Paper Class Paper No 23

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wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2024 wf.daia;=

General Certificate of Education (Adv. Level) Examination, August 2024

ridhk úoHdj I meh 1 ñ' 30

Chemistry I 1 Hours 30 Minutes

ie,lsh hq;=hs
} fuu m%Yak m;%h msgq 06 lska hqla; fõ.
} ish¨ u m%Yakj,g W;a;r imhkak.
} .Kl hka;% Ndú;hg bv fokq fkd,efì
} 1 isg 35 f;la jQ tla tla m%Yakh ioyd (1), (2), (3), (4), (5) hk ms<s;=rej,ska ksjerÈ fyda b;du;a .e<fmk ms<;
s =r
f;dardf.k" th W;a;r m;%fha msgqmi ±lafjk Wmfoia mßÈ l;srhla (×) fhdod olajkak'

id¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1

wej.dâfrda ksh;h" NA = 6.022 × 1023 mol-1

01. my; i|yka ms<s;=re w;ßka olajd we;s ld¾hhg iïnkaO úoHd{hska ±lafjk ms<s;r
= f;darkak'

fm%df
a gdakh iuia:dksl kshqfg%dak úlsrKYS,S;djh

(1) w¾kiaÜ ro¾*â fnd;a yd fíl¾ w¾kiaÜ ro¾*â fykaß fnlr,a

(2) fÊ'fÊ' f;dïika ú,shï weiag¾ka fÊïia peâúla fnd;a iy fíl¾

(3) fÊïia peâúla we,anÜ whskaiaghska w¾kiaÜ ro¾*â fnd;a iy fíl¾
(4) w¾kiaÜ ro¾*â ú,shï weiag¾kaa fÊïia peâúla fykaß fnlr,a
(5) fÊ'fÊ' f;dïika ú,shï weiag¾ka fÊ'fÊ' f;dïika we,anÜ whskaiaghska

02. S2O32- , SO42- iy SO32- hk wekdhkj, uOH mrudKqj jgd bf,lafg%dak hq., cHdñ;sh ms<s fj,ska"
(1) p;=ia;,Sh " p;=ia;,Sh " ;s%hdk;s msróv
(2) p;=ia;,Sh " p;=ia;,Sh " p;=ia;,Sh
(3) ;,Sh iup;=r i% " ;,Sh iup;=ri% " ;,Sh ;s%fldaKdldr
(4) ;s%hdk;s msróv " p;=ia;,Sh " p;=ia;,Sh
(5) ;,Sh iup;=ri% " p;=ia;,Sh " p;=ia;,Sh

03. yhsv%ckaj, whkSlrK Yla;sh 1310 kJmol-1 fõ kï ,hsudka fY%aKsfhys wNsidÍ iSudjg wod, ixLHd;h jkqfha"
(1) 32.83×1016 Hz (2) 3.283×1015 Hz (3) 2.383×1015 Hz
15 15
(4) 42.83×10 Hz (5) 32.83×10 Hz

04. a , b , c , d f,i kï lr we;s ldnka mrudKq j, úoHq;a iDK;djh wdfrdaykh jk ksjerÈ wkqms<sfj< olajd we;af;a"

(1) a<b<c<d (2) b<c<d<a (3) b<d<c<a (4) b<d<a<c (5) d<c<b<a

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 23 Paper Class
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05. tla;rd uQ,øjHhl uq,a wkqhd; whkSlrK Yla;s y; (kJmol-1) ms<sfj,ska fufiah'
1018 , 1909 , 2916 , 4969 , 6275 , 21300 , 24403
fï uQ,øjHh wh;a jkafka wdj¾;s;d j.=fõ l=u k ldKavhgo@
(1) 14 (2) 15 (3) 16 (4) 17 (5) 2

06. tal NdIañl wï, folla jk Lactic (HC3H5O3) yd Caproic(HC6H11O2) 0.1g l ñY%Khla msfkdama;,Ska o¾Ylh
yuqfõ§ WÑ; mßÈ NaOH(aq) iu. wkqudmkh lrk ,§' wka; ,laIfha§ 0.05moldm-3 jQ ødjKh 20.4cm3 jeh jqKs'
ñY%Kfha Lactic wï, nr wkqj m%;sY;h ñka l=ula úh yelso@ (C = 12, O = 16, H = 1)
(1) 28% (2) 42% (3) 52% (4) 58% (5) 64%

