Fiber-reinforced rubber hose

Abstract

<P>PROBLEM TO BE SOLVED: To provide a fiber-reinforced rubber hose having excellent adhesiveness of

an ethylene-propylene rubber and fiber, and suitable for a brake oil hose of automobile. <P>SOLUTION: This
fiber-reinforced hose has a fiber-reinforcing layer composed of a polyester fiber cord and placed between an
inner rubber layer and an outer rubber layer at least one of which is composed of an ethylene-propylene rubber.
The polyester fiber cord is produced by applying a treating agent containing a resorcinol-formaldehyde-rubber
latex (RFL), a blocked isocyanate compound and a compound produced by the cocondensation of p-
chlorophenol and resorcinol with formaldehyde to a fiber cord produced by twisting a polyethylene naphthalate
fiber treated with a polyepoxide compound or applying the polyepoxide compound to a twisted polyethylene
naphthalate fiber. <P>COPYRIGHT: (C)2005,JPO&NCIPI
JP2004316027A
Japan
Download PDF Find Prior Art Similar
Other languages
Japanese
Inventor
Yoshiji Suzuki
芳史 鈴木
Hirosuke Watanabe
博佐 渡邊

Worldwide applications
2003 JP

Application JP2003112540A events

2003-04-17

Application filed by Teijin Techno Products Ltd, 帝人テクノプロダクツ株式会社

2003-04-17

Priority to JP2003112540A

2004-11-11

Publication of JP2004316027A

2010-04-28

Application granted

2010-04-28

Publication of JP4456825B2

Status

Active

2023-04-17

Anticipated expiration
Info
Cited by (4)
Legal events
Similar documents
Priority and Related Applications
External links
Espacenet
Global Dossier
Discuss

Description

[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a fiber-reinforced rubber hose that is a composite of fibers and rubber. More
specifically, even if α-olefin / non-conjugated diene copolymer rubber such as ethylene propylene rubber
(EPDM) is used, it has excellent adhesion between fiber and rubber, and is particularly suitable as a high
pressure rubber hose for oil brakes in automobiles. The present invention relates to a fiber reinforced rubber hose
that can be used in the present invention.
[0002]
[Prior art]
Conventionally, polyester fibers typified by polyethylene terephthalate fibers are widely used as rubber
reinforcing fibers for tires, hoses, belts and the like because of their relatively high strength and elastic modulus.
However, in recent years, the environment and conditions of use of the hose itself have become more severe, and
there has been a demand for reinforcing fibers with higher strength, higher elastic modulus, and higher heat
resistance, and rubber has better chemical resistance and heat resistance. Ethylene propylene rubber has been
used.
[0003]
For example, in a fiber reinforced rubber hose having a reinforcing layer composed of polyethylene naphthalate
fiber having higher strength, higher elastic modulus, and higher heat resistance than polyethylene terephthalate
fiber, for example, on the inner rubber layer disposed in the innermost layer, A first reinforcing layer made of
phthalate fibers is disposed, and an outer rubber layer for protecting the reinforcing layer is disposed thereon.
Alternatively, a first reinforcing layer made of polyethylene naphthalate fiber is disposed on the inner rubber
layer disposed in the innermost layer, and a second reinforcing layer is disposed through an intermediate rubber
layer. An outer rubber layer is provided for protection. And in the case of oil brake hoses, usually, ethylene
propylene rubber (EPDM) or ethylene propylene rubber blended with chloroprene rubber (CR) or styrene
butadiene rubber (SBR) as the inner rubber layer and outer rubber layer. Used rubber.
[0004]
However, since polyethylene naphthalate fiber and ethylene propylene rubber are both poor in reactivity, there is
a problem that adhesion between the fiber and the rubber is very difficult.
[0005]
In order to eliminate such adhesion problems, polyester fiber cords previously treated with a treatment
containing an epoxy compound are treated with a treatment containing a resorcin / formalin / polybutadiene latex
(RFL), a blocked isocyanate compound and a chlorophenol compound. A method has been proposed (Japanese
Patent Laid-Open No. 11-286875). However, in general, polybutadiene latex has a small molecular weight and is
easily emulsified, so that good adhesiveness is easily obtained, but it has a problem in processability. That is,
when handling a polyester fiber cord that has been subjected to an adhesive treatment, there is a problem in that
adhesive scum tends to accumulate on a guide or the like through which the fiber cord passes. When the scum of
the scum is significant, the scum is peeled off and mixed into the processing cord, and the accumulated scum
needs to be frequently cleaned and removed to reduce the quality of the rubber hose obtained. This is a problem
in process management.
[0006]
[Patent Document 1]
Japanese Patent Laid-Open No. 11-286875 [0007]
[Problems to be solved by the invention]
The present invention has been made against the background of the above circumstances, and the object thereof
is a fiber that is excellent in adhesiveness between an ethylene-propylene rubber and a fiber and that can be
suitably used for an oil brake hose of an automobile. The object is to provide a reinforced rubber hose.
[0008]

