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Yashpatil TG~ @bohring_bot

Sri Chaitanya IIT Academy., India.


AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec:` N ew M odel_P1 D ate: 00-00-00
T ime: 02.30Pm to 05.30Pm GT A-05 M ax. M ar k s: 198
GTA-05_Syllabus

PHYSICS : TOTAL SYLLABUS


CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy GTA-05_ Q.P

Name of the Student: ___________________ H.T. NO:

JEE-ADVANCED- Sri Chaitanya IIT Special -P1-Model


Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 198

MATHEMATICS:
+ Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 6) +4 -2 6 24
Choice Type
Sec – II(Q.N : 7 – 10) Numerical Value Answer Type +3 0 4 12
Questions with Non-negative Integer
Sec – III(Q.N : 11 – 15) +3 0 5 15
Value Type
Tw o Paragraph with Numerical Value
Sec – IV(Q.N : 16 – 20) +3 0 5 15
Answer Type
Total 20 66

PHYSICS:
+ Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 21 – 26) +4 -2 6 24
Choice Type
Sec – II(Q.N : 27 – 30) Numerical Value Answer Type +3 0 4 12
Questions with Non-negative Integer
Sec – III(Q.N : 31 – 35) +3 0 5 15
Value Type
Tw o Paragraph with Numerical
Sec – IV(Q.N : 36– 40) +3 0 5 15
Value Answer Type
Total 20 66

CHEMISTRY:
+ Ve - Ve
No.of Total
Section Question Type Mark Mark
Qs marks
s s

Sec: Space for rough w ork Page 2


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

Sec – I(Q.N : 41 – 46)


Questions with Multiple Correct
+4 -2 6
GTA-05_ Q.P

24
Choice Type
Sec – II(Q.N : 47 – 50) Numerical Value Answer Type +3 0 4 12
Questions with Non-negative Integer
Sec – III(Q.N : 51 – 55) +3 0 5 15
Value Type
Sec – IV(Q.N : 56 – Tw o Paragraph with Numerical
+3 0 5 15
60) Value Answer Type
Total 20 66

MATHEMATICS Max. Marks: 66


SECTION-1(Maximum Marks: 24)
MULTIPLE CORRECT
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s). For each question, choose the option(s) corresponding to (all) the correct answer(s).
Marking scheme: + 4 for correct answ er, 0 if not attempted and -2 in all other cases.

1. If b2  4ac for the equation ax 4  bx 2  c  0, then all roots of the equation will be real,
if :
A) b  0, a  0, c  0 B) b  0, a  0, c  0
C) b  0, a  0, c  0 D) b  0, a  0, c  0
2. Let S 2  0 be the mirror image of

S1 : x 2  y 2  4 x  6 y  12  0 w.r.t the line

   
L1  10 4 x  10 4  10 y  104  20  0 let

L2  211 x   211  212  y   211  213   0 be a line. The equation of the line passing
through the point of intersection of the line L2  0 with the radical axis of S1  0, S 2  0
and making equal length of intercepts with coordinate axes can be
A) x  y  3  0 B) x  y  1  0 C) 2 x  2 y  1  0 D) 2 x  2 y  3  0

3. Let f :  0,1  R be continuous on  0,1. Which of the following is/are correct?

A) If f is differentiable on  0,1 such that f ' x   f  x  0 x  0,1 and f  0  0 then


f  x   0 x  0,1

Sec: Space for rough w ork Page 3


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy
1 c
GTA-05_ Q.P

B) If  f  x dx  0 then  c  0,1 such that f  c   f  x dx


0 0
1 c
C) If  f  x dx  0 then  c  0,1 such that 1  c f  c  c f  x dx
0 0

f  c
1 c
D) If  f  x  dx  0 then  c  0,1 such that   f  x dx
c
0 0
4. Let normal to the ellipse x 2  4 y 2  4 at point  2cos  ,sin   ,   n , n  I meet it again
at point  2cos  ,sin   . If sin   f   , then
 23  5  23
A) f     B) f   
 4 17 2  4  17 2
 37    37
C) f     D) f   
 6 38  3  38
5. If a variable straight line x cos   y sin   P, is a chord of the hyperbola

x2 y2
 2  1,  b  a  , such that it subtends a right angle at the centre of the hyperbola,
a2 b
then the line always touches a fixed circle whose,
ab ab
A) Radius is B) radius is absolute value of
b 2  2a 2 b2  a 2
C) centre is  0,0 D) centre is at the centre of hyperbola

