Professional Documents
Culture Documents
TDS THERMODYNAMIQUE FMSB - FB - IDE - FASA - Fr.en
TDS THERMODYNAMIQUE FMSB - FB - IDE - FASA - Fr.en
d. 29.1 J / K.mole
15. Determine the entropy variation for an isobaric evolution of a mole of oxygen between 0 and 100 degrees
Celsius (in J / K.mole).
To. 6.21 J / K.mole
b. 6.08 J / K.mole
vs. 8.08 J / K.mole
d. 9.08 J / K.mole
d. is constant
17. What is the value of the ideal gas constant in the SI system
To. 0.082
b. 1.98
vs. 8.2
d. 8,314
18. The entropy is:
To. Measuring the disorder of matter and energy
b. Measuring the disorder of matter
vs. Measurement of energy disorder
d. The measure of disorder at equilibrium
19. Disorder is a phenomenon:
To. Not spontaneous
b. Provoked
vs. Spontaneous
20. The entropy function is symbolized by
To. U
b. E
vs. G
d. S
21. The 2th principle is defined by the following postulate:
To. The entropy of the universe is the state of equilibrium
A-Cleanliness
B- Order
C- Disorder
D- Heat
E-None of the preceding propositions is exact
28. the variations a cycle of the total entropy of a system is:
A-Always positive
B-Always negative
C-Still zero
DN 'is not measurable
E-None of the preceding propositions is exact
A- U = Q + W
B- U = integral of (CpdT) + integral of (hdP)
C- U = - integral of (PdV)
D- U = nCpdT - PdV
33. The zero kelvin represents
various particles of matter which compose it and without there being any displacement of this
matter:
Convection
Conduction
Radiation
Condensation
36. Un__________ is a device which measures the humidity of the air:
Thermometer.
Hygrometer.
Thermoscope.
Barometer.
37. lyophilization, or freeze-drying, is the desiccation of a product previously frozen by:
Sublimation
Vaporization
Evaporation
Merger
38. In the Carnot cycle:
Isothermal expansion is characterized by the fact that no heat exchange takes place with the outside.
Adiabatic compression is characterized by a change in the internal energy of the system. A Carnot
cycle admits the possibility of a return equal to 100%.
A Carnot cycle admits a non-zero entropy variation along the cycle. A
Carnot cycle is an irreversible process.
39. In an isobaric transformation of a closed system, the quantity of heat exchanged:
Is greater than the change in enthalpy of the system
is less than the change in enthalpy of the system is
equal to the change in enthalpy of the system none
of the above answers
40. the 2nd principle is defined by the following postulate:
a change of state
a physical transformation a
chemical transformation none
of the above
42. What will be, in joules, the quantity of heat received by a mole of ideal gas evolving in an
isothermal way, at 100 degrees celcius, when its pressure decreases by half?