2
[Means for Solving the Problems]
According to the study by the present inventors, the above object is as follows: "At least one of the inner rubber
layer and the outer rubber layer is composed of ethylene propylene-based rubber, and the inner rubber layer and
the outer rubber layer are interposed between the inner rubber layer and the outer rubber layer. In a fiber
reinforced rubber hose having a reinforcing layer made of a polyester fiber cord made of polyethylene
naphthalate, the polyester fiber cord is twisted to polyethylene naphthalate fiber to which a polyepoxide
compound is previously attached, or twisted to polyethylene naphthalate fiber Treatment containing a resorcin /
formalin / rubber latex (RFL), a blocked isocyanate compound, and a compound obtained by co-condensation of
parachlorophenol and resorcin with formaldehyde to a fiber cord to which a polyepoxide compound has been
applied Poly with attached agent Fiber reinforced rubber hose characterized in that it is a ester fiber cord. It has
been found that can be achieved by ".
[0009]
In this case, the rubber latex is a styrene-butadiene-vinylpyridine terpolymer latex and / or a chloroprene latex,
and the proportion of the chloroprene latex is preferably 80% by weight or less based on the total rubber latex
weight.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described in detail.
The polyethylene naphthalate referred to in the present invention may contain 90% by mole or more of ethylene-
2,6-naphthalate units, and may be a polymer containing an appropriate third component in a proportion of 10%
by mole or less. . In general, polyethylene-2,6-naphthalate is synthesized by polycondensation of naphthalene-
2,6-dicarboxylic acid or an ester-forming derivative thereof with ethylene glycol in the presence of a catalyst
under appropriate reaction conditions. At this time, if one or more appropriate third components are added before
the completion of the polymerization of polyethylene-2,6-naphthalate, a copolyester is synthesized.
[0011]
Suitable third components include: (a) compounds having two ester-forming functional groups; for example,
aliphatic dicarboxylic acids such as succinic acid, adipic acid, sebacic acid and dimer acid; and alicyclic rings
such as hexahydroterephthalic acid Aromatic dicarboxylic acids; aromatic dicarboxylic acids such as phthalic
acid, isophthalic acid, naphthalene-2,7-dicarboxylic acid, diphenyldicarboxylic acid; diphenyl ether dicarboxylic
acid, diphenylsulfone dicarboxylic acid, diphenoxyethanedicarboxylic acid, 3,5-dicarboxyl Dicarboxylic acids
such as sodium benzenesulfonate; oxycarboxylic acids such as glycolic acid, p-oxybenzoic acid, p-
oxyethoxybenzoic acid; trimethylene glycol, diethylene glycol, tetramethylene glycol, hexamethylene glycol,
neopentylene Coal, p-xylylene glycol, 1,4-cyclohexanedimethanol, bisphenol A, p, p'-dihydroxydiphenylsulfone,
1,4-bis (β-hydroxyethoxy) benzene, 2,2-bis (p-β -Hydroxyethoxyphenyl) propane and the like.
[0012]
Needless to say, the polyethylene naphthalate may contain a matting agent such as titanium dioxide and a
stabilizer such as phosphoric acid, phosphorous acid and esters thereof.
[0013]
The intrinsic viscosity of polyethylene naphthalate is preferably 0.65 or more, particularly preferably in the range
of 0.7 to 1.0. The intrinsic viscosity here is a value obtained from the viscosity measured at 35 ° C. by dissolving
the polymer or undrawn yarn before drawing in a mixed solvent of phenol and orthodichlorobenzene (volume
ratio 6: 4). When the intrinsic viscosity is less than 0.65, it is difficult to obtain high-strength, high-toughness
fibers required as reinforcing fibers. On the other hand, if it exceeds 1.0, the spinning process tends to be
defective, which is not practically desirable.
[0014]
These polyethylene naphthalate fibers are not particularly limited in terms of the single fiber fineness, the
number of filaments, the cross-sectional shape, the fiber properties, the fine structure, etc., and may be
appropriately selected and set according to the purpose.
[0015]
The polyester fiber cord according to the present invention is a filament yarn made of the above polyethylene
naphthalate fiber, a spun yarn, or a fiber cord made of a filament yarn and a spun yarn, which is subjected to an
