SECTION -A NCERT Based MCQs Correct order of ionic size is [NCERT Pg. 88] () S@>PS>cr — @ Cr>PS>se @ Cr>s2>Ps @) PS>s2> cr Element having highest ‘st ionisation energy in the following is INCERT Pg. 83] (1) Na (2) Mg @A (4) He Select the element of highest electronegativity in the following INCERT Pg. 92] au @) Be @) B @N Select the element of positive electron. gai enthalpy INCERT Pg. 91] au (2) Na @P @) He Electrovalency of Alin Al,O, compotind is INCERT Pg. 93] m2 @3 @4 @ 5 Select the species of highest electronegativity INCERT Pg. 92] (1) Na @) Nae (@) New (@) Nar ‘An element, X has electronic configuration of 2, 8, 8, 2. The incorrect statement(s) about this element isfare INCERT Pg. 83] (i) Itbetongs to 10th group of the periodic table, (ii) It has 20 neutrons. (ii) ts ionisation energy is higher than the element placed left to this in the same period but lower than the element placed just above it (1) Only «) 2) Both (i) & (i) @) Both (ii) & (ii) (4) Both (i) & (ii) 10. 11 12. 13, 14, The symbol of element with atomic number 105 is INCERT Pg, 81] (1) up (2) Unp (3) Uw (4) Una Which of the following elements show properties that are characteristic of both metals and nonsmetals? INCERT Pg. 95] (1) Mg Qs @) (4) Si Which of the following pairs of elements do not follow Newland's law of octave? [NCERT Pg. 75] (1) Nak 2) Ca, Sr @Fol Os ‘An element with atomic number 34 belongs to INCERT Pg, 85] (1), block (2) piock (@)) dbI0ck (4) block The electronic configuration for the various elements are given below a tstastops b. Astastap%ast 6. Ast2stopiast dd. 1s%28%2p8 From the above configurations, the correct order of their ionisation energy will be [NCERT Pg. 89] (i) bNa>k = Electropositive character (@) N>P>Sb>As — — Electron affinity (4) Sn>Ge>Si>C — Nonmetallic character SECTION -B Objective Type Questions Modern periodic law is (1) The physical and chemical properties of the elements are periodic function of their atomic numbers. (2) The physical and chemical properties of the elements depend upon the energy of the electrons (3) The physical and chemical properties of the elements are periodic function of their atomic, (4) The physical and chemical properties of the elements are periodic function of their density 2. The element with atomic number 31 belongs to which group and period respectively? (1) 13,4 @ 14,3 @) 4,13 4) 4,8 3. Which of the following is correct order of metalic character for Si, Be, Mg, Na and P? (1) P Be > Mg > Be > P (4) Na > Si> Mg > Be > P. 4, Beryllium shows diagonal relationship with (1) Mg 2) Al @ ui @) si 5. Ce (z= 58) is a member of (1) ssblock elements (2) p-block elements (3) Glock elements (4) block elements 6. The least electronegative element has the following ‘electronic configuration (1) nstnp® (2) ns?np* ()nstnp? (4) nsinp® 7. Which of the following is a representative element? () 2 @ sr (3) Cu (4) Fe 8 10. 11 12. 43, 14, 16. NEET ‘The elements whose atoms have three outer most shells incomplete are called (1) seblock elements (2) prblock elements (3) block elements (4) d-block elements The ionic radii of S-* and Te are 1.84 and 2.21 A respectively. The ionic radii of Se~ is (1) 1.83 (2) 222A (3) 454 (4) 202A When a neutral atom is converted into a cation its (1) Atomic weight increases (2) Atomic weight decreases (3) Size increases (@) Size decreases The correct order of ionic radi is (1) Fe> Fev > Few Q) O->O>0% 3) Fela (4) Allofthese Ff the following, which one is a correct statement? ()oTonie radius of ametal is same as its atomic radius (2) The ionicradius of a metal is greater than its atomic radius (9) The‘ atomic radius of a non-metal is more than its ionic radius (4) The ionic radius of a metal is less than its atomic radius Consider the iso-electronic series : Kt, S*, Cr and Ca®*. The radii of the ions decreases as (1) Catt > KP > ch > Se @) Ch >st>K*> cat (@) S*>Cr>Kr > Cae (8) Kt> Cat > St > cr The element having lowest first ionization potential among Sr, As, S and F is sr (2) As es () F The element having least