05-11-2023 - SR - STAR CO-SC (MODEL-A) - Jee - Adv - 2020 - P2 - GTA-4 - QP

Yashpatil TG~ @bohring_bot
SR.STAR CO-SC(MODEL-A) Date: 05-11-23

Time: 3HRS GTA-5 Max. Marks: 198
Name of the Student: ___________________ H.T. NO:
05-11-23_ SR.STAR CO-SC(MODEL-A) _JEE-ADV_GTA-4(P2)_SYLLABUS
PHYSICS: TOTAL SYLLABUS
CHEMISTRY: TOTAL SYLLABUS
MATHEMATICS: TOTAL SYLLABUS

Narayana IIT Academy 05-11-23_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_GTA-4_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -2 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -2 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
SR.IIT_*CO-SC Page. No. 2

MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. Number of complex numbers " z " satisfying
| z (3  4i)  z (3  4i )  4 |  | z (4  3i )  z (4  3i )  6 | 10 and | z  1|  | z  i | 2 is
2. A 2  6 A  6 A 1  11I " A 3  I , " A 3  8I ", are both non singular matrices of order 2,
  A  1
then adj adj
| A |     , then  
  
x 1 y  3 z  4
3. The image of the line   in the plane 2 x  y  z  3  0 be L. A plane
3 5 2
7 x  py  qz  r  0 is such that it contains line L and perpendicular to
2 x  y  z  3  0 then p  3q  r 
dy 1
4. 2 xy  y 2  2 x 2  0; y  2 when x  1 , then value of y when x  is  , then | ln  |
dx e
5. If the complete set of values of a for which ax 2  (3  2a) x  6  0, a  0 is positive for
c 2  16d 2
exactly three negative integral values of x is (c,d] then the value of is......
2
n
r 3
 6r 2  11r  2  2r 
6. lt
n

r 1  r  3 !
  where  n  N  , then    = _____(where [.] denotes
G.I.F)

SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. Let ' f(a) ' be the area bounded by the curves y | x  1|  | x  1| and y  a  2 | x  a | .
Then which of the following options is/are correct?
A) f (2)  f (3) B) f (4)  1 C) f (1)f (2) D) f (2)  f (3)
8. f ( x )  sin  x  tan 1 x   cos  x  cot 1 x  ; x  R , then which of the following options is

/are correct?
A) y  f ( x) is an odd function
B) Range of y  f ( x) is [2,2]

C) The least positive value of ' x ' for which f ( x)  2 is  , then   .
4
D)  0 f ( x)dx   1 where [] denotes G.I.F

 /4
 
9. Let ' S1 ' be the set of all real points lying on  y 2  4 x  x 2  y 2  4 x  4 y   0 and let
' S 2 ' be the set of all real points lying on y  a ( x  2) . Then which of the following
options is/are correct? ( a  R ) .
 1 3 
A) Values of ' a ' for which n  S1  S2  is 1 is  ,1  
 2 2 
 3 1 
B) Values of ' a ' for which n  S1  S2  is 4 is 1  ,   {0}
 2 2 
C) Number of values of ' a ' for which n  S1  S2  is 3 is 4 .
D) Number of values of ' a ' for which n  S1  S2  is 3 is 3 .

10. tan 1 x  tan 1 f ( x)  tan 1 (2) , then which of the following options is/are correct?
A) Minimum value of x 2  ( f ( x )) 2  3  5
 1 
B) Domain of y  f ( x) is  ,  
2 
C) f (4)  f 1 (4)
D) | x |  | f ( x) | 2 for exactly 2 values of ' x '.
11. 1,1,2,3,3,4,5,5 are the numbers written on eight separate cards. Three cards are picked at
random. Then which of the following options is/are correct?
13
A) Probability that sum of 3 numbers on the picked cards is odd is .
28
B) Probability that variance of the 3 numbers on the picked cards is the greatest variance
1
possible is .
7
1
C) Probability that sum of 3 numbers on the picked cards is odd is .
2
D) Probability that variance of the 3 numbers on picked cards is the least variance
1
possible is .
14
 3  cos x  2  sin x
12. I   /2 dx, J   / 2 dx , then which of the
13  3cos x  2sin x 13  3cos x  2sin x
following options is/ are correct?
1 27  1 27 
A) I    ln B) J    ln
13  8  13  8 
 2
C) 3I  2 J  D) 2 I  3J  ln
2 3