adhesion treatment described later. What is necessary is just to set a yarn fineness, the number of twists, and the
number of combined yarns suitably according to a use.
[0016]
Here, the adhesion treatment is firstly performed by twisting the polyethylene naphthalate fiber into a cord, for
example, applying a polyepoxy compound in the yarn-making stage, or twisting the fiber cord into a cord and
then polyepoxy compound Is granted.
[0017]
The polyepoxide compound used here is preferably a compound containing 0.2 g equivalent or more per
molecule of at least two epoxy groups per molecule. For example, reaction products of polyhydric alcohols such
as ethylene glycol, glycerol, sorbitol, pentaerythritol, polyethylene glycol and halogen-containing epoxides such
as epichlorohydrin, resorcin / bis (4-hydroxyphenyl) dimethylmethane, phenol / formaldehyde resin Reaction
3
products of polyhydric phenols such as resorcin / formaldehyde resin and the halogen-containing epoxides,
polyepoxide compounds obtained by oxidizing unsaturated compounds with peracetic acid or hydrogen
peroxide, etc. Examples include 3,4-epoxycyclohexene epoxide, 3,4-epoxycyclohexene methyl-3,4-
epoxycyclohexene carboxylate, bis (3,4-epoxy-6-methyl-cyclohexene. Or the like can be mentioned Rumechiru)
adipate. Among these, a reaction product of a polyhydric alcohol and epichlorohydrin, that is, a polyglycidyl
ether compound of a polyhydric alcohol is preferable because it exhibits excellent performance.
[0018]
Such polyepoxide compounds are usually used as emulsions or solutions. In order to obtain an emulsified
solution or solution, for example, these polyepoxide compounds are dissolved as they are or in a small amount of
a solvent as necessary, and known emulsifiers such as sodium alkylbenzenesulfonate, dioctylsulfosuccinate
sodium salt, nonylphenolethylene Emulsified or dissolved using an oxide adduct or the like.
[0019]
When a treating agent containing such a polyepoxy compound is applied to polyethylene naphthalate fiber in
advance and then twisted into a fiber cord, the treating agent is usually applied together with an oil agent in a
yarn making process. Under the present circumstances, it is preferable that the adhesion amount of this
polyepoxide compound shall be the range of 0.1 to 5.0 weight%. When the adhesion amount of the polyepoxide
compound is less than 0.1% by weight, the effect of the polyepoxide compound is not sufficiently exhibited, and
there is a possibility that satisfactory adhesiveness with the target rubber cannot be obtained. On the other hand,
when the adhesion amount of the polyepoxide compound exceeds 5.0% by weight, the fiber becomes very hard
and not only the process stability of the yarn production is lowered but also the permeability of the treatment
agent in the process described later is lowered. As a result, the adhesive performance is often lowered, which is
not preferable.
[0020]
On the other hand, when a polyepoxy compound is applied after twisting a polyethylene naphthalate fiber, it is
preferable to use a blocked polyisocyanate compound together with a treatment agent containing the polyepoxy
compound. Here, the blocked polyisocyanate compound is an adduct of a polyisocyanate compound and a
blocking agent, which releases a block component by heating to produce an active polyisocyanate compound.
Examples of the polyisocyanate compound include polyisocyanates such as tolylene diisocyanate,
metaphenylene diisocyanate, diphenylmethane diisocyanate, hexamethylene diisocyanate, polymethylene
polyphenyl isocyanate, triphenylmethane triisocyanate, or two or more of these polyisocyanates and active
hydrogen atoms. For example, trimethylolpropane, pentaerythritol, polyalkylene glycol, and the like having a
terminal isocyanate group-containing compound obtained by reacting an isocyanate group (—NCO) and a
hydroxyl group (—OH) in a molar ratio exceeding 1. And monohydric alcohol adduct polyisocyanate. In
particular, aromatic polyisocyanates such as triresin isocyanate, diphenylmethane diisocyanate, and
polymethylene polyphenyl isocyanate exhibit preferable performance.
[0021]
Examples of the blocking agent include phenols such as phenol, thiophenol, cresol and resorcinol, aromatic
secondary amines such as diphenylamine and xylidine, lactams such as phthalimides, caprolactam and
