AB-20

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TotalMarks Obtained: Invigilator Signature :

202)
B.SÇ. Part-III (Semester-V) Examination Year: Winterm ai
Subject Name : CHEMISTRY
Time : 1Hour Ma[imum Marks : 80

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Centre Code :
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Note :- 1) All 40 MCQquestions are compulsory.

2) Every questioncarries 2 marks.
3) For offline examination please tick (V)the correct option.
4) AllOfficers Incharge / Invigilators should write College Code &Centre Code,
on this page.

1. Complex with bidentate ligands are called

A) Ligands B) Chelates C) Complexes D) All
2 The primary valency of Fe in Ks[Fe(CN)e] is
A) 3 B) 2 C) 1 D) Zero

3. The shape of complex [Ag(NH))]* is

A) Octahedral B) Square planar C).Tetrahedral D) Linear
4. The EAN of Fe in [Fe(CN)6J complex is
A) 35 B) 34 C) 36 D) 38
5 Which of the following is an example of ambident ligand ? 5Email
A) CI F C) CN D) NO2
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m
In the complex, theprimary valency ofa metal is always
A) Positive B) Negative C) Neutral D) Zero
7 The oxidation state of metal ion in (Mn(CN is
A) +2 B) Zero C) +3 D) 3
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 8.
In octahedral ficld of ligand around central metal oil, d' orbital split into
A) tg and eg B) t; and e C) big and e D) bg and e
9 The distribution of d electron in low spin octahedral field is
A) tg'eg' aB bg'eg? C) tag'eg' D) tg'eg
10. Which of the followingcomplex ion has highest Avalue ?
CA) [COH0)6]'? B) [CO(H,0)%1*3 C) [Ru(H,0)%|2 D) (Ru(HzÖ)
11. Total splitting of 'd' orbital in octahedral field is:
A) 10Dg B) 4 Dq C) 6 Dq 203
20Dq
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The ground term symbol for d configuration is :
A) °Ss/2 B) D2 C) Fs/2 D) All of these
13. The CFSE for high spin octahedral complex of d ion is

A) -0.6 A B) 1.2 Ao C) 1.8 Ao D) -0.4 Ag

14. The colour of [Ti(H;0)6j* is
A) Green B) White ) Pink D) Colourless
15. Pyrrole is member heterocyclic eompound.
A) Four B) Five 20 C) Six D) None of these
16. Substitution of an electrophile in pyrrole mainly occurs at position number
A) One B) Two C) Three D) Three and four
17. Organomagnesium compound are called as reagent.
A) Lucas B) Grignard C) Gilmans D) Linders
18. In pyridine, nitrogen atom is ina state of hybridisation.
A) sp B) sp C) sp D) dsp
19. Which is more basic of the following ?
A) Pyridine B) Pyrrole C) Phenol D) Benzene
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20. What product is obtained when methyl lithium is treated with
formaldehyde ?
A) Ethane B) Ethyl alcohol C) Acetaldehyde D) Acetonie
21. Methýl lithium is also called as
A) Organometallic compound B) Lucas
C) Linders D) Gilmans

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 22. Congo red is an example of
A) Azo dye B) Phthalein dye C) Nitroso dye D) Indigoide dye
23. The groups which are responsible for imparting colour to dye is called
A) Oxochrome B) Chromophore C) Bathochrome D) None of these
24. Pesticides which kill the insects are called as
À)-Fungicide B) Herbicide C) Insecticide D) RodeDtícides
25. The chemical substance which produces sleep and unconsciousness is called
A) Carbonate B) Analgesic C) Narcotics D' None of these
26 Which of the following compound is used in treatment of malaria ?
A) P-aminobenzene B) Sulphonamide
C) Chloroquine D) Sulphadizine
27. The dyes which are applied for fabric with the help of salt are
called as
A) Direct dye B) Ingrain dye odantdye D) Vat dye
28. 2,4-D can be prepared from: 205EI
A) 2,4-dichloroaniline
B) 2,4-dichlorobenzoic acid
C) 2,4-dichlorophenol D) Acetic acid
29. The process in which light radiation is absorbed by a
excited molecule molecule resulting in the formation of an

A) Primary process B) Secondary process

C) Tertiary process
D) Dark process
30. The law of absorption of light
concerned with solid absorbing material is
A) Beer's law
B) Lambert's law
C) Clausius-Clapeyron's law D) Newton's law
31. The 205Email
photochemicalireactions are concerned with
A) Refletion of light B) Transmitted light,
C) Äbsorbing light
D) Heat
32. Visible light in
electromagnetic spectrum have wavelength range
A) 100-400nm B) 400-700 nm C) 700-2500 nm
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 33. Fluorescence or phosphorescence of photoclectric effect is process.

A) Photochemical B) Thermal C) Photophysical D) Photosensitised

34. Intersystem crossing refers to

A) Change in eledtronic state without changing spin
B)_ Change in electronic state by changing spin 5Emal.

Collapse tothe lowest vibrational levelof first excited singlet state

D) The O-0 bond
35. The distance between two successive crests or troughs is called

A) Wavelength B) Frequency C) Wave number D) Velocity

36. Which of the following molecule shows rotational spectra ?
A) H B) O; C) CH D) H,0
37. Which of the following is IR active?
A) N B) Clh C) D) H,
38. For linear molecule, vibrational degree of freedom is :
A) 3n-5 B) 2n-5
2031 C) 2n-6 D) 3n-6
39. Which of the following molecule shows highest force constant ?

A) C-C B) C-H C) C-C D) C=C

40. For diatomic molecule HCI, total degree of freedom is

A) 2 B) 3 C) 5 D) 6