CPP-14

SS JEE(M) &
ADVANCED

Chemistry
Chapterwise Practise Problems (CPP) for JEE (Main & Advanced)
Chapter - Biomolecules and Polymers
Level-1

3. Which of the following is the major solute species

SECTION - A in a solution of lysine at pH = 10.5 ?
Straight Objective Type
COOH COOH
This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its 

(A) H3N H (B) H2N H

answer, out of which ONLY ONE is correct.

(CH2)4 (CH2)4
H
NH3 NH3
H OH  

H OH HIO4
1. A+ B
H OH
H OCH3 COO– COO–
OCH3
(C) H2N H (D) H2N H
(A) HCHO & HCOCH(OCH3)2
(CH2)4 (CH2)4
(B) (CH3O)2CH – COOH & HCHO
NH3 NH2

(C) (CH3O)2CH – CHO + HCOOH + HCHO

(D) HCOOH & HCOCH(OCH3)2 4. Which of the following is the major solute species
2. Consider the following three bases of DNA and in a solution of glutamic acid at pH = 1.3 ?
RNA
COOH COO–
(7)
NH2 
O O (A) H3N H (B) H2N H
(1) (3) CH3 (5)
HN HN HN

(2) (4) (6)

(CH2)2 (CH2)2
O O O
N N N
COOH COOH
H H H
Uracil Thymine Cytosine
(In RNA) (In DNA) (In both DNA and RNA)
COO– COO–

Order of acidic strength on different sites will be 

(C) H3N H (D) H2N H
(A) (2) > (1) (B) (3) > (4)
(CH2)2 (CH2)2
(C) (7) > (6) (D) (6) > (5)
COOH COO–

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Biomolecules and Polymers Aakash Institute
5. Which of the following statements most correctly 9. Which of the following is/are not polyamide fibre ?
defines the isoelectric point ?
(A) Nylon-6, 6 (B) Nylon-6
(A) The pH at which all molecular species are
ionised and that carry the same charge (C) Teflon (D) Terylene
10. If sucrose is treated with conc. H 2SO 4 , the
(B) The pH at which all molecular species are
product formed is
neutral and uncharge
(A) CO2 (B) C
(C) The pH at which half of the molecular species (C) CO (D) H2O
are ionised and the other half unionised
11. Identify the correct statement(s) out of the
(D) The pH at which a molecule carries no net following sugars:
electrical charge. (A)  - D - Glucopyranose has a hemi acetal
structure and is a reducing sugar
6. Which of the following on hydrolysis gives only
(B) Methyl  - D - Glucopyranoside has acetal
glucose?
structure and is a non-reducing sugar
Maltose Sucrose Cellobiose Lactose Starch (C)  - D - Glucopyranose and  - D -
I II III IV V Glucopyranose are anomers
(A) I, II & IV (B) I, III & V (D) Lactose is a disaccharide and is a reducing
sugar
(C) II, III & V (D) I, III, IV & V
12. Which of the following statements are correct ?
7. The following polymer is used for athletic shoe (A) Monosaccharides are opt icall y act iv e
innersoles because of its resilience and durability. polyhydroxy carbonyl compounds
(B) Fructose does not react with Fehling’s solution
–CH–CH2–CH–CH2– because it is keto
OCOCH3 OCOCH3 n . (C) -D-Glucose and -D-Glucose are anomers
(D) D-Glucose and D-Mannose are epimers
The monomer is/are likely to be 13. Which of the following statements are correct ?
(A) Ethylene + methyl acrylate (A) Hydrolysis of sucrose with dilute acid yields an
(B) Allyl acetate equimolar mi xture of D-Glucose and
D-Fructose
(C) Vinyl acetate (B) Acidic hydrolysis of sucrose is accompanied
(D) Vinyl acrylate by a change in optical reaction
8. The isoelectric point of alanine is 6. In a solution (C) In sucrose, the glycosidic linkage is between
of pH = 1, alanine predominantly exists as C — 1 glucose and C — 2 of fructose
(D) Aqueous solution of sucrose exhibits
3 3
mutarotation
+
(A) H 3N–CH–CO 2H (B) H 3N–CH–CO 2H 14. Which of the following statements are correct for
glucose ?
3
3
(A) It gives positive test with Schiff’s reagent
+
(C) H3N–CH–CO2– (D) H3N–CH–CO2– (B) It reacts with NaHSO3 and NH3
(C) Pentaacetate derivative of glucose does not
SECTION - B
react H2N — OH
Multiple Correct Answer Type (D) It gives positive test with Fehling solution

This section contains multiple choice questions. Each

question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct.

