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Aldehyde Ketone
Aldehyde Ketone
UNIT EXAMINATION
27- 08 - 2023 CHEMISTRY 151
LT24B/TP/JM/H/151/(OFF) Aldehydes and Ketones
Time: 1 hr Mark : 100
1) C6 H 5 CO Cl 2) C6 H 5 Cl
3) C6 H 5 CO CH3 4) C6 H5 CH 3
LT24B/TP/JM/H/151 2 Chemistry
1) CH 2 CH CH 2 OH 2) CH3 COCH 3
CHO
50% KOH
13. Predict the product in the given reaction:
Cl
1) + 2) +
Cl Cl OH OH
3) + 4) +
Cl Cl Cl OH
1) CH3COONa
2) CH3COOH
3) CH3CHO
OH
LT24B/TP/JM/H/151 3 Chemistry
16. How many structural isomeric carbonyl compounds are possible for a compound with MF C5H10O?
1) 4 2) 5 3) 7 4) 6
17. The catalyst used in Rosenmund’s reduction is
1) HgSO4 2) Pd/BaSO4
3) Anhydrous AlCl3 4) Anhydrous ZnCl2
18. Less reactivity of ketone towards nucleophilic additions is due to
1) +I effect decrease positive charge on carbonyl carbon atom
2) Steric effect of two bulky alkyl groups
3) sp2 hybridised carbon atom of carbonyl group
4) Both (1) and (2)
19. The most appropriate reagent to distinguish between acetaldehyde and formaldehyde is
1) Fehling’s solution
2) Tollen’s reagent
3) Schiff’s reagent
4) Iodine in presence of base
20. Identify A in the following reaction
i) dil. NaOH
O ii )
A
1)
OH
2)
O
3)
OH
4)
O O
LT24B/TP/JM/H/151 4 Chemistry
[For each question enter the correct integer value. Rounded off to the nearest integer if the
answer is decimal. Eg: If the answer is 25.67, rounded off to 26. If the answer is 9.35, rounded
off to 9. If the answer is 0.75, rounded off to 1. If the answer is 0.45, rounded off to 0.
21. Total No. of isomeric product obtained when a mixture of acetaldehyde and acetone is treated with
hydroxylamine
24. How many of the following will give positive haloform reaction
O OH
O
O O CH3
C
CH C CH3
CH3C CH2 C OEt
CH3
CH3 C
25. Number of aldols formed when a mixture of ethanal and propanal treated with dil.NaOH will be ..........
TEST ID
UNIT EXAMINATION
27- 08 - 2023 CHEMISTRY 151
LT24B/TP/JM/H/151/(OFF) Aldehydes and Ketones
1. 2 C = O + H2NOH C = NOH
CH3 CH3
C 2H5ONa
NH 2 NH 2 C = NNH2 CH2
3. 2 A is acetone, CH3COCH3
CH 3 CH3
4. 4 Carbonyl compound form crystalline addition product with NaHSO3, which on treatment with
dilute acid or alkali regenerates the carbonyl compound.
5. 3 Gattermann K och reaction; C6H6 + CO + HCl Anhy.AlCl
3 C 6 H 5 CHO HCl
6. 3 R C N SnCl
2 / HCl
RCH NH H
2 O/ H
RCHO NH 3
7. 1
8. 2
9. 3
10. 3
11. 3 Benzaldehyde having resonance stabalisation
12. 2
13. 3
14. 1
30% H2SO4 NaOH CH3 CH CH2 CHO
CH CH CH3CHO
15. 4 HgSO4 Aldol condensation
OH
16. 3
17. 2
18. 4 +I and steric effect decreases reactivity of carbonyl group
19. 4 Haloform reaction
20. 2
21. 3
22. 7
23. 4
O O
24. 4 CH3C CH2 C OEt will not give positive haloform reaction due to presence of active
methylene group
25. 4