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
x2 y 2
13. Mid point of the chord, intercepted on the line 2 x  y  3  0 by the ellipse  1
10 6
 
is  ,  , then    
 23 23 
14. If a, b, c are the distinct roots of 2x 3  x 2  12  0 , then

2bc  a 2 c2 b2
1
c2 2ac  b 2 a2   , then 

b2 a2 2ab  c 2
e   sec    (ln5) , then   ______

2
2 x ln 5
1 1
1  x2
15. It lim 2
x 0 
x  tan 1
 sin  tan x  
1
16. The coefficients of x n , x n 1 and x n 2 in the binomial expansion of (1  x) 23 are in A.P.
Then arithmetic mean of possible values of n is
2023
 r   r  1
17.  cos 2    cos    
r 1  3   3  4
    
18. u  aiˆ, v  biˆ  bjˆ,   ciˆ  cjˆ  ckˆ, a, b, c  I and [u v  ]  12 , then maximum volume of
    
the tetrahedron formed by the coterminous edges u , v and u  (v  w) is ___ cu.units.

PHYSICS MAX.MARKS: 66
numeric
19. A dumbbell consisting of two masses m each, connected by a light rigid rod of length  ,
falls on two pads of equal height, through a height h. The coefficients of restitution are
1/3 and 2/3 respectively. The maximum height to which the centre of mass of the
dumbbell rise after bouncing off the pads is h / n . Find the value of n .
20. The plates P and Q of a photocell have a separation of 10cm. They are connected
through a galvanometer without any cell. Bi-chromatic light of wavelength 4000A0 and
6000 A0 are incident on plate Q whose work function is 3.028 eV. If a uniform magnetic
field B exists parallel to the plates such that the galvanometer shows zero deflection. If
the minimum value of B for which this happens is k  106 T , then find the value of k.
12400
(Take mass of the electron as 9  1031 kg and energy of photon  eV )
 (in A0 )
21. A boomerang has mass m, surface area A, radius of curvature of lower surface r and it
is moving with velocity V in air of density  . The resistive force on it is given by
 Ar
2  aV b Ac log . The value of a  b  c is _______
m

22. Two parallel beams of light P and Q containing radiations of wavelength 4000 A0 and
5000 A0 which are mutually coherent are incident on a prism normally as shown in
figure. The refractive index of prism is given as   1.20  b /  2  where  is in A0
and b  8  1015 . Only one wavelength suffers total internal reflection at face AC and the
other wavelength when comes out from AC will have intensities 4I and I in beams P and
Q. These emerging beams are brought to focus by a convex lens. The light intensity at
focus is nI. Find n ?
23. A thin uniform rod of length 2 and specific gravity 0.75 is hinged at one end to a point
at a vertical distance  / 2 above the water surface with other end immersed in water.

The rod inclination to horizontal in equilibrium is where n is __________
n
24. At a particular instant a source of sound of frequency 100 Hz is at (2m, 1m) and an
observer is at (5m, 5m). The velocity of source and observer are 15  2iˆ  ˆj  m / s and
5iˆ  15 ˆj m / s respectively at this instant. The velocity of sound in air is 330 m/s. The
frequency of the sound received by the observer is found to be 15x Hz . Find the value of
x.

correct options.
option.
25. A charged particle having its charge to mass ratio as  goes in a conical pendulum of
length L making an angle  with vertical and angular velocity  . If a magnetic field B
is directed vertically downwards (see figure), then choose correct options.