07. oDV n÷kl óf;aka (CH4) yd tf;aka (C2H6) jdhq ñY%Kh uq¿ mSv kh 0.53atm fõ' iïmQ¾K oykh isÿùug muKla
wjYH m%udKhg Tlaisc ka jdhqj we;=¿ lrkq ,efí' oykfhka miq n÷fka wvx.= jkqfha CO2(g) yd H2O(g)muKla jk
w;r tajdfha uq¿ mSvkh 2.2atm fõ' wdrïNl ñY%Kfha jQ CH4 ujq, Nd.h jkqfha" ^WIa K;aj h ksh ;j mj;S hehs
i,lkak'&
(1) 0.37 (2) 0.43 (3) 0.48 (4) 0.54 (5) 0.58

08. ixY=oaO Na2CO3 yd MgCO3 wvx.= ñY%Khls ka 5g la ksh; nrl ,efnk ;=re ;Èka r;a lf<a h' ñY%Kfha wjidk
ialkaOh 2.8g la úh' ñY%Kfha Na2CO3 j, ialkaO m%;sY;h jkqfha"
(Na=23 , Mg=24 , C=12 , O=16)
Na2CO3(s) ;dm úfhdackh fkdfõ' MgCO3(s) MgO(s) + CO2(g)
(1) 84% (2) 42% (3) 16% (4) 25% (5) 50%

09. uQ,øjHl mj;sk úhq.au bf,lafg%dakhla i`oyd lafjdkagï wxl n yd l ie,l+ úg my; iuankaO;djhg tl`. jk
ixhqc;d ljpfha bf,lafg%dak mj;sk uQ,øjH jkqfha"
(n+l)2 - n2=l4
(1) Cr (2) S (3) P (4) N (5) Cl

10. yhsv%cka úfudapk j¾Kdj,sfha tla fY%aKshlg wod< m<uq f¾Ld y;frys Yla;s w.hla my; rEmfha ±lafjk w;r
úoHq;a pqïNl j¾Kdj,sfha wod< l,dmj,g ysñ jk ;rx. wdhdu mrdi olajd we;'

by;ska i`oyka f¾Ld fY%aKsh wh;a jkqfha"

(1) ,hsudka fY%aKshgh' (2) ndu¾ fY%aKshgh' (3) mdIka fY%AKshgh'
(4) n%elÜ fY%aKshgh' (5) *kaâ fY%K
a shgh'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 23
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11. jdKsc yhsfv%dlaf,dßla wï, fnda;,hlska wï,h 25ml la f.k ialkaOh uek.;a úg ialkaOh 25g ls' th c,fha
Èhlr 100ml f;la c,fhka ;kql lr bka 25ml la jeämqr Mg málen,s iu`. m%;sl%shd l< úg iïu; WIaK;aj
mSvk ;;a;aj hgf;a § msg jQ H2 jdhq fõ mßudj 851.2ml úh' jdKsc yhsfv% dlaf,daßla wï,fha m%;sY; ixY=oaO;djh
jkqfha" ^iïu; WIaK;aj yd mSvk hgf;a jdhqjl ujq,sl mßudj 22.4dm3) (H=1, Cl=35.5, Mg=24)
Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)
(1) 40% (2) 43% (3) 74% (4) 85% (5) 44%

12. Fe2+ whkfha mj;sk bf,lafg%dk

a j,ska j, Yla;sh jeäu bf,lafg%dakhl lafjdkagï wxl l=,lh ksjerÈj ±lafjkafka"
(1) (3, 1, 1, + ) (2) (4, 0, 0, - ) (3) (3, 2, -2, + )
(4) (4, 3, 0, + ) (5) (3, 3, -2, + )

13. my; i`oyka ms<s;=re w;ßka ish¨u úfYaI i;=j tla mrudKqjl fyda úhq.au bf,lafg%dakhla ne.ska mj;skqfha"
(1) NO, N2O, ClO2, NO2 (2) NO, NO2, O2-, NO2+
(3) NO, NO2, ClO2, O2- (4) ClO2, N2O4, ClO-, NO
(5) O2-, NO, NO2, ClO-

14. ødjKhl mj;sk Xn+ legdhkh NdIañl udOHfha H2O2 u`.ska TZlrKh ù XO42- whkh idohs' Xn+ : H2O2 wkqmd;h
2 : 3 fõ' n ys w.h jkqfha"
(1) 1 (2) 2 (3) 3 (4) 4 (5) 7

