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Spray Characteristics of Fischer-Tropsch Alternate Jet Fuels
Spray Characteristics of Fischer-Tropsch Alternate Jet Fuels
Spray Characteristics of Fischer-Tropsch Alternate Jet Fuels
GT2013
June 3-7, 2013, San Antonio, Texas, USA
GT2013-95761
ABSTRACT need for cleaner, alternate fuel for the transportation sector [1].
Increase in energy demand and stringent emission norms drive The synthetic fuels derived from feed-stocks, such as biomass,
the need for clean, alternative energy source. Recently, gas-to- natural gas, and coal are being considered as a viable
liquid (GTL), a synthetic jet fuel produced from natural gas alternative fuel for transportation, without any modifications to
using Fischer-Tropsch synthesis has grabbed global attention the existing fuel injection system and combustor design. It is
due to its cleaner combustion aspects when compared to the expected that consumption of the synthetic fuels increases to
conventional jet fuel. The chemical and physical properties of 25% of the total fuel consumption in the transportation sector in
GTL fuels are different from the conventional fuels which the near future in spite of the current limitation in the
could potentially affect the atomization and in turn the production capacity of these fuels at commercial scale [2].
combustion characteristics and pollutant formation. In this There has been an increased interest in gas-to-liquid (GTL)
work the spray characteristics of two GTL blends and synthetic paraffinic kerosene (SPK) fuel derived from natural
conventional Jet A-1 fuels are investigated downstream of a gas using Fischer-Tropsch process for diesel and gas turbine
pressure swirl nozzle exit at two injection pressures and the engines due to its cleaner combustion aspects owing to the near
results are then compared. Microscopic spray characteristics, absence of aromatic and sulphur content in the fuel
droplet size and velocity distributions are obtained at global as composition. However, the alternative fuels are expected to
well as local levels of the spray using global sizing velocimetry meet the vital qualities such as quick atomization, vaporization,
and phase Doppler anemometry measurement techniques, combustion and emission characteristics of conventional fuel in
respectively. Results clearly show that although the GTL fuels order to qualify as a drop-in fuel in the current aviation gas
have different physical properties, such as viscosity, density, turbines.
and surface tension the spray characteristics of the GTL fuels The chemical composition of GTL fuel produced from F-T
are found to be similar to those of Jet A-1 fuel. synthesis is mainly composed of paraffins (iso- and normal-
paraffins). This composition alters the physical and chemical
1. NOMENCLATURE properties, such as density, viscosity, surface tension, H/C ratio,
GTL Gas-to-Liquid and aromatics content of GTL fuel from those of the
RME Rapeseed methyl ester conventional jet fuel. Many studies are carried out recently to
SPK Synthetic Paraffinic kerosene investigate the effect of the change in chemical and physical
GSV Global Sizing Velocimetry properties of GTL fuel on the combustion and emission in
PDA Phase Doppler Anemometry diesel [3] [4] as well as gas turbine [5] [6] engines. On the other
F-T Fischer-Tropsch hand, any change in the physical properties of the fuels affects
H/C ratio Hydrogen to Carbon ratio its macro- and micro-spray characteristics, which eventually
CCD Charge-Coupled Device affect the combustion and emission process in the combustor.
SMD Sauter mean diameter This could have significant impact on the pollutant formation,
NS Nozzle station life, durability and efficiency of the combustor [7]. Hence, it is
essential to have a better understanding of the fuel spray
2. INTRODUCTION characteristics that influences the quality of air-fuel mixture
Increasing concern on the supply security and high cost of inside the combustor and in turn the combustion and emission
the petroleum based fuels and strict emission policies drive the processes.
The GTL and conventional Jet A-1 fuels used in this work
are supplied by Shell Inc., and the chemical composition and
property details are summarized in Table 1. The SPK-1
represents the Shell commercial GTL fuel and SPK-2 is a blend
of SPK-1 and ShellSol solvents. The fuel composition of SPK-2
mimics the composition of future commercial GTL fuel from
“Qatar-Pearl” from a pilot plant sample from Shell. The key
difference in chemical composition between SPK-1 and SPK-2
Figure 2. Field of view and the measurement locations for is the carbon range, the former has the narrow carbon range and
the GSV and PDA techniques the latter has the wide carbon range. Despite the difference in
carbon range, the overall hydrogen to carbon ratio is almost the
Two different measurement techniques of Global Sizing same among the GTL fuels. The change in chemical properties
Velocimetry (GSV) and Phase Doppler Anemometry (PDA) are has resulted in an increase in viscosity, density, and surface
used to map droplet diameters in the spray. Figure 2 shows the tension of SPK-2 by 27%, 2%, and 1.8%, respectively, when
schematic of the spray and field of view for the planar GSV compared to SPK-1. Furthermore, the surface tension of Jet A-1
measurement technique and the black dots represent the PDA is higher than SPK-1 and SPK-2 by 12% and 11%, respectively.