1 g 
A) B  
  L cos  
B) Angular momentum of the particle about the point of suspension remains constant
C) If the direction of B were reversed maintaining same  and L, then  will remain
unchanged
D) Rate of change of angular momentum of the particle about the point of suspension is
not a constant vector
26. A ring of mass m, radius R, cross-sectional area A and Young’s modulus Y is kept on a
smooth cone of radius 2R and semi vertical angle 450 , as shown in the figure. Assume
that the extension in the ring is small.
A) The tension in the ring will be same throughout
B) The tension in the ring will be independent of the radius of ring
mgR
C) The extension in the ring will be
AY
m2 g 2 R
D) Elastic potential energy stored in the ring will be
8 YA

27. A thin cylindrical metal rod is bent into a ring with a small gap as shown in figure. On
heating the system.
A)  decreases, r and d increases B) r and d increases

C)  , d and r increases D)  is constant
28. A thin uniform rod of mass 5 kg and length 1m is held in horizontal position with the
help of strings attached to ends of rod. Other ends of strings are held by some external
agent. Now end A is pulled down with speed vA  3t and B is pulled down with speed
vB  t where t is time in sec. Choose the correct choices at time t = 0.
A) Angular acceleration of rod is 2 rad / s 2 B) Tension in the left string is 185/6 N

C) Acceleration of rod is 1 m / s 2 D) Tension in the right string is 170/3 N
29. ‘A’ is a huge planet with uniform mass distribution, mass M, radius R. B is a circular
R
tunnel made in it, concentric with planet. Radius of tunnel is r ,  r   cross-sectional
 2
diameter is d (d  r ) . C is a small ball of mass m(m  M ) which moving freely inside
the tunnel without friction in a uniform circular motion, take acceleration due to gravity
on surface of A as g:

R
A) If contact force on C is double the gravitational force, its time period  2 .
3g
R
B) If contact force on C is double the gravitational force, its time period  2 .
g
C) If contact force is zero, time period T, radius of tunnel r, then T  r .
D) If contact force is zero, time period T, radius of tunnel r, then T would be

independent of r.
30. In a projectile motion neglecting air drag let tOA  t1 and t AB  t2 . The horizontal
displacement from O to A is R1 and from A to B is R2 . Maximum height is H and time
of flight is T. If air drag is to be considered, then choose the correct alternative(s).
A) t1 will decrease B) H will increase

C) R1 will decrease while R2 will increase D) H will decrease

31. Two spheres A and B of the same mass m and the same radius are placed on a rough
horizontal surface. A is a uniform hollow sphere and B is uniform solid sphere. A and
B can roll without sliding on the floor. They are also tied centrally to a light spring of
spring constant k as shown in figure. A and B are released when the extension in spring
n x0
is x0 . The amplitude of SHM of the sphere A is then n is __________
46

32. In a resonance tube experiment, a 1m long pipe is resonated with a tuning fork of
frequency 340 Hz. Initially the pipe is completely filled with water. A small hole is
drilled very close to the bottom and water is allowed to leak. If the radii of the pipe and
hole are 2 cm and 1 mm respectively, then the time interval between the occurrences of
first two resonances is ________ seconds. Neglect end correction. (Take speed of
sound  340 m / s, g  10 m / s 2 , 5  2.2, 3  1.73 )
33. Between the plates of a parallel plate capacitor having separation d, we put a metallic
plate of thickness 0.6 d. When that plate is absent the capacitor has a capacity c  20 nF .
The capacitor is connected to a dc voltage source of emf of 100 volt. The metallic plate
is slowly extracted from the gap. The mechanical work performed in the process of
plate extraction in  J is ________
34. A non-conducting cylindrical vessel of length 3 is placed horizontally and is divided
into three parts by two easily moving piston having low thermal conductivity as shown.
Three parts contain H 2 , He and CO2 gas at initial temperatures
1  3720 C ,  2  150 C , 3  157 0 C respectively. If initial length and pressure of each part
are  and P0 respectively. If the length of middle part finally is n , then find n .
35. A mass m1 lies on a fixed smooth cylinder. An ideal chord attached to m1 passes over
the cylinder and is connected to m2 . The system is released at   300 . Acceleration of
5
m1 just after release the system is m / s 2 . Find n .
n
36. A block of mass m = 2 kg is placed on a plank of mass M = 10 kg which is placed on a

smooth horizontal plane. The coefficient of friction between the block and the plank is
1
  . A horizontal force F is applied on the plank. If the maximum value of F for
3
which the block and the plank stay together is K N then value of K is __________
(Take g  10 m / s 2 and neglect height of plank).

