II are true.

(B) Statement I is false but statement II is true.

(C) Both statement I and statement II are false.

(D) Statement I is true but statement II is false.

Q54: Given below are two statements:
Statement I: and AgCN both can generate nucleophile.
Statement II: KCN and AgCN both will generate nitrile nucleophile with all
reaction conditions.
Choose the most appropriate option
(A) Both statement I and statement II are true.

(B) Statement I is false but statement II is true.

(C) Both statement I and statement II are false.

(D) Statement I is true but statement II is false.

Solution:

⇒ C2H5OH & AgCN both can generate nucleophile

⇒ AgCN & KCN both not generate nitrite nucleophile in all reaction condition
because AgCN is covalent in nature so N is a donor.
While KCN is ionic in nature and K+ + -CN (nitrile) C atom is donor.
Q55: In the following molecule,

Hybridisation of Carbon a, b and c respectively are:

(A)

(B)

(C)

(D)
Q55: In the following molecule,

Hybridisation of Carbon a, b and c respectively are:

(A)

(B)

(C)

(D)

Solution:

a → sp3
b → sp2
c → sp2
Q56: In the given reaction 3-Bromo-2, 2-dimethyl butane Product A

is:
(A) 2-Ethoxy-3, 3-dimethyl butane

(B) 1-Ethoxy-3, 3-dimethyl butane

(C) 2-Ethoxy-2, 3-dimethyl butane

(D) 2-Hydroxy-3, 3-dimethyl butane

Q56: In the given reaction 3-Bromo-2, 2-dimethyl butane Product A

is:
(A) 2-Ethoxy-3, 3-dimethyl butane

(B) 1-Ethoxy-3, 3-dimethyl butane

(C) 2-Ethoxy-2, 3-dimethyl butane

(D) 2-Hydroxy-3, 3-dimethyl butane

Solution:
Q57: In Carius method, halogen containing organic compound is heated with fuming nitric
acid in the presence of:
(A)

(B)

(C)

(D)
Q57: In Carius method, halogen containing organic compound is heated with fuming nitric
acid in the presence of:
(A)

(B)

(C)

(D)

Solution:

Organic compound is heated with fuming nitric acid in the presence of silver nitrate in carius method.
AgNO3 is used as reagent to distinguish Cl–, Br– and I– respectively.
Q58:

The correct order of their reactivity towards hydrolysis at room temperature is:
(A) (A) > (B) > (C) > (D)

(B) (D) > (A) > (B) > (C)

(C) (D) > (B) > (A) > (C)

(D) (A) > (C) > (B) > (D)

Q58:

The correct order of their reactivity towards hydrolysis at room temperature is:
(A) (A) > (B) > (C) > (D)

(B) (D) > (A) > (B) > (C)

(C) (D) > (B) > (A) > (C)

(D) (A) > (C) > (B) > (D)

Solution:

Rate of hydrolysis is directly proportional to positive charge present on carbon of C = O group. Rate of hydrolysis follows
following order: Acid chloride > Acid anhydride > ester > Acid amide
Q59: Which of the following compounds does not exhibit resonance?
(A)

(B)

(C)

(D)
Q59: Which of the following compounds does not exhibit resonance?
(A)

(B)

(C)

(D)

Solution:

No conjugation is present.
Q60: Which of the following molecules does not show stereoisomerism?
(A) 3, 4-Dimethylhex-3-ene

(B) 3-Methylhex-1-ene

(C) 3-Ethylhex-3-ene

(D) 4-Methylhex-1-ene
Q60: Which of the following molecules does not show stereoisomerism?
(A) 3, 4-Dimethylhex-3-ene

(B) 3-Methylhex-1-ene

(C) 3-Ethylhex-3-ene

(D) 4-Methylhex-1-ene
Solution:
Q61: Which one among the following resonating structures is least stable?
(A)

(B)

(C)

(D)
Q61: Which one among the following resonating structures is least stable?
(A)

(B)

(C)

(D)

Solution:

Options (b), (c), (d) are resonating structures to each other while Option (a) do not represent correct structure due to positive
charge on adjacent atoms. Hence it is least stable.
Q62: Which among the following is the strongest acid?
(A)

(B)

(C)

(D)
Q62: Which among the following is the strongest acid?
(A)

(B)

(C)

(D)

Solution:

Conjugate base of compund (d) is aromatic hence it is most acidic compound.