valerolactam, acetoxime and methyl ethyl ketone. Examples include oximes such as oxime and cyclohexane
oxime, and acidic sodium sulfite.
[0022]
Such blocked isocyanate compounds are usually used as emulsions, dispersions or solutions. In order to obtain
an emulsified liquid, a dispersion liquid or a solution, for example, these blocked isocyanate compounds are
dissolved as they are or dissolved in a small amount of a solvent as required, and known emulsifiers such as
sodium alkylbenzene sulfonate, dioctyl sulfosuccinate It is emulsified, dispersed or dissolved using sodium salt,
nonylphenol ethylene oxide adduct and the like.
[0023]
The blending ratio of the polyepoxide compound and the block polyisocyanate compound is not particularly
limited, but usually 2 to 5 parts by weight of the block polyisocyanate compound is blended with respect to 1
part by weight of the polyepoxide compound. The concentration of the polyepoxy compound in the treatment
agent is 3.0% by weight or less, preferably 0.5 to 2.0% by weight in view of handling.
[0024]
Thus, in the case where a treating agent in which a polyepoxide compound and a broccated polyisocyanate
compound are blended is added to a twisted fiber cord, the amount of adhesion is 1.0 to 8.0% by weight with
respect to the fiber weight, Preferably it is set as the range of 3.0 to 5.0 weight%.
[0025]
In the present invention, resorcin / formalin / rubber latex (RFL), the same blocked isocyanate compound as
described above, and parachlorophenol and resorcin are co-condensed with formaldehyde to the fiber cord to
which the polyepoxide compound is added. A treatment agent containing a compound (special chlorophenol
compound) is applied. Here, the resorcin / formalin / rubber latex is generally referred to as RFL, and a product
obtained by mixing and aging an initial condensate (RF) of resorcin, formaldehyde and rubber latex (L) is used.
The molar ratio of the resorcin to formaldehyde is in the range of 1: 0.1 to 1: 8, preferably 1: 0.5 to 1: 5,
4
particularly 1: 1 to 1: 3. The mixing ratio of RF and L varies depending on the content of the special
chlorophenol compound described later, but the solid content ratio of the total amount of RF and special
chlorophenol compound to the rubber latex is 1: 1 to 15, preferably 1. : It is desirable to be in the range of 3-12.
The rubber latex used here is a styrene-butadiene-vinylpyridine terpolymer latex and / or a chloroprene rubber
latex, and the proportion of the chloroprene rubber latex is 80% by weight or less based on the total rubber latex
weight. In particular, it is a mixture of both latexes, and the mixing weight ratio thereof is preferably in the range
of styrene-butadiene-vinylpyridine terpolymer latex / chloroprene rubber latex latex = 2/8 to 8/2.
[0026]
Next, examples of the blocked isocyanate compound that can be used in combination with the RFL include the
aforementioned compounds. If the amount used is too large or too small, it becomes difficult to obtain sufficient
adhesiveness. Therefore, the amount is in the range of 2 to 40% by weight, preferably 5 to 35% by weight based
on the RFL solid content weight. Is appropriate.
[0027]
Moreover, the special chlorophenol compound mix | blended with said RFL is a compound which co-condensed
parachlorophenol and resorcin with formaldehyde, for example, Nagase Kasei Co., Ltd. product: "Denabond" is
used preferably. The blending ratio of the special chlorophenol compound and RF slightly changes depending on
the blend of the rubber to be adhered, but is in the range of 1 / 1.5 to 1 / 2.5 (RF / special phenol compound:
weight ratio). It is preferable to do this.
[0028]
The adhesion amount of such a treatment agent is preferably in the range of 0.5 to 6.0% by weight, preferably
1.0 to 5.0% by weight with respect to the fiber weight.
[0029]
In the present invention, when the polyepoxy compound-containing treatment agent is applied to the twisted
polyethylene naphthalate fiber cord, it is dried at 100 to 180 ° C. for 1 to 5 minutes, preferably 1 to 3 minutes,
and then 180 to Heat treatment is performed at a temperature of 260 ° C., preferably 220 to 250 ° C. for 0.5 to
5.0 minutes, preferably 1 to 3 minutes. Subsequently, when applying the treatment agent containing RFL,
blocked isocyanate compound and special phenol compound, drying is performed at 130 to 250 ° C. for 0.5 to 5