measurement locations. An in depth analysis of the compositional details is reported
Measurements are carried out in the near nozzle region up elsewhere [13].
to 123mm downstream of the nozzle exit. The region of interest
is divided into two zones, nozzle station-1 (NS1) and nozzle 3.3 OPTICAL DIAGNOSTICS
station-2 (NS2) as shown in Figure 2. For GSV measurements In this study, the droplet size and velocity in the spray are
these regions (field of view) are constructed based on the focal measured at planar (global) and point (local) level using Global
length of the camera lens and the chamber dimensions. The Sizing Velocimetry (GSV) and Phase Doppler Anemometry
field of view has a width of 55mm and a height of 41mm. The (PDA), respectively. Details of the measurement techniques are
region of interest in the radial direction is covered in two steps, discussed next.
each step having a dimension of the field of view as mentioned
above. For PDA measurements data is obtained at the points in 3.3.1 GLOBAL SIZING VELOCIMETRY
the midsection of NS1 and NS2 as shown in the figure. All the GSV (TSI Inc.,) is a planar, laser-based imaging technique
zones are positioned on one side of the spray, since the spray is working on the interferometric principle [14]. A Quantel,
All the four beams (two green and two blue) are converged
at the focal length of the lens mounted in front of the
transmitting probe to create the measurement volume. PDA is
also developed based on the interferometric principle wherein,
the fringe pattern is created by intersecting two laser beams at
the measurement volume. The spacing between the fringes and
the number of fringes are fixed since the beam parameters, such
Figure 3 Laser and camera arrangement for GSV system as wavelength and diameter are constant. In addition, the fringe
[14] patterns also move continuously at a frequency of 40MHz
caused by the beam frequency shift.
Prior to the spray measurements, the CCD camera is The signal emitted by a droplet crossing the measurement
focused on a 2D calibration target placed in the field of interest volume (fringe pattern) is received at the receiver probe. Here,
in order to get the magnification factor in the images. Later, the the receiver is positioned at an angle (42o) to collect the first
camera is defocused (by moving the camera away from the order refraction in forward scatter mode. The signals are then
field of view) without disturbing the lens magnification to processed using signal processing unit in order to determine the
capture the out-of-focus angular oscillations emitted by the droplet size and velocity information. At each radial location
droplets [16], [17]. The droplet size information is extracted the measurement is conducted to collect either a maximum of
from the out-of-focus image based on the spacing between the 10,000 droplet samples or 30s sample time to have statistically
oscillations patterns [14]. The droplet velocity information can independent droplet measurements. More details about the PDA
also be obtained using a particle tracking technique by principle and methodology are described elsewhere [18].
capturing images in frame straddling mode (capturing two
consecutive images separated by a short time interval). 3.3.3 VERIFICATIONS
In this section, the verification and uncertainty evaluation
3.3.2 PHASE DOPPLER ANEMOMETRY methodology for the measurement techniques outlined in the
A 2-Channel, Phase Doppler Anemometry (PDA) system previous sections are discussed. The measurement techniques
from Dantec Dynamics is also installed and integrated with the are calibrated using a mono-disperse droplet generator (MDG-
experimental facility (Figure 1) for point-wise, droplet size and 100) from TSI Inc., [19]. The Mono-disperse droplet generator
velocity measurement. The PDA system consists of a stand- produces a train of droplets with a uniform diameter when the
alone Argon-ion, multiline laser, transmitter probe, receiver excitation frequency applied to the piezo-electric transducers on
probe, photo detector unit, signal processing hardware and the reservoir matches the resonant frequency of the reservoir
software. The multiline laser beam operated at a power of (Figure 5). The theoretical droplet diameter, d is obtained using
290mW serves as the light source which is then split into green the excitation frequency and liquid flow rate. Typically, the
(λ=532nm) and blue (λ=488nm) beams inside the transmitter. system can produce a train of droplets having a diameter in the
The resultant power of each laser beam is about 35~40mW. range of 50μm to 300μm. This method of droplet generation
Bragg cell [18] is used to shift the frequency (by 40MHz) of has been established as a standard method for droplet size
one beam of each wavelength to facilitate the measurement of measurement calibration.
reverse flows. The green and blue wavelengths are used to