Q63: Given below are two statements:
Statement I: Hyperconjugation is a permanent effect.

Statement II: Hyperconjugation in ethyl cation involves the overlapping of

bond with empty 2p orbital of other carbon.

Choose the correct option:
(A) Both statement I and statement II are false

(B) Statement I is incorrect, but statement II is true

(C) Statement I is correct, but statement II is false

(D) Both Statement I and statement II are true

Q63: Given below are two statements:
Statement I: Hyperconjugation is a permanent effect.

Statement II: Hyperconjugation in ethyl cation involves the overlapping of

bond with empty 2p orbital of other carbon.

Choose the correct option:
(A) Both statement I and statement II are false

(B) Statement I is incorrect, but statement II is true

(C) Statement I is correct, but statement II is false

(D) Both Statement I and statement II are true

Solution:

Hyperconjugation is permanent effect.

involve bond with empty 2p orbital hence given statement is false.

Q64: Staggered and eclipsed conformers of ethane are:
(A) Polymers

(B) Rotamers

(C) Enantiomers

(D) Mirror images

Q64: Staggered and eclipsed conformers of ethane are:
(A) Polymers

(B) Rotamers

(C) Enantiomers

(D) Mirror images

Solution:

Rotamers are any of a number of isomers of a molecule which can be inter converted by rotation of part of the molecule about
a particular bond.

Staggered and Eclipsed form of ethane are inter convertible by rotation of the molecule about a bond. Hence these are
rotamers.
Q65:

The correct order of stability of given carbocation is:

(A) A>C>B>D

(B) D>B>C>A

(C) D>B>A>C

(D) C>A>D>B
Q65:

The correct order of stability of given carbocation is:

(A) A>C>B>D

(B) D>B>C>A

(C) D>B>A>C

(D) C>A>D>B

Solution:
Q66: Which one of the following compounds is non-aromatic?
(A)

(B)

(C)

(D)
Q66: Which one of the following compounds is non-aromatic?
(A)

(B)

(C)

(D)
Solution:
Q67: The number of stereoisomers possible for 1, 2-dimethyl cyclopropane is:
(A) One

(B) Four

(C) Two

(D) Three
Q67: The number of stereoisomers possible for 1, 2-dimethyl cyclopropane is:
(A) One

(B) Four

(C) Two

(D) Three

Solution:
Q68: The major product (A) formed in the reaction given below is:

(A)

(B)

(C)

(D)
Q68: The major product (A) formed in the reaction given below is:

(A)

(B)

(C)

(D)
Solution:
Q69: The correct order of reactivity of the given chlorides with acetate in acetic acid is
(A)

(B)

(C)

(D)
Q69: The correct order of reactivity of the given chlorides with acetate in acetic acid is
(A)

(B)

(C)

(D)
Solution:

As it is example of SN1. So, carbocation stability ↑, reaction rate ↑.

Q70: Choose the correct name for compound given below :

(A) (4E)-5-Bromo-hex-4-en-2-yne

(B) (2E)-2-Bromo-hex-4-yn-2-ene

(C) (2E)-2-Bromo-hex-2-en-4-yne

(D) (4E)-5-Bromo-hex-2-en-4-yne
Q70: Choose the correct name for compound given below :

(A) (4E)-5-Bromo-hex-4-en-2-yne

(B) (2E)-2-Bromo-hex-4-yn-2-ene

(C) (2E)-2-Bromo-hex-2-en-4-yne

(D) (4E)-5-Bromo-hex-2-en-4-yne
Solution:

h.p. ⇒ higher priority

l.p. ⇒ lower priority
(2E) –2- bromo hex –2- en–4-yne
Q71: The major product of the following reaction is?

