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CHEMISTRY

1. An adiabatic transformation is a transformation that takes place at


a) Constant temperature
b) Regular time interval
c) Without heat exchange
d) Constant volume
e) Other
2. A closed exchange system
a) Labor only
b) Work and heat
c) Heat only
d) Material
e) No exchange possible
3. An isolated exchange system
a) Labor only
b) Work and heat
c) Heat only
d) Material
e) No exchange possible
4. The temperature of a system is related to
a) At the impact of molecules
b) Agitation of molecules
c) Kinetic energy of molecules
d) Interaction between molecules
e) No answer is correct
5. The pressure of a system containing an ideal gas is related to
a) At the impact of molecules
b) Agitation of molecules
c) Kinetic energy of molecules
d) Interaction between molecules
e) No answer is correct
6. A gas is perfect if
a) It is a rare gas
b) The molecules are point
c) The molecules are monoatomic
d) There is no interaction between the molecules
e) No response
7. Choose the exact proposal (s)
a) Work corresponds to a transfer of energy between the system and the outside
b) During an isobaric reaction, the enthalpy change is equal to the heat of reaction
c) If the standard enthalpy of the reaction: reactants → products is ∆H, that of the reaction products → reagents is
∆H
d) The standard enthalpy of formation of a compound is the change in enthalpy of the reaction leading to its
formation from atoms, carried out under standard conditions
e) For chemical reaction reagents → products, the standard enthalpy is
∆H ° = ∑ [∆Hf° (reagents)] - ∑ [∆Hf° (products)]
8. Choose the exact proposal (s)
a) A phase transition is a reaction of a pure substance without change in chemical composition
b) The triple point is the point of intersection of the three curves of change of state
c) The standard entropy of a pure body is zero at 298 K
d) A spontaneous reaction carried out at constant P and T is characterized by a decrease in free enthalpy
e) The free enthalpy of an exergonic reaction is positive
9. Consider a thermodynamic system evolving between two states 1 and 2. During the transformation, it receives a
heat of 600 J and provides a work of 450 J. Then it returns from state 2 to state 1 by providing a work of 1200 J.
Which of the following statements are correct?
a) The direct transformation (1 2) is exothermic.
b) The variation of internal energy during the direct transformation (1 2), ΔU = U2 - U1 is worth 1,050 J.
c) The return transformation (2 1) is endothermic.
d) We cannot calculate the heat exchanged during the return transformation.
e) When going from state 2 to state 1, the system receives a heat of 1050 J
10. For the following reaction O2 (g) + 2H2 (g)→ 2 hours2O (l) carried out under a pressure of 1.0 bar, we give ΔrH = - 572
kJ mol–1. Which of these statements are correct?
a) The reaction is endothermic.
b) The reaction releases heat to the external environment.
c) For the reaction ½ O2 (g) + H2 (g) H2O (l), we have ΔrH = - 572 kJ mol- 1.
d) The formation of four molecules of water from two molecules of oxygen and four molecules of
hydrogen at constant pressure consumes 1144 kJ.
e) The formation of water from a molecule of hydrogen in an excess of oxygen at pressure
constant releases 286 kJ.
11. Which of the following reactions are 298 K training reactions?
a) C (s) + 2H2 (g) CH4 (g).
b) ½ O2 (g) + CO (g) CO2 (g).
c) N (g) + O2 (g) NO2 (g).
d) N2 (g) + 2O2 (g) 2NO2 (g).
e) ½ O2 (g) + H2 (g) H2O (l).
12. We consider the combustion at 298 K and under a pressure of 1.0 bar of a mole of a hydrocarbon of
formula C20H20 according to the equation: C20H20 (s) + 25 O2 (g) → 20 CO2 (g) + 10 H2O (l) The enthalpy change
during this transformation is ΔH = - 10 828 kJ. We give the ideal gas constant R = 8.314 J K- 1 Mol- 1. What is the
internal energy variation ΔU worth?
a) ΔU = - 10 828 kJ.
b) ΔU = - 10 816 kJ.
c) ΔU = - 10 840 kJ.
d) ΔU = - 1 560 kJ.
13. Hydrogen peroxide can decompose according to the reaction whose equation is: 2 H2O2 (the)→ O2 (g) + 2 H2O (l)
We give 298 K the enthalpiesof formation and molar entropies:
H2O2 (the O2 (g) H2O (l)
)
ΔfH ° (kJ mol- 1) - 188 - 285
S ° m (J K1Mol- 143 205 70
1)

Which of these statements are correct?