difference in the values of first and second ionization potential is (1) Na Qk @) ui (4) Mg ‘The first four ionization energy values of an element are 191, 578, 872 and 5962 kcal. The number of valence electrons in the element is qay4 (2) 2 @) 3 (4 ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456NEET Classification of Elements and Periodicity in Properties 67 417. lonization potential of Na would be numerically the 28. The electronegatvity of Beis almost same as same as wal @) Mg (1) Electron affinity of Nat (@) Na @ ui (2) Electronegatvity of Na* 29, Which element has lowest electron affinity? (8) Electron affinity of Ne “yo as (4) lonization potential of Mig @ se (4) To 18. Which of the following configuration is associated 39, The correct order regarding second ionisation with biggest jump between 2nd and 3rd 1E? potentials (1) 19? 2s? 2p? 2) 13? 2? apf 3st () N>c>B>Be (8) 19? 2s? 2p 3s? (4) 15? 25% 2p! @) N>C>Be>B 19. The process requiring absorption of energy is (@) N>B>C>Be (1) FoF @) HoH (@) Be>N>c>B @) clocr (4) O+0— 20, Which of the following element has the lowest first SECTION -c ionisation potential? : ; i) Na ene Previous Years Questions @) cs @ 1 1, Match the oxide given in column A with its property 21. If you are given Avogadro's number of atoms of a sicentin cokirm B) INEET-2019 (Odisha)} ‘gas °X If half of the atoms are converted into X'(a) Column. Column-B by energy AH. The IE of X per mole is, 0 re Neural (1) 28H @ aH @ Ai, () Basic * (ii) NO. (c) Acidic aH Ww c.0, (@) Amphoteric (@) aH oN Xs hn ‘Which of the following options has all correct pairs? 22. Which of the following is most acidic in nature? MAOH GHA), (a), (WHC) (1) So, @) co 2) Wie), iA, (ive) (3) Al,O, (4) P08, ie ' m 23. Which of the following has positive electron gain 8) (Ae), (0), (ipa), (w){A) enthalpy? 4) (4A), A), (10), (We) aa @s 2. For the second period elements the correct (3) He ac increasing order of first ionisation enthalpy is 24, Electronegativiy ofthe folowing elements increases INEET2019] in the order () ON SLE @nsicP (1) Li (increasing ionic size) (8) B< C F-> 0% (3) OF > F> Nat (4) AP > Mig > N= 7. Identity the wrong statement in the following [AIPMT (Pretims)-2012} (1) Atomic radius of the elements increases as oné moves down the first group ofthe periodic table (2) Atomic radius ofthe elements decreasés as one moves across from lef to rightin the 24 period ofthe periodic table {@) Amongst isoelectronic species, smaller the positive charge on the cation, smalls the tonio radius (4) Amongst isoelectronic species, greater the negative charge on the anion, largeris the ionio radius 8, Whatis the value of electron gain enthalpy of Nat if ITE, ofNa=5.1 eV? [AIPMT (Mains)-2011] (1) +255 ev @ +02ev @) -S1ev (4) -1o2ev 9. Which of the following represents the correct order of increasing electron gain enthalpy with negative sign for the elements O, S, F and Cl? [AIPMT (Prelims)-2010] @) OK' > S#> Cr @) cr>st>Cat>kt (8) St > Cr> Kt > Ca® (4) Kr> Gat > Cra se ‘Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is [AIPMT (Mains)-2010] (1) Mg Alt > Ale (1) Al> Al > al (8) 2745 kJ (4) 514.0kd @) AP > Al'> Al 23. The sizeof jonic species is correctly given in the (3) Al = Al’ = Al order (4) Allof these (1) Nat > Mg’ > C7 > site 22. The first {onization potentials (€V) of Nand O (2) Nat > Mg’? > Sit* > Ch7 respectively are (@) OFT > Sitt> Mg'?> Nat (1) 8.29, 8.29 (4) CI'? > Na* > Mg*? > Sit* 2) 11.32, 11.32 30, Match the following, regarding nature of the oxides @) 8.29, 11.32 Column Column (4) 11.32, 8.21 a HO @ Basic 23. Correct order of | ionization potential among b.Na,O i) Amphoteric elements Be, B, C, N, O is ©. 20 (i) Acidic (1) B Barig) 2) Balg) > Ba’(g) + e- (8) Bas) > Ba‘(g) + &- (4) Ba(g) -» Ba’2(g) + 26- ff 5, Maximum number of elements which can be placed in 7 period (1) 18 12. (2) 32 3) 80 (4) 86 6. Which of the given statements Is correct? (1) The elements in which electrons are filed in 4f 49, orbitals called lanthanoids. 