(A)

(B)

(C)

(D)
Q71: The major product of the following reaction is?

(A)

(B)

(C)

(D)
Solution:

NaOH + EtOH is known as alcoholic NaOH, so it gives E2 reaction with given alkyl halide.
Q72: Which one of the following pairs of isomers is an example of metamerism?
(A)

(B)

(C)

(D)
Q72: Which one of the following pairs of isomers is an example of metamerism?
(A)

(B)

(C)

(D)
Solution:

Metamers are compounds which have different alkyl groups present along both side of polyvalent functional group.
Only options 4 represent metamers

(1) These are chain isomers

(2) Not isomers having different molecular formula

(3) Position isomers

Q73: Arrange the following carbocations in decreasing order of stability.

(A) B>A>C

(B) A>B>C

(C) C>B>A

(D) C>A>B
Q73: Arrange the following carbocations in decreasing order of stability.

(A) B>A>C

(B) A>B>C

(C) C>B>A

(D) C>A>B

Solution:

Among the given carbocations, B is most stable as Lone pair of oxygen will be involved in resonance due to which B
carbocation gets stabilised . Then ,Carbocation A will show +I effect and has 4 alpha hydrogens which stabilises carbocation
A .But Carbocation C shows -I effect due to which it is least stable. So, the correct order is B > A > C
Q74: In the following structures, which one is having staggered conformation with maximum
dihedral angle?
(A)

(B)
(C)

(D)
Q74: In the following structures, which one is having staggered conformation with maximum
dihedral angle?
(A)

(B)
(C)

(D)
Solution:

In anti conformation the dihedral angle is 180o (maximum)

Q75: The IUPAC name of ethylidene chloride is:
(A) 1-Chloroethene

(B) 1-Chloroethyne

(C) 1,2-Dichloroethane

(D) 1,1-Dichloroethane
Q75: The IUPAC name of ethylidene chloride is:
(A) 1-Chloroethene

(B) 1-Chloroethyne

(C) 1,2-Dichloroethane

(D) 1,1-Dichloroethane

Solution:

1,1-Dichloreoethane
Q76:
Consider the above reaction and identify the intermediate ‘X’
(A)

(B)

(C)

(D)
Q76:
Consider the above reaction and identify the intermediate ‘X’
(A)

(B)

(C)

(D)
Solution:
Q77: Which will have the highest enol content?
(A)

(B)

(C)

(D)
Q77: Which will have the highest enol content?
(A)

(B)

(C)

(D)
Solution:

Enol form of (c) is most stable due to formation of aromatic benzene-1,3,5-triol.

So, option (c) has maximum enol content.

Q78: Which of the following is most stable?
(A)

(B)

(C)
(D)
Q78: Which of the following is most stable?
(A)

(B)

(C)
(D)
Solution:

Aromatic molecule is the most stable

Hence (a) is correct.
Q79: Which one of the following techniques is not used to spot components of a mixture
separated on a thin layer chromatographic plate?
(A) I2 (Solid)

(B) U.V. Light

(C) Visualisation agent as a component of mobile phase

(D) Spraying of an appropriate reagent

Q79: Which one of the following techniques is not used to spot components of a mixture
separated on a thin layer chromatographic plate?
(A) I2 (Solid)

(B) U.V. Light

(C) Visualisation agent as a component of mobile phase

(D) Spraying of an appropriate reagent

Solution:

The function of the mobile phase is to carry the components present on a thin layer chromatographic plate.
Q80: Which of the following structures are aromatic in nature?

(A) A, B, C and D

(B) Only A and B

(C) Only A and C

(D) Only B, C and D

Q80: Which of the following structures are aromatic in nature?

