Blatannex 2 15 Gel-En-SDS 09 GHS

THE MINISTRY OF AGRICULTURE
OF
THE REPUBLIC OF INDONESIA
DIRECTORATE GENERAL
OF
AGRICULTURAL INFRASTRUCTURE AND FACILITIES
DIRECTORATE OF FERTILIZER AND PESTICIDE
Jl. Harsono RM No. 3, D Building 8-9th Floor, Ragunan Pasar Minggu - Jakarta Selatan
Phone (62.21) 7890043 - 7810044, Fax (62.21) 7890043
No. : 852/Kompes/2021
In accordance with the Decree of the Minister of Agriculture number

288/KPTS/SR.330 /M/5/2021
We hereby certify that :
Company name : PT. Bayer Indonesia

Company address : GEDUNG MENARA ASTRA LANTAI 33
JL JENDRAL SUDIRMAN KAV 5-6
Is recognized as the registration holder of the following product :
Trade name : BLATTANEX 2.15 GEL

Common name and content of a.i. : imidacloprid: 2.15%
Registration number : RI.06090120072646
The product mentioned above is offically registered.
Expiry: 4 May 2026 Jakarta, 7 July 2021

Director,
Muhammad Hatta, S.STP, MM
This document is official document of Ministry of Agriculture which do not require signature
since being issued electronically from Sistem Informasi Manajemen Pelayanan Perizinan Pertanian (SIM-PPP).
Ministry of Agriculture is responsible for any information in this document.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
BLATTANEX GEL RB 20X(16X12)G TUB ID 1/10

Version 2 / DOM Revision Date: 01.02.2021
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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1 Product identifier
Trade name BLATTANEX GEL RB 20X(16X12)G TUB ID
Product code (UVP) 05178819
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier Bayer, S.A.
Avenida Luperón, Zona Industrial
de Herrera
11113 Sto. Domingo
Dominican Rep.
Telephone 1-809-5308086
Responsible Department Calidad, Salud Ocupacional, Seguridad
Laboral y Medio Ambiente
(502) 66287200
Email: qhse-bcs.centroamericaycaribe@bayer.com
Country of origin France

1.4 Emergency telephone no.
Emergency telephone no. (502) 24369720
Global Incident Response +1 (760) 476-3964 (Company 3E for Bayer AG, Crop Science Division)
Hotline (24h)
SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Hazard label for supply/use required.
Hazardous components which must be listed on the label:
 Imidacloprid

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Signal word: Warning

Hazard statements
EUH208 Contains 1,2-benzisothiazolin-3-one. May produce an allergic reaction.
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.
Precautionary statements
P501 Dispose of contents/container in accordance with local regulation.
2.3 Other hazards
No other hazards known.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Bait (ready for use) (RB)
Imidacloprid 2,15 %
Hazardous components
Hazard statements according to Regulation (EC) No. 1272/2008
Name CAS-No. / Classification Conc. [%]
EC-No. / REGULATION (EC) No
REACH Reg. No. 1272/2008
Imidacloprid 138261-41-3 Acute Tox. 4, H302 2,15
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
1,2-Benzisothiazol-3(2H)- 2634-33-5 Acute Tox. 4, H302 > 0,005 – <
one 01-2120761540-60-0003 Skin Irrit. 2, H315 0,05
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400
Glycerine 56-81-5 Not classified > 1,0
01-2119471987-18-XXXX
Further information
Imidacloprid 138261-41-3 M-Factor: 10 (acute), 1.000 (chronic)
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures
General advice Move out of dangerous area. Place and transport victim in stable
position (lying sideways). Remove contaminated clothing immediately
and dispose of safely.

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Skin contact Wash off thoroughly with plenty of soap and water, if available with
polyethyleneglycol 400, subsequently rinse with water. If symptoms
persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Get medical attention if irritation
develops and persists.
Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison
control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms If large amounts are ingested, the following symptoms may occur:
Dizziness, Abdominal pain, Nausea
4.3 Indication of any immediate medical attention and special treatment needed
Treatment Treat symptomatically. Monitor: respiratory and cardiac functions. In
case of ingestion gastric lavage should be considered in cases of
significant ingestions only within the first 2 hours. However, the
application of activated charcoal and sodium sulphate is always
advisable. There is no specific antidote.
SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising Dangerous gases are evolved in the event of a fire.
from the substance or
mixture
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. In the event of
equipment for firefighters fire, wear self-contained breathing apparatus.
Further information Contain the spread of the fire-fighting media. Do not allow run-off from
fire fighting to enter drains or water courses.
SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.
6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions

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6.3 Methods and materials for containment and cleaning up

Methods for cleaning up The nature of this product, when contained in commercial packs,
makes spillage unlikely. However, if significant amounts are spilled
nevertheless, the following advice is applicable. Soak up with inert
absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Clean contaminated floors and objects thoroughly, observing
environmental regulations. Keep in suitable, closed containers for
disposal.
6.4 Reference to other Information regarding safe handling, see section 7.

sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling
Advice on safe handling No specific precautions required when handling unopened
packs/containers; follow relevant manual handling advice.
Advice on protection against No special precautions required.
fire and explosion
Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Wash hands before breaks and immediately after handling
the product. Remove soiled clothing immediately and clean thoroughly
before using again. Garments that cannot be cleaned must be destroyed
(burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in original container. Keep containers tightly closed in a dry, cool
areas and containers and well-ventilated place. Store in a place accessible by authorized
persons only. Keep away from direct sunlight.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
Suitable materials Sheet metal packages with LDPE (Low Density Polyethylene) interior
package.
7.3 Specific end use(s) Refer to the label and/or leaflet.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components CAS-No. Control parameters Update Basis
Imidacloprid 138261-41-3 0,7 mg/m3 OES BCS*
(TWA)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following
recommendations would apply.
Respiratory protection Respiratory protection is not required under anticipated circumstances
of exposure.

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Respiratory protection should only be used to control residual risk of

short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand protection Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination on the outside cannot
be removed. Wash hands frequently and always before eating,
drinking, smoking or using the toilet.
Material Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0,4 mm
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 6 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Form gel
Colour white to beige
Odour weak, characteristic
Odour Threshold No data available
pH No data available
Melting point/range No data available
Boiling Point No data available
Flash point No data available
Flammability The product is not highly flammable.
Auto-ignition temperature No data available
Ignition temperature > 381 °C

Minimum ignition energy No data available
Self-accelarating No data available

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decomposition temperature
(SADT)
Upper explosion limit No data available
Lower explosion limit No data available
Vapour pressure 21,3 hPa (20 °C)
25,2 hPa (25 °C)
53,6 hPa (50 °C)
Evaporation rate No data available
Relative vapour density No data available
Relative density No data available
Density ca. 1,21 g/cm³ (20 °C)
Water solubility miscible
Partition coefficient: Imidacloprid: log Pow: 0,57

n-octanol/water
Viscosity, dynamic No data available

Viscosity, kinematic No data available
Surface tension 60,1 mN/m (20,2 °C)
Impact sensitivity Not impact sensitive.
Oxidizing properties No oxidizing properties
Explosivity Not explosive
92/69/EEC, A.14 / OECD 113
9.2 Other information Further safety related physical-chemical data are not known.
SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Thermal decomposition to 168 °C
Endothermic.
from 168 °C
Exothermic decomposition.
10.2 Chemical stability Stable under recommended storage conditions.
10.3 Possibility of No hazardous reactions when stored and handled according to

hazardous reactions prescribed instructions.
10.4 Conditions to avoid Extremes of temperature and direct sunlight.
10.5 Incompatible materials Store only in the original container.
10.6 Hazardous No decomposition products expected under normal conditions of use.

decomposition products
SECTION 11: TOXICOLOGICAL INFORMATION


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11.1 Information on toxicological effects

Acute oral toxicity LD50 (Rat) > 5.000 mg/kg
Acute inhalation toxicity
During intended and foreseen applications, no respirable aerosol is
formed.
Acute dermal toxicity LD50 (Rat) > 5.000 mg/kg
Skin corrosion/irritation No skin irritation (Rabbit)
Serious eye damage/eye Slight irritant effect - does not require labelling. (Rabbit)
irritation
Respiratory or skin Skin: Non-sensitizing. (Guinea pig)
sensitisation OECD Test Guideline 406, Buehler test
Skin: Non-sensitizing. (Guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
Assessment STOT Specific target organ toxicity – repeated exposure
Imidacloprid did not cause specific target organ toxicity in experimental animal studies.
Assessment mutagenicity
Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro
and in vivo tests.
Assessment carcinogenicity
Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.
Assessment toxicity to reproduction
Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to
the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity.
Assessment developmental toxicity
Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental
effects seen with Imidacloprid are related to maternal toxicity.
Aspiration hazard
Based on available data, the classification criteria are not met.
SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 211 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient imidacloprid.
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 85 mg/l
invertebrates Exposure time: 48 h
EC50 (Chironomus riparius (non-biting midge)) 0,0552 mg/l