3120 joules
312 joules
2149 joules
5651 joules
43. For an isochoric evolution of 4 g of oxygen O2 (M = 32 g) evolving from 100 to 200 degrees celcius,
130 joules
- 130 joules
2600 joules
260 joules
44. For an isobaric evolution of 4 g of oxygen O2 (M = 32 g) evolving from 100 to 200 degrees celcius,
364 joules
264 joules
- 130 joules
0 joule
45. What is the molar heat at constant pressure Cp of a diatomic ideal gas, in J / K.mole?
30.1 J / K.mole
41.8 J / K.mole
33.5 J / K.mole
29.1J / K.mole
46. Determine the entropy variation for an isobaric evolution of a mole of oxygen between 0 and 100
6.21 J / K.mole
6.08 J / K.mole
8.08 J / K.mole
9.08 J / K.mole
22- what is the value of the ideal gas constant in the SI system
0.082
1.98
8.2
8,314
47. The ideal gas law reads as follows:
A. PT = nRV
B. VT = nRP
C. PV = nRT
D. PR = -Nvt
48. The mathematical basis of Boyle's
law is:
a) V / T = constant
b) V / N = constant
c) P / T = constant
d) PV = constant
a) V / T = constant
b) V / N = constant
c) P / T = constant
d) PV = constant
50. What is the molar heat at constant pressure Cp of a diatomic ideal gas, in J / K.mole
30.1 J / K.mole
41.8 J / K.mole
33.5 J / K.mole
29.1J / K.mole
51. Thereaction4Al (s) +3O2 =2Al2O3 (s) ⍙H ° = -3351KJ
B-Entropy
C-Internal energy
Free Energy
E-None of the preceding propositions is exact
6-the variation over one cycle of the total entropy of a system is:
A- Always positive
B-Always negative
C- Still zero
D- Is not measurable
E- None of the preceding propositions in 'is exact
13-the temperature of anidealgas increasesfrom20 ° cto40 ° cwhile the pressure stays the same: what happens to
the volume of the gas?
A- It doubles
B- It quadruple
C- It is cut to one-half D-
It is cut to one-fourth E-It
lightly increases
19-work:
A-Is a state function B- Is
not a state function
C -Vaut `` Pdv '' (by elementary variation)
VS-⍙U = 0
D-⍙H = 0
27-enthalpy change which accompanies this freezing (∆sH °253; in J at10-1close) corresponding: A-
-6019, 0
B- -5185.8
C- -671.6
D- 1504.8
E- 6852.2
F-None of the preceding propositions is exact
28-the variation of internal energy which accompanies this freezing (∆sU °253;enJà10-1near) corresponding:
A- -6019, 0
B- -5185.8
C- -671.6
D- 1504.8
E- 6852.2
F-None of the preceding propositions is exact
29-the entropy variation which follows this freezing (∆sS °253in J / K at 10-1near) corresponds:
A- -22.1
B- - 18.9
C- -2.6
D- 5.7
E- 25.2
F-None of the preceding propositions is exact
30-following this solidification, the environment determines an entropy (∆SenvyenJ / K at10-1near) of the order of:
A- -27.1
B- -6.0
C- 2.7
D- 20.5
E- 23.8
F-None of the previous propositions is correct
A- -427, 7
B- -404.1
C- -13, 6
D- 54.6
E- 476.6
F-None of the preceding propositions is exact
Consider the heating from 300 to 400K of two moles of an ideal gas under (a) isobaric conditions on the one
hand; and (b) isochoric on the other hand. Data Cp = 40J.K-1.mol-1, R =8.31JK-1.mol-1.
39-the enthalpy variation which results from the transformation (a) (in J, at 10-1near) corresponds:
B- Q (a) = -1662.0
VS- Q (a) = 0
D- Q (a) =6338.0
E- Q (a) =8000.0
B- W (a) = - 1662.0
VS- W (a) = 0
D-Wa = 6338.0
E- Wa = 8000.0
F-none of the propositions are exact
42-the variation of internal energy which results from the transformation (b) (in J, at 10-1near) ,, represents:
C-∆U (b) =0
C-∆H (b) =0
B- W (b) = -1662.0
VS- W (b) = 0
D- W (b) =6338.0
E- W (b) =8000.0
B- Q (b) = -1662.0
VS- Q (b) = 0
D- Q (b) =6338.0
E- Q (b) =8000.0
Let be the reaction of forma tion of water: H2 (g) +1 2O2 (g) =H2
Part A
̀̀
At 25 ° C, water is likely, according to the table above, to be in liquid or gaseous form, the determination of
certain thermodynamic quantities thus takes these two states into account: 50-The initial state corresponds
to a state of equilibrium:
A- Thermal
B- Mechanics
C- Thermodynamics
D- Chemical
E- Thermodynamics and chemicals
F- None of the preceding propositions is exact
51-The final state corresponds to a state of equilibrium
A. Thermal
B. Mechanics
C. Thermodynamics
D. Chemical
E. Thermodynamics and chemicals
F. None of the statements are correct
̀̀
52 -In the initial state, the system is constituted
A. From H2 (g)
B. From O2 (g)
D. From H2O
A. From H2 (g)
B. From O2 (g)
D. From H2O
E. From the set (H2 (g) +1 2O2 (g) =H2O)