(A) A, B, C and D

(B) Only A and B

(C) Only A and C

(D) Only B, C and D

Solution:

and are aromatic as they are cyclic, planar and have

Q81: The formula of the purple colour formed in Laissaigne’s test for sulphur using sodium
nitroprusside is
(A) NaFe[Fe(CN)6]

(B) Na[Cr(NH3)2(NCS)4]

(C) Na2[Fe(CN)5(NO)]

(D) Na4[Fe(CN)5(NOS)]
Q81: The formula of the purple colour formed in Laissaigne’s test for sulphur using sodium
nitroprusside is
(A) NaFe[Fe(CN)6]

(B) Na[Cr(NH3)2(NCS)4]

(C) Na2[Fe(CN)5(NO)]

(D) Na4[Fe(CN)5(NOS)]

Solution:

Na2S + Na2[Fe(CN)5NO] Na4[Fe(CN)5NOS]

Sodium sulphide reacts with sodium nitroprusside to form a violet colour compound, which confirms the presence of sulphur.
Q82: The correct IUPAC name of the following compound is

(A) 4-methyl-2-nitro-5-oxohept-3-enal

(B) 4-methyl-5-oxo-2-nitrohept-3-enal

(C) 4-methyl-6-nitro-3-oxohept-4-enal

(D) 6-formyl-4-methyl-2-nitrohex-3-enal
Q82: The correct IUPAC name of the following compound is

(A) 4-methyl-2-nitro-5-oxohept-3-enal

(B) 4-methyl-5-oxo-2-nitrohept-3-enal

(C) 4-methyl-6-nitro-3-oxohept-4-enal

(D) 6-formyl-4-methyl-2-nitrohex-3-enal

Solution:

4-methyl-6-nitro-3-oxohept-4-enal
Q83: Which of the following carbocations is most stable?
(A)

(B)

(C)

(D)
Q83: Which of the following carbocations is most stable?
(A)

(B)

(C)

(D)

Solution:

More is the delocalization of charge, more will be the stability of carbonation. Hence, (d) is correct.
Q84: Arrange the following in decreasing acidic strength.

(A) A>B>C>D

(B) B>A>C>D

(C) D>C>A>B

(D) D>C>B>A
Q84: Arrange the following in decreasing acidic strength.

(A) A>B>C>D

(B) B>A>C>D

(C) D>C>A>B

(D) D>C>B>A
Solution:

-I effect of -NO2 group is stronger than -OCH3 group.

So, the order is A > B > C > D
Q85: Which of the following compounds is not aromatic?
(A)

(B)

(C)

(D)
Q85: Which of the following compounds is not aromatic?
(A)

(B)

(C)

(D)

Solution:

is a non-planar compound, hence it is not aromatic.

All other molecules follow Huckel rule, hence they are aromatic.
Q86: The correct stability order of the following diazonium salt is

(A) (A) > (B) > (C) > (D)

(B) (A) > (C) > (D) > (B)

(C) (C) > (A) > (D) > (B)

(D) (C) > (D) > (B) > (A)

Q86: The correct stability order of the following diazonium salt is

(A) (A) > (B) > (C) > (D)

(B) (A) > (C) > (D) > (B)

(C) (C) > (A) > (D) > (B)

(D) (C) > (D) > (B) > (A)

Solution:

Diazonium salt containing aryl group directly linked to electron donating group is most stable due to resonance. The +M effect
stabilizes the intermediate whereas the electron withdrawing group on benzene destabilizes the intermediate at para position.