Exposure time: 24 h
Chronic toxicity to aquatic EC10 (Chironomus riparius (non-biting midge)): 0.87 µg/l
invertebrates Exposure time: 28 d

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Toxicity to aquatic plants IC50 (Desmodesmus subspicatus (green algae)) > 10 mg/l
Growth rate; Exposure time: 72 h
12.2 Persistence and degradability
Biodegradability Imidacloprid:
Not rapidly biodegradable
Koc Imidacloprid: Koc: 225
12.3 Bioaccumulative potential
Bioaccumulation Imidacloprid:
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Imidacloprid: Moderately mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Imidacloprid: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Additional ecological No other effects to be mentioned.
information
SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product In accordance with current regulations and, if necessary, after
consultation with the site operator and/or with the responsible authority,
the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging Not completely emptied packagings should be disposed of as hazardous
waste.
SECTION 14: TRANSPORT INFORMATION
ADR/RID/ADN
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(IMIDACLOPRID MIXTURE)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
Hazard no. 90
Tunnel Code -
This classification is in principle not valid for carriage by tank vessel on inland waterways. Please refer
to the manufacturer for further information.

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IMDG
14.1 UN number 3077
N.O.S.
14.5 Marine pollutant YES
IATA
14.1 UN number 3077
N.O.S.
(IMIDACLOPRID MIXTURE )
14.5 Environm. Hazardous Mark YES
14.6 Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.
SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Further information
WHO-classification: U (Unlikely to present acute hazard in normal use)
SECTION 16: OTHER INFORMATION
Text of the hazard statements mentioned in Section 3

H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
Abbreviations and acronyms
ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances

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EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
TWA Time weighted average
UN United Nations
WHO World health organisation
The information contained in this document was obtained from reliable sources. This is the information
that is available on the matter up until the date of revision. Its objective is to describe our products from a
safety standpoint, which is why it does not guarantee concrete properties about the products. This
document is complementary to the user's instructions, but does not replace them. Considering the
supplier is not in control of the use given to this information and of the possible risks of using the product
for purposes other than what it was developed for, the Company is not liable for these concepts. Users
are requested to determine safe use conditions for the product and to strictly comply with additional local
law.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
LEMBARAN DATA KESELAMATAN BAHAN Sesuai Peraturan (ID)
MPRI GHS Klasifikasi & label pada bahan kimia Nomor 23 / M-ID / PER / 4/2013.

Versi 1 / RI Revisi tanggal: 28.05.2019
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BAGIAN 1: IDENTITAS BAHAN DAN PERUSAHAAN
1.1 Identitas Produk

Nama dagang BLATTANEX GEL RB 20X(16X12)G TUB ID
Kode produk (UVP) 05178819
1.2 Penggunaan yang relevan dari bahan atau campuran yang diidentifikasi dan penggunaan
yang disarankan
Penggunaan Insektisida
1.3 Rincian penyuplai lembar data keselamatan
Pemasok PT. Bayer Indonesia
Jalan Rungkut Industri I no 12
Surabaya 60292
Indonesia
Telefax +62-31-8439541
Bagian Yang Menangani Kesehatan dan Keselamatan Lingkungan (Departemen HSE)
+62-31-8438627 (Hanya selama jam kerja)
1.4 Nomor telepon darurat
Nomor Darurat Indonesia 08071-801-801 (24 Jam/hari)
Global Respon Insiden +1 (760) 476-3964 (3E untuk Bayer AG, Crop Science)
Hotline (24h)
BAGIAN 2: IDENTIFIKASI BAHAYA
2.1 Klasifikasi bahan atau campuran

Klasifikasi sesuai dengan Peraturan (ID) MPRI GHS Klasifikasi & label pada bahan kimia Nomor
23 / M-ID / PER / 4/2013
Toksisitas akuatik kronis: Kategori 1
H410 Sangat toksik bagi kehidupan akuatik dengan efek jangka panjang.
2.2 Elemen label
Pelabelan sesuai dengan Peraturan (ID) MPRI GHS Klasifikasi & label pada bahan kimia Nomor
23 / M-ID / PER / 4/2013.
Label bahaya untuk keperluan penggunaan / pemasok.
Komponen-komponen berbahaya yang harus didaftarkan pada label:
 Imidacloprid
Kata sinyal: Awas
Pernyataan Bahaya
H410 Sangat toksik bagi kehidupan akuatik dengan efek jangka panjang.
Pernyataan kehati-hatian
P501 Buanglah isi/wadah sesuai dengan peraturan setempat.