minutes, preferably 1 to 3 minutes, and then 150 to 260 ° C., The heat treatment is preferably performed at a
temperature of 220 to 250 ° C. for 0.5 to 5.0 minutes, preferably 1 to 3 minutes. If the heat treatment temperature
is too low, adhesion to rubber tends to be insufficient, while if the temperature is too high, the treatment agent
itself will be cured, making the fiber hard and causing the cord to deteriorate, making it difficult to put it into
practical use. .
[0030]
The treated polyester fiber cord is disposed on a known technique, for example, on an inner rubber layer made of
tube rubber at a predetermined angle so as to have a predetermined density by a blader. If necessary, an
interlayer rubber sheet is further disposed thereon, and then the polyester fiber cord is again disposed a
predetermined number of times by a blader. Finally, after an outer rubber layer made of cover rubber for
protecting the outer fiber cord is disposed, the fiber reinforced rubber hose is steam vulcanized in, for example, a
steam vulcanizer. The fiber cords may be arranged in a spiral structure. The vulcanization may be steam
vulcanization or a press method using a mold.
[0031]
In the present invention, in order to improve weather resistance and chemical resistance, such as a hose used in
an engine room of an automobile, particularly a high pressure rubber hose for brake oil, it can be used in an
atmosphere of high temperature and high pressure. In addition, at least one of the inner rubber layer and the outer
rubber layer, preferably the inner rubber layer, the interlayer rubber layer, and the outer rubber layer, need to be
an ethylene propylene copolymer rubber having excellent high temperature characteristics. is there.
[0032]
【Example】
Hereinafter, the present invention will be described more specifically with reference to examples. In addition,
evaluation of the characteristic in an Example was measured in accordance with the following method.
[0033]
<Cord peeling adhesive strength>
Twenty-five fiber cords subjected to adhesion treatment are arranged at intervals of 25.4 mm, embedded in an
ethylene-propylene copolymer (compounded in Table 1) unvulcanized rubber, temperature 150 ° C., pressure
4.91 MPa (50 kg / cm 2 ) Press vulcanize for 30 minutes. Next, the force (N / 25.4 mm) required for peeling the
fiber cord from the rubber is measured.
[0034]
<Scum generation state>
Two pieces of the fiber cord subjected to the adhesion treatment were combined and then braided using a blader.
At this time, the state of the dip residue generated in the vicinity of the guide was visually confirmed. The
symbol “◯” indicates that the scum was generated without any scum and good processability was exhibited, and
the symbol “x” indicates that the scum was generated and adhered to the brader device.
5
[0035]
<Hose adhesive strength>
The vulcanized hose was cut into a 1-inch wide ring according to JIS K 6330-6: 1998 and subjected to a peel
test. The peeling speed was adjusted to 50 mm / min, and the fiber side rubber attachment after peeling was
confirmed. The case with good rubber attachment was indicated by ○, and the case with poor rubber attachment
was indicated by ×.
[0036]
[Examples 1-2, Comparative Examples 1-2]
Polyester compound (trade name: Denacol EX611; manufactured by Nagase Kasei Co., Ltd., sorbitol glycidyl
ether) is obtained by twisting 10T / 10 cm of polyester fiber (manufactured by Teijin Ltd.) with 1110 dtex, 250
filament polyester fiber made of polyethylene naphthalate, A block polyisocyanate compound (trade name: S3;
manufactured by Meisei Chemical Industry Co., Ltd.) mixed in an active ingredient amount ratio of 20:80 is
immersed in a treatment liquid adjusted to a 5% by weight aqueous dispersion and does not sag. The film was
dried at 150 ° C. for 2 minutes under a certain tension, and then heat-treated at 235 ° C. for 1 minute.
[0037]
Next, the treatment cord was immersed in a treatment agent prepared by the following method, and then heat
treatment was performed at 220 ° C. for 1 minute. The obtained adhesion-treated polyester fiber cord had an
adhesion amount of the polyepoxide compound treatment agent of 0.8% by weight and a solid content of the
RFL treatment agent of 1.2% by weight.
[0038]