15. wixY=oaO K2Cr2O7 3.00g la c,h 250cm3 ys Èhlr idod.;a ødjKfhka 25.00cm3 la i,a*h
s qßla wï,fhka wdï,sl lr
Bg jeämqr KI ødjKhla tl;= lrk ,§'
fuys§ msgjk whäka 0.2moldm-3 Na2S2O3 ødjKhla iu`. wkqudmkh lrk ,§' fuys§ m%;sl%shdj iïmQ¾K ùug
Na2S2O3 ødjK 30.0cm3 jeh úh'
2Na2S2O3 + I2 2NaI + Na2S4O6
K2Cr2O7 idïm,fha m%;sY; ixY=oaO;dj jkqfha" (K = 39, O = 16, Cr=52)
(1) 80.2 (2) 82.8 (3) 82.5 (4) 88.6 (5) 98.0

16. tla;rd NaCl ødjKhl >k;ajh dgcm-3 fõ' tys wvx.= NaCl ys ialkaOh wkqj m%;Y
s ;h w% iy wvx.= NaCl
ys ujq,sl ialkaOh Mgmol kï ødjKfha NaCl ys ixhq;sh ppm j,ska iy ødjKfha idkaøKh moldm-3 j,ska jkqfha"
-1

(1) 104w, (2) dw ´ 104, (3) ,

(4) 106dM, (5) 106dM,

17. Na2CO3. 10H2O 1.43 ´ 10-3g l ialkaOhla wdi%e; c,h 250.0cm3 l Èhlr idod.;a ødjKfha >k;ajh 1.2gcm-3
fõ' ødjKfha Na+ ys ixhq;sh ppm(mgkg-1) j,ska jkqfha"
(Na = 23, C = 12
(1) 47.67 (2) 0.3825 (3) 4.77 (4) 0.767 (5) 76.67

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 23 Paper Class
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18. msiagkhla fh¥ ;dm ia:dhS nÿkl A2(g) hï ujq, m%udKhla wvx.= fõ' msiagkh ksYap, úg ndysr jdhqf.da,sh mSvkh
1×105 o" n÷fka mßudj 30dm3 o n÷fka WIaK;ajh 400K fõ' tu A2 jdhq fjka yß wvla 800K § 2A njg
m;ajQfhakï" msiagkh ;,a¨ ù kej; ksYap, jk fudfydf;a n÷fka mßudj fldmuKo@
(1) 90cm3 (2) 45dm3 (3) 50dm3 (4) 45cm3 (5) 90dm3

19. my; tajdhska i;H jkaafka"

(1) AgI j,g jvd AgF j, whksl ,laIK jeä fõ'
(2) KI j,g jvd LiI j, iyixhqc ,laIK wvq fõ'
(3) Ca2+ whkj, O%eùlrK n,h Be2+ j, O%eùlrK n,hg jvd jeäfõ'
(4) 2 jk ldKavfha uQ,øjH j, khsfÜ%g j, úfhdack WIaK;ajh ldKavfha my,g h;au wvqfõ'
(5) 2 jk ldKavfha my,g h;au ldnfkag j, úfhdack WIaK;aj úp,khg " wekdhkfha O%ejKYS,S;djh
úp,kh fya;=fõ'

20. 42
Mo iïnkaOfhka my; l=uk j.ka;sh ksjerÈ fõo@
(1) tys WoaÈ.xY ^fldaKsl .uH;d& lafjdkagï wxlh (l), l = 0 jk bf,lafg%dak 10 la we;'
(2) tys WoaÈ.xY ^fldaKsl .uH;d& lafjdkagï wxlh (l), l = 2 jk bf,lafg%dak 9la we;'
(3) tys pqï Nl lafjdkagï wxlh (ml), ml = 2 jk bf,lafg%dak 3la we;'
(4) tys m%Odk lafjdkagï wxlh (n), n = 5 iy fldaKl
s .uH;d lafjdkagï wxlh (l), l = 0 jk bf,lafg%dk
a 2 la we;'
(5) tys wjidk m%Odk Yla;s uÜgfï bf,lafg%dak 6la mj;s'

21. wmøjH jYfhka je,s ñY% jQ fidaähï laf,darhsâ idïm,hlska 2.5g la jeämqr MnO2 yd idkaø H2SO4 iuÕ r;a l< úg
msgjk jdhqj c,h u; tl;= lr.kakd ,§' 270C § yd 101 kPa ys § tl;= lr.;a laf,daÍka mßudj 400cm3 la jk w;r tys
§ msg jQ jdhq mßudfjka 10% la c,fha Èh úh' fidaähï laf,darhsâ idïm,fha m%;Y
s ; ixY=oO
a ;djh jkafka"
wod< m%;l %s dj( MnO2 + 2NaCl + 3H2SO4 ® MnSO4 + 2NaHSO4 + Cl2 + 2H2O
s h
(1) 94.76% (2) 90.8% (3) 29.67% (4) 84.24% (5) 8.12%