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2.3 Bahaya lain

Tidak diketahui bahaya yang lain.
BAGIAN 3: KOMPOSISI/INFORMASI TENTANG BAHAN PENYUSUN
3.2 Campuran
Sifat kimiawi
Umpan (siap digunakan) (RB)
Imidacloprid 2,15 %
Komponen berbahaya
Nama No-CAS / Conc. [%]
No-EC
Imidacloprid 138261-41-3 2,15
1,2-Benzisothiazol-3(2H)-one 2634-33-5 > 0,005 – < 0,05
Glycerine 56-81-5 > 1,0
Informasi lebih lanjut
Imidacloprid 138261-41-3 Faktor M: 10 (acute), 1.000 (chronic)
BAGIAN 4: TINDAKAN PERTOLONGAN PERTAMA PADA KECELAKAAN (P3K)
4.1 Penjelasan mengenai tindakan pertolongan pertama

Saran umum Keluarlah dari area berbahaya. Tempatkan dan pindahkan korban
dalam posisi yang stabil (berbaring miring). Segera lepaskan pakaian
yang terkontaminasi dan buang dengan aman.
Kena kulit Cucilah dengan air dan sabun yang banyak, jika tersedia cuci dengan
Polyethylene Glycol 400, kemudian bilas dengan air. Jika gejala
berlanjut, hubungi dokter.
Kena mata Segera bilas dengan air banyak, juga di bawah kelopak mata,
sedikitnya selama 15 menit. Jika menggunakan lensa kontak segera
lepaskan setelah 5 menit membilas mata dan lanjutkan membilas.
Tangani secara medis jika terjadi iritasi dan iritasi tidak kunjung hilang.
Tertelan Berkumur. JANGAN merangsang untuk muntah. Segera hubungi
tenaga medis atau pusat penanggulangan keracunan.
4.2 Gejala / efek penting, baik akut maupun yang berdampak tidak langsung
Tanda-tanda Jika tertelan dalam jumlah besar, gejala berikut ini mungkin terjadi:
Pening, Sakit perut, Mual
4.3 Indikasi pertolongan medis pertama dan perawatan khusus yang diperlukan

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Perawatan Tangani menurut gejala. Memonitor: fungsi pernapasan dan jantung.

Pembilasan lambung hanya boleh dilakukan dalam 2 jam pertama jika
menelan dalam jumlah yang signifikan. Dianjurkan diberikan arang
aktif dan sodium sulfat.
Tidak ada penawar racun yang khusus.
BAGIAN 5: TINDAKAN PEMADAMAN KEBAKARAN
5.1 Media pemadaman api

Sesuai Gunakan semprotan air, busa tahan alkohol, media pemadam
"Powder" atau karbon dioksida.
5.2 Bahaya khusus yang Saat terjadi kebakaran akan mengembangkan sejumlah gas
muncul dari bahan atau berbahaya.
campuran
5.3 Saran bagi petugas pemadam kebakaran
Alat pelindung khusus Jika terjadi kebakaran dan/atau ledakan, jangan menghirup asap. Jika
bagi petugas pemadam terjadi kebakaran, pakai alat bantu pernapasan SCBA.
kebakaran
Informasi lebih lanjut Cegah penyebaran media pemadam kebakaran. Jangan biarkan sisa
air limbah dari pemadaman kebakaran memasuki saluran
pembuangan atau saluran air lainnya.
BAGIAN 6: TINDAKAN PENANGGULANGAN JIKA TERJADI TUMPAHAN DAN

KEBOCORAN
6.1 Langkah-langkah pencegahan personil, alat pelindung diri dan prosedur tanggap darurat
Tindakan pencegahan Hindari bersentuhan dengan tumpahan produk atau media yang
terkontaminasi. Gunakan alat pelindung diri.
6.2 Langkah-langkah Jangan biarkan masuk ke dalam air permukaan, saluran air dan air
pencegahan bagi tanah.
lingkungan
6.3 Metode dan bahan-bahan untuk penampung dan pembersihan
Metode untuk pembersihan Pada dasarnya produk ini dalam kemasan komersial kemungkinan
kecil terjadi kebocoran akan tetapi jika bocor dalam jumlah yang
besar dapat dilakukan penanganan berikut ini. Rendam dengan
bahan penyerap (mis. pasir, silika gel, pengikat asam, pengikat
universal, serbuk gergaji). Bersihkan lantai dan benda benda yang
lain secara seksama, perhatikan peraturan tentang lingkungan yang
berlaku Simpan dalam wadah yang sesuai dan tertutup untuk
dibuang.
6.4 Rujukan ke bagian Informasi mengenai penanganan yang aman, lihat bagian 7.
lainnya Informasi mengenai alat pelindung diri, lihat bagian 8.
Informasi mengenai pembuangan limbah, lihat bagian 13.

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BAGIAN 7: PENYIMPANAN DAN PENANGANAN BAHAN
7.1 Kehati-hatian dalam menangani secara aman

Saran penanganan yang Tidak ada tindakan pencegahan khusus yang diperlukan ketika
aman menangani bungkus / wadah yang belum dibuka; ikuti petunjuk
penanganan yang relevan.
Saran mengenai Tidak ada tindakan pencegahan khusus yang diperlukan.

perlindungan terhadap api
dan ledakan
Tindakan higienis Hindari kontak dengan kulit, mata, dan pakaian. Simpan pakaian kerja
secara terpisah. Cuci tangan sebelum waktu istirahat dan segera
setelah menangani produk. Segera lepaskan pakaian kotor dan
bersihkan secara menyeluruh sebelum digunakan lagi. Pakaian yang
tidak dapat dibersihkan harus dimusnahkan (dibakar).
7.2 Kondisi penyimpanan yang aman, termasuk adanya inkompatibilitas
Persyaratan bagi area Simpan dalam wadah asal. Simpan wadah tertutup rapat di tempat yang
penyimpanan dan wadah kering, dingin, dan berventilasi baik. Simpan di tempat yang hanya
dapat dijangkau oleh orang yang berwenang. Jauhkan dari sinar
matahari langsung.
Nasehat mengenai Jauhkan dari makanan, minuman, dan makanan hewan.
penyimpanan sehari-hari
Bahan yang sesuai Paket lembaran logam dengan LDPE (Low Density Polyethylene)
paket interior.
7.3 Penggunaan akhir Lihat label dan / atau leaflet.
khusus
BAGIAN 8: KONTROL PAPARAN/ PERLINDUNGAN DIRI
8.1 Parameter pengendalian

Komponen No-CAS Parameter pengendalian Terkini Dasar
Imidacloprid 138261-41-3 0,7 mg/m3 OES BCS*
(TWA)
Glycerine 56-81-5 10 mg/m3 11 2011 ID OEL
(NAB)
(Kabut.)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Pengendalian paparan
Alat perlindungan diri
Dalam kondisi penggunaan dan penanganan yang normal silahkan lihat label dan / atau leaflet. Pada
kasus lain rekomendasi berikut akan berlaku.
Perlindungan pernapasan Biasanya tidak diperlukan alat bantu pelindung pernapasan personil.
Perlindungan pernapasan seharusnya hanya digunakan untuk

102000007347 Tanggal Cetak: 22.11.2021
mengendalikan risiko residual kegiatan durasi pendek, setelah

semua langkah praktis telah diambil untuk mengurangi paparan
pada sumber misalkan wadah tertutup dan / atau ventilasi. Selalu
ikuti petunjuk manufaktur respirator mengenai pemakaian dan
pemeliharaan alat.
Perlindungan tangan Pelajari instruksi berhubungan dengan daya tembus dan waktu
tembus yang diberikan oleh pensuplai sarung tangan. Perhatikan
kondisi lokal spesifik dimana produk digunakan, seperti bahaya
sobek, tergosok, dan waktu kontak.
Buang ketika terkontaminasi di bagian dalam, ketika berlubang atau
ketika kontaminasi di bagian luar tidak bisa dihilangkan.
Bahan Karet nitril
Laju permeabilitas > 480 Mnt
Tebal sarung tangan > 0,4 mm
Arahan Sarung tangan pelindung yang mentaati
EN 374.
Perlindungan mata Kenakan kacamata (sesuai dengan EN166, Gunakan = 5 atau
setara).
Perlindungan kulit dan tubuh Gunakan baju standar dan sesuai kategori 3 Tipe 6.
Jika ada risiko paparan yang signifikan, tingkatkan jenis baju
pelindung.
Gunakan dua lapis pakaian jika memungkinkan. Pakaian pelindung
berbahan Poliester/katun atau seluruhnya katun harus dikenakan di
bawah pakaian pelindung kimia dan harus sering di laundry.
Jika pakaian pelindung bahan kimia tersiram, tersemprot, atau

terkontaminasi secara signifikan, lakukan dekontaminasi sejauh
mungkin kemudian pindahkan dengan hati-hati dan buang sesuai
dengan saran dari manufacturer.
BAGIAN 9: SIFAT-SIFAT FISIKA DAN KIMIA
9.1 Informasi tentang sifat fisik dan kimia

