Section-II (CHEMISTRY)

Single Correct Type Questions (D) (SiH3)3N is pyramidal and less basic than
31. Borax is made of two tetrahedral and two (CH3)3N.
triangular units joined together and should be
written as: 36. The nonexistence of PbI4 is due to:
Na2[B4O5(OH)4]8H2O (A) Small size of Pb4+ ions and large size I– ions
Consider the following statements about borax: (B) Highly oxidizing power of Pb4+ ions
a. Each boron atom has four B–O bonds. (C) Highly reducing power of I– ions
b. Each boron atom has three B–O bonds. (D) Both (B) and (C)
c. Two boron atoms have four B–O bonds
while other two have three B–O bonds. 37. Which of the following statements are correct?
d. Each boron atom has one –OH groups. (I) SnCl4 is more easily hydrolysed than SnCl2
Select correct statement(s): (II) SnCl2 is good reductant while PbCl4 is oxidant
(A) a, b (B) b, c (III) SnCl4 is more volatile than SnCl2
(C) c, d (D) a, c (IV) PbI4 does not exist
(A) I, II, IV (B) II, IV
32. In the following reaction: (C) I, II, III, IV (D) Only IV
B(OH)3 + H2O → [B(OH)4]– + H+
(A) B(OH)3 is a Lewis acid. 38. N2O3 is–
(B) B(OH)3 is a Lewis base. (A) An acidic oxide and the anhydride of HNO2
(C) B(OH)3 is amphoteric. (B) An acidic oxide and the anhydride of H2N2O2
(D) None is correct. (C) A neutral oxide and the anhydride of HNO3
(D) A basic oxide and the anhydride of HNO2
33. BCl3 does not exist as dimer but BH3 exist as
39. The relative stability of +1 oxidation state of
dimer (B2H6) because:
group 13 elements follows the order:
(A) Chlorine is more electronegative than (A) Ga < Al < In < Tl (B) Tl < In < Ga < Al
hydrogen (C) Al < Ga < Tl < In (D) Al < Ga < In < Tl
(B) There is p-p back bonding in BCl3 but BH3
does not contain such multiple bonding 40. The property of halogen acids which is incorrect
(C) Large sized chlorine atoms do not fit in is:-
between the small boron atoms whereas (A) HF > HCl > HBr > HI : Acidic strength
(B) HI > HBr > HCl > HF : Reducing strength
small sized hydrogen atoms get fitted in
(C) HI > HBr > HCl > HF : Bond length
between boron atoms
(D) HF > HCl > HBr > HI : Thermal stability
(D) None of the above
41. Coordination number, oxidation state
34. The bonds present in borazine (B3N3H6) are:
and number of isomers in K3[Cr(C2O4)3] are
(A) 9, 6 (B) 12, 3
(C) 6, 9 (D) 15 Only respectively:
(A) 6, +3, 2 (B) 4, +2 & 2
35. The correct statement among the following is: (C) 3 & +3 & 3 (D) 3, 0 & 3
(A) (SiH3)3N is planar and less basic than
(CH3)3N. 42. In which of the following complex ion the value of
(B) (SiH3)3N is planar and more basic than magnetic moment is 3 B.M. and outer
(CH3)3N. d-orbitals is used in hybridisation.
(C) (SiH3)3N is pyramidal and more basic than (A) [Mn(CN)6]4– (B) [Fe(NH3)6]3+
(CH3)3N. (C) [Co(CO)4] (D) [Cu(H2O)6]2+
 (I) IUPAC name of the compound is
43. Select the correct option regarding [PtCl4]2–: Pentaamminenitrito-N-chromium (III) tetra
(A) paramagnetic, tetrahedral chlorozincate (II)
(B) diamagnetic, tetrahedral (II) It shows geometrical isomerism
(C) diamagnetic, square planar (III) It shows linkage isomerism
(D) paramagnetic, square planar (IV) It shows co-ordination isomerism
(A) III, IV (B) I, III & IV
44. Which of the following statement correct for the (C) II, III & IV (D) I, II, III & IV
complex K4[Fe(CN)5O2].Fe having t 2g6eg0
configuration? Integer Type Questions
(A) d2sp3 and diamagnetism 51. How many of given species is/are paramagnetic:
N2O, KO2, NO2, ClO2, ClO3, N2O3, O3
(B) sp3d2 and diamagnetism
(C) d2sp3 and paramagnetism 52. In phosphorus acid, if X is number of non-bonding
(D) sp3d2 and paramagnetism electron pairs. Y is number of -bonds and Z is
number of -bonds. Then calculate value of “Y ×
45. Which of the following is not planar? Z – X.”
(A) [Ni(CN)4]2– (B) [PtCl4]2–
(C) [Pd(CN)4]2– (D) [Zn(CN)4]2–

53. The number of halogen(s) forming halic (V) acid is

46. Which of the following ligands are capable of ____.
forming chelate rings?
(I) NH2 – CH2 – CH2 – NH2
(II) CH3 – CH2 – CH2 – NH2 54. Among the following allotropic forms of sulphur,
(III) NH2 – CH2– CH2– NH – CH2– COO – the number of allotropic forms, which will show
Para magnetism is _______.
(IV) NH2– CH2– CH2– NH3 (A) -sulphur (B) -sulphur
(A) I and II (B) II and IV (C) S2-form
(C) I and III (D) I, II, III and IV

93. Find the number of complexes which satisfy EAN

47. Which among the following ligand is a type of flex
rule.
dentate ligands?
Ni(CO)4, Fe2(CO)9, H[V(CO)6], [Fe(CO)4]2–,
(A) NH3 (B) H2O
Co2(CO)8, [Fe(CO)2(NO)2], [(6–C6H6)2Cr], [Fe
(C) SCN– (D) CO32–
(CN)6]3–, [Ni(NH3)6]2+
48. The correct name of linkage isomer of
[Co(NH3)5(SCN)]SO4 94. Find the number of inner orbital octahedral
(A) Pentaamminethiocyanato-S-Cobalt (III) sulphate complexes (d2sp3 hybridisation) of the following.
(B) Pentaamminethiocyanato-N-Cobalt (II) sulphate [Co(H2O)6]3+, [Fe(NH3)6]2+, [CoF6]3–, [NiF6]2–,
(C) Pentaamminethiocyanato-N-Cobalt (III) sulphate [Pt(NH3)2Cl4], [Co(Ox)3]3–, [RhF6]3–,
(D) Pentaamminecyanato-N-Cobalt (III) sulphate [Cr(H2O)6]3+, [Mn(CN)6]4–, [Fe(CN)6]3–,
[Co(NH3)6]2+
49. The total number of possible coordination isomer
for the given compound is: [Pt(NH3)4Cl2][PtCl4] 95. Find the total number of ligands which act as -
(A) 2 (B) 4
acceptor.
(C) 5 (D) 3
O2–, F¯, CO, CH3NC, CN¯, CH3O¯, OH¯, CH2=
50. Select correct code about complex CH2, NO+, PF3, AsF3
[Cr(NO2)(NH3)5][ZnCl4]

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98. Find the total number of diamagnetic complexes.
K3[Fe(CN)6], [Co(NH3)6]Cl3, Na3[Co(Ox)3], 100. Find total number of complexes having square
[Ni(H2O)6]Cl2 , K2[Pt(CN)4], [Zn(H2O)6](NO3)2, planar geometry.

K2[NiCl4] , [Pt(NH3)2Cl2], [Ni(CO)4] [Co(CO)4]–, [Cu(NH3)4]2+, [Cu(CN)4]3–,

[Ni(CN)4]2– , [AuCl4]–, [PtCl4]2–,

99. How many of the following are tetrahedral? [Pt(NH3)2Cl2], [NiCl4]2–, [PdCl4]2–
(a) Ni(dmg)2 (b) [Ni(CN)4]2–

(c) [Ni(CN)4]4– (d) [Ni(CO)4]

(e) [Ni(Cl)4]2– (f) K2Cr2O7

(g) K2CrO4 (h) KMnO4
(i) K2MnO4 (j) CrO2Cl2

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