PRACTICE TEST

Level 1

CLASS: XII

Unit 12: ALDEHYDES, KETONES & CARBOXYLIC ACID

Full marks: 20 Time: 40 Min

Q.No Questions M
1 Write the structures of the following compounds-
(i) Di-sec. butyl ketone (ii) 4-Fluoroacetophenone 1
2 Write the structures of products of the following reactions-
1

3 Give names of the reagents to bring about the transformation of But-2-ene

into ethanal. 1
4 Give the IUPAC names of the following compounds:
(i) Ph CH2CH2COOH (ii) (CH3)2C=CHCOOH 1
5 Would you expect benzaldehyde to be more reactive or less reactive in
nucleophilic addition reactions than propanal? Explain your answer. 2
6 Illustrate the following reaction with one example:
i. Clemmensen reduction
ii. Wolff-Kishner reduction 2
7 Write the sequence of reactions involved in the following conversions-
i. Bromobenzene into benzoic acid
ii. Phenylethene (Styrene) into benzoic acid 2
8 Which acid of each pair shown here would you expect to be stronger?
(i) CH3COOH or CH2FCOOH (ii) CH2FCOOH or CH2ClCOOH 2
9 What is meant by the following terms? Give an example of the reaction in
each case.
i. Hemiacetal ii. Oxime 2
10 Give plausible explanation for each of the following:
(i) Cyclohexanone forms cyanohydrin in good yield but
2,2,6 trimethylcyclohexanone does not.
(ii) There are two –NH2 groups in semicarbazide. However, only one is
involved in the formation of semicarbazones.
(iii) During the preparation of esters from a carboxylic acid and an alcohol in
the presence of an acid catalyst, the water or the ester should be removed as
soon as it is formed. 3
11 Give simple chemical tests to distinguish between the following pairs of
compounds.
(i) Propanal and Propanone (ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid 3

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