Bentuk gel
Warna putih hingga krem
Bau lemah, ciri khas
Flamabilitas (padatan, gas) Produk ini tidak mudah terbakar.
Suhu dapat membakar > 381 °C
sendiri (auto-ignition
temperature)
Tekanan uap 21,3 hPa (20 °C)
25,2 hPa (25 °C)
53,6 hPa (50 °C)
Densitas kira-kira 1,21 g/cm³ ( 20 °C)
Kelarutan dalam air larut

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Koefisien partisi (n- Imidacloprid: log Pow: 0,57

oktanol/air)
Tegangan permukaan 60,1 mN/m ( 20,2 °C)
Kesensitifan terhadap Tidak sensitif terhadap benturan.
benturan
Sifat oksidator Tidak ada zat pengoksidasi
Explosif Tidak mudah meledak
92/69/EEC, A.14 / OECD 113
9.2 Informasi lain Data lebih lanjut mengenai keselamatan yang terkait sifat fisik-kimia
tidak diketahui.
BAGIAN 10: REAKTIFITAS DAN STABILITAS
10.1 Reaktifitas
Dekomposisi termal ke 168 °C
Endotermik.
dari 168 °C
Dekomposisi eksotermis.
10.2 Stabilitas kimia Stabil pada kondisi penyimpanan yang disarankan.
10.3 Reaksi berbahaya yang Tidak ada reaksi berbahaya bila disimpan dan ditangani sesuai dengan
mungkin di bawah kondisi instruksi yang ditentukan.
spesifik/khusus
10.4 Kondisi yang harus Suhu ekstrem dan cahaya matahari langsung.
dihindari
10.5 Bahan yang harus Hanya simpan dengan wadah aslinya.

dihindari
10.6 Produk berbahaya hasil Dalam kondisi normal tidak terjadi dekomposisi produk.
penguraian
BAGIAN 11: INFORMASI TOKSIKOLOGI
11.1 Informasi tentang efek toksikologis

Toksisitas oral akut LD50 (Tikus) > 5.000 mg/kg
Toksisitas inhalasi akut
Selama pemakaian, tidak ada aerosol yang terbentuk yang dapat
terhirup.
Toksisitas kulit akut LD50 (Tikus) > 5.000 mg/kg
Korosi/iritasi kulit Tidak menyebabkan iritasi kulit (Kelinci)
Kerusakan mata efek iritasi sedikit - tidak memerlukan label (Kelinci)
serius/iritasi mata

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Sensitisasi saluran Kulit: Tidak sensitif. (Kelinci percobaan)

pernafasan atau pada kulit OECD Test Guideline 406, Buehler test
Kulit: Tidak sensitif. (Kelinci percobaan)
OECD Test Guideline 406, Magnusson & Kligman test
Penilaian Toksisitas pada organ target tertentu (STOT) – paparan berulang
Imidacloprid tidak menyebabkan keracunan organ target khusus dalam studi hewan percobaan.
Penilaian Mutagenik
Imidacloprid tidak mutagenik atau genotoksik berdasarkan berat bukti keseluruhan dalam in vitro
Penilaian Karsinogenik
Imidacloprid tidak karsinogen dalam studi rantai makanan pada tikus dan tikus putih
Penilaian toksisitas reproduksi
Imidacloprid menyebabkan toksisitas reproduksi dalam studi dua generasi pada tikus hanya pada
tingkat dosis yang juga beracun untuk hewan induk.
Toksisitas reproduksi terlihat dengan Imidacloprid terkait dengan toksisitas parental.
Penilaian perkembangan toksisitas
Imidacloprid menyebabkan perkembangan toksisitas hanya pada tingkat dosis toksik pada induk.
Efek perkembangan yang terlihat dengan Imidacloprid terkait dengan toksisitas maternal.
Bahaya jika terhirup

