Experiment No....I Date.

Name of the Experiment. Page No......01

PoTENTIOMETRIC ESTIMATION OF FAS USING STANOARD

K,C,O2 SoLUT ION

aIM: De te vmPna!Pon o amounf of FAs prese nl P

the 9Pven soto Pon usfng standard K, Cr, O
by poten t Pome tPealle
PRINCIPLE :

The procedure op measusfng of emf to determhe

the concentratPon p Porfe specPes Pn Solutfon Y
Teperred to as pote ntfomety: The pofncple
Povelved Pn pote ntPomet e QptatPon %the
measuYMen e! emp befoeen too electrodes ; an
Pndfeator elec tyde ard epence electrode. The
potentfal f which a func4on af the concentadto
the Pon to be determPhed and a sePrence eete ctree
(calomel electrode ) af consBant poten teal. In the
tratonc, the measurments p e.m. ae madecik
whPle the teraon R Pn Pregrecs, The euPvalen ce
Pont p the reac tFbn s detemfned by a Sudden
Chanpe Pn the ptoB ep e.mf veadfng aqafnst the
Volwme ep tetrant.
The determPn Png Dactor Pn Oxedoton- reductPon
TeactPon Ps the atfo e the Concenta tPon Q the
 08SFCVATTONS AND CALCULATIONS Experment No Date
Nane of he Experent

DxdPyed and vedoced ermt eg certan Pon pecfes

for the reac Fon:
Volume o E Pa AE
AV
K,oy6, bade AV
-4 Pn Cmns

150 The potenllal, E acquired Ly the PodPcodor ele ctvode

209 59
a32 23
|,5
6-5 E =E D.059t
201 HA n

430 H29
3. O 420 HO The potental the Pmmersed electrode pc thus
3.5 Contrel tedby the Tatfo op these Concentva4Ponc.
18
the ox PlaPon
H.5
486
490
During
recuc ton
a
vedueêng agert
or the
af an Oxfd?zeng a9ent the ratfo, and
5,0 245 0.5 therefore the pobe ntPal, chanqec mbre oprd ty Pn the
Vefnity ef the end pofnt.
Nature
PROcEDURE:
Transfer a Known volume FAs Casem) us Png
Ptpette Pnto D60 cmt beaKer.
Prov?de a glacs
eoufvalence rod. Add Js em? opof tote sutphue acPd
PoPnt. So Cm? o dePonPzed watex to Pt wach the
electro das place the electvode assem bly Cptatnum
electro de as Pnd?cator and a Ca lomel electrode as
CalculadPons

Gen
= l2s
Nsa _(Nxv) K,c,0, 25
Vas

= N X Eqy wetght) FAs

O05 X 34 2.
19.6
 Date.
Experiment No.
Page No. 03
Name of the Expeiment.

electrode) Pn the beaker and Conne ct

Ye ferernce
potentPomete. Re ad he
the same to the
derence betuen the electsodes LwPth
po tenPal
po mPll Pvolt) and
the afd ep the mefer Cexprecsed n
k,Cr,0, SolotPon Pre
re cord Pt. Add o.s Cms )
the buyette s , the con te nts and aptex oa?Po9
othe ce ll.
Por a hal-m fnote, measure the em
p k,cy,og
2e peat the addPLPon a o,sSem' por 4Fons each
stPrsPnq and measurfnq the e.m.f optev
addon Unl a Sudden change Fn the e.m.p
Pncre me
observed. Hence Dorth, add the soloton Pn
-nt ap Ois cm' and reco vd the TeadPngs al ler each
ad dPtPon. Tãke I2- I6 readPngs. Plot a qaph o
e.m.f Wercus Volume o kc,O, added,
Draw a

Smooth Curve The eguPvalence

thmaugh the pofnts
pont Ps the velume CovYepondng to the Steepest
portPon ef the CorVe. Lec ate the end poPnd .ol
tetraton plottPnq 4E/AV versos velome of
LPtran t. there Ps max?mum 6 the plot at the
end pofnt. Take the end pofnt Prom the qraph ?n
volome ond Caleolate the amoUnt o As Prese nt
n the qfven. Solotton.
RESULT:

Welght op FAS present PsT9.6. gldm'.