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Aakash Institute Biomolecules and Polymers
15. Which of the following monosaccharides will have Paragraph for Question Nos. 18 and 19
D-configuration?
Four structures are given
Structure I Structure II
CH2OH
CH2OH CH2 OH HO CH2OH H OH
O O H O
HO H HO H H
H
H2 C O H HO
H O OH H
H
OH H H HO OH H H
(A) H OH (B) HO O
CH2 OH H
HO H H H O OH
H OH H OH OH H H OH CH2OH

CH2OH CHO A B A B
(+) Erythrose
(–) Fructose
Structure III Structure IV
CH2OH OH H
CHO CH2OH HO O CH2
H H OH
H OH H H HO
OH H
HO H H
OH (D) H OH H O CH2 O H
(C) H
H OH
H OH OH

CH2OH CHO A B
(+) Glucose (–) Glyceraldehyde
18. Which of the above is(are) non-reducing sugar(s)?
16. Which of the following statement(s) is (are) correct
(A) Only I (B) Both II and III
with reference to aspartic acid and lysine?
(C) Both I and IV (D) Only IV
(A) Aspartic acid and lysine together form two type
19. In which structure(s), both the units are glucose?
dipeptides
(A) Only II (B) Both II and III
(B) Isoelectric point of aspartic acid is given by the
average of pKa1 and pKa2 (C) Only I (D) Only IV

(C) Isoelectric point of lysine is given by the

average of pKa2 and pKa3 SECTION-D

(D) Both of them give violet colour when separately
treated with ninhydrin
17. Which of the following is/are correctly matched?
(A) –D–glucose––D–fructose–(1, head to head)–
sucrose
Matrix-Match Type
This Section D have “match the following” type question.
Question contains two columns, Col-I and Col-II. Match
the entries in Col-I with the entries in Col-II. One or more
entries in Col-I may match with one or more entries in
Col-II.

(B) –D–glucose––glucose–(1, head to tail)– 20. Match the following columns:

maltose
Column-I Column–II
(C) –D–glucose––glucose–(1, head to tail)–
cellulose
(A) Sucrose (p) Two acetals
(D) –D–galactose––D–glucose–(1, head to
head)–lactose (B) Maltose (q) No hemiacetal

SECTION - C (C) Lactose (r) -1,4-glycosidic bond

Linked Comprehension Type
(D) Cellulose (s) Hydrolysis product is
This section contains paragraphs. Based upon this glucose
paragraph, multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which ONE/MORE is/are correct.

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Biomolecules and Polymers Aakash Institute
21. Match the following columns:
O O
Column-I Column–II 23. H2 N – CH – C – NH – CH – C – OH

(A) Polythene (p) Synthetic Polymer CH 2– Ph CH 3

Number of moles of C2H5OH react with the above
(B) Terylene (Polyester) (q) Linear Polymer compound in dilute acid medium is

(C) Natural rubber (r) Addition Polymer

24. Number of naturally occuring amino acids from the
(D) Buna – N (s) Condensation Polymer following list is

(t) Homo Polymer CH3 – CH – NH2 Ph – CH2 – CH – NH2

, ,
COOH COOH
SECTION-E

Integer Answer Type HOOC – CH2 – CH – NH2

, N COOH ,
COOH
This section contains Integer type questions. The answer H
to each of the questions is a single digit integer, ranging (CH3)2 CH – CH – NH 2 HS – CH 2 – CH – COOH
from 0 to 9. The appropriate bubbles below the respective , ,
COOH NH 2
question numbers in the ORS have to be darkened. For
example, if the correct answers to question numbers X,
Y and Z(say) are 6, 0 and 9, respectively, then the correct H 2N (CH2)4 CH – COOH
, COOH
darkening of bubbles will look like the following : NH2 N
X Y Z
H
0 0 0
1 1 1 NH4Cl HCl,H2O
25. CH3 – CHO 
KCN
  
2 2 2
3 3 3 In the first intermediate the number of C – N 
4 4 4 bonds is

5 5 5 26. How many of the following are polyester?