CHEMISTRY MAX.MARKS: 66
numeric
37. Difference in the two different oxidation states of Br atoms in Br3O8 .
38. In the chemical reaction between stoichiometric quantities of KMnO4 and KI in weakly
basic solution, what is the number of moles of I 2 released for 4 moles of KMnO4 consumed?
39. A solution containing 500g of a protein per liter is isotonic with a solution containing
3.42g sucrose per litre. The molecular mass of protein in 5 10 x , hence x is.
[Van’t Hoff factor for protein = 1]
40. A Carnot engine has a cycle as given in figure. If W1 and W2 represent work done by one
mole of monoatomic and diatomic gas respectively in the complete cyclic process, then
calculate W1 ?
W2
41. Consider the below conductometric titration curve.
This graph is plotted when HCl is titrated with P. In given list of titrants, numbers (1, 2, 3,
4…) are assigned to P. Sum of numbers (assigned) to titrants for which above graph is
possible is X. then find X.

Number Titrant
1. NaOH
2. CH 3COOH
3. NH 4OH
4. Ca(OH )2
5. KOH
6. Pyridine
42.  X 2 ( s )  3Y2 ( g )

2 XY3 ( s ) 
If above reaction attains equilibrium at 3 atm and a certain temperature. What will be the
equilibrium constant in atm3 units. Express your answer by dividing with 3.

correct options.
option.
43. The correct option(s) to distinguish nitrate salts of Mn 2 and Cu 2 taken separately is (are)
:-
A) Mn 2 shows the characteristic green colour in the flame test
B) Only Cu 2 shows the formation of precipitate by passing H 2 S in acidic medium
C) Only Mn 2 shows the formation of precipitate by passing H 2 S in faintly basic medium
D) Cu 2 / Cu has higher reduction potential than Mn 2 / Mn (measured under similar

conditions)

44. Which complex is likely to show optical activity?
A) Trans-[Co( NH 3 ) 4 Cl2 ] B) [Cr ( H 2O)6 ]3
C) Cis-[Co( NH 3 )2 (en) 2 ]3 D) Trans-[Co( NH 3 ) 2 (en) 2 ]3
45. 3c  2e  (3 centre 2 electron) bond is present in
A) AlCl3 dimer B) BeH 2 dimer C) B2 H6 D) Al ( BH 4 )3
46. Choose the correct statements regarding complete hydrolysis of XeF2 , XeF4 and XeF6
A) XeF2 and XeF4 shows redox reactions.
B) All form HF as one of the product
C) XeF2 forms only one gaseous product
D) XeF6 forms two gaseous products
47. Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is (are)
A) B)
C) D)
48. Which of the following metal(s) extraction involve froth floatation, roasting and self
reduction?
A) lead from Galena
B) Copper from chalcopyrite
C) Tin from cassiterite
D) Zinc from sphalerite

49. Scheme 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3
describes the synthesis of T from Q and S. The total number of Br atoms in a molecule of
T is____________
Scheme 1:
Scheme 2:
Scheme 3:
50. The total number of possible isomers (including stereosiomers) which are formed on
mono-bromination of 1-methylclohex-1-ene using NBS/UV light is_______.