2) The properties of elements are periodic function of atomic number, @) Non metallic elements are less in number than metallic elements in periodic table (@) All are correct The formula of oxide of metal whose successive ionisation enthalpies are 10, 20, 50, 2000 kJ molt respectively (1) MO @) MO, @) Mo (4) Mo, ‘Among group 16 elements, electron gain enthalpy of which is least negative? (1) 0 as @) Se @) Te Electronic configuration of element with atomic number 117 will be (1) [RnIB 6a 752 7p (2) [RnIB¢" 752 7p? Gc (9) RnITs® 7p* 6a"? sf? (4) [RnIB# 6° 75? 7p \n atomic volume curve of Lothar Meyer ascending portions are occupied by (1) Alkali metals @) Alkaline earth metals {@) Transition elements (4) Halogens CO and NO are (1) Neutral oxides (2) Acidic oxides 9) Basic oxides (4) Neutral and basic respectively Which of the following sequences contains atomic number of only representative elements? (1) 3, 33, 53, 87 (2) 2, 10, 22, 36 (3) 7, 17, 25, 37, 48 (4) 10, 35, 87, 88 Which of the following set of elements does not belong to the same group, but resemble in. properties? (1) Liand Mg (2) Be and Al (3) Band Si (4) Allof these ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456NEET Classification of Elements and Periodicity in Properties 71 14, Symbol of eloment with atomic number 102 is () 170 (1) Unb @ 1724 @) Und (9) 179 (3) Uub (@ 901 (4) Uon 21, 18? 2s? 2p? 3s" represents 18. s electrons in Ne are same in number as (1) Excited state of neon (1) p electrons in O (2) Ground state of fluorine (2) delectrons in Fe** (8) Excited state of fluorine (8) delectrons in Cr (4) Excited state of sodium (4) Allof these 22. Long form of periodic table consists of 16. When a neutral atom is converted to cation, there (1) 7 periods and 18 groups is (2) 6 periods and 7 groups (1) A decrease in size @) 7 groups and 18 periods gr @) An increase in size (4) 7 periods and 8 groups (@) A decrease in atomic number 23, First ionisation energy of Mg is (4) A decrease in mass number (1) More than Al 17. The number of naturally occurring block elemerits, (2)‘Less than Al that are diamagnetic is agit an (4) Zero @s 24, Most electropositive among halogens is 87 OF @s @ cl 18, Nature of three oxides formed by A, B and Cis (3) br acid, basic and amphoteric. Give the sequence of a their electronegativity 4 4) A>C>B 25, Incorrect electronic configuration ts represented by o (At. No.: Gd: 64, W: 74, Pd: 46, Mo: 42) @) A>B>c a (a) Gd=[Xe] 4f75a'6s? @) C>B>A . (b) W = [Xe] 4f"4, Sat, 6s? @) B>Arc (c) Pd = [Kr] 40°, Sst 19, The order of screening effect of electrons of s, p, ; d and f orbitals of a given shell of an atom on its (a) Mo = [Kr] 4¢°, 5 outer shell electrons is (1) (@) only () se paar (2) (b) and (c) only Q) f>d>p>s (3) (c) only @) pedes>f (4) (@) & (6) only () f> posed 26, If each orbital contain 3 electrons then total 20. First IE of Li is 5.4 eV atom and electron affinity ‘number of elements present in 5" period will be of Cl is 3.61 eV atom. What is AH for the following reaction (in eV atom-1)? Li(g) + Clg) > Lir(g) + cr(@) (Resulting ions do not combine) (1) 18 (2) a (3) 32 4) 6 ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-4762345672 Classification of Elements and Periodicity in Properties NEET 27. (a) Be and Mg are alkaline earth metal 32, (0) K* have larger radii than Ca®* () All d-block elements are transition elements (@) H® ion have larger size than F® Incorrect statements is/are (1) @). (6) &(@) 2 w)&@ 33. @ @a@ @ @ae 28, (a) Cly > Fy > Bry > |, + Bond-dissociation energy (0) S>Se> Te > 0 > Electron gain enthalpy ) 4. (©) ‘Ne >F>N>0- First ionisation energy (@) CH = CH > CH, = CH, > CH, - CH, > Electronegatvity of carbon The correct statements are (1) (@) & (a) only 2) (@) & (b) only (8) (©), (c) & (d) only 36. (4) (a), (b) & (c) only 29. Electron gain enthalpy of F is -328 kJ/mol, lonisation energy of F* ion will be (IE, off Fis: +1683 kuimol) (1) +1683 kJ/mol (2) +328 kJ/mol ve (2) -1628 kumol (4) +164 ksimol 30. Correct statement(s) among the following istare 37 (1) Second electron gain