Berdasarkan data yang tersedia, kriteria klasifikasi tidak terpenuhi.
BAGIAN 12: INFORMASI EKOLOGI
12.1 Toksisitas
Keracunan untuk ikan LC50 (Oncorhynchus mykiss (Ikan rainbow trout)) 211 mg/l
Waktu paparan: 96 j
Nilai yang disebutkan berhubungan dengan bahan aktif imidacloprid.
Toksisitas terhadap EC50 (Daphnia magna (kutu air)) 85 mg/l
invertebrata air Waktu paparan: 48 j
EC50 (Chironomus riparius (bukan tergolong nyamuk penggigit))

0,0552 mg/l
Waktu paparan: 24 j
Toksisitas kronis pada EC10 (Chironomus riparius (bukan tergolong nyamuk penggigit)): 0.87
invertebrata akuatik µg/l
Waktu paparan: 28 H
Toksisitas terhadap IC50 (Desmodesmus subspicatus (Ganggang hijau)) > 10 mg/l

tanaman air Laju pertumbuhan; Waktu paparan: 72 j
12.2 Persistensi dan penguraian oleh lingkungan

102000007347 Tanggal Cetak: 22.11.2021
Daya urai secara biologis Imidacloprid:

Tidak dapat terbiodegradasi dengan cepat
Koc Imidacloprid: Koc: 225
12.3 Potensi bioakumulasi
Bioakumulasi Imidacloprid:
Tidak terakumulasi secara hayati.
12.4 Mobilitas dalam tanah
Mobilitas dalam tanah Imidacloprid: Agak dapat bergeser/bergerak di tanah
12.5 Hasil dari asesmen PBT dan vPvB
Penilaian PBT dan vPvB Imidacloprid: Bahan ini tidak dianggap persisten, bioakumulatif dan
beracun (PBT). Bahan ini tidak dianggap sangat persisten dan sangat
bioakumulatif (vPvB).
12.6 Efek merugikan lainnya
Informasi ekologis Tidak ada efek lain yang disebutkan.
tambahan
BAGIAN 13: PEMBUANGAN LIMBAH
13.1 Metode penanganan limbah

Produk Sesuai dengan peraturan yang berlaku dan jika perlu, setelah
berkonsultasi dengan operator dan / atau dengan pihak berwenang
yang bertanggung jawab, produk dapat dibawa ke tempat pembuangan
limbah atau pabrik insinerasi.
Kemasan yang telah Kemasan yang tidak sepenuhnya kosong diperlakukan sebagai limbah
tercemar berbahaya
BAGIAN 14: INFORMASI PENGANGKUTAN
ADR/RID/ADN
14.1 Nomor PBB 3077
14.2 Nama pengapalan yang sesuai ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
berdasarkan PBB N.O.S.
14.3 Kelas bahaya transportasi 9
14.4 Kelompok pengemasan III
14.5 Tanda Bahaya bagi YA
Lingkungan
Nomor Bahaya 90
Klasifikasi ini pada prinsipnya tidak berlaku untuk pengangkutan dengan kapal tangki di perairan
darat (sungai). Silakan merujuk pada manufaktur untuk informasi lebih lanjut.
IMDG
14.1 Nomor PBB 3077

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14.5 Bahan pencemar laut YA
IATA
14.1 Nomor PBB 3077
(IMIDACLOPRID MIXTURE )
14.5 Tanda Bahaya bagi YA
Lingkungan
14.6 Tindakan kehati-hatian khusus bagi pengguna

Lihat bagian 6 hingga 8 pada Lembar Data Keselamatan ini.
14.7 Transportasi dalam jumlah besar berdasarkan pada MARPOL Lampiran II dan IBC Code
Tidak ada transportasi dalam jumlah besar sesuai dengan Kode IBC.
BAGIAN 15: PERATURAN PERUNDANG - UNDANGAN
15.1 Regulasi tentang lingkungan, kesehatan dan keamanan untuk produk tersebut
Informasi lebih lanjut
Klasifikasi WHO: U (Mungkin ada sebagai bahaya akut dalam penggunaan normal)
BAGIAN 16: INFORMASI LAIN
Singkatan dan persamaan Kata

ADN Perjanjian Eropa mengenai Internasional Pengangkutan Barang Berbahaya melalui
perairan darat
ADR Perjanjian Eropa tentang transportasi Barang Berbahaya di jalan raya
ATE Perkiraan toksisitas akut
CAS-Nr. Nomor Layanan Kimia Abstrak
Conc. Konsentrasi
EC-No. Nomor Masyarakat Eropa
ECx Konsentrasi efektif dalam x %
EINECS Persediaan zat komersial yang ada oleh Eropa
ELINCS Daftar zat kimia Eropa yang diinformasikan
EN Standart Eropa
EU Masyarakat Eropa
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code) (Kode Internasional dalam Pembangunan dan Peralatan
Kapal tercatat Kimia Berbahaya dalam jumlah besar)
ICx Konsentrasi inhibisi dalam x %

