ishnan
1. R. Gurumurthy, K. Sathiyanarayanan, and M. Gop:
Unt. J. Chem. Kinet., 24, 953 (1992)] studied the oxidation of Rate x 10*(M/s) qx 1M) Cy X 10%)
several phenylmercaptoacetates (A) by chloramine-B (B) in 05767 10 10.00
aqueous cthanol media 1.2788 1s 4st} 10.00
CgHs-S-CH,CO-OC3Hs + C,HsSO,NHC1 + H,0 2.3162 20 10.00.
5.24q 30 10.00
iy 14.5155 50 10.00
CeHls-$-CH,CO-0C,H, + C,H5SO,NH, + HCL 204126 60 10.00
28.0147 70 10.00
The following
pH of ea. 6.5.
a0 i900
> 200
300
ed 70
11.25
1500
i730
2000
r=k UIC for dat wing eons
Y= qe ° n(n ae
Ne ogee
InialnkeBalscu, by liway vegvesion
v.68 iN Pa
Sik Cey fhe hc
\u To alae & BelnCa
by Vito wagvess fea= — 0,06!
To Fog Ky
ke = Ke a
k -0;5 (S442. 8.D. Furrow [Int. J. Chem. Kinet
ied the kinetics of the hydroxy i
(B) in aqueous solution:
14, 927-932 (1982)] stud-
ination of 2-butenoic acid
21, +B +10; +H* +2H,0 5¢
where C is CH, CH(OH)CHICOOH.
(a) Furrow used absorbance measurements to monitor the
concentration of I, as a function of time for an experiment
in which the initial concentrations of I,, B, 10;, and H*
were 1.98 x 104, 0.10, 0.025, and 0.10M, respectively.
If the rate expression is of the form
r= k(l,)"(B)"(0;)(H")!
Time 1, x10
(5) (M)
0 1,98
35 1.94
96 1.84
232 1.68
339 1.56
588 1.28
824 1.06
1060 0.856
1290 0.650
1530 0.479
1760 0.350
2000 0.250
2250 0.145
2500 0.063
2750 0.017
where the various orders are either integers or half-
integers, use the following data to determine the order
of this reaction with respect to 1, and the corresponding
value of the pseudo-mth-order rate constant. What
assumptions must be made to arrive at numerical values
of these parameters?