TAWRI TUTORIAL

CHEMISTRY TEST - 2
Solutions Colligative properties
XII CBSE Marks : 40

Question no 1- 5 carry one mark each.

Question no 6-10 carry three mark each.
Question no 11-14 carry five mark each.

1. Which out of molarity or molality will change with change in temperature and why?

2. Mixing of acetone with chloroform taken place with reduction in volume? What type of devia-
tion from Raoult’s law is seen in this case?

3. Two liquid A and B boll at 1450C and 1900 C respectively. Which of them has higher vapour
pressure at 800C?

4. The colligative properties of a dilute solution depend on

i) The nature of the solute ii) the nature of the solvent

iii) The number of particles of solute iv) the number of particles of solvent

5. Why is the vapour pressure of a liquid constant at a constant temperature?

6. A solution of glucose in water is labeled as 10 % ( w/v ). The density of the solution is

1.20 g mL-1. Calculate:

i) Molality ii) Molarity iii) Mole fraction of each component in solution.

7. Give applications of Henry’s law.

8. Boiling point of water at 750 mm Hg is 99.630C. How much sugar is to be added to 500 g water
so that it boils at 1000C.

9. Differentiate between ideal and non- ideal solutions. (four points)

10. Calculate the boiling point of a solution containing 0.456 g of camphor ( mol. mass = 152) dis-
solved in 31.4 g of acetone ( b.p = 56.300C) if molal elevation constant is 1.72 km-1.
11. 1.4 g of acetone dissolved in 100 g benzene gave a solution which freezes at 277. 12K. Pure
benzene freezes at 278.4 K, 2.8 g of a solid (A) dissolved in 100 g of benzene gave a solution
which freezes at 277.76 K. Calculate the molecular weight of (A).

12. 0.052 g of glucose (C6H12 O6) has been dissolved in 80.2 g of water. Calculate (i) the boiling
point and (ii) freezing point of the solution ( Kf = 1.86 K m-1, Kb = 5.2 K m-1)

13. Two elements A and B from compounds having molecular formula AB2 and AB4. When dis-
solved in 20 g of benzene, 1 g of AB2 lowers the freezing point by 2.3 K, whereas 1.0 g of AB4
lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K kg mol -1. Calculate the
atomic mass of A and B .

14. i) What is meant by an azeotropic mixture? What is a minimum boiling azotrope (Explain
graphically with example).

ii) The partial pressure of ethane over a solution containing 6.56 x 10 -3 g of ethane is 1 bar. If
the solution contains 5.00 x 10-2 g of ethane, then what shall be the partial pressure of the gas?