Order will be (A) > (C) > (D) > (B)

Q87: The correct decreasing order of priority of functional groups in naming an organic
compound as per IUPAC system of nomenclature is :
(A) –COOH > –CONH2 > –COCl > –CHO

(B) –SO3H > –COCl > –CONH2 > –CN

(C)

(D) –COOH > –COOR > –CONH2 > –COCl

Q87: The correct decreasing order of priority of functional groups in naming an organic
compound as per IUPAC system of nomenclature is :
(A) –COOH > –CONH2 > –COCl > –CHO

(B) –SO3H > –COCl > –CONH2 > –CN

(C)

(D) –COOH > –COOR > –CONH2 > –COCl

Solution:

The order of decreasing priority for functional group is

Hence correct order is

–SO3H > –COCl > –CONH2 > –CN
Q88: Which of the following is not an example of benzenoid compound ?
(A)

(B)

(C)

(D)
Q88: Which of the following is not an example of benzenoid compound ?
(A)

(B)

(C)

(D)
Solution:

Option (b) is not a benzenoid compound, and it exists in tub shape (non-aromatic molecule).
Q89: Given below are two statements. One is labelled as Assertion A and the other is labelled
as Reason R.
Assertion A: [6] Annulene. [8] Annulene and cis –[10] Annulene, are respectively aromatic,
not-aromatic and aromatic.

[6] Annulene

[8] Annulene

Cis-[10] Annulene

Reason R: Planarity is one of the requirements of aromatic systems.

In the light of the above statements, choose the most appropriate answer from the options
given below.
(A) Both A and R are correct and R is the correct explanation of A.

(B) Both A and R are correct but R is NOT the correct explanation of A.

(C) A is correct but R is not correct.

(D) A is not correct but R is correct.

Q89: Given below are two statements. One is labelled as Assertion A and the other is labelled
as Reason R.
Assertion A: [6] Annulene. [8] Annulene and cis –[10] Annulene, are respectively aromatic,
not-aromatic and aromatic.

[6] Annulene

[8] Annulene

Cis-[10] Annulene

Reason R: Planarity is one of the requirements of aromatic systems.

In the light of the above statements, choose the most appropriate answer from the options
given below.
(A) Both A and R are correct and R is the correct explanation of A.

(B) Both A and R are correct but R is NOT the correct explanation of A.

(C) A is correct but R is not correct.

(D) A is not correct but R is correct.

Solution:

[6] Annulene is aromatic because it is planar. [8] Annulene and [10] Annulene are both not aromatic because they are not
planar. So, Assertion (A) is not correct. Reason (R) is correct because planarity is one of the requirements of an aromatic
system.
Q90: In Carius method of estimation of halogen, 0.45 g of an organic compound gave 0.36 g
of AgBr. Find out the percentage of bromine in the compound.
(Molar masses: AgBr = 188 g mol-1, Br = 80 g mol–1)
(A) 34.04%

(B) 40.04%

(C) 36.03%

(D) 38.04%
Q90: In Carius method of estimation of halogen, 0.45 g of an organic compound gave 0.36 g
of AgBr. Find out the percentage of bromine in the compound.
(Molar masses: AgBr = 188 g mol-1, Br = 80 g mol–1)
(A) 34.04%

(B) 40.04%

(C) 36.03%

(D) 38.04%

Solution:

188 g of AgBr = 80 g of Br
0.36 g of AgBr
% of Br in given organic compound
Q91: Match List-I with List-II

List-I (Mixture) List-II (Purification Process)

(A) Chloroform & Aniline (I) Steam distillation
(B) Benzoic acid & Napthalene (II) Sublimation
(C) Water & Aniline (III) Distillation
(D) Napthalene & Sodium chloride (IV) Crystallisation

(A) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

(B) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

(C) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

(D) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Q91: Match List-I with List-II

List-I (Mixture) List-II (Purification Process)

(A) Chloroform & Aniline (I) Steam distillation
(B) Benzoic acid & Napthalene (II) Sublimation
(C) Water & Aniline (III) Distillation
(D) Napthalene & Sodium chloride (IV) Crystallisation

(A) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

(B) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

(C) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

(D) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Solution:

List-I (Mixture) List-II (Purification Process)

(A) Chloroform & Aniline (III) Distillation
(B) Benzoic acid & Napthalene (IV) Crystallisation
(C) Water & Aniline (I) Steam distillation
(D) Napthalene & Sodium chloride (II) Sublimation
Q92: Which among the following is the strongest Bronsted base ?
(A)