6 6 6
DNA, RNA, Nylon-6,6, Nylon-6,10, Rayon, Dacron,
7 7 7 Terylene, Glyptal
8 8 8
9 9 9 O O
HO – C – CH2 – CH – C –OH
27. Pka=2.1.
OH NH3
O +
Pka=3.9
HO OCH3 Pka=9.8
22.
HO OH Isoelectric point of above amino acid is

Number of moles of HIO 4 consumed in the

eleavage of the above is

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Aakash Institute Biomolecules and Polymers

Level-2

SECTION - A
O
Straight Objective Type
C – OH
This section contains multiple choice questions. Each
H OH
question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct. H
(B)
CHO H OH
H OH O H OH
1. H OH Br2 Ca(OH) 2 H 2O 2
H OH 2+ C
H 2O Fe
H OH O

CH2OH
‘A’ is (C) It can’t form a lactone

CHO CHO O
H OH H OH
(A) HO H (B) H OH C
HO H H OH (D) H OH
CH2OH CH2OH HO H O

H
CHO CHO
H OH HO H H OH
(C) H OH (D) HO H CH2OH
HO H HO H
CH2OH CH2OH 3. Which of the following is correct structure of
histidine at pH = 0 ?
2. If D-Glucaric acid is allowed to undergo

intramolecular esterification. The compound (s) NH 3
formed is/are
CH—CH—COOH
2
(A) 
O H— N N—H
C
H OH 
NH 3
(A) HO H O –
CH—CH—COO
2

H (B) 
H— N N—H
H OH
COOH 
NH3
–
CH—CH—COO
2

(C) N N—H

–
CH—CH—COO
2

(D) N NH2
N–H

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Biomolecules and Polymers Aakash Institute
CHO
1.HCN/H O 
4. Glucose  3
2.P/HI
 A. A is H OH
7. HO H Is subjected to Killani-Fischer synthesis.
(A) n - heptanoic acid
H OH
(B)  - methyl hexanoic acid
CHOH
2

(C) n - heptane
The product formed is
(D)  - methyl hexane
CHO
5. Which one of the following statements is false H OH CHO
about the reaction given below ? HO H
H OH
(A) (B) H
HO H OH

CHOH H OH CH2OH
H OH CH3OH
HO H O CH2OH
HCl
H OH
CHO
H CHO HO H
HO H
CH2OH H OH
(C) (D)
H OH
(A) A carbocation participates H OH
HO H
(B) Only one –OH group becomes –OCH3 CH2OH
H OH
(C) The product is an acetal
CH2OH
(D) The third –OH group from anomeric carbon HNO3
becomes –OCH3 group A

SECTION - B 8. D-erythrose
Br2
Multiple Correct Answer Type B
H2O
This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its Which of the following is/are true about A and B ?
answer, out of which ONE OR MORE is/are correct.
(A) A is optically active but B is not
6. Which of the following alternatives is/are correct
regarding the statement(s) ? (B) A is a dicarboxylic acid

(A) With bromine water, glucose oxidizes into (C) B can form a lactone
gluconic acid, but fructose gives no reaction
(D) Compound ‘B’ can show 4 optical isomers
(B) W it h nit ric acid, glucose oxidi zes i nto
saccharic acid, but fructose oxidizes into SECTION - C
mixture of glycolic acid, tartaric acid and
trihydroxy glutaric acid Linked Comprehension Type
This section contains paragraphs. Based upon this
(C) Glucose on reduction gives sorbitol and
fructose on reduction gives mixture of sorbitol paragraph, multiple choice questions have to be
and mannitol. answered. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which ONE/MORE is/are correct.
(D) Glucose gives positive test with alcoholic -
naphthol + conc. HCl

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 Aakash Institute Biomolecules and Polymers
Paragraph for Question Nos. 9 to 11 Paragraph for Question Nos. 12 to 14