To) Under standard conditions at 298 K, the decomposition reaction of hydrogen peroxide is exothermic.
b) Under standard conditions at 298 K, the decomposition reaction of hydrogen peroxide is exergonic.
c) Under standard conditions at 298 K, hydrogen peroxide is stable.
d) At 298 K, the standard reaction entropy is negative.
e) At 298 K, the standard free enthalpy of reaction is - 212 kJ mol- 1.
f) At 298 K, the standard free enthalpy of reaction is + 212 kJ mol- 1.
14. What is the molar heat at constant pressure Cp of a diatomic ideal gas, in J / K.mole?
To. 30.1 J / K.mole
b. 41.8 J / K.mole

vs. 33.5 J / K.mole

d. 29.1 J / K.mole

15. Determine the entropy variation for an isobaric evolution of a mole of oxygen between 0 and 100 degrees
Celsius (in J / K.mole).
To. 6.21 J / K.mole
b. 6.08 J / K.mole
vs. 8.08 J / K.mole
d. 9.08 J / K.mole

16. For an irreversible evolution of an isolated system the entropy S:


To. is zero
b. always decreasing

vs. always increasing

d. is constant

17. What is the value of the ideal gas constant in the SI system
To. 0.082
b. 1.98
vs. 8.2
d. 8,314
18. The entropy is:
To. Measuring the disorder of matter and energy
b. Measuring the disorder of matter
vs. Measurement of energy disorder
d. The measure of disorder at equilibrium
19. Disorder is a phenomenon:
To. Not spontaneous
b. Provoked
vs. Spontaneous
20. The entropy function is symbolized by
To. U
b. E
vs. G
d. S
21. The 2th principle is defined by the following postulate:
To. The entropy of the universe is the state of equilibrium

b. The entropy of the universe tends to increase The

vs. entropy of the universe tends to decrease

d. None of the above

22. The change in entropy is equal to


To. The energy that is reversibly supplied as heat divided by the temperature at which this transfer
takes place
b. The energy that is reversibly supplied as heat divided by the temperature at which this transfer takes
place
vs. The energy that is reversibly supplied as heat multiplied by the pressure at which this transfer
takes place

d. Energy that is reversibly supplied in the form of heat


23. The expansion of a gas is
To. a change of state
b. a physical transformation
vs. a chemical transformation
d. none of the above
24. the entropy of vaporization corresponds to
To. a change of state
b. a temperature variation
vs. a pressure variation
d. none of the above
25. The thermodynamic function U denotes
To. entropy
b. enthalpy
26. the second principle of thermodynamics defines a state function called:
A-Enthalpy
B-Entropy
C-Internal energy
D-Free energy
E-None of the preceding propositions is exact
27. entropy translates the degree:

A-Cleanliness
B- Order
C- Disorder
D- Heat
E-None of the preceding propositions is exact
28. the variations a cycle of the total entropy of a system is:
A-Always positive
B-Always negative
C-Still zero
DN 'is not measurable
E-None of the preceding propositions is exact

29. When two state variables are additive:


A-They are intensive B-
They are extensive
C- They each characterize a system
D- They are identical

30. In a cycle as for isolated systems:


AQ = 0
BW = 0
VS-⍙U = 0
D-⍙H = 0

31. a system is:


A- The studied object

B- The evolving object


C- The static object
D- The variable object

32. By definition, the variation of internal energy is equal to:

A- U = Q + W
B- U = integral of (CpdT) + integral of (hdP)
C- U = - integral of (PdV)
D- U = nCpdT - PdV
33. The zero kelvin represents