(B)

(C)
(D)
Q92: Which among the following is the strongest Bronsted base ?
(A)

(B)

(C)
(D)

Solution:

is the strongest base among the given compounds due to maximum +I effect over ‘N’ atom.
Q93: Correct structure of -methylcyclohexane carbaldehyde is :
(A)

(B)

(C)

(D)
Q93: Correct structure of -methylcyclohexane carbaldehyde is :
(A)

(B)

(C)

(D)
Solution:
Q94: Given below are two statements.

Statement I : The compound is optically active.

Statement II : is mirror image of above compound A.

In the light of the above statement, choose the most appropriate answer from the options
given below.
(A) Both Statement I and Statement II are correct

(B) Both Statement I and Statement II are incorrect.

(C) Statement I is correct but Statement II is incorrect.

(D) Statement I is incorrect but Statement II is correct.
Q94: Given below are two statements.

Statement I : The compound is optically active.

Statement II : is mirror image of above compound A.

In the light of the above statement, choose the most appropriate answer from the options
given below.
(A) Both Statement I and Statement II are correct

(B) Both Statement I and Statement II are incorrect.

(C) Statement I is correct but Statement II is incorrect.

(D) Statement I is incorrect but Statement II is correct.
Solution:
Therefore, statement I is true, but statement II is false.
Q95: The decreasing order of reactivity towards dehydrohalogenation (E1) reaction of the
following compounds is:

(A) B>A>D>C

(B) B>D>C>A

(C) B>D>A>C

(D) D>B>C>A
Q95: The decreasing order of reactivity towards dehydrohalogenation (E1) reaction of the
following compounds is:

(A) B>A>D>C

(B) B>D>C>A

(C) B>D>A>C

(D) D>B>C>A

Solution:

In E1 mechanism, the rate determining step is formation of carbocation. So, stability of carbocation formed decides the rate.
In option D, the cation formed is resonance stabilised. In option C, the cation formed is a 2o carbocation.
In option A and B, the carbocations formed are 1o but there is a chance of rearrangement in option b and after the
rearrangement, the carbocation formed in option b will be allylic. So, the order of reaction is as follows:
D > B > C > A.
Q96: The decreasing order of basicity for the following intermediates is (from strong to weak)

(A) A>B>D>E>C

(B) B>A>D>C>E

(C) A>B>E>D>C

(D) C>E>D>B>A
Q96: The decreasing order of basicity for the following intermediates is (from strong to weak)

(A) A>B>D>E>C

(B) B>A>D>C>E

(C) A>B>E>D>C

(D) C>E>D>B>A

Solution:

As we know weaker the conjugate base, stronger the acid and higher is the stability of conjugate base.
The order of stability of conjugate base:

Hence, the order of basicity

A>B>D>E>C
Q97: Compound with molecular formula can show :
(A) Both positional isomerism and metamerism

(B) Metamerism

(C) Functional group isomerism

(D) Positional isomerism

Q97: Compound with molecular formula can show :
(A) Both positional isomerism and metamerism

(B) Metamerism

(C) Functional group isomerism

(D) Positional isomerism

Solution:

C3H6O DOU = 1
CH3 – CH3 – CH = O and

are functional isomer

Q98: Which of the following is an aromatic compound?
(A)

(B)

(C)

(D)
Q98: Which of the following is an aromatic compound?
(A)

(B)

(C)

(D)
Solution:

electron system
It is aromatic in nature.
Q99: Mesityl oxide is a common name of :
(A) 4-Methyl pent-3-en-2-one

(B) 2,4-Dimethyl pentan-3-one

(C) 3-Methyl cyclohexane carbaldehyde

(D) 2-Methyl cyclohexanone

Q99: Mesityl oxide is a common name of :
(A) 4-Methyl pent-3-en-2-one

(B) 2,4-Dimethyl pentan-3-one

(C) 3-Methyl cyclohexane carbaldehyde

(D) 2-Methyl cyclohexanone

Solution:

(Mesityl oxide)
4-methyl pent – 3 – en – 2 – one
Q100: Glycerol is separated in soap industries by :
(A) Fractional distillation

(B) Distillation under reduced pressure

(C) Differential extraction

(D) Steam distillation

Q100: Glycerol is separated in soap industries by :
(A) Fractional distillation

(B) Distillation under reduced pressure

(C) Differential extraction

(D) Steam distillation

Solution:

Glycerol is separated by reduced pressure distillation in soap industries

Hence, the answer is (b)
Q101: The IUPAC name of the following compound is :

(A) 2 - nitro - 4- hydroxymethyl -5- amino benzaldehyde

(B) 3 - amino - 4- hydroxymethyl -5- nitro benzaldehyde

(C) 4 - amino - 2- formyl -5-hydroxymethyl nitrobenzene

(D) 5 - amino - 4- hydroxymethyl -2- nitro benzaldehyde

Q101: The IUPAC name of the following compound is :

(A) 2 - nitro - 4- hydroxymethyl -5- amino benzaldehyde

(B) 3 - amino - 4- hydroxymethyl -5- nitro benzaldehyde

(C) 4 - amino - 2- formyl -5-hydroxymethyl nitrobenzene

(D) 5 - amino - 4- hydroxymethyl -2- nitro benzaldehyde

Solution:

5 - amino - 4- hydroxymethyl -2- nitro benzaldehyde

Q102:
Which purification technique is used for the organic compound that decomposes near its
boiling point?

(A) Simple distillation

(B) Steam distillation

(C) Fractional distillation

(D) Reduced pressure distillation

Q102:
Which purification technique is used for the organic compound that decomposes near its
boiling point?

(A) Simple distillation

(B) Steam distillation

(C) Fractional distillation

(D) Reduced pressure distillation

Solution:

Reduced pressure distillation or vacuum distillation is used for the purification of organic liquids which decompose at or below
their boiling point.
Q103: Which one of the following set of elements can be detected using sodium fusion
extract?
(A) Sulfur, Nitrogen, Phosphorous, Halogens

(B) Phosphorous, Oxygen, Nitrogen, Halogens

(C) Nitrogen, Phosphorous, Carbon, Sulfur

(D) Halogens, Nitrogen, Oxygen, Sulfur

Q103: Which one of the following set of elements can be detected using sodium fusion
extract?
(A) Sulfur, Nitrogen, Phosphorous, Halogens

(B) Phosphorous, Oxygen, Nitrogen, Halogens

(C) Nitrogen, Phosphorous, Carbon, Sulfur

(D) Halogens, Nitrogen, Oxygen, Sulfur

Solution:

By sodium fusion extract we can detect sulphur, nitrogen, Phosphorous and halogens, because they are converted in to their
ionic form with sodium metal.
Q104:

Among the given species the resonance stabilised carbocations are:

(A) (C) and (D) only

(B) (A), (B) and (D) only

(C) (A) and (B) only

(D) (A), (B) and (C) only

Q104:

Among the given species the resonance stabilised carbocations are:

(A) (C) and (D) only

(B) (A), (B) and (D) only

(C) (A) and (B) only

(D) (A), (B) and (C) only

Solution:

Positive charge is in conjugation with pi bond in the A and B only hence only A and B are resonance stabilized carbocation.
Q105: Given below are two statements: one is labelled as Assertion (A) and the other is
labelled as Reason (R).
Assertion (A): A simple distillation can be used to separate a mixture of propanol and
propanone.
Reason (R): Two liquids with a difference of more than 25°C in their boiling points can be
separated by simple distillations.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) (A) is false but (R) is true.

(B) Both (A) and (R) are correct but is(R) not the correct explanation of (A).

(C) (A) is true but (R) is false.