6. Let P1 denotes the equation of a plane to which vector  i  j  is normal and which

 
contains the line whose equation is L : r  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ and P2 denotes the

equation of the plane containing the line L and point with position vector ˆj. Which of the
following holds good?
A) The equation of P1 is x  y  2
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Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy GTA-05_ Q.P

 
B) The equation of P2 is r . iˆ  2 ˆj  kˆ  2

C) The acute angle between P1 and P2 is cot 1 3

D) The angle between P2 and L is tan 1 3

Sec: Space for rough w ork Page 5


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

SECTION-2(Maximum Marks: 45)


GTA-05_ Q.P

NUMERICAL VALUE
This section contains FOUR (04) questions. The answer to each question is a NUMERICAL VALUE, For each question, enter the correct numerical value
of the answer using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/ round-off the value to TWO decimal places.. Answer to each question will be evaluated according to the following
marking scheme: (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Full Marks: + 3 If ONLY the correct numerical value is entered; Zero Marks: 0 In all other cases.

7. Let A   4,0 and B   4,0 if the number of points C on the circle x 2  y 2  16, such
that the area of triangle whose vertices are A,B and C is positive integer is N, then value
of N is equal to?

 
2
8. Let P  x  1  x  x 2 .....  x17  x17 has 34 complex roots of the form

zk  rk ei 2 ak , k  1,2,3.......34 such that 0  a1  a2  a3........  a34  1 and rk  0. If


m
a1  a2  .....  a5  where m, n are relatively prime positive integers then m  n
n
equals
   
9. Consider tetrahedron whose three coterminous edges are represented by a  b , b  c and
 
c  a , where
   2   2   4 
a   2  sin   iˆ  cos  ˆj  sin 2 kˆ, b  sin     iˆ  cos     ˆj  sin  2   kˆ
 3  3  3
  2   2   4   
and c  sin     iˆ  cos     ˆj  sin  2   kˆ;  0, 
 3  3  3  2
5
 n 
Let function f    volume of tetrahedron, then twice the sum  f  33  is equal to
n 1
10. Consider four players P1, P2 , P3 and P4 playing in a knockout tournament, They are
paired randomly in first round. If the probability that P1 will be paired up with

Pk , k   2,3,4 is proportional to k, then reciprocal of probability that P2 will not reach


second round is equal to
(Assume that lower suffix player always wins the match)
Sec: Space for rough w ork Page 6
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

SECTION-3(Maximum Marks: 15)


GTA-05_ Q.P

NON-NEGATIVE INTEGER ANSWER TYPE


This section contains FIVE (05) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct integer is entered;
Zero Marks: 0 In all other cases.

11.
1 
 
If 2  x 2  3, then the positive root of x 2    , (where  x denotes the fractional
x
a b
part of x ) is equal to  a, b  I  then a  b 
2
x  F ''  2
2
12. If f  x  is continuous function and F  x      2t  3  f  x  dx dt then is equal
  f  2
0 t

to
 1  cos x cos 2 x 3 2 
13. lim   3   cos x  3cos x  3cos x  is equal to
x 0  x2 cos x  63 

14. Two perpendicular chords PQ and PR are drawn through the vertex P of a parabola

x 2  4 y. If circle drawn with diameter on a focal chord of the locus of circumcentre of


triangle PQR, always touches a line by  c  0, find b  c. (Given that HCF of b & c is 1)

 2 3
15. Let, a matrix A    , then it will satisfy the equation A2  I   A for  
1 2
SECTION-4(Maximum Marks: 15)
NUMERICAL VALUE WITH PARAGRAPH
This section contains TW O (02) paragraphs. Based on each paragraph has 2 or 3 questions. (2 Paragraph- 2 + 3 = 5Q or 3+ 2= 5Q)
The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value corresponding to the answer in the
designated place using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two decimal places, truncate/ round-
off the value to TWO decimal places. (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases

Paragraph-I

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Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

        
Let f x and g x be continuous function on R and A  x : f x  g x . Then the
GTA-05_ Q.P

 f  x  , x is rational
function h  x    is continuous on A and discontinuous on R  A.
 g  x  , x is irrational

5 x 1  7 x 1  74, x Q
16. If h  x    ,
x 1 x 1
74  5  7 , x Q

Then the only real value of x for which h  x  is continuous is

 sin 5 x cos3 x, x Q
17. Let h be defined on  0,   by h  x    , then number of points
sin 6 x cos 2 x , x  Q
where h is continuous is
Paragraph-II
Let a curve be S1 : z  1  1. Let conic S 2 represents the locus of point w given by

z2  z  2
w , then
1 z

18. If e is the eccentricity of conic S 2 then the vlaue of 9e2 is equal to

19. Let m is the slope of the line that touches S 2 and is also normal to S1 then m2 is equal
to
20. If a pair of tangents are drawn to S 2 from the point 1,0 , then Length intercepted by
them on the ordinate passing through centre of S 2 is

Sec: Space for rough w ork Page 8


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

PHYSICS
GTA-05_ Q.P
Max. Marks: 66
SECTION-1(Maximum Marks: 24)
MULTIPLE CORRECT
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s). For each question, choose the option(s) corresponding to (all) the correct answer(s).
Marking scheme: + 4 for correct answ er, 0 if not attempted and -2 in all other cases.

21. Two blocks of masses m1 and m2  m2  m1  are placed on an inclined plane of


inclination  and joined by a string as shown in Fig. If the coefficient of friction between
the blocks and the plane is  and the blocks are released,    tan  

A) the acceleration of the blocks is g (sin    cos )


B) the acceleration of the blocks is zero.
C) the tension in the string is zero.
D) the tension in the string is  m1  m2  g (sin    cos  ) .
22. Fig (a) shows a spring of force constant k fixed at one end and carrying a mass m at the
other end placed on a horizontal frictionless surface. Fig (b) shows the same spring with
both ends free and a mass m fixed at each free end. Each spring is stretched by the same
force F and is at equilibrium. The mass in case (a) and the masses in case (b) are then
released by the agent applyin force F. Which of the following statements are true?

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Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

A) While oscillating, the maximum extension of the spring is more in case (a) than in
GTA-05_ Q.P

case (b)
B) While oscillating, the maximum extension of the spring is the same in both cases.
C) The time period of ocsillation is the same in both cases.
D) The time period of oscillation in case (a) is 2 times that in case (b)
23. A wire AB of length 2l and cross–sectional area a is stretched without tension between
fixed points A and B (Fig). The wire is pulled at the centre into shape ACB such that
d  l. The tension in the string is T and the strain produced in it is . If the Young’s
modulus of the material of wire is Y. Then

d d2 d  d2 
A)   B)   C) T  aY   D) T  aY  
2l 2l 2  2l   2l 2 
24. Choose the correct statements from the following
A) A circuit consisting of an inductance is carrying a current. When the circuit is
suddenly switched off, the direction of the induced current will be the same as that of the
main current.
B) Sparking is observed in the switch when an electrical appliance is suddenly switched
off because the induced emf suddenly falls to zero.
C) A coil is connected in series with a bulb and this combination is connected to a dc
source. When an iron core is inserted in the coil, there will be no change in the brightness
of the bulb at steady state.
D) A coil is connected in series with a bulb and this combination is connected to an ac
source. When an iron core is inserted in the coil, the brightness of the bulb will increase.
Sec: Space for rough w ork Page 1 0
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

q
GTA-05_ Q.P

25. In Gauss’s theorem  E.ds  0 . The surface integral is evaluated by choosing a closed
s
surface called the Gaussian surface. Here
A) The closed surface can be of any shape or size
B) q is the net charge enclosed inside the Gaussian surface; charges outside the surface
are not included in q
C) E is the electric field due to all the charges both inside and outside the surface
D) The exact location of the charges inside the surface does not affect the value of the
integral
26. A convex lens made of glass of refractive index 1.5 has both surfaces of the same radius
of curvature R. In case  i  the lens is immersed in a medium of refractive index 1.25 and

in case  ii  it is immersed in a medium of refractive index 1.75. Then

A) In case  i  the lens will behave as a convergent lens of focal length 2.5R

B) In case  i  the lens will behave as a divergent lens of focal length 3.0R

C) In case  iii the lens will behave as a convergent lens of focal length 3.0R

D) In case  ii  the lens will behave as a divergent lens of focal length 3.5R

SECTION-2(Maximum Marks: 12)


NUMERICAL VALUE
This section contains FOUR (04) questions. The answer to each question is a NUMERICAL VALUE, For each question, enter the correct numerical value
of the answer using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/ round-off the value to TWO decimal places.. Answer to each question will be evaluated according to the following
marking scheme: (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Full Marks: + 3 If ONLY the correct numerical value is entered; Zero Marks: 0 In all other cases.
27. A moving particle of mass m makes a head-on collision with a particle of mass 2m

initially at rest. If the collision is perfectly elastic, the percentage loss of energy of the

colliding particle is_____________%

Sec: Space for rough w ork Page 1 1


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

28. Water from a tap emerges vertically downwards with an initial speed of 1.0ms 1. The
GTA-05_ Q.P

cross – sectional area of the tap is 10 4 m 2 . Assume that the pressure is constant
throughout the stream of water and that the flow is teady. The cross–sectional area of the

 
stream 0.15m below the tap is take g  10 ms 2 n  105 m2 , then n is ______

29. The frequencies of tuning forks A and B are respectively 3% more and 2% less than the
frequency of fork C. When A and B are simultaneously excited 5 beats per second are
produced. The frequency (in Hz) of fork A is
30. An inductor of self inductance 100 mH and a resistor of resistance 50 are connected to
a 2V battery. The time required for the current to fall to half its steady value
is___________milliseconds.
SECTION-3(Maximum Marks: 15)
NON-NEGATIVE INTEGER ANSWER TYPE
This section contains FIVE (05) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct integer is entered;
Zero Marks: 0 In all other cases.

31. An escalator is moving downwards with a uniform speed u. A man of mass m is running
upwards on it at a uniform speed v w.r.t escalator  v  u  . If the height of the escalator is

 mghv 
h, the work done by the man in going up the escalator is n 
 v  u 
then n is ______

32. A satellite in force–free space sweeps stationary interplanetary dust at a rate


dM / dt   , where M is the mass and  is the velocity of the satellite and  is a

n 2
constant. The magnitude of acceleration of the satellite is then n is ________
M

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Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

33. A small drop of water of surface tension  is squeezed between two clean glass plates so
GTA-05_ Q.P


that a thin layer of thickness d and Large area A A  d 2 is formed between them. If 
  A
the angle of contact is zero, the force required to pull the plates apart is n 
 d 
then n is

_______
34. A metal wire of m slides without friction on two rails spaced at a distance d apart. The
track lies in a vertical uniform magnetic field B. A constant current I flows along one
rail, across the wire and back down the other rail. If the wire is initially at rest, the time

 xm 
n
 BId 
taken by it to move through a distance x along the track is then n is _______

35. When the energy of the incident radiation is increased by 20%, the kinetic energy of the
photoelectrons emitted from a metal increased from 0.5 eV to 0.8 eV. The work function
of the metal is ____eV
SECTION-4(Maximum Marks: 15)
NUMERICAL VALUE WITH PARAGRAPH
This section contains TW O (02) paragraphs. Based on each paragraph has 2 or 3 questions. (2 Paragraph- 2 + 3 = 5Q or 3+ 2= 5Q)
The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value corresponding to the answer in the
designated place using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two decimal places, truncate/ round-
off the value to TWO decimal places. (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases

Paragraph-I
The maximum height attained by a projectile is increased by 1% by increasing its speed
of projection without changing the angle of projection. Then the percentage increase in
the
36. horizontal range will be ______________%

37. time of flight will be ______________%

38. speed of projection will be ______________%


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Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

Paragraph-II
GTA-05_ Q.P

A rod of mass M= 0.9 kg and length L = 1 m is suspended at a fixed point O as shown in


Figure. A bullet of mass m = 100 g moving with velocity v  80 ms 1 in the horizontal
direction strikes the end P of the rod and gets embedded in it. If I is the moment of inertia
of the system (Rod + particle) about O and  is the angular velocity immediately after
the collision, then

39. I  _______________ kg  m2
40.   _______________ rad / s

Sec: Space for rough w ork Page 1 4


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy

CHEMISTRY
GTA-05_ Q.P
Max. Marks: 66
SECTION-1(Maximum Marks: 24)
MULTIPLE CORRECT
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s). For each question, choose the option(s) corresponding to (all) the correct answer(s).
Marking scheme: + 4 for correct answ er, 0 if not attempted and -2 in all other cases.

41. Select the incorrect statement(s)


A) H atomisation of graphite is equal to H f of C  g  
B) H combustion of H atom is equal to H f of  H 2O  l  
C) H f of  H 2O  l   is zero
D) H combustion of graphite is equal to H f of C  g  
42. Consider one mole of an ideal gas undergoing from state A to state–B through different
process. Column–I shows graph of the process & Column – II shows change in
parameter in these processes.
Match the following
Column–I Column–II

A P q0

B Q W 0

C R U  0

D S H  0

T W 0
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Which of the following is/are correctly matched?


GTA-05_ Q.P

A) A  PRST B) B  PT C) C  PRST D) D  Q
43. The correct match(es) of the given complex compound and its IUPAC name is/are

A)  Pt  PPh3  4   tetrakis(triphenylphosphine)platinum(0)

B) Co  en 3  Cl3  tris(ethylenediammine)cobalt  III  chloride

C) CoCl3  CH 3 NH 2 3   trichloridotrimethylaminecobalt  III 


 

D)  Fe  CCPh  2  CO  4   tetracarbonylbis(phenylethynyl)iron  II 

44. The correct statement(s) is/are


A) Extraction of iron from Fe2O3 involves smelting.
B) During calcination, S, As, Sb are removed as volatile oxides
C) Kaolinite is an ore of aluminium containing hydroxide and silicate
D) Sodium cyanide is used as depressant during concentration of galena by froth
floatation process.
45.
CHO
dilute
NaOH
 CH 3COCH 2  O  CH 3 
?

CHO
Select the correct statement(s) regarding the major product formed.
A) It has two aromatic rings. B) It has 8 degree of unsaturation.
C) It reacts with cold HI. D) It has one aromatic ring.

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46. Consider the compound given below


GTA-05_ Q.P

HOOC OH
HO

HO OH

HO OH COOH
X
On standing for a long time, the given optically active compound  X  is converted into

an optically inactive compound Y  . Select the correct statement(s).

A) The compound Y  has 12 degree of unsaturation

B) One mole of compound  X  would liberate 8 moles of CH 4 gas when treated with

excess of CH 3MgBr (Assume 100% completion of reaction)

C) The compound Y  on complete hydrolysis produces racemic mixture

D) The compound  X  is non–planer

SECTION-2(Maximum Marks: 12)


NUMERICAL VALUE
This section contains FOUR (04) questions. The answer to each question is a NUMERICAL VALUE, For each question, enter the correct numerical value
of the answer using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/ round-off the value to TWO decimal places.. Answer to each question will be evaluated according to the following
marking scheme: (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Full Marks: + 3 If ONLY the correct numerical value is entered; Zero Marks: 0 In all other cases.
47. The structure of diamond and silicon is same and can be described as atoms taking
corners and faces of a cube and also taking positions of alternate tetrahedral voids. What
density  diamond
is the value of .
density  silicon 

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Sri Chaitanya IIT Academy GTA-05_ Q.P

48.  
What is S in cal K 1 for 16 gram of O2 gas
5
(assume ideal behavior; Cv,m  R )which is heated and compressed from 300K and 1
2
bar to 600K and 4 bar? ( R  2 cal mol 1K 1, ln 2  0.70, M o  32 gmol 1 )
2
49. A conductivity cell is filled with 0.01M Na2C2O4 Solution. If resistance of solution is
200 ohm, find cell constant in cm1. Degree of dissociation of Na2C2O4 is 80%.

 
Given eq Na   75ohm 1 cm 2 gm eq 1

eq  C2O42    50ohm1 cm 2 gm eq 1.

1  6r r 2   r /3ao
50. The radial part of an orbital is given by R  r    2 e
9 6a0 3/2  a0 a0 
nl
Find the value of (Where n and l are principal and azimuthal quantum numbers
5
corresponding to the orbital associated with the given radial function

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SECTION-3(Maximum Marks: 15)


GTA-05_ Q.P

NON-NEGATIVE INTEGER ANSWER TYPE


This section contains FIVE (05) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct integer is entered;
Zero Marks: 0 In all other cases.