Read the paragraph carefully and answer the fol- Observe these compounds and give answer of following
lowing questions : questions
In a polyhydric alcohol, the total numbers of hydroxyl
groups are estimated by the following methods : CHO CHO
H – C – OH HO – C – H
(i) A known mass of the acetyle derivative of H – C – OH H – C – OH
polyhydric groups alcohol is taken. It is mixed
H – C – OH H – C – OH
with an excess volume of a standard alkali so-
lution. Both are refluxed. Alkali is used in the CH2OH CH2OH
hydrolysis of acetyl derivative. The unused al-
kali is measured by carrying out titration with a
D-ribose D-arabinose
standard acid solution and total number of hy-
droxyl groups (n) can thus be calculated stoi-
chiometrically.
CHO CHO
nCH3COCl nKOH H – C – OH HO – C – H
A  OHn  A  OCOCH3 n   A OH n  nCH3COOK
Polyhydric Acetylderivative HO – C – H HO – C – H
alcohol H – C – OH H – C – OH
CH2OH CH2OH
OH n  A OCOCH3 n  A  OHn  nCH3COOK
D-xylose D-lyxose
(ii) Total number of –OH groups in vicinal position
can be calculated by oxidation with periodic acid CHO CHO CHO CHO
or lead tetra acetate. H – C – OH HO – C – H H – C – OH HO – C – H
H – C – OH H – C – OH HO – C – H HO – C – H
H – C – OH H – C – OH H – C – OH H – C – OH
C OH C O
HlO4 H – C – OH H – C – OH H – C – OH H – C – OH
CH2OH CH2 OH CH2OH CH2OH
or Pb (OCOCH3)4
C OH C O D(+)allose D(+)altrose D(+)glucose D(+)mannose

CHO CHO CHO CHO

9. 0.436g of acetylderivative of a polyhydric alcohol H – C – OH HO – C – H H – C – OH HO – C – H
(molecular mass = 92) require 0.336g KOH for hy- H – C – OH H – C – OH HO – C – H HO – C – H
drolysis. The total numbers of hydroxyl groups (s) in HO – C – H HO – C – H HO – C – H HO – C – H
the alcohol are–– H – C – OH H – C – OH H – C – OH H – C – OH
(A) 1 (B) 2 CH2OH CH2 OH CH2OH CH2OH
D(–)-gulose D(–)-idose D(+)galactose D(+)talose
(C) 3 (D) 4
12. In the giv en Aldoses which can form same
10. A compound with molecular formula C4H10O3 is con- osazone
verted by the action of acetyl chloride to a compound
with molecular weight 190. The original compound has (I) D-glucose (II) D-gulose
(A) one-OH group (B) two-OH groups (III) D-mannose (IV) D-galactose
(C) three-OH groups (D) no-OH group
(A) I and III (B) I, III, IV
11. The ratio of the number of moles of lead tetra ac- (C) I, II (D) III, IV
etate required for the oxidation of 1 mole of glucose
to that of 1 mole of fructose is–– 13. A carbohydrate undergoes the following conversion.

(A) 1 : 1 (B) 2 : 1

(C) 5 : 4 (D) 4 : 3

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Biomolecules and Polymers Aakash Institute
NaCN
H2 /PdBaSO4 CH2OH O
D-Lyxose 
HCl
‘A’  
HO
(C)

H3O
‘B’  ‘C’ O
HO

‘C’ can be CH2OH O

(A) D-Galactose HO
(D) OH
(B) D-Talose HO OH

(C) Both D-galactose and D-Talose 16. Select the correct option.

(D) D-idose CH2OH O

14. Which of the following is correct presentation of HO
(A) Y is H
L(+)-Gulose ? OH
HO OMe
CHO CHO
H – C – OH H – C – OH CH2OH O
HO
(A) HO – C – H (B) HO – C – H (B) Z is OCH3
HO – C – H HO – C – H HO OH
H
HO – C – H H – C – OH
CH2OH CH2OH
CH2OH O

OH
CHO CHO (C) Y is H OH
HO – C – H HO – C – H
OCH3
(C) HO – C – H (D) H – C – OH
H – C – OH HO – C – H
CH2OH O
HO – C – H H – C – OH
HO
CH2OH CH2OH H
(D) Z is
OH
HO OCH3
Paragraph for Question Nos. 15 to 17
Consider the following reversible process for a reaction of 17. Which of the following is positional isomer of -D-
D-glucose. glucose ?