(D) Both (A) and (R) are correct and (R) is the correct explanation of (A).
Q105: Given below are two statements: one is labelled as Assertion (A) and the other is
labelled as Reason (R).
Assertion (A): A simple distillation can be used to separate a mixture of propanol and
propanone.
Reason (R): Two liquids with a difference of more than 25°C in their boiling points can be
separated by simple distillations.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) (A) is false but (R) is true.

(B) Both (A) and (R) are correct but is(R) not the correct explanation of (A).

(C) (A) is true but (R) is false.

(D) Both (A) and (R) are correct and (R) is the correct explanation of (A).

Solution:

A method of separating mixtures based on differences in their volatilities in a boiling liquid mixture. Two liquids with a
difference of more than 25°C in their boiling points can be separated by simple distillations.
Both assertion & reason are correct & (R) is the correct explanation of (A)
Q106: Arrange the following conformational isomers of n-butane in order of their increasing
potential energy:

(A) II < III < IV < I

(B) I < IV < III < II

(C) II < IV < III < I

(D) I < III < IV < II

Q106: Arrange the following conformational isomers of n-butane in order of their increasing
potential energy:

(A) II < III < IV < I

(B) I < IV < III < II

(C) II < IV < III < I

(D) I < III < IV < II

Solution:

More stable less potential energy.

Stability order: I > III > IV > II
So Potential energy: II > IV > III > I
Q107: Which one of the following compounds is aromatic in nature?
(A)

(B)

(C)

(D)
Q107: Which one of the following compounds is aromatic in nature?
(A)

(B)

(C)

(D)
Solution:

(1) (Acenaphthene)

4πe – in ring conjugation - Anti Aromatic

4πe – in ring conjugation - Antiaromatic

NOTE: As Correct answer is A and D but as per NTA key answer is D only
Q108: The IUPAC name of the following compound is:

(A) 3-Bromo-5-methylcylopentane carboxylic acid

(B) 4-Bromo-2-methylcyclopentane carboxylic acid

(C) 5-Bromo-3-methylcylopentanoic acid

(D) 3-Bromo-5-methylcylopentanoic acid

Q108: The IUPAC name of the following compound is:

(A) 3-Bromo-5-methylcylopentane carboxylic acid

(B) 4-Bromo-2-methylcyclopentane carboxylic acid

(C) 5-Bromo-3-methylcylopentanoic acid

(D) 3-Bromo-5-methylcylopentanoic acid

Solution:

4-Bromo-2-methylcyclopentane carboxylic acid

Q109: Nitrogen can be estimated by Kjeldahl’s method for which of the following compound ?
(A)

(B)

(C)
(D)
Q109: Nitrogen can be estimated by Kjeldahl’s method for which of the following compound ?
(A)

(B)

(C)
(D)

Solution:

For this compound, nitrogen can be estimated by Kjeldahl’s method.

Q110: Match List-I with List-II:

List-I List-II
Test/Reagents/Observation(s) Species detected
(a) Lassaigne’s Test (i) Carbon
(b) Cu(II) oxide (ii) Sulphur
(iii) N, S, P and
(c) Silver nitrate
halogen
(d) The sodium fusion extract gives black precipitate with acetic acid (iv) Halogen
and lead acetate Specifically

Tile correct match is:

(A) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)

(B) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

(C) (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)

(D) (a)-(i), (b)-(ii), (c)-(iv), (d)- (iii)

Q110: Match List-I with List-II:

List-I List-II
Test/Reagents/Observation(s) Species detected
(a) Lassaigne’s Test (i) Carbon
(b) Cu(II) oxide (ii) Sulphur
(iii) N, S, P and
(c) Silver nitrate
halogen
(d) The sodium fusion extract gives black precipitate with acetic acid (iv) Halogen
and lead acetate Specifically

Tile correct match is:

(A) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)

(B) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

(C) (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)

(D) (a)-(i), (b)-(ii), (c)-(iv), (d)- (iii)

Solution: