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Pages From Narayana Module-2
Pages From Narayana Module-2
1
1) e kt 2) 100.434kt 3) n 4) e kt 3 1
2
1) 2) 3) zero 4) None
51. For a first order reaction, if ‘a’ is the initial 2 2
concentration of reactant, then the half life
time is
MOLECULARITY
1) independent of a 2) a 60. The molecularity of a reaction will be
3) a2 4) a3 1) fractional 2) zero
52. The rate expression for a reaction is 3) positive whole number 4) negative
61. Which of the following is wrong
dx 1 3
1) order of the reaction is negative, positive or
K [ A] [ B]
2 2 , the overall order of the
dt fractional
reaction is. 2) molecularity of the reactions is always equal
3 to the sum of stoichiometric co-efficients
1) 2 2) 12 3) 2 4) 1 3) the order of a reactions may be zero
53. Which of the following statements is false? 4) half life is independent of the concentration
1)a fast reaction has a large rate constant and of reactants in first order reaction
short half-life 62. Which statement is correct ?
2) Half life depends on concentration of 1) Molecularity of a reaction is same as the order
reactants for first order reaction. of reaction
3)For a first order reaction,the half-life is 2) In some cases order of reaction may be same
independent of concentration as the molecularity of the reaction
4)The half-life of a reaction is half the time 3) Molecularity may be zero
required for the reaction to go to completion 4) Molecularity may be fractional
63. Which of the following cannot be 72. The excess of energy required for the reactant
determined experimentally. molecules to undergo a reaction is
1) Order 2) Rate 1) Potential energy 2) Kinetic energy
3) Rate constnat 4) Molecularity 3) Thermal energy 4) Activation energy
64. Which of the following statements regarding 73. Threshold energy (TE), internal energy of
molecularity of the reaction is correct? reactants (IE) and energy of activation (AE)
1) Molecularity relates to mechanism of reaction are related as
2) It cannot be negative or fractional 1) AE = TE + IE 2) TE = AE + IE
3) Molecularity of a complex reaction has two 3) IE = AE - TE 4) TE = AE = IE
(or) more steps and each individual step has its 74. The energy to be possessed by the molecule
own molecularity.
participating in the reaction to give the
4) All are correct
products
COLLISION THEORY 1) < activation energy 2) threshold energy
65. To increase the rate of a chemical reaction, 3) < average energy
catalyst 4) threshold energy + average energy
1) increase the activation energy 75. For a given reaction which one is higher than
2) decrease activation energy the rest among the following
3) reacts with products 1) Average energy 2) Threshold energy
4) do not changes the activation energy 3) activation energy 4) Normal energy
66. The energy of activation of a reaction is 76. The value of energy of activation for radio
dependent on active decay is
1) temperature 2) pressure 1) high 2) low 3)zero 4) moderate
3) concentration 4) nature of reactants
77. In arrhenius equation, the fraction of
67. If the activation energy of both the forward
effective collisions is given by
and the backward reactions are equal , H of
1) K=Ae-Ea/RT 2) A 3) e-Ea/RT 4) RT
the reaction is
78. On increasing the temperature by 100C,
1) zero 2) +Ve 3) -Ve
4)cannot be predicted 1) number of collisions get doubled
68. For the exothermic reaction A+B C+D. 2) value of rate constant does not change
3) energy of activation increases
H is the heat of reaction and E a is the
activation energy. The activation energy for 4) specific rate of the reaction gets doubled
the formation of A+B will be 79. The threshold energy of a chemical reaction
1) Ea 2) H 3) Ea+ H 4) H - Ea depends upon
69. The rate constant (K1) of one reaction is found 1) nature of reacting species 2) temperature
to be double that of the rate constant of (K2) 3) concentration of species
another reaction. Then the relationship 4) number of collisions
between the corresponding activation 80. Activation energy is _____ to rate of reaction
energies of two reactions (E1 and E2) can be 1) directly proportional 2)inversely proportional
represented. 3) equal 4) not related
1) E1 > E2 2) E1 < E2 3) E1 = E2 4) E1 = 4E2 81. The rate of a reaction can be increased in
70. Collision theory is applicable to general by all the factors except
1) Unimolecular reactions 1) using a catalyst
2) Bimolecular reactions 2) increasing the temperature
3) Trimolecular reactions 3) increasing the activation energy
4) Tetra molecular reactions 4) increasing the concentration of reactants
71. The rate constant is given by the equation 82. The energy of activation of positive catalyzed
K P.Ze Ea / RT Which factor should register reaction as compared to that of an
a decrease for the reaction to proceed more uncatalyzed reaction is
rapidly? 1) more 2) less
1) T 2) Z 3) Ea 4) P 3) same 4) may be more or less
83. For producing the effective collisions, the 10. Ionic reactions are faster then covalent reactions
colliding molecules must posses 12. Rate of a reaction increases with increase in
1) a certain minimum amount of energy temperature
2) energy equal to greater than threshold energy 13. As the reaction proceeds, the rate of the reaction
3) proper geometry decreases.
4) threshold energy and proper orientation 14. Molecular mass does not influence the rate of
the reaction where as others influence
15. Rate of the reaction is directly proportional to
C.U.Q - KEY
the product of active masses of the reactants
1) 2 2) 3 3) 2 4) 3 5) 4 6) 3 7) 1
19. mol1 n .lit n 1.sec 1
8) 3 9) 1 10) 3 11) 4 12) 1 13) 2 14) 4 21. Rate constant does not depend an activation
15) 1 16) 2 17) 1 18) 4 19) 3 20) 3 21) 3 energy
22) 1 23) 3 24) 3 25) 4 26) 4 27) 2 28) 3 22. The concentration of the reactants decreases
while that of products increases with time.
29) 4 30) 3 31) 2 32) 3 33) 3 34) 1 35) 1
1 d NO2 1 d NO d O2
36) 3 37) 2 38) 2 39) 1 40) 2 41) 3 42) 1 24. rate
2 dt 2 dt dt
43) 2 44) 4 45) 4 46) 3 47) 2 48) 2 49) 1 25. with decrease in the activation energy, the rate
50) 4 51) 1 52) 1 53) 2 54) 1 55) 3 56)1 of the reaction increases
57) 2 58) 3 59) 2 60) 3 61) 2 62) 2 63) 4 26. Another form Arrheniou
64) 4 65) 2 66) 4 67) 1 68) 3 69) 2 70) 2 Ea 1
27. ln K ln A ; y mx c
71) 3 72) 4 73) 2 74) 2 75) 2 76) 3 77) 3 R T
78) 4 79) 1 80) 2 81) 3 82) 2 83) 4
28. r k A n (1); 2r K 4 A n (2)
log k
32.
1
T 1
33. t1/2 for n = 2, the expression becomes
5. Due to more number of bond rerrrangements Ka n 1
6. For the gaseous reactants units of rate are
1
Atm.sec 1 t1/2
Ka
7. Slowest step is the rate determining step for
34. If the concentration of one of the reactants is
which ' K1 ' is least. much higher than the other reactant, the reaction
9. Higher the rate constant. more will be the extent becomes an example of first order.
of completion
6. Observe the following reaction
LEVEL-I (C.W) A g 3B g 2C g
d A
RATE OF REACTION & FACTORS The rate of this reaction is
1. The rate of gaseous reaction is given by dt
K[A] [B]. If the volume of reaction vessel is
3×10-3 mole lit -1 min -1 . What is the value of
1
reduced to
4
of initial volume the reaction d B
- in mole lit -1 min -1 ?
rate relative to the original rate is dt
1 1 1) 3 103 2) 9 103
1) 2) 3) 8 4) 16
16 8 3) 103 4) 1.5 10 3
2. The rate of reaction for A products is 10 7. For which of the following reactions K310 / K300
mole.lit -1 .min -1 when t1=2min. The rate of would be maximum
reaction when t2=12min. in the same units is 1) A B C ; Ea 50 kJ
1) >10 2) <10 3) 10 4) 12
2) X Y Z ; Ea 40 kJ
3. C12 H 22O11 H 2O C6 H12O6 C6 H12O6
(excess) ( glu cos e) ( fructose) 3) P Q R ; Ea 60 kJ
Rate law is expressed as 4) E F G ; Ea 100 kJ
1) r K C12 H 22O11 H 2O 8. The slope in the activation energy curve is
2) r K C12 H 22O11 5.42 103 . The value of the activation energy
is approximately
3) r K H 2O
1) 104 J mol1 2) 104 MJ mol1
4) r K C12 H 22 O11 H 2 O
2
3) 104 KJ mol1 4) 104 J mol1 K 1
4. A chemical reaction was carried at 300K and
9. For the reaction 4NH3 5O 2 4NO 6H 2O,
280K. The rate constants were found to be
K1 and K2 respectively. then the rate of reaction with respect to NH3 is
energy
39. Half-life periods for a reaction at initial
concentrations of 0.1M and0.01 are 5 and 50
minutes respectively. Then the order of A C
reaction is
Reaction coordinates B D
1) zero 2) 1 3) 2 4) 3
40. Assertion (A) : Half life period is inversely 1) Reaction A B is faster and more exothermic
proportional to rate constant in second order than reaction C D
reaction 2) Reaction C D is faster than reaction A B
Reason (R) : Half life period is always but less exothermic
independent of initial concentration. 3)Reaction C D is faster and more exothermic
1) Both (A) and (R) are true (R) is the correct than the reaction A B.
explanation to (A) 4)Reaction C D 2 1 2 times faster than reaction
2) Both (A) and (R) are true but (R) is not the
correct explanation to (A) A B at the same temperature
3) (A) is true but (R) is false 44. For a reversible reaction A B , which one
4) Both (A) and (R) are false of the following statements is wrong from the
given energy profile diagram
COLLISION - THEORY
41. In the equilibrium A B C D , the
activation energy for forward reaction is
25k.cal/mole and that of backward reaction
E B
is 15k.cal/mole. Which one of the following A
statement is correct
1) It is an exothermic process
Reaction coordinate
2) It is an endothermic process
3) It is reaction for which H 0 1) Activation energy of forward reaction is
4) It is a sublimation process greater than backward reaction
42. For an exothermic chemical process, occuring 2) The forward reaction is endothermic
in two steps as 3) The threshold energy is less than that of
i) A B X slow ii) X AB fast activation energy
4)The energy of activation of forward reaction
The progress of the reaction can be best is equal to the sum of heat of reaction and the
described by
energy of activation of backward reaction.
x 45. Assertion (A) : A catalyst increases the rate
of the reaction
x
Reason(R) : A catalysed reaction proceeds
through a new path having higher activation
1) A B 2) A B energy.
AB AB 1) Both (A) and (R) are true (R) is the correct
explanation to (A)
2) Both (A) and (R) are true but (R) is not the
correct explanation to (A)
x 3) (A) is true but (R) is false
4) Both (A) and (R) are false
3) A B 4) All correct
AB
LEVEL -I (C.W) - KEY 13. Unit of K mole1nlit n 1 sec1
1) 4 2) 2 3) 2 4) 3 5) 4 6) 2 7) 4 14. For every 100 C rising in temperature, rate of
8) 1 9) 1 10) 3 11) 4 12) 3 13) 2 14) 3 reaction becomes double due to double the no.
of effective collisions
15) 3 16) 2 17) 4 18)4 19) 3 20) 3 21) 2
15. Order w.r.to A = 1
22) 1 23) 1 24)3 25) 2 26) 4 27) 2 28)3
Order w.r.to B = 2
29) 4 30)3 31) 1 32) 3 33) 3 34) 3 35)2
Over all order = 1 + 2
36)2 37) 2 38) 1 39) 3 40) 3 41) 2 42)2 16. For zero order, rate remains constant with time.
43) 3 44) 3 45) 3 17. Order can be fractional
18. r K conc
n
LEVEL-I - HINTS
19. From units of rate constant, the reaction is third
1. r K A B order
A B 16K 20. 3 9n
r1 K A B
1/ 4 1/ 4 n 1/ 2
2. Rate of the reaction decreases with time 21. Both A and R correct only
from A products 22. For zero order reaction t completion a/k
3. Rate does not depends on excess quantity of
23. Rate K A
2
reactant
4. The rate constant becomes double for every
100 C rise in temperature. For 20 C rise, the 24. r1 K A
1
0
r2 K A
2
rate constant will be 4 times
K1 4 K 2 or K 2 0.25K1 r3 K A
3
d H2 d I2 1 d HI
5.
dt
dt
2 dt If A 1 r3 r2 r1
d A 1 d B 25. Rate K A
m
6.
dt 3 dt
6.25 r K 2.5A
m
2) Both (A) and (R) are true but (R) is not the
3) r K A 4) r K AC correct explanation to (A)
2
beginning Products
1) 1/2 2) 1/4 3) 1/8 4) 3/4
24. Out of 300g substance [decomposes as per 1st Reaction coordinate
order]. How much (nearly)will remain after
Then the activation energy of the reverse
18 hr? t1/2 3hr reaction is
1) 4.6 gm 2) 5.6 gm 3) 9.2 gm 4) 6.4 gm 1) 2x 2) 2y 3) x y 4) y x
25. 75% of a first order process is completed in 30. The energies of activation for forward and
30 min .The time required for 93.75% reverse reactions for A 2 B2 2AB are 180
completion of same process(in hr)? kJ/mol and 200 kJ/mol, respectively. The
1) 1 2) 120 3) 2 4) 0.25 presence of a catalyst lowers the activation
26. The half life of a radio active material is one energy of both (forward and reverse) reac-
hour. What would be the time required for tions by 100 kJ/mol. The enthalpy change of
99.9% completion the reacton A 2 B2 2AB in the presence
1) 5 hours 2) 10hours of a catalyst will be (in kJ/mol)
3) 2 hours 4) 20 hours 1) 300 2) 120 3) 280 4) -20
31. Effective collisions are those in which mol- dx
ecules must: 13. K A for first order sec 1
dt
1) Have energy equal to or greater than the
threshold energy dx
K for zero order M ol. lit 1 .sec 1
2) Have proper orientation dt
3) Acquire the energy of activation 14.Both A and R correct only
4) All of these
2.303 a
15. K log
LEVEL-I (H.W) - KEY t ax
1)1 2) 4 3) 3 4) 3 5) 1 6) 2 7) 2 16. Rate K A B
8) 3 9) 1 10) 1 11) 2 12) 2 13) 1 14) 2
1
15) 1 16) 2 17) 2 18) 4 19) 1 20) 2 21) 2 R 1 K 1 1
2
22) 2 23) 4 24) 1 25) 1 26) 2 27) 3 28) 1
1
29) 3 30) 4 31) 4 R 2 K 4 1 4 8
2
LEVEL-I (H.W) - HINTS 17. For zero order reactions rate is independent of
01 Rate constant is inversly proportional to concentrations.
temperature. 18. See examples of different order reactions
19. For elementary process both order and
1 d A 1 d B
02 molecularity same
3 dt x dt 20. Molecularity is 2 order is 1
03. Rate K Y Z
1/2
21. For simple reactions order of reaction is equal
to molecularity
1 d A d C
04. 1
2 dt dt 22. t 1 a n 1
2
3 9 16
rate of the reaction at 30 minutes is 7. The concentration of reaction decreases from
1) 2.5x10-4 mole lit-1 sec-1 0.2M to 0.05M in 5 minutes. The rate of
2) 2.5x10-6 mole lit-1 sec-1
3) 2.5x10-2 mole lit-1 sec-1 reaction in mole.lit 1.sec 1 is
4) 2.5x10-8 mole lit-1 sec-1 1) 8.3x10-4 2) 0.05 3) 0.0005 4) 0.15
8. A B KA = 10 e 15 -2000/T
2. For 2 NH 3 Au
N 2 3H 2 rate w.r.t N 2 is C D KC = 1014 e-1000/T
2 10 3 M min 1 , then rate w.r.t N 2 after 20 Temperature T; K at which (KA=KC)
min will be (in M min-1) 1) 1000K 2) 2000K
1) 2 103 2) 2 10 3 3) 104 4) 2 10 32000 1000
K 4) K 3)
3. The specific rate of a reaction is 1.5x10-4 lit 2.303 2.303
mole-1sec-1. If the reaction is commenced with 9.From the following data for the
0.2 mole/lit of the reactant, the initial rate ofdecomposition of N2O5 at 300C, find out the
the reaction in mole lit-1sec-1 is rate constant(in min–1). Volume of O2 after
1) 1.5 10 4 2) 3 1 0 5 10 min. of the reaction=90ml. Volume of O2
after completion of the reaction=100ml
3) 6 1 0 6 4) 6 1 0 5 1) 2.303 2) 0.2303 3) 0.02303 4) 23.03
4. For the process 2A products, rate of 10. If doubling the concentration of the reactant
reaction w.r.t A at 10th second is A increases the rate by 4 times and tripling
2
2 10 M s 1 then rates of same process at the concentration of A increases the rate by 9
5th and 15th seconds (order 0) respectively times, the rate is proportional to
are (in M/s) 1) concentration of A
2) square of concentration of A
1) 101 & 4 102 3) under root of conc. of A
2 2
2) 2.7 10 &1.6 10 4) cube of concentration of A
3) 1.6 102 & 2.7 102 11. Consider a system containing NO2 and SO2
in which NO2 is consumed in the following
4) 2 102 & 2 102
two parallel reactions
5. In the process 2 N 2O5( g ) 4 NO2( g ) O2( g ) at
2NO2
K1
N2O4 ; NO2 SO2
K2
NO SO3
t = 10 rate of reaction w.r.t N 2O5 , NO2 & O2 The rate of disappearance of NO2 will be
respectively are equal to
N 2O5 NO2 O2 1) K1[ NO2 ]2 K 2 [ NO2 ]
1) 500mm/min 400mm/min 200mm/min
2) K1[ NO2 ]2 K 2 [ NO2 ][ SO2 ]
2) 1000mm/min 1000mm/min 500mm/min
2
3) 1000mm/min 2000mm/min 4000mm/min 3) 2 K1[ NO2 ]
4) 400mm/min 400mm/min 400mm/min
4) 2
2 K1[ NO2 ] K 2 [ NO2 ][ SO2 ]
12. Consider the reaction, 17. Idm 3 2M CH3COOH is mixed with 1dm 3 of
2A B Products,When concentration of B
alone was doubled, the rate did not change. 3M ethanol to form ester. The decrease in the
When the concentration of A alone was initial rate if each solution is diluted with an
doubled, the rate increased by two times. The equal volume of water would be
unit of rate constant 1) 2 times 2) 4 times
for this reaction is 3) 0.25 times 4) 0.5 times
1) s 1 2) lit.mol1.s1 18. For a reaction, K 2 1013 e 30000/ RT . When log
1 1
3) Unitless 4) mol. lit .s
K y axis is plotted against 1/T x axis ,
13. For a reaction, the rate constant is expressed
as, K A.e40000/T slope of line will be.......Cal
The energy of the activation is 30000 30000
1) 2)
1) 40000 cal 2) 88000 cal 4.6 46
3) 80000 cal 4) 8000 cal 30000 30000
14. The reaction 3) 4)
2.303 4.6
CH 3COOC2 H 5 NaOH 19. The rate of a reaction doubles when its
CH 3COONa C2 H 5OH temperature changes from 300K to 310K.