— m%Yak wxl 22 isg 28 f;la m%Yak j,g Wmfoia

wxl 22 isg 28 f;la jq tla tla m%Yakfha olajd we;s (a), (b), (c) iy (d) hk m%;sp dr 4 w;frka tlla fyda jeä
ixLHdjla fyda ksjerÈh. ksjerÈ m%;spdrh$ m%;spdr ljf¾±hs f;dard .kak.
(a) iy (b) muKla ksjerÈ kï (1) u; o
(b) iy (c) muKla ksjerÈ kï (2) u; o
(c) iy (d) muKla ksjerÈ kï (3) u; o
(d) iy (a) muKla ksjerÈ kï (4) u; o
fjk;a m%;sp dr ixLHdjla fyda ixfhdac khla fyda ksjerÈ kï (5) u; o W;a;r m;%fhys ±lafjk mßÈ ,l=Kq lrkak.
by; Wmfoia iïmsKavkh
(1) (2) (3) (4) (5)
(a) yd (b) (b) yd (c) (c) yd (d) (d) yd (a) fjk;a m%;spdr ixLHdjla fyda
muKla ksjerÈh. muKla ksjerÈh. muKla ksjerÈh. muKla ksjerÈh. ixfhdackhla fyda ksjerÈh.

22. laIdßh udOHhl § ld¾ñl wm c,h OCl- iu. msßhï lsÍfuka" wm c,fhys wvx.= ihkhsâ whk my; i|yka
iólrKhg wkqj N2 iy ldnfkaÜ whkj,g mßj¾;kh fõ'
2CN-+ 5OCl- + 2OH- 2CO2- + N + 5Cl- + H O
3 2 2

fuu m%;sls%hdj iïnkaOj my; i|yka l=uk m%ldYh ^h& ksjerÈ o@

(a) OCl- ys Tlaisckaj, TlaislrK wxlh 0 isg -2 olaj d fjkia fõ'
(b) OCl- ys Cl j, TZlrK wxlh +1 is g -1 olaj d fjkia fõ'
(c) CN- ys N j, TZlrK wxlh -3 isg 0 olaj d fjkia fõ'
(d) CN- ys C j, TZlrK wxlh +2 isg +4 olaj d fjkia fõ'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 23
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23. my; ±lafjk wKqj iïnkaOfhka isÿlr we;s m%ldY w;ßka i;H jkqfha l=uk m%ldYh o@

(a) ish¿u mrudKq tlu ;,hl mj;s' (b) ish¿u C - H nkaOk j,g tlu nkaOk È.la mj;s'
(c) C-C nkaOk È. wdldrhg jeäfõ' (d) C mrudKq mfyka ;=kla mukla tlu f¾Ldjl mj;S'

24. my; m%ldY j,ska wi;H m%ldYh$m%ldY jkafka

(a) ,kavka nkaOkhla wKqj, ;djld,sl we;sjk oaúO%ej u.ska we;s úh yel'
(b) wKqjl wjldYSh úysÿu wkqj wKq w;r we;sj k ,kavka n,j, m%N,;djh fjkia úh yel'
(c) ´kEu jdhq jl wKq w;r ,kav ka n, mj;S'
(d) ,kavka n, j, m%n,;djh wKqfõ ialkaOh u; muKla r|d mj;S'

25. my; i|yka l=uk m%ldYh $ m%ldY i;H fõ o@

(a) 24
Cr ys bf,lafg%daksl úkHdih [Ar] 3d5 4s1 fõ'
(b) 29
Cu ys bf,lafg%dak 14 l N%uKh tl wdldrhla jk w;r wfkla 15 ys N%uKh ;j;a wdldrhla fõ'
(c) 7
N ys bf,lafg%%dak 7 la we;s ksid bka bf,lafg%dak y;rl N%uKh iudk jk w;r 3 l N%uKh Bg m%;súreoaO fõ'
(d) Cu2+ ys úhq.au bf,lafg%dak fkdue;'

26. nkaOk w;r fldaKh jeäjk wdldrhg ms< sfh, lr we;af;a"

(a) H2O < NH3 < CH4 (b) NH3 < BeCl2 < CO2
(c) H2O < BF3 < C2H2 (d) NH3 < CCl4 < NO3