A- the vaporization temperature of water B-


the melting temperature of ice C- the
solidification temperature of water D- the
temperature of a gas at zero pressure
34. What is the role of the heat engine?
A- Converting solar energy into electrical energy
B- Converting thermal fuel energy into mechanical energy C-
Converting mechanical energy into heat energy D- Converting
mechanical energy into electrical energy
35. __________ is the way heat spreads through a body. This phenomenon is done by contact of the

various particles of matter which compose it and without there being any displacement of this

matter:
Convection
Conduction
Radiation
Condensation
36. Un__________ is a device which measures the humidity of the air:
Thermometer.
Hygrometer.
Thermoscope.
Barometer.
37. lyophilization, or freeze-drying, is the desiccation of a product previously frozen by:
Sublimation
Vaporization
Evaporation
Merger
38. In the Carnot cycle:
Isothermal expansion is characterized by the fact that no heat exchange takes place with the outside.
Adiabatic compression is characterized by a change in the internal energy of the system. A Carnot
cycle admits the possibility of a return equal to 100%.
A Carnot cycle admits a non-zero entropy variation along the cycle. A
Carnot cycle is an irreversible process.
39. In an isobaric transformation of a closed system, the quantity of heat exchanged:
Is greater than the change in enthalpy of the system
is less than the change in enthalpy of the system is
equal to the change in enthalpy of the system none
of the above answers
40. the 2nd principle is defined by the following postulate:

The entropy of the universe is the state of


equilibrium The entropy of the universe tends
to increase The entropy of the universe tends
to decrease None of the above
41. the expansion of a gas is

a change of state
a physical transformation a
chemical transformation none
of the above

42. What will be, in joules, the quantity of heat received by a mole of ideal gas evolving in an

isothermal way, at 100 degrees celcius, when its pressure decreases by half?

3120 joules
312 joules
2149 joules
5651 joules
43. For an isochoric evolution of 4 g of oxygen O2 (M = 32 g) evolving from 100 to 200 degrees celcius,

what is the quantity of heat received (in joules)?

130 joules
- 130 joules
2600 joules
260 joules
44. For an isobaric evolution of 4 g of oxygen O2 (M = 32 g) evolving from 100 to 200 degrees celcius,

what is the quantity of heat received (in joules)?

364 joules
264 joules
- 130 joules
0 joule
45. What is the molar heat at constant pressure Cp of a diatomic ideal gas, in J / K.mole?
30.1 J / K.mole
41.8 J / K.mole
33.5 J / K.mole
29.1J / K.mole
46. Determine the entropy variation for an isobaric evolution of a mole of oxygen between 0 and 100

degrees celcius (in J / K.mole).

6.21 J / K.mole
6.08 J / K.mole
8.08 J / K.mole
9.08 J / K.mole
22- what is the value of the ideal gas constant in the SI system
0.082
1.98
8.2
8,314
47. The ideal gas law reads as follows:
A. PT = nRV
B. VT = nRP
C. PV = nRT
D. PR = -Nvt
48. The mathematical basis of Boyle's

law is:

a) V / T = constant

b) V / N = constant

c) P / T = constant

d) PV = constant

e) None of the above is correct

49. The mathematical basis of the law of

gay Lussac is:

a) V / T = constant

b) V / N = constant

c) P / T = constant

d) PV = constant

e) None of the above is correct

50. What is the molar heat at constant pressure Cp of a diatomic ideal gas, in J / K.mole
30.1 J / K.mole
41.8 J / K.mole
33.5 J / K.mole
29.1J / K.mole
51. Thereaction4Al (s) +3O2 =2Al2O3 (s) ⍙H ° = -3351KJ

Is …………………………, and there for heats ……………………… .By the reaction: A-


Exothermic; released
B-Exothermic; absorbed
C-Endothermic; released
D-Endothermic; absorbed
E-Thermo neutral either released or absorbed
52. Which of the following equations represents both the standard enthalpy of formation of zinc

oxide and the standard enthalpy of combustion of zinc?