51. Reaction of x g of Sn with HCl quantitatively produced a salt. Entire amount of the salt
reacted with y g of nitrobenzene in the presence of required amount of HCl to produce
1.29 g of an organic salt (quantitatively).
(Use Molar masses (in g mol 1 ) of H, C, N, O, Cl and Sn as 1, 12, 14, 16, 35 and 119,
respectively)
Sum of the value of x and y is________.
52.
O O
CH3
+
(i) H 3O
O O (B) + (C)
(ii) 
CH3
O O
(A)
1.1 mole of (A) was reacted according to above reaction. 'C' is the gas produced which
turns lime water milky. The amount of C formed in gram is x. The value of x is ______.
(Given At. Wt. of C, O, H are 12, 16, 1 gm respectively)
53. If the reaction sequence given below is carried out with 15 moles of acetylene, the
amount of the product D formed (in g) is______.
(Atomic weight: H=1, C=12, N=14, O=16, Cl=35.5)

54. How many of the following reactions produce carbonyl compound (aldehyde/ketone ) as
one of the products.
HCl
A) + CO
AlCl3/CuCl
F)
B) G)
C) H)
Cl Cl
D) H2O I)
373 K
E) J)

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Yashpatil TG~ @bohring_bot

SR.STAR CO-SC(MODEL-A) Date: 05-11-23

Name of the Student: ___________________ H.T. NO:

05-11-23_ SR.STAR CO-SC(MODEL-A) _JEE-ADV_GTA-4(P2)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

SR.IIT_*CO-SC Page. No. 2

5. If the complete set of values of a for which ax 2  (3  2a) x  6  0, a  0 is positive for

SR.IIT_*CO-SC Page. No. 3

A) f (2)  f (3) B) f (4)  1 C) f (1)f (2) D) f (2)  f (3)

8. f ( x )  sin  x  tan 1 x   cos  x  cot 1 x  ; x  R , then which of the following options is

D)  0 f ( x)dx   1 where [] denotes G.I.F

C) Number of values of ' a ' for which n  S1  S2  is 3 is 4 .

D) Number of values of ' a ' for which n  S1  S2  is 3 is 3 .

SR.IIT_*CO-SC Page. No. 4

D) | x |  | f ( x) | 2 for exactly 2 values of ' x '.

SR.IIT_*CO-SC Page. No. 5

14. If a, b, c are the distinct roots of 2x 3  x 2  12  0 , then

e   sec    (ln5) , then   ______

16. The coefficients of x n , x n 1 and x n 2 in the binomial expansion of (1  x) 23 are in A.P.

Then arithmetic mean of possible values of n is

SR.IIT_*CO-SC Page. No. 6

is moving with velocity V in air of density  . The resistive force on it is given by

SR.IIT_*CO-SC Page. No. 7

SECTION - 2 (Maximum Marks : 24)

SR.IIT_*CO-SC Page. No. 8

A) The tension in the ring will be same throughout

B) The tension in the ring will be independent of the radius of ring

SR.IIT_*CO-SC Page. No. 9

A)  decreases, r and d increases B) r and d increases

A) Angular acceleration of rod is 2 rad / s 2 B) Tension in the left string is 185/6 N

SR.IIT_*CO-SC Page. No. 10

C) If contact force is zero, time period T, radius of tunnel r, then T  r .

D) If contact force is zero, time period T, radius of tunnel r, then T would be

A) t1 will decrease B) H will increase

SECTION - 3 (Maximum Marks : 24)

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36. A block of mass m = 2 kg is placed on a plank of mass M = 10 kg which is placed on a

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[Van’t Hoff factor for protein = 1]

41. Consider the below conductometric titration curve.

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42.  X 2 ( s )  3Y2 ( g )

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C) Only Mn 2 shows the formation of precipitate by passing H 2 S in faintly basic medium

D) Cu 2 / Cu has higher reduction potential than Mn 2 / Mn (measured under similar

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A) Trans-[Co( NH 3 ) 4 Cl2 ] B) [Cr ( H 2O)6 ]3

C) Cis-[Co( NH 3 )2 (en) 2 ]3 D) Trans-[Co( NH 3 ) 2 (en) 2 ]3

45. 3c  2e  (3 centre 2 electron) bond is present in

A) AlCl3 dimer B) BeH 2 dimer C) B2 H6 D) Al ( BH 4 )3

A) XeF2 and XeF4 shows redox reactions.

B) All form HF as one of the product

C) XeF2 forms only one gaseous product

D) XeF6 forms two gaseous products

47. Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is (are)