Preparation of treatment agent To the water added with sodium hydroxide aqueous solution and ammonia
aqueous solution, resorcin-formalin initial condensate (Sumitomo Chemical Co., Ltd., Sumikanol 700S: 65%
aqueous solution) reacted with an acidic catalyst was added and stirred sufficiently to disperse. Let To this,
formalin was added so as to have a resorcin / formalin (R: F) ratio of 1: 2 (molar ratio), mixed uniformly, and
aged at a temperature of 20 ° C. for 2 hours. Next, Nippon 2518FS (manufactured by Nippon Zeon Co., Ltd.,
styrene / butadiene / vinylpyridine terpolymer (Vp) water emulsion) and LT-50 (manufactured by Denki Kagaku
Kogyo Co., Ltd., chloroprene rubber latex (CR): 50% Emulsified) in a predetermined ratio was mixed with the
resorcin / formalin initial condensation dispersion at a solid content ratio (RF / L ratio) of 1: 9 (weight ratio), and
Elastron BN69 (Daiichi Kogyo Seiyaku ( Co., Ltd., diphenylmethane diisocyanate methyl ethyl ketone oxime
block compound: 33% aqueous dispersion) was added to RFL to a solid content ratio of 6: 1 (weight ratio), and
further aged at 20 ° C. for 24 hours. Immediately before fiber treatment use, Denabond (manufactured by Nagase
Kasei Kogyo Co., Ltd., special chlorophenol compound 20% solution) is added so as to be 30% (weight ratio)
relative to the solid content of RFL, and sufficiently stirred to adjust the treatment agent Went. The control of the
viscosity and adhesion amount of the treatment agent was adjusted by adding and diluting water to the treatment
agent.
[0039]
The obtained adhesive-treated polyester fiber cord was bladed on an inner tube rubber made of ethylene
propylene copolymer rubber at an intersecting angle of 108 degrees, and an outer tube rubber made of ethylene
propylene copolymer rubber was placed thereon. The obtained hose was vulcanized in a steam vulcanizer at 150
° C. for 30 minutes to obtain a hose. Table 2 shows the results. The unvulcanized rubber used for the
measurement of the cord peeling adhesive strength is as shown in Table 1.
[0040]
When the obtained hose of the present invention (Examples 1 and 2) was used for a brake oil hose of an
automobile, it could be used stably for a long time.
[0041]
[Table 1]
[0042]
[Table 2]
[0043]
【The invention's effect】
The polyester fiber cord used in the fiber-reinforced rubber hose of the present invention is first activated on the
fiber surface by a treating agent containing a polyepoxy compound, and then resorcin / formalin / nitrile rubber
latex (RFL), blocked isocyanate compound, and Since a treatment agent containing a compound obtained by co-
condensing parachlorophenol and resorcin with formaldehyde is provided, it exhibits excellent adhesion
performance with ethylene-propylene copolymer rubber. Therefore, the fiber reinforced rubber hose of the
present invention having a reinforcing layer made of the fiber cord is excellent in heat resistance and
adhesiveness, and is also suitable for fields requiring high characteristics such as high pressure rubber hoses for
automobile oil brakes. It is a very useful thing that can be used.

Claims (3)

6
Hide Dependent

1. A fiber reinforced rubber hose in which at least one of the inner rubber layer and the outer rubber
layer is made of ethylene propylene rubber, and has a polyester fiber cord reinforcing layer made of
polyethylene naphthalate between the inner rubber layer and the outer rubber layer In this case, the
polyester fiber cord is formed by twisting a polyethylene naphthalate fiber to which a polyepoxide
compound has been previously attached, or by applying a twist to the polyethylene naphthalate fiber
and then attaching a polyepoxide compound to the fiber cord to which the polyepoxide compound is
attached. Fiber reinforcement comprising a polyester fiber cord to which a treatment agent
containing a marine rubber latex (RFL), a blocked isocyanate compound, and a compound obtained
by co-condensing parachlorophenol and resorcin with formaldehyde is attached. Muhosu.
2. The fiber-reinforced rubber hose according to claim 1, wherein the rubber latex is a styrene-
butadiene-vinylpyridine terpolymer latex and / or a chloroprene latex, and the proportion of
the chloroprene latex is 80% by weight or less based on the weight of the total rubber latex. .
3. A rubber hose for automobile brake oil, comprising the fiber-