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IMDG International Maritime Dangerous Goods - Benda-benda berbahaya Maritim

Internasional
LCx Konsentrasi mematikan dalam x %
LDx dosis mematikan dalam x %
LOEC/LOEL Dampak konsentrasi/tingkat rendah yang teramati
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships -
Konvensi Internasional untuk pencegahan pencemaran laut dari kapal
N.O.S. Not otherwise specified / Tidak ditentukan
NOEC/NOEL Tidak ada dampak level/konsentrasi yang teramati
OECD Organisasi dalam Kerjasama Ekonomi dan Pembangunan
RID Peraturan mengenai Internasional Pengangkutan Barang Berbahaya oleh Rail
TWA TWA (Waktu terhitung rata-rata)
UN United Nations
WHO Organisasi Kesehatan Dunia
Informasi yang diberikan dalam lembar data keselamatan benar pada tanggal dibuat.
Namun seiring dengan perkembangan ilmu pengetahuan dan teknologi, informasi ini mungkin tidak
sesuai di masa depan.
Perubahan-perubahan setelah versi paling belakangan akan disoroti di garis tepi. Versi ini
menggantikan semua versi-versi sebelumnya.

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Blatannex 2 15 Gel-En-SDS 09 GHS

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THE MINISTRY OF AGRICULTURE

In accordance with the Decree of the Minister of Agriculture number

We hereby certify that :

Company name : PT. Bayer Indonesia

Is recognized as the registration holder of the following product :

Trade name : BLATTANEX 2.15 GEL

The product mentioned above is offically registered.

Expiry: 4 May 2026 Jakarta, 7 July 2021

Muhammad Hatta, S.STP, MM

BLATTANEX GEL RB 20X(16X12)G TUB ID 1/10

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

Country of origin France

SECTION 2: HAZARDS IDENTIFICATION

BLATTANEX GEL RB 20X(16X12)G TUB ID 2/10

Signal word: Warning

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

SECTION 4: FIRST AID MEASURES

BLATTANEX GEL RB 20X(16X12)G TUB ID 3/10

SECTION 5: FIREFIGHTING MEASURES

SECTION 6: ACCIDENTAL RELEASE MEASURES

BLATTANEX GEL RB 20X(16X12)G TUB ID 4/10

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other Information regarding safe handling, see section 7.

SECTION 7: HANDLING AND STORAGE

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

BLATTANEX GEL RB 20X(16X12)G TUB ID 5/10

Respiratory protection should only be used to control residual risk of

Hand protection Please observe the instructions regarding permeability and

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Ignition temperature > 381 °C

BLATTANEX GEL RB 20X(16X12)G TUB ID 6/10

Water solubility miscible

Partition coefficient: Imidacloprid: log Pow: 0,57

Viscosity, dynamic No data available

SECTION 10: STABILITY AND REACTIVITY

10.3 Possibility of No hazardous reactions when stored and handled according to

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.

SECTION 11: TOXICOLOGICAL INFORMATION

BLATTANEX GEL RB 20X(16X12)G TUB ID 7/10

11.1 Information on toxicological effects

SECTION 12: ECOLOGICAL INFORMATION

EC50 (Chironomus riparius (non-biting midge)) 0,0552 mg/l

BLATTANEX GEL RB 20X(16X12)G TUB ID 8/10

The value mentioned relates to the active ingredient imidacloprid.

SECTION 13: DISPOSAL CONSIDERATIONS

SECTION 14: TRANSPORT INFORMATION

BLATTANEX GEL RB 20X(16X12)G TUB ID 9/10

14.6 Special precautions for user

SECTION 15: REGULATORY INFORMATION

SECTION 16: OTHER INFORMATION

Text of the hazard statements mentioned in Section 3

BLATTANEX GEL RB 20X(16X12)G TUB ID 10/10

BLATTANEX GEL RB 20X(16X12)G TUB ID 1/10

BAGIAN 1: IDENTITAS BAHAN DAN PERUSAHAAN

1.1 Identitas Produk

BAGIAN 2: IDENTIFIKASI BAHAYA

2.1 Klasifikasi bahan atau campuran