NIST Institute of Science &Technology(AUTONOMOUS)

www.nist.edu (Approved by AICTE, New Delhi, Affiliated to BPUT: Rourkela)

INSTITUTE PARK, PALLUR HILLS, BERHAMPUR, ODISHA -761 008

ASSIGNMENT NO # 02
Sub- Chemistry(19FY1BS02T) Due Date – 27.07.2023
Program: B.Tech, 2ndSemester (Batch-2022) Full Marks-- 50

PART-I
(Answer all the questions)

Q1. CO Level 2x5

(a) 2 2 State Gibb’s Phase rule and explain the terms involved in it? 2

Is it possible to have a quadruple point in phase diagram of a one

(b) 2 2 2
component system?Justify

1. A eutectic mixture has definite composition and a sharp melting

(c) 2 2 2
point but it is not a compound. Explain?

1. What is synthetic petrol?

(d) 3 3 2

(e) 3 2 Why Ethylene bromide is used in leaded petrol? 2

PART-II
(Answer Any Four questions out of Six)

Q2. CO Level 6x4

(a) 2 2 Discuss the need and application of condensed phase rule in 6

connection to Bi-Cd system.
Which is most pure form of iron in Fe-C system and explain
(b) 2 3 6
why Fe-C phase diagram is drawn up to 6.67% carbon?
Calculate the gross and net calorific values of a coal sample
(c) 3 4 6
containing 80% carbon, 8% nitrogen, and 10% hydrogen and 2%
oxygen.
Explain octane and cetane rating of fuel. Why water gas is
(d) 3 3 6
superior to producer gas?
What do you mean by moving bed catalytic cracking and what is
(e) 3 3 6
advantage of moving bed catalytic cracking over fixed bed
catalytic cracking?
 NIST Institute of Science &Technology(AUTONOMOUS)
www.nist.edu (Approved by AICTE, New Delhi, Affiliated to BPUT: Rourkela)
INSTITUTE PARK, PALLUR HILLS, BERHAMPUR, ODISHA -761 008

(f) 3 4 Describe the method to find the percentage of Carbon and 6

Hydrogen in a coal sample in ultimate analysis.

PART-III

(Answer Any One question out of Two)

CO Level 16 x 1

a.Draw a phase diagram of a substance existing in three phases

Q3. (a) 2 3 4+4
viz., solid, liquid &vapor. The density of the liquid is less than
that of the solid.
b. NaCl-KCl-H2O is a three component system while NaBr-KCl-
H2O is a four component. Explain.
H a.What is power alcohol and why it can’t be used as prime fuel?
(b) 3 4 4+4
b.A gaseous fuel on analysis is found to contain 40% CH 4,
35% C2H6, 12% H2, 8%O2& 5%N2. Calculate the weight &
volume of air required for combustion of 1m3 of the fuel.
Q.4 (a) 3 3 Describe the process of refining of crude oil and mention the 8
major products with their carbon chain length.

Explain the Proximate analysis of coal

(b) 3 4 8