enthalpy is always endothermic 2) Electronegativity is the property of bonding atoms (3) A,0, and BeO are amphoteric oxide (@) All are correct 31. Set representing the correct order of second ionisation potential is (1) K> Ca> Ba @) Ca>Ba>k (@) Ba>K>Ca (4) K>Ba>Ca Correct order of 3 ionisation energy of B, C, N and O will be (1) O>N>C>B @ O>C>N>B (3) N>O>C>B () C>N>O>8 Ca** is isoelectronic with (1) ge (2) ke (3) Ar (4) Nat ‘An atom of an element has electronic configuration 2, 8, 1, Which of the following statement is correct? (1) The valency of element is 7 (2) The element exists as a triatomic molecule (3) The element is metalioid (@) The element forms basic oxide The symbol of element with atomic number Z = 109 (1) Unp (2) Uns (3) Uno (4) Une Pd has exceptional electronic configuration of 4d"? 5sP. It belong to (1) 4 petiod, group 14. (2) 5 period, group 10 (G3) 6" period, group 9 (4) 3 period, group 16 All elements in the third period have (1) Three complete shells (2) Three complete subshells, (@) Three valence electrons (4) Three electrons less than octet Which one of the following represents a d-block element? (1) [Rn] 60°? 732 7p? (2) el 4f Sat 65? (3) Xe] 4f* 5a" 6s? (4) eo] Sa" 6s? ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456NEET Classification of Elements and Periodicity in Properties 73 39. Which of the following set of atomic number 46, In which of the following pais the radii of second represents only representative elements? species is greater than that of fist? (1) 55, 12, 48, 53 (1) K, Ca Q) 13, 23, 54, 83 (2) H. He @) 3, 33, 53, 87 (3) Mg’, Mg? 4) 22, 33, 55, 66 (6) 0% 0 40. Which of the following pairs of atomic numbers ‘The successive ionization energies for element X is represents elements belonging tothe same group? gen bee (1) 11 and 20 IE, 250 kJ mot @) 12 and 30 IE, 820 kJ mob" 13 and 31 2 ; oe IE, +1100 ki mot an @ IE, 1400 kJ mot? 41. Total number of elements present in Sth period of modern pevies E Find out the number of valence electrons for the te element X oe 3 (3) 18 a4 4) 32 Op 42. The electronegativty follows the order “4 () F>0>Cl>Br 48, Ity@U are given Avogadro's number of atoms of a >Cl>Br> gas X. If haif of the atoms are converted into Xio* @) F>ci>Br>0 by energy AH. The IE of X is @) O>F>Cl>Br wcersose yy 43. The correct order of shielding effect of s, p, d and . f orbitals is ® 2Na () s>p>a>r aH @) sp Hg"{g) +e (2) Hg!) —> Hg"(g) + e (3) Hg(g)— Hg'(g) + e- (4) Hga*(g)—> Hg" + &- ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-476234567A Classification of Elements and Periodicity in Properties 51 52 53. 56. NEET The energy required to conver all atoms present in 4.2 g magnesium to Mg” ions if IE, and IE, of magnesium are 120 kJ mol and 240 kJ mol~* respectively (1) 18 ks 2) 36 kK (3) 360 kJ (4) 24 ks ‘The process requiring absorption of energy is 0) For Q HoH @) cloct @) O40 The least electronegative element has the following ‘electronic configuration (1) nstnp® (2) nstnpt (8) ns?np> (4) nstnp® Which of the following is correct order of metalic character for Si, Be, Mg, Na and P? (1) P Be > Mg > Be > P (4) Na> Si> Mg > Be > P With which of the following electronic configuration, an atom has the lowest ionization enthalpy? (1) 18? 2s? 2p? (2) 1s? 2s? 2p? 3s! (@) 1s? 2s? apt (4) 18? 282 2p 56. 87 59, 60, The electronic configuration having maximum, difference in first and second ionization energies is (1) 15? 2s? 2p8 3s? 2) 15? 2s? 2p8 3s? 3p! (3) 1s? 2s? 2p8 3s? 3p? (4) 18? 2s? 2p 3s" The electronic configurations of the elements X, Y, Z and J are given below. Which element has the highest metallic character () X=2,8,4 ) ¥=2.8.8 (3) 2=2,8,8,1 ( 4=2,8.8,7 Eloment of highest second ionization energy is (t) Na @ Al @) Mg (ey8i Which of the. following electronic configuration represent element of highest ionisation potential is (1) xe] 6s? (2) 18d] 4s 3a"? Gy 182 (4) [Rn] 7s? 6d" 5f* Which of the following has maximum charge density? (1) Se @ @ oO (4) Te* ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456