To. 2Zn (s) +O2 (g) = 2ZnO (s)


b. Zn (s) + ½ O2 (g) = ZnO (s)
vs. Zn (s) +O (g) = ZnO (s)
d. Zn (s) + ½ O2 (g) = ZnO (s)
e. None of the responses
1-a quasistatic transformation is:
A-A transformation without thermal transfer
B-Carried out "slowly"
C-Reversible
D-Irreversible
E-None of the preceding propositions is exact
2-if the temperature of a closed system is constant, then:
AI there is no heat transfer with the outside B-Its internal
energy is constant
C-The transformation is isothermal D-
The transformation is monothermal
E-None of the previous propositions is exact 3-Entropy is a size: A-
Intensive
B-Extensive
C-constant
D-Null
E-None of the preceding propositions is exact

4-the second principle of thermodynamics defines a state function called: A-Enthalpy

B-Entropy
C-Internal energy
Free Energy
E-None of the preceding propositions is exact

5-entropy translates the degree: A-


Of cleanliness
BD 'order
C-Of disorder
C-Heat
E-None of the preceding propositions is exact

6-the variation over one cycle of the total entropy of a system is:
A- Always positive
B-Always negative
C- Still zero
D- Is not measurable
E- None of the preceding propositions in 'is exact

7-which of these states has high entropy?


A-Liquid
B-Solid
C-Condensed
D-Gaseous
E-No proposition is exact

8-the internal energy of an ideal gas: A-


Depends on the quantity of matter
B-Depends on the amount of material and the temperature C-
Depends on the temperature
D-Depends on the amount of material; temperature and pressure E-
None of the statements is correct
9-if during a transformation the energy has not changed, then: A-The
temperature of the system has not changed
B-Obviously, the heat transfer is zero
C-For an ideal gas, the temperature does not change
D-We are on a cycle which means that we have returned to the initial
state E-None of the previous propositions are exact
10-a monothermal transformation is:
A- A transformation that takes place at constant temperature
B- Performed by a system which is in contact with a single heat source C-
Performed by a system which is in contact with two heat sources
D-Identical to an isothermal transformation
D- None of the preceding propositions is exact
11-Answer true or false, justifying the exact propositions:
A-A cycle is a process at the end of which system returns to its initial
state B- In a cycle, as in an adiabatic transformation, Q = 0
VS-⍙U = 0 for cycles and for isolated systems
D- Entropy allows to know the spontaneous meaning of a
reaction E-When heat increases, the value of entropy increases
F-None of the preceding propositions is exact

13-the temperature of anidealgas increasesfrom20 ° cto40 ° cwhile the pressure stays the same: what happens to
the volume of the gas?
A- It doubles
B- It quadruple
C- It is cut to one-half D-
It is cut to one-fourth E-It
lightly increases

14-when two state variables are additive: A-


They are intensive
B-They are extensive
C-They each characterize a system D-
They are identical

15- a transformation without thermal transfer is: A-


Without temperature variation
B- Carried out `` slowly ''
C-Reversible
D-Irreversible

16-if the temperature of a closed system is constant,


then: A- There is no heat transfer with the outside
B- The system is in thermal equilibrium C-
The transformation is isothermal

C- The transformation is monothermal


17-during adadabatic transformation: A-
The system is isolated
B-The system is thermally insulated
C- The system is open
D-The system is closed

18-heat quantity: A-Is


a state function
B- Not a state function
C-Vaut``n cp dT '' (by elementary variation)

D - '' n cv dT '' (by elementary variation)

E-Is zero during an isothermal transformation

19-work:
A-Is a state function B- Is
not a state function
C -Vaut `` Pdv '' (by elementary variation)

E -''- Pext dv '' (by elementary variation)

F-Is zero during an isothermal transformation


20-internal energy:
A-Is a state function
B- Not a state function
C-Vaut``n cp dT '' (by elementary variation)

D-Vaut``n cv dT '' (by elementary variation) E-Is

zero during an isothermal transformation

21-in a cycle as for isolated systems: AQ


=0
BW = 0

VS-⍙U = 0

D-⍙H = 0

22-Thereaction4Al (s) +3O2 =2Al2O3 (s)⍙H ° = -3351KJ

Is …………………………, and There fore heatis ……………………… .By the reaction: A-


Exothermic; released
B-Exothermic; absorbed C-
Endothermic; released D-
Endothermic; absorbed
E-Thermo neutral neither released nor absorbed
Liquid water can exist at a temperature below 20 ° in supercooled state! this state is very unstable
and can disappear at the slightest disturbance by spontaneous freezing Part a: at the temperature of
- 20 ° C, one mole of water undergoes freezing at atmospheric pressure, considered as standard state.
Data: C° P (H20.1) = 75.24J / K / mol C° P (H2O, s) = 33.58J / K / mol, the enthalpy of fusion at 0 ° C isfH °273
= 6019 J / mol