27. f,dayuh uQ,øjH iïnkaOfhka i;H jkafka ñka ljrlao@

(a) whksl ixfhda. iE§fï§ iEuúgu f,dayuh uQ,øjHhla iyNd.s fõ'
(b) f,dayuh uQ,øjH j, wjidk Yla;s uÜgfï we;s bf,lafg%dk
a ixLHdj muKla tys fN!;sl ,laIK yd ne§ mj;s'
(c) f,dayh ;=, ksoyia bf,lafg%dak c,dYhla mej;Su" tys úoHq;a ikakdhl;djh flfrys n,mdhs'
(d) f,day whkfha m%udKh jeäjk úg f,dayl nkaOk m%N,;djh jeä fõ'

28. fok ,o WIaK;ajhl § A yd B jdhq j, >k;ajh ms<sfj,ska dA yd dB o ujq,sl ialkaOh ms<sfj,ska MA yd MB fõ'
dA = 3dB o MB = 4MA o kï tu jdhq iïnkaO my; m%ldYj,ska i;H jkafka l=uk m%ldYh $ m%ldYhkao@
(a) B ys mSvkh PB =
(b) A yd B w;r mSvk wkqmd;h PA : PB = 1:2 fõ'
(c) A ys mSvkh PA =
(d) A ys ujq,sl ia lkaOh MA =

— m%Yak wxl 29 isg 35 f;la m%Yak j,g Wmfoia

wxl 29 isg 35 f;la jQ tla tla m%Yakh i|yd m%ldY fol ne.ska bÈßm;a lr we;' tu m%ldY hq.<hg fyd¢ka u
.e<fmkqfha my; j.=fjys ±lafjk (1) , (2) , (3) , (4) iy (5) hk m%;p
s drj,ska ljr m%;p
s drh ±hs f;dard W;a;r m;%fhys
WÑ; f,i ,l=Kq lrka k'

m%;spdrh m<uqjeks m%ldYh fojeks m%ldYh

(1) i;H h' i;H jk w;r" m<uq jekak ksjerÈ j myod fohs'
(2) i;H h' i;H jk kuq;a m<uqjekak ksjerÈ j myod fkdfohs'
(3) i;H h' wi;H h'
(4) wi;H h' i;H h'
(5) wi;H h' wi;H h'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 23 Paper Class
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m<uq m%ldYh fojk m%ldYh

29. PCl+4 whkfha iïm%hq la; oaúO%ej >Q¾Kh Y+kH fõ' PCl+4 ys§ P jgd yevh p;=ia;,Sh jk w;r whkh iuñ;sl
fõ'

30. N2O4 wKqfõ iEu N - O nkaOkhlau os.ska iudk fõ' N2O4 wKqj i`oyd iïm%hqla; jHQy 3la muKla ks¾udKh
l< yelsh'

31. wdï,sl udOHfha idkaøKh okakd KMnO4 ødjKhla KMnO4 ødjKhla ìhqfrÜgqjg f.k wdï,sl udOHfha
u.ska Na2C2O4 ødjKh 25cm la wkqudmkh lsÍfï
3 Na2C2O4 iu`. wkqudmkfha § KMnO4 ødjKh Mn2+ olajd
§ KMnO4 ia jhx o¾Ylhla f,i l%shd lrhs' TlaisyrKh jk neúka m%;l
s %shdj wjika jQ miq wkqudmkfha
wka; ,CIHfha § oï meyeh wj¾Kjkq ±lsh yelsh'

32. Cl ys m%:u bf,lafg%dakSlrK Yla;sh Ok w.hla fõ' wdj¾;hla Èf.a ol=Kg m%:u bf,lafg%dk
a l
S rK Yla;sh Okj
wvq fõ'

33. b;d by< mSvkj,§ muKla ;d;aúl jdhq i|yd pd,aia b;d my< mSvkj,§ jdhq wKqj, wka;¾ wKql n, ÿ¾j,
kshuh fhÈh yelsh' fõ'

34. lef;dav lsrk úoHq;a lafIa;h

% l § lafIa;%hg ,ïNlj lef;dav lsrK wxY= j,g wdfrdamKhla ke;'
W;al%uKh fõ'

35. O%eùh nkaOk iys; iEu wKqjlu oaú O%ej >Q¾Khla oaúO%ej >Q¾Kh" nkaOkj, wjldYSh úys§u u; r|d mj;S'
olakg ,efí'

pß; Èidkdhl B.Sc. Engineering (Hon's)