CH2OH
O
+
H
CH2OH O
Y
HO H
+ -D-isomer HO
OH [X] CH OH
3

OH (A)
HO OH
D-glucose
Z HO OCH3
-D-isomer
( or  form)
CH2OH O
15. The structure of intermediate [X] is
HO OCH3

(B)
CH2OH O OH
HO
HO
(A)
HO OH CH2OH OH
(C) HO
OH
CH2OH O O OH

(B) OH
OH CH2OH OH
O (D) HO
OCH3
O OH

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Aakash Institute Biomolecules and Polymers
darkening of bubbles will look like the following :
SECTION-D
Matrix-Match Type X Y Z
This Section D have “match the following” type question.
0 0 0
Question contains two columns, Col-I and Col-II. Match
the entries in Col-I with the entries in Col-II. One or more 1 1 1
entries in Col-I may match with one or more entries in
2 2 2
Col-II.
3 3 3
18. Match the following columns:
4 4 4
Column-I Column–II
5 5 5
CHOH
2 O
(A) HO H (p) -glycoside bonds 6 6 6
HO OH O 7 7 7
8 8 8
CHOH
2 O
OH 9 9 9
HO OH
H

19. Maximum number of carbon atoms in a product

O H
OH obtained by treatment of fructose with conc. HNO3 is
(B) (q) Reducing sugar
HO OH O 20. Primary structure of a protein is given as :
HO
ala, gly, val, phe, leu, Iso.
OH
OH On partial hydrolysis, number of fragments from
H OH the given list that can possibly be obtained is :
O CHOH
2

Leu. phe, gly. val. phe,

(C) O H (r) Forms
CH2OH val. ala. gly, phe. val. gly,
enediol
HO HO intermediate Iso. leu. phe, phe. val. leu,
O
HO phe. leu. Iso
HOCH2 O
HO 21. The total number of compounds among the following
CH2OH which give red ppt. with Fehlings solution: formic
acid, P-chlorobenzaldehyde, maltose, fructose,
HOCH2 OH
HOCH2 sucrose, 2-methylpropanal, paraldehyde, cellulose.
O
HO O
O
(D) OH (s) -glycoside bond 22. Total number of moles of HIO4 consumed per mole
HO
OH HO
OH of the following compound is _____

SECTION-E
HC O CH2OH
Integer Answer Type | |
This section contains Integer type questions. The answer CHOH C
to each of the questions is a single digit integer, ranging | |
CHOH O CHOH
from 0 to 9. The appropriate bubbles below the respective
| | O
question numbers in the ORS have to be darkened. For CHOH CHOH
example, if the correct answers to question numbers X, | |
Y and Z(say) are 6, 0 and 9, respectively, then the correct CH CH
| |
CH2OH CH2OH
  
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Biomolecules and Polymers Aakash Institute

CPP-14
SS JEE(M) &
ADVANCED

ANSWERS

LEVEL-1

1. (C) 2. (B) 3. (D) 4. (A) 5. (D) 6. (B)

7. (C) 8. (A) 9. (C,D) 10. (B,D) 11. (A,B,C,D) 12. (A,C,D)

13. (A,B,C) 14. (C,D) 15. (A,B,C) 16. (A,B,C,D) 17. (A,B,C) 18. (A)

19. (D) 20. (A-q,s,B-s,C-r,s,D-q,r,s) 21. (A-p,q,r,t,B-p,q,s,C-q,r,t,D-p,q,r)

22. (3) 23. (1) 24. (7) 25. (2) 26. (5) 27. (3)

LEVEL-2

1. (B) 2. (A) 3. (A) 4. (C) 5. (D) 6. (A,B,C)

7. (A,C) 8. (B,C,D) 9. (C) 10. (B) 11. (A) 12. (A)

13. (C) 14. (C) 15. (A) 16. (D) 17. (C)

18. (A-p,q,r,B-p,C-p,s,D-p,q,r) 19. (5) 20. (5) 21. (4) 22. (3)

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