23-this mole of water


constitutes: A- A state parameter
B- The environment
C- The system
D- Earth
E- The universe
F-None of the preceding propositions is exact

24-this mole of water is in:


A- Thermodynamic equilibrium
B- Chemical equilibrium
C- Physical balance
D- Thermodynamic and chemical equilibrium E-
Thermodynamic and physical equilibrium

F-None of the preceding propositions is exact

25-this mole of water undergoes:


A- A chemical reaction
B- A transformation
C- A lowering of temperature
D- A heating
E- A mess
F- None of the preceding propositions is exact
26-this mole of water thus undergoes a `` change '' carried out in a way:
A- Adiabatic
B- Isobaric
C- Isothermal
D- Monothermal
E- Isochore
F-None of the preceding propositions is exact

27-enthalpy change which accompanies this freezing (∆sH °253; in J at10-1close) corresponding: A-
-6019, 0
B- -5185.8
C- -671.6
D- 1504.8
E- 6852.2
F-None of the preceding propositions is exact
28-the variation of internal energy which accompanies this freezing (∆sU °253;enJà10-1near) corresponding:
A- -6019, 0
B- -5185.8
C- -671.6
D- 1504.8
E- 6852.2
F-None of the preceding propositions is exact

29-the entropy variation which follows this freezing (∆sS °253in J / K at 10-1near) corresponds:

A- -22.1
B- - 18.9
C- -2.6
D- 5.7
E- 25.2
F-None of the preceding propositions is exact

30-following this solidification, the environment determines an entropy (∆SenvyenJ / K at10-1near) of the order of:

A- -27.1
B- -6.0
C- 2.7
D- 20.5
E- 23.8
F-None of the previous propositions is correct

31-the entropy of the universe which accompanies this solidification


(∆Suniverse,enJ / K) is translated by the value
A- -1.9
B- -0.3
C- 0.1
D- 1.6
E- 1.9
F-None of the preceding propositions is exact

32-entropy results state for this `` change '': A-A creation


of disorder
B- A creation of the order
D- A reversible transformation
E- An irreversible transformation
F- An impossible transformation
G- None of the preceding propositions is exact
33-free enthalpy variation corresponding to this transformation (∆sG °253enJ) if we calculated it, it would
amount to:

A- -427, 7
B- -404.1
C- -13, 6

D- 54.6

E- 476.6
F-None of the preceding propositions is exact

34-this solidification is: A-


Spontaneous
B- Non-spontaneous
C- Balanced
D- Endergonic
E- Exergonic
F-None of the preceding propositions is exact

Consider the heating from 300 to 400K of two moles of an ideal gas under (a) isobaric conditions on the one
hand; and (b) isochoric on the other hand. Data Cp = 40J.K-1.mol-1, R =8.31JK-1.mol-1.

35- Such a system is in both cases:


Opened
B- Closed
C- isolated
D – thermally insulated
E- mechanically isolated
F-none of the above is correct

36-as in the case (a) the transformation is isobaric; the gas :


A- Relax
B- Compresses
C- Increases volume D-
Decreases volume E-
Remains exchanged
F- None of the preceding propositions is exact.
37-as in case (b) the transformation is isochoric, the gas:
A- Relax
B- Compresses
C- Increases volume D-
Decreases volume E-
Remains exchanged
F- None of the preceding propositions is exact.
38- the variation of internal energy which results from the transformation (a) (in J, à10-1near) corresponds:

TO-⍙U (a) = -6338.0

B-⍙U (a) = -1662.0


VS-⍙U (a) = 0

D-⍙U (a) =6338.0

E-⍙U (a) =8000.0

F-none of the propositions are exact

39-the enthalpy variation which results from the transformation (a) (in J, at 10-1near) corresponds:

TO- ⍙H (a) = -6338.0


B- ⍙H (a) = -1662.0
C- ⍙H (a) = 0
D- ⍙H (a) =6338.0
E- ⍙H (a) =8000.0
G- None of the propositions is exact 40-the quantity of heat obtained (in J, at 10-1
near), during transformation (a), represents:

TO- Q (a) = -6338.0

B- Q (a) = -1662.0

VS- Q (a) = 0

D- Q (a) =6338.0

E- Q (a) =8000.0

F-none of the propositions are exact

41-the work obtained (in J, at 10-1near), during transformation (a), represents:


TO- W (a) = - 6338.0

B- W (a) = - 1662.0

VS- W (a) = 0

D-Wa = 6338.0
E- Wa = 8000.0
F-none of the propositions are exact
42-the variation of internal energy which results from the transformation (b) (in J, at 10-1near) ,, represents:

A-∆U (b) = -6338.0

B-∆U (b) = -1662.0

C-∆U (b) =0

D-∆U (b) =6338.0

E-∆U (b) =8000.0


F- None of the propositions are exact
43 — the enthalpy variation which results from the transformation (b) (in J, at 10-1near), represents:

A-∆H (b) = -6338.0

B-∆H (b) = -1662.0

C-∆H (b) =0

D-∆H (b) =6338.0

E-∆H (b) =8000.0

F-none of the propositions are exact


44-the work done during transformation (b) is:

TO- W (b) = -6338.0

B- W (b) = -1662.0

VS- W (b) = 0

D- W (b) =6338.0

E- W (b) =8000.0

F-none of the propositions are exact


45-the quantity of heat which results from the transformation (b) (in J, at 10-1near), is:

TO- Q (b) = -6338.0

B- Q (b) = -1662.0

VS- Q (b) = 0

D- Q (b) =6338.0

E- Q (b) =8000.0

F-none of the propositions is exact 46-these


transformations take place in a way: A-
Exothermic
B- Endothermic
C- Athermic
D- Spontaneous
E- Non-spontaneous
F- None of the previous propositions is exact
47-in the two transformations, the
system: A-Receives heat and work
B-Provide heat and work C-Receive heat and
provide work D-Provide heat and receive
work E-Neither provide nor receive F-None of
the above is correct
48-in the transformation (a), the system: A-
Receives heat and work B-Provides heat and
work C-Receives heat and provides work D-
Provides heat and receives work E-Does not
provide or receive either of the two F-None of
the above is correct

49-in the transformation (b) on the other


hand: A-Receives heat and work B-Provides
heat and work C-Receives heat and provides
work D-Provides heat and receives work E -Do
not provide or receive either F-None of the
above is correct

Let be the reaction of forma tion of water: H2 (g) +1 2O2 (g) =H2

Data at 25 ° CR = 8.314J / K / mol


H2O (l) H2O (g)
O2 (g) H2 (g)

∆fH ° 298 1 / JK- 0 0 - 285.84 - 241.83


-1
. mol

S ° 298 / JK-1.mol 205.0 130.59 69.94 188.72


-1

C ° P / JK-1.mol-1 34.58+ 1.10.10- 27.71+ 3.34.10- 75.3 29.59+ 11.37.10-3T


3T 3T

Part A
̀̀
At 25 ° C, water is likely, according to the table above, to be in liquid or gaseous form, the determination of
certain thermodynamic quantities thus takes these two states into account: 50-The initial state corresponds
to a state of equilibrium:
A- Thermal
B- Mechanics
C- Thermodynamics
D- Chemical
E- Thermodynamics and chemicals
F- None of the preceding propositions is exact
51-The final state corresponds to a state of equilibrium
A. Thermal
B. Mechanics
C. Thermodynamics
D. Chemical
E. Thermodynamics and chemicals
F. None of the statements are correct
̀̀
52 -In the initial state, the system is constituted