Activation energy of such a reaction will be
is allowed to take place with initial
(JEE MAINS - 2013)
concentrations of 0.2 mole/lit of each reactant.
If the reaction mixture is diluted with water R 8.314JK1mol1 and log 2 0.3010
so that the initial concentration of each
1) 48.6kJ mol1 2) 58.5kJ mol1
reactant becomes 0.1 mole/lit. The rate of the
reaction will be 3) 60.5kJ mol1 4) 53.6kJ mol1
1) 1/8 th of the original rate 20. Give the following data for the reaction:
2) 1/4 th of the original rate XYZ
3) 1/2 th of the original rate
4) same as the original rate X Y Rate 101 ms 1
15. For the decomposition reaction: 1.0 M 1.0 M 0.25
N 2 O 4 g 2NO 2 g ; the initial pressure of 2.0 M 1.0 M 0.50
1.0 M 2.0 M 0.25
N 2 O 4 falls from 0.46 atm to 0.28 atm in 30 1.0 M 3.0 M 0.25
minute. What is the rate of appearance of Which one is the rate law equation?
1) Rate K X Y 2) Rate K X Y
0 1
NO 2 ?
1) 12 102 atm.min 1 2) 1.2 102 atm.min 1 3) Rate K X Y 4) Rate K X Y
0 2
3) 1.2 10 2 atm.min 1 4) 1.8 10 1 atm.min 1 21. The activation energy for a reaction is
16. The rate for decomposition of NH3 on 9.0kcal/mol. The increase in the rate constant
when its temperature is increased from 298K
platinum surface is zero order. What are the
to 308 K is:
rate of production of N 2 and H 2 in 1) 10 % 2) 100 % 3) 50 % 4) 63 %
mole.lit 1.sec 1 if K 2.5 104 mole.lit 1.sec 1 22. At 300K rate constant for
1) 3.75 104 ,1.25 104 A products at t = 50 min is 0.02 s 1 , then
rate constant at t = 75 min and
2) 1.25 104 ,3.75 104 310 K will be (in s 1 )
3) 1.25 104 ,3.75 104
0.04 0.02
4) 1.25 10 ,3.75 10
4 4 1) 2) 0.04 25 3) 0.04 4)
25 25
23. The rate expression for the reaction ORDER OF REACTION
A( g ) B( g ) C( g ) is rate KC A2 CB1/ 2 . What 28. The decomposition of CH3CHO occurs as
changes in the initial cocentations of A and B CH3CHO(g) CH4(g)+CO(g), the kinetic
will cause the rate of reaction to increase by data provided is
a factor of eight? [ C H
3
CHO] Rate(mol.lit-1.sec-1)
1.75 x 10-3 2.06 x 10-11
1) C A 2; CB 2 2) C A 2; CB 4
3.5 x 10-3 8.25 x 10-11
3) C A 1; CB 4 4) C A 4; CB 1 7.0 x 10-3 3.30 x 10-10
24. For the reaction system: The rate expression thus can be given as
1) K[CH3.CHO] 2) K[CH3.CHO]2
2 NO( g ) O2( g ) 2 NO2( g ) volume is suddenly
3) K[CH3.CHO]3 4) K[CH3.CHO]1/2
reduced to half of its value by increasing the 29. Obseve the following data regarding
pressure on it. If the reaction is of first order
2 NH 3 W
N 2 3H 2
with respect to O2 and second order with
Pressure(in atm) : 5 10 20
respect to NO, the rate of reaction will Half life (min) : 3.6 1.8 0.9
1) diminish to one - eight of its initial value The unit of K is
2) increase to eight times of its initial value 1) min 1 2) atm . m in 1
3) increase to four times of its initial value 3) ( atm . min) 1 4) atm 2 . min 1
4) diminish to one fourth of its initial value
30. For a first order reation t 0.75 is 1386 seconds,
25. The rate constant of a first order reaction at
then the specific rate constant in sec 1 is.
3 1
27 C is 10 min .The ‘temperaturee
0
1) 103 2) 102 3) 109 4) 105
coefficient’ of this reaction is 2.What is the
31. For N 2O5 2 NO2 1/ 2O2 , it is found that
rate constant in min 1 at 17 0 C for this
d d
reaction? [ N 2O5 ] K1[ N 2O5 ], [ NO2 ] K2 [ N2O5 ] ;
dt dt
1) 103 2) 5 104
d
[O2 ] K3[ N 2O5 ] then
3) 2 103 4) 102 dt
26. A reaction was found to be second order 1) K1 2K2 3K3 2) 2K1 4K2 K3
with respect to the concentration of carbon 3) 2K1 K2 4K3 4) K1 K2 K3
monoxide. If the concentration of carbon
monoxide is doubled, with everything else 32. For a given reaction of first order, it takes 20
kept as same, the rate of reaction will: min for the cocentration to drop from 1.0 M
to 0.6 M. The time required for the
1) Remain unchanged 2) Tripled cocentration to drop from 0.6 M to 0.36 M
3) Increases by a factor four 4) Doubled will be
27. The initial concentration of cane sugar in 1) more than 20 min 2) less than 20 min
presence of acid was reduced from 0.20 to 3) equal to 20 min 4) infinity
33. The half life of a reaction is 46 minutes when
0.10M in 5 hours and to 0.05M in 10 hours,
the initial concentration of the reactant is 0.4
value of K? in hr
1
mole/lit and 92 minutes when the initial
concentration is 0.2 mole/lit. The order of the
1) 0.693 2) 1.386 reaction is
3) 0.1386 4) 3.465 1) zero 2) 0.5 3) 2 4) 1
34. The rate constant of a reaction at 40. The rates of a reaction at different times are
temperature 200K is 10 times less than the given below
rate constant at 400K. What is the activation Time (in min) Rate
energy E a of the reaction? (R= Gas
0 2.8 x 10-2
10 2.8 x 10-2
constant) 20 2.8 x 10-2
1) 1842.4R 2) 921.2 R 30 2.79 x 10-2
3) 460.6 R 4) 230. 3 R The order of the reaction is
35. The decomposition of ozone proceeds as 1) 2nd order 2) zero order
O3 O2 O (fast) 3) 3rd order 4) 1st order
41. The isomerization of cyclopropane to form
O O3 2O2 (slow)
propene( CH 3 CH CH 2 ) is a first
the rate expression should be
order reaction. At 760K, 85% of a sample of
1) Rate K O3 2) Rate K O3 O2
2 2 1
cyclopropane changes to propene in 79 min.
Calculate the value of the rate constant.
3) Rate K O3 O2 4) Rate K O3 O2
1
1) 2.42 min 1 2) 3.66 102 min1
36. 50% of a reaction is completed in 16min, 3) 2.40 102 min1 4) 1.04 102 min1
under similar conditions 75% of the reaction 42. For a reaction following first-order kinetics,
is completed in 48min. Order of the reaction which of the following statements are
will be correct?
1) 3 2) 1 3) 2 4) 0 1) The time taken for the completion of 75% of
37. For a process, A B products, the rate of
the reaction is twice t1/2.
the reaction is second order with respect to A
and zero order with respect to B. When 1.0 2) A plot of the reciprocal of the concentration
mole each of A and B are taken in a one litre of the reactants against time gives a straight line
3) The degree of dissociation is equal to 1ekt
vessel, the initial rate is 1102 mol. lit 1. s1 .
4) A plot of A0 / A versus time gives a straight
The rate of the reaction, when 50% of the
reactants have been converted to products line.
would be 43. t 1 / 4 can be taken as the time taken for the
1) 1102 mol.lit 1 . s1 concentration of a reactant to drop to 3/4 of
its initial value. If the rate constant for a first
2) 2.5103 mol. lit 1. s1
order reaction is K, t1/4 can be written as
3) 5.0 102 mol.lit 1.s1 1) 0.75/K 2) 0.69/K 3) 0.29/K 4) 0.10/K
4) 0.5102 mol. lit 1.s1 44. The rate constant is numerically the same for
three reactions of first, second and third
38. SO2 Cl2 SO2 Cl2 is a first order gas order respectively. Which of the following is
reaction with K 2.2 105 sec1 at 3200 C . correct:
The percentage of SO2Cl2 decomposed on 1) if A 1 then r1 r2 r3
heating for 90 minutes is: 2) if A 1 then r1 r2 r3
1) 1.118 2) 0.1118 3) 18.11 4) 11.18
39. For the reaction a A x P when [A] = 2.2 mM 3) if A 1 then r3 r2 r1 4) All of these
the rate was found to be 2.4 mM s 1 . On 45. 99% of a 1st order reaction completed in
reducing concentration of A to half, the rate 2.303 minutes. What is the rate constant and
1
changes to 0.6 m M s . The order of reaction half-life of the reaction
with respect to A is 1) 2.303 and 0.3010 2) 2 and 0.3465
1) 1.5 2) 2.0 3) 2.5 4) 3.0 3) 2 and 0.693 4) 0.3010 and 0.693
46. For a first order reation, (A) products, the 53. An endothermic reaction A B has an
concentration of A changes from 0.1 M to activation energy 15 K Cal/mole and enthalpy
0.025 M is 40 min. The rate of reaction when change ( H ) of the reaction is 5 KCal/mole.
the concentration of A is 0.01 M is The activation energy of the reaction B A
( AIE - 2012 ) is
1) 3.47 10 M min 2) 3.47 10 M min
4 1 5 1 1) 20 K cal/mole 2) 15 K cal/mole
3) 10 K cal/mole 4) 5 Kcal/mole
3) 1.73 104 M min 1 4) 1.73 105 M min 1
47. The reaction 2A B is first order in A with LEVEL-II (C.W) - KEY
a rate constant of 2.8 10 2 s 1. How long will 1) 2 2) 1 3) 3 4) 2 5) 4 6) 3 7) 3
it take(nearly) for A to decrease from 8) 4 9) 2 10) 2 11) 4 12) 1 13) 3 14) 2
0.88 M to 0.22M ? 15) 3 16) 2 17) 3 18) 4 19) 4 20) 3 21) 4
1) 60 s 2) 76 s 3) 50 s 4) 44 s 22) 3 23) 2 24) 2 25) 2 26) 3 27) 3 28) 2
HALF - LIFE 29) 2 30) 1 31) 3 32) 3 33) 3 34) 2 35) 2
48. For a first order reaction with half-life of 150 36) 3 37) 2 38) 4 39) 2 40) 2 41) 3 42) 1
seconds, the time taken for the concentration 43) 3 44) 4 45) 2 46) 1 47) 3 48) 3 49) 2
of the reactant to fall from M / 10 to M / 100 50) 3 51) 2 52) 2 53) 3
will be approximately
1) 1500 sec 2) 900 sec LEVEL-II (C.W) - HINTS
3) 500 sec 4) 600 sec
49. In a first order reaction, 50 minutes time is 1. r K A
2
taken for the completion of 93.75% of a 2. Given reaction is Zero order reaction.
reaction. Half life of the reaction is For zero order rate remains constant with time.
1) 25 min 2) 12.5 min 3) 20 min 4)10 min 3. From units of rate constant, it is second
50. In 69.3 min, a first order reaction is 50% order Rate K reactant
2
If A 1 r1 r2 r3 2 5 t
3. The rate reaction for the reaction 2A B C 9. For 2A B C products, rate law is given
is found to be rate =K[A] [B]. The correct
by rate K A B & rate constant (K) is
2
statement is relation to this reaction is that
the 2 106 M 2 . S 1 . Then rate of the reaction
1
1) unit of K must be s
become 2 10 9 M 2 . S 1 only when
2) value of K is independent of the initial
concentration of A and B A B C
3) rate of formation of C is twice the rate of
1) 0.3 M 0.2 M 0.2 M
disappearance of A.
2) 0.2 M 0.1 M 0.2 M
4) t1/ 2 is a constant 3) 0.1 M 0.1 M 0.1 M
4. The rate law for a reaction between the 4) 0.2 M 0.2 M 0.1 M
substances A and B is given by Rate= K An Bm
ORDER OF REACTION
on doubling the concentration of A and halving 10. Rate expression for xA + y B
products is
the concentration of B, the ratio of the new
rate to the earlier rate of the reaction will be Rate K[ A]m [ B]n . Units of K w.r.t A and B
as respectively are s 1 and M 1.s 1 when
1 concentrations of A and B are increased by 4
1) m n 2) (m + n) 3) (n – m) 4) 2 n m times, then
2
5. Hydrogenation of vegetable ghee at 250 C 1) R f 16 Ri 2) Ri 16 R f
reduces pressure of H 2 from 2 atmospheree 3) R f 8 Ri 4) R f 64 Ri
to 1.2 atmosphere in 50 minutes. The rate of 11. A first order reaction was commenced with
reaction in terms of molarity per second is 0.2 M solution of the reactants. If the molarity
1) 1.09 106 2) 1.09 105 of the solution falls to 0.02M after 100
3) 1.09 10 7 4) 1.09 10 8 minutes the rate constant of the reaction is
1) 2 x 10-2 min-1 2) 2.3 x 10-2 min-1
6. For a reaction 2 SO2 O2 2 SO3 rate of
3) 4.6 x 10-2 min-1 4) 2.3 x 10-1 min-1
consumption of SO2 is 6.4 10 kg / sec. the 12. The experimental data for the reaction
3
rate of formation of SO3 in same units will 2NO g Cl2 g 2 NOCl g are given below
be
Expt Cl2 NO Initial rate
1) 6.4 103 2) 8 103 3) 4 103 4) 16 103
7. A gaseous reaction 1 0.020 0.010 2.4 10 4
1 2 0.020 0.030 2.16 10 3
A2 ( g ) B ( g ) C (g) shows increase of
2 3 0.040 0.030 4.32 10 3
pressure from 100mm to 120mm in 5 min. What is the order of the reaction ?
The rate of disappearance of A2 is 1) 1 2) 2 3) 3 4) 0
1) 4mm min-1 2) 40mm min-1 13. The reaction, 2A B Products, follows the
3) 8mm min-1 4) 20mm min-1 mechanism
8. Concentration of a reactant ‘A’ is changed
2 A A2
from 0.044M to 0.032M in 25 minutes, the
average rate of the reaction during this A2 B Products (Slow) The order of the
interval is reaction is
1) 0.0048 mol.lit 1.min 1 2) 0.00048 mol.lit 1.sec1 1
1) 2 2) 1 3) 3 4) 1
3) 4.8 104 mol.lit 1.min 1 4) 0.0048 mol.lit 1.sec 1 2
14. Diazonium salt decomposes as HALF LIFE
C6 H 5 N 2 Cl C6 H 5 Cl + N 2 18. The half-life for the reaction.
1
At 0o C , the evolution of nitrogen becomes N 2 O5 2NO 2 O 2 is 24hrs. at 300 C.
2
two times faster when the initial
concentration of the salt is doubled therefore Starting with 10g of N 2 O5 how much grams
it is. of N 2 O5 will remain after a period of 96
1) a first order reaction. hours?
2) a second order reaction. 1) 1.25 g 2) 0.625 g 3) 1.77 g 4) 0.5 g
3) independent of the initial concentration of the 19. The half life of a first order reaction
salt. A B C is 10 minutes. The concentration
4) a zero order reaction of ‘A’ would be reduced to 10% of the original
15. Using the data given below the order and rate concentration in
constant for the reaction : 1) 10 minutes 2) 33 minutes
CH 3CHO g CH 4 g CO g would be 3) 90 minutes 4) 70 minutes
Experiment Initial conc. Initial rate 20. A first order reaction is half-completed in 45
No (mol/l) (mol/l) minutes.How long does it need for 99.9% of
a 0.10 0.020 the reaction to be completed?
b 0.20 0.080 1
1) 7 hours 2) 20 hours
c 0.30 0.180 2
3) 10 hours 4) 5 hours
d 0.40 0.320
Answer is COLLISION THEORY
21. The reaction A C has activation energy for
1) 2, K 2.0 l / mol sec 2) 0, K 2.0 mol / l sec
the forward and the backward reaction has
25KJ and 32KJ respectively. The H for
3) 2, K 1.5 l / mol sec 4) 1, K 1.5 sec 1
the reaction is
16. For the first order reaction A product. 1) 57 KJ 2) -57 KJ 3) 7 KJ4) -7 KJ
22. Consider an endothermic reaction X Y
When the concentration of A is 2.5 10 2 M
with the activation energies E b and E f for the
the activation energy is 20K.Cal/mole. If the
backward and forward reactions
conc. of A is doubled, at same temperature, respectively. In general.
the activation energy becomes equal to 1) E b E f 2) E b E f 3) E b E f
4) There is no definite relation because E b and E f
1) 40K.cal/mole 2) 10K.cal/mole
3) 20K.cal/mole
20
4) 2 RT K.cal/mole LEVEL-II (H.W) - KEY
1) 2 2) 4 3) 2 4) 4 5) 2 6) 2 7) 3
17. A g B g is a first order reaction. The initial 8) 3 9) 3 10) 4 11) 2 12) 3 13) 3 14) 1
concentration of A is 0.2 mol.lit 1. After 10 15) 1 16) 3 17) 1 18) 2 19) 2 20) 1 21) 4
minutes the concentration of B is found to be 22) 1
3) 4)
[ A2 ] K [ A] .................. (ii)
2
Time Time
From (i) and (ii)
r KK[ A]2 [ B] K '[ A]2 [ B] 3. Which one of the following statements is
14. r K A ; 2 r K 2 A n 1 correct for the reaction (E-2012)
n n
CH 3COOC 2 H 5 NaOH
CH 3COONa C 2 H 5OH
15. r K CH 3CHO (1)
n (aq) (aq)
aq aq
d A d B d C
a Atm.m1 b mol s1 respectively
1. xA yB zC. If 1.5 1) 0.002, 8.58 107 2) 0.001,8.58 10 7
dt dt dt
then x,y and z are: 3) 0.002,8.58 104 4) 0.001,8.58 103
1) 1,1,1 2) 3,2,3 3) 3,3,2 4) 2,2,3 6. A B & C D are first order reactions,
2. For the complex
ratio of t99.9% values is 4 : 1, then ratio of rate
Ag 2 NH 3 Ag NH 3 2
constans K1 to K2 is
1) 4 : 1 2) 2 : 1 3) 1 : 1 4) 1 : 4
dx
dt
2 10 L mol s Ag NH 3
7 2 2 1 2
7. A substance ‘A’ decomposes in solution
following first order kinetics. Flask I contains
1L of a 1M solution of A and flask II contains
1 102 s 1 Ag NH 3 2 100 ml of a 0.6 M solution. After 8 hours the
Hence, ratio of rate constants of the forward concentration of A in flask I has become 0.25.
What will be the time taken for concentration
and backward reaction is:
of A in flask II to become 0.3 M?
1) 2 107 L2 mol 2 2) 2 109 L2 mol 2 1) 0.4 h 2) 2.4 h 3) 4.0 h
3) 1102 L2 mol 2 4) 0.5 109 L2 mol 2 4) Can’t be caculated since rate constant is not
3. The following reaction is first order in A and given
first order in B: 8. The energy of activation for a reaction is
50kJ/mol. Presence of a catalyst lowers the
A B Product, Rate kI A B energy of activation by 25%. What will be
the effect on rate of reaction at 300C . Other
things remains same.
A 1) 142.75 2) 242.75 3) 342.75 4) 442.75
9. For the reaction 2 A 3B product, A is in
B
excess and on changing the concentration of
B from 0.1 M to 0.4 M, rate becomes doubled.
I II Thus, rate law is:
dx dx
k A B k A B
2 3
Relative rate of this reaction in vessel I and 1) 2)
II of equal volume is: dt dt
A dx dx 1
1) 1:1 2) 1:2 3) 2:1 4) 1:4 k A B k B 2
0 2
3) 4)
B dt dt
II
10. A reaction is catalysed by H+ ion; in 15. For the reactions of I, II and III
3 1
presence of HA rate constant is 2 10 min orders, K1 K 2 K 3 when concentrations aree
and in presence of HB rate constant is expressed in mol litre1 . What will be
3 1
1 10 min . HA and HB (both strong acids) the relation in K1 , K 2 , K 3 ,if concentrations aree
have relative strength as: expressed in mol/mL ?
1) 0.5 2) 0.002 3) 0.001 4) 2
1) K1 K2 K3 2) K1 K2 103 K3 106
ORDER AND HALF LIFE
3) K1 2K2 K3 4) 2K1 3K2 4K3
16. 900 ml of pure and dry O2 is subjected to
seilent electric discharge, so that after a time
10 min. volume of ozonized oxygen is found
to be 870 ml. Now average rate of reaction in
this interval is (in ml/min)
1) 3 2) 9 3) 90 4) 60
11.
17. At some temperature, the rate constant for
the decomposition of HI on the surface of gold
is 0.08 MS1 2HI g H 2 g I2 g what is the
Half-life is independent on concentration of order of the reaction. Howlong will it take
A. After 10 minutes volume of N2 gas is 10 L for the concentration of HI to drop from 1.50
and after completion of reaction 50 L. Hence, M to 0.30 M.
rate constant is : 1) zero order, t 7.5Sec
2.303 2.303 2) zero order, t=15 Sec
1) log 5 min 1 2) log1.25 min 1
10 10 3) first order, t=22.5 Sec
2.303 2.303 4) first order, t=7.5 Sec
3) log 2 min 1 4) log 4 min 1 18. For the first order gaseous reaction:
10 10
12. When the initial concentration is changed x ( g ) 2 y ( g ) z ( g ) the initial pressure,
from 0.50 to 1.0 mole lit , the time of half Px 90 mm Hg . The pressure after 10
1
2
O2 in presence of
o s i t i o n o f H
1) 3 2) 2 3) 2 4) 4 5) 1 6) 4 7) 3
K2 Ae37.510 / RT
3
8) 1 9) 4 10) 4 11) 2 12) 2 13) 3 14) 2
15) 2 16) 2 17) 2 18) 3 19) 4 20)3 21)3
K1
e
37.5 50 103 / RT
e12.510 / RT
3
E a
2.303 308 298 1.987
log1.75cal mol1 Cl2 HS 2Cl H S slow
10 1) (B) only 2) Both (A) and (B)
E a 10.207 kcal mol 1 3) Neither (A) nor (B) 4) (A) only
k E T T 5. For the non-stoichiometric reaction
33. log k 2.303R T T
2 a 2 1
d A 1 d B d A 1 d B
energy Ea2 . If Ea2 2 Ea1 , then K1 and K2 aree 1) 2)
related as ( AIE -2011) dt 2 dt dt 4 dt
1) K1 2 K 2 e Ea2 / RT 2) K1 K 2 e Ea1 / RT d A d B d A d B
3) 4) 4
dt dt dt dt
3) K 2 K1e Ea2 / RT 4) K1 AK 2 e Ea1 / RT
PREVIOUS JEE MAINS - KEY 2. The acid hydrolysis of ester is:
1) 3 2) 2 3) 2 4) 4 5) 4 6) 2 (i) first order reaction
(ii) bimolecular reaction
PREVIOUS JEE MAINS HINTS (iii) unimolecular reaction
x (iv) second order reaction
1. For a zero order reaction K .....(1) The true statements are
t
1) i, ii 2) All are correct
A0
K 3) ii, iv 4) ii, iii, iv
for zero order reaction 2t 1 .....(2) 3. Which of the following statements are
2
correct:
since A0 = 2 M, t 1 1 h , K 1 (i) law of mass action and rate law expressions
2 are same for single step reaction
from equation (1) (ii)the slowest step of a complex reaction gives
0.25 the order of the complex reaction
t 0.25 h
1 (iii) both order and molecularity have
2. For every 100 C temperature raises rate of normally a maximum value of 3
reaction becomes doubled (iv) molecularity of a complex reaction
3. By based on arrhenius equation A+2B C is 3
4. Slowest step is the rate determining step. Thus 1) i, ii, iii 2) All are correct
in case (A) rate law is given as 3) ii, iv 4) ii, iii, iv
rate K Cl2 H 2 S 4. Consider the following reactions at 300 K
While for the reaction given in case (B), rate X Y uncatalysed reaction
1
law is given as rate K Cl2 H 2 S H X
catalyst
Y catalysed reaction
Hence, only mechanism (A) is consistent with The energy of activation is lowered by
the given rate law
0.314 K J. m ol 1
for the catalysed reaction.
5. The rate only depends upon A
The rate of reaction is
6. According to rate equation 1) 28 times 2) 15 times 3) 25 times
4) 22 times that of uncatalysed reaction.
LEVEL-IV 5. A substance undergoes first order
decomposition. The decomposition follows
1. For the reaction A 2 B C D 2 E the rate two parallel first order reaction as :
equation is rate = K A B 0 C then the rate
is K1 B
i) Doubled when [A] is doubled keeping B K 1 1.26 10 4 sec 1
and C constant A
and K 2 3.8 105 sec1
ii) Doubled when [C] is doubled keeping A
and B constant K2
C
iii)The same when [B] is doubled keeping A
and B constant The percentage distribution of B and C are
iv) Doubled when [B] is doubled keeping A 1) 80% B and 20%C
and C constant
2) 76.83% B and 23.17% C
The correct combination is
1) i, ii, iii 2) All are correct 3) 90% B and 10%C
3) ii, iv 4) ii, iii, iv 4) 60% B and 40% C
6. The rate of the reaction between haemoglobin 1
(Hb) and carbon monoxide (CO) was studied 8. Graph between log k and
T
is a straight line
at 20 0 C . The following data were collected 1
with OX = 5, tan 2.303 . Hence Ea will be
with all concentration units in mol / L (A
haemoglobin concentration of 2.21 mol / L
is equal to 2.21 10 6 mol/L )
5
Determine the orders of this reaction 1) 2.303 2 cal 2) cal
2.303
with respect to Hb and CO and rate constant.
3) 2 cal 4) none of these
1)1st order in Hb and Ist order in CO
9.
In a first order reaction the concentration of
0.140 L mol 1 s 1 product 'x' at time 't' is given by the
2) 1st order Hb and 1st order in CO expression (a=initial concentration, k=rate
constant, n=order)
0.280 L mol 1 s 1
1
1 1
3) 1st order, 2nd order, 0.35 L mol s 1) x a
1 e kt
2) x
a x
4) 2nd, order, 2nd order, 0.24 L mol 1s 1 1 a
3) x n 1 4) x
7. Consider following graphs (1) and (2) 2 a x
Passage : 1
A collision between reactant molecules must occur
with a certain minimum energy before it is
effective in yielding product molecules. This
minimum energy is called activation energy Ea .
Larger is the value of activation energy, smaller
is the value of rate constant. Larger is the value
of activation energy, greater is the effect of
temperature rise on rate constant K.
Et I
The order of reaction and the value of rate
Potential energy
constant is: Ef
1) First order, 2.37 10 5 min 1 Eb
2) Second order, 2.37 105 torr 1 min 1 R H
1 1 P
3) Zero order, torr min
4) None of the above Collision number
Energy
temperature, according to the equations,
2 N 2O5 4 NO2 O2
R
P
1
2 NO2 O2 N 2O5 the activation energies Reaction path
2
are E1 and E2 respectively. Then Answer the following questions:
1) E1 E2 2) E1 E2 1. The activation energy of the forward reaction is
1) x 2) y 3) x y 4) x y
3) E1 2E2 4) E1 E22 1 2. The activation energy of the backward reaction
3. In a hypothetical reaction, A Y , the activation is
energies for the forward and backward reactions 1) x 2) y 3) x y 4) x y
3. The heat of the reaction is
are 15 and 9kJ mol 1 respectively. The potential
1
1) x 2) y 3) x y 4) x y
energy of A is 10kJ mol . Which of the 4. The threshold energy of the reaction is
following is wrong ? 1) x y z 2) x y z
1) Threshold energy of the reaction is 25 kJ
3) x y z 4) x y z
2) The potential energy of B is 16 kJ
3) Heat of reaction is 6 kJ
4) The reaction is exothermic LEVEL-IV - KEY
1) 1 2) 1 3) 1 4)1 5)2 6) 2 7) 2
4. For two reactions, activation energies are Ea1
8) 3 9) 1
and Ea2 ; rate constants are K1 and K2 at the same Passage - I:
1) 2 2) 1 3) 4 4) 3 5) 4 6) 1
temperature. If K1 K2 , then
Passage - II:
1) Ea1 Ea2 2) Ea1 Ea2 1) 1 2) 3 3) 2 4) 3
3) Ea1 Ea2 4) Ea1 Ea2
LEVEL-IV - HINTS
5. The rate constant of a certain reaction is given
r K A B C
0
by K Ae Ea / RT ( where A = Arrhenius constant 1.
). Which factor should be lowered so that the 2. In acid hydrolysis of ester. water is taken in
rate of reaction may increase ? excess quantity r k Ester
1) T 2) Z 3) A 4) Ea order = 1
6. The activation energies for forward and molecularity = 2
backward reactions in a chemical reaction are 3. Molecularity is always a whole number
30.5 and 45.4 kJmol 1 respectively. Then 4. K uncat A e Euncat / RT
reaction is
K Cat A e Ecat / RT
1) exothermic 2) endothermic
3) neither exothermic nor endothermic
4) independent of temperature