51. How many of the following has/have all the three types of Vander waals forces (Keesom,
Debye and London’s forces)?
HCl  g  , SO2  g  , H 2O  g  , I 2  g  , Xe  g  , ICl  g  , H 2S  g  , NH 3  g  , NO2  g  , Cl2  g 
52. Quinhydrone is a sparingly soluble one–to–one addition compound formed from
hydroquinone and quinone. When solid quinhydrone is dissolved in an aqueous medium,
equal concentration of hydroquinone and quinone result. If a platinum wire is dipped into
the solution, the potential of the electrode is governed by the reversible reaction:
O OH

2 H   2 e  

O OH
 Q  H 2Q
Where Q denotes quinone and H 2Q denotes hydroquinone. The E value of this half cell
reaction is +0.46V with respect to the saturated calomel reference electrode (SCE).
Because the potential of the quinone–hydroquinone half reaction depends on the
concentration of hydrogen ion, it is possible to use this system to measure pH. A sample
solution of unknown pH was saturated with quinhydrone and a platinum electrode was
dipped into it. If the potential of the such electrode was found to be +0.22V with respect
to SCE, what was the pH of the sample solution?
2.303 RT
[Given :  0.06 ]
F

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53. Consider the reaction given below


GTA-05_ Q.P

O
||
 I  N 2 H 4 ; H   mild acidic 
CH 3 2 N  CH 2  C  CH 3 
 II C2 H5ONa;
 P  Q  Base

of ' a '  maximum number of atoms in one plane in a molecule of ‘P’ and b  number of
compounds among the given below which are more basic than the compound  Q ,

CH 3 NH 2 , C2 H 5 NH 2 ,  CH 3  N , NH 3 , NH 2OH , N 2 H 4 ,  C2 H 5  N 
 3 3 

Find the value of  a  b


54. Find the total number of complexes which exhibit both optical as well as geometrical
isomerism.
   
Co  gly   , Co  dien Cl3  , Co  NH3  Cl3  ,  Pt  CH 3  CH  COO  ,
 3  3   2
NH 2

   
 Be4O  NO3   ,  Zn  CH 3  CH  COO 
 6
  2
NH 2

55. Consider the reaction given below:


H O
Ph  CO  CO  Ph  PhMgBr (1equivalent) 
 ? 
3
  P  major  .

If  X   no.of given compounds which would liberate H 2 gas when treated with the

product  P  under suitable condition Na, K , LiAlH 4 , CaH 2 , NaH , CH 3MgBr , NaNH 2

and Y   total number of degree of unsaturation in one molecule of  P  , find the vlue of

X Y
.
2

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Yashpatil TG~ @bohring_bot
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SECTION-4(Maximum Marks: 15)


GTA-05_ Q.P

NUMERICAL VALUE WITH PARAGRAPH


This section contains TW O (02) paragraphs. Based on each paragraph has 2 or 3 questions. (2 Paragraph- 2 + 3 = 5Q or 3+ 2= 5Q)
The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value corresponding to the answer in the
designated place using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two decimal places, truncate/ round-
off the value to TWO decimal places. (e.g. 0004.32, 003.43, 6.23, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30, -1234.50).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: + 3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases

Paragraph-I

Consider the confirmatory tests for sulphide ion


 I  Na2S  Na2  Fe  CN 5  NO    X  Purple colouration
 II  Methylene blue Test:
N , N  Dimethyl–p–phenylenediamine  P  is converted by FeCl3 and H 2 S in strongly
acidic solution into the water – soluble dyestuff, methylene blue. This is a sensitive test
for soluble sulphides and hydrogen sulphide.
a
56. Find the value of where a is the total number of linkage isomers possible for complex
2
 X  including  X  .
x y
57. Find the value of
2
Where
x  number of moles of reagent  P  required for formation of one moles of methylene
blue.
y  number of degree of unsaturation in one formula unit of methylene blue
(Assume 100% completion of reaction(s) and other reactants in sufficient amount)
Paragraph-II
Consider the reactions given below
O

I OTs
  major product  X 
NaOH
Heat

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OTs
GTA-05_ Q.P

 I  BMe H THF

2
 major product Y 
 II   II  NaOH

O
O2 N OH

  major product  Z 
DMSO
 III  
80C
Br

58. Select the total number of correct statement(s) regarding reaction  I 

1. The major product  X  gives effervescence with NaHCO3 solution.

2.  X  decolourises  Br2  H 2O 
3. Formation of major product involves nucleophilic attack.
4. The reaction  I  involves S N 2 path.

59. Find the total number of degree of unsaturation in the major product Y  .

60. Select the total number of incorrect statements regarding the reaction  III 
O O NO2

1) The major product is


2) It involves nucleophilic substitution
3) DMSO acts as a base
4) It involves electrophilic aromatic substitution
5) Total number of degree of unsaturation in the major product is 7

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