A. From H2 (g)

B. From O2 (g)

C. From the mixture (H2 (g) + 12O2 (g))

D. From H2O

E. From the set (H2 (g) +1 2O2 (g) =H2O)

F. None of the preceding propositions is exact ̀ ̀

53-In the final state, the system is constituted

A. From H2 (g)

B. From O2 (g)

C. From the mixture (H2 (g) + 12O2 (g))

D. From H2O
E. From the set (H2 (g) +1 2O2 (g) =H2O)

F. None of the preceding propositions is correct


54-The enthalpy variation corresponding to this water formation is
A. -285.84
B. -282.12
C. -44.01
D. 0
E. 44.01
F. None of the preceding propositions is correct
55-The variation of internal energy corresponds to this formation is
A. -265.60
B. -282.12
C. -240.59
D. -238.11
E. 0
F. None of the preceding propositions is correct
56-The entropy variation corresponding to this formation is
A. -265.65
B. -163.15
C. -146.87
D. -44.37
E. 118.78
F. None of the preceding propositions is correct
57- The sign of the entropy variation corresponding to this formation prefigures
A. A creation of disorder
B. A creation of the order
C. A reversible reaction
D. An irreversible reaction
E. An impossible reaction
F. None of the preceding propositions is correct
58-The variation of free enthalpy corresponding to this formation is
A. -237.22
B. -228.61
C. -206.68
D. -198.06
E. 8.61
F. None of the preceding propositions is correct
59-This water formation is
A. Spontaneous
B. Non-spontaneous
C. Balanced
D. Endergonic
E. Exergonics
F. None of the preceding propositions is correct

60. the entropy of vaporization corresponds to


A change of state
A change in temperature A
change in pressure None of
the above

61. the above diagram is a state diagram:


By Clapeyron
Some water

Pure substances other than water


None of the above answers
62. Zone 1 in the diagram above represents:
Solid
Liquid
Gas
None of the above
63. Point A in the diagram above is point:
Critical
Triple
Fusion
None of the above

64. The passage from C to D is:


Isothermal
Isobaric
A change of state
Isochore
65. Which proposition is wrong: There are many ways to express air humidity (amount of
water vapor in the air), including using:
relative humidity which is the ratio between the quantity of water contained in a mass of air and the maximum
quantity of water that this mass of air can contain, for a given temperature.
dew point temperature which is the temperature at which water evaporation occurs. the
humidity level which is the same magnitude as the relative humidity.
absolute humidity which is the ratio of the mass of water vapor for a given volume of air.
specific humidity which is the ratio of the mass of water vapor to the mass of humid air.
66. It can be confirmed that for evaporation:
The phenomenon of evaporation is accelerated in the presence of wind because it facilitates the renewal of the
air humidified by evaporation by drier air.
As long as the partial pressure of water vapor is greater than the saturated vapor pressure of water
evaporates.
Evaporation is a process that causes the surrounding air to heat up as water molecules draw
their energy from the environment.
Evaporation is all the more important as the temperature is high because at constant pressure the saturated
vapor pressure decreases with the temperature.
67. A Carnot cycle is made up:
two reversible isothermal transformations and two isentropic transformations two
reversible isobaric transformations and two isentropic transformations two reversible
isothermal transformations and two isobaric transformations two reversible
isothermal transformations and two isochoric transformations
68. In a cycle of transformations of a closed system
the system can only trade work
the system can only exchange heat
the system can exchange heat and work
69- An isentropic transformation
is a reversible isobaric transformation is a
reversible isothermal transformation is a
reversible isochoric transformation is a
reversible adiabatic transformation
70- What is the course of a 4-stroke engine cycle?
Intake, Compression, Combustion-Expansion, Exhaust
Intake, Compression, Exhaust, Combustion-Expansion
Compression, Combustion-Expansion, Intake, Exhaust
Intake, Combustion-Expansion, Exhaust, Compression
71- What is the role of heat engine?
Converting solar energy into electrical energy
Converting thermal fuel energy into mechanical energy
Converting mechanical energy into heat energy Converting
mechanical energy into electrical energy
72- The standard state is defined for
a temperature of 298 K
atmospheric pressure
the atmospheric pressure and T = 298 K
the pressure is zero and T = 298 K
73- For an isothermal evolution of an ideal gas, the quantity of heat Qreceived is:
Toilet
- Received
0
- Wcédé

84- during an adiabatic transformation:


A- The system is isolated
B- The system is thermally insulated
C- The system is open
D- The system is closed
85. Under normal atmospheric pressure, pure water evaporates:

A- at any temperature less than or equal to 100 ° C. B- at


exactly 100 ° C.
C- at a temperature equal to or greater than 100 ° C.
D- none of the previous answers
86. disorder is a phenomenon
A- non spontaneous
B- provoked
C- spontaneous

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