ANALISIS DATA

1. Standarisasi larutan standar KMnO4

Diketahui :
BM H2C2O4.2H2O = 126 mg/mmol
W H2C2O4.2H2O = 0,65 g = 650 mg
V1 = 5,7 mL
V2 = 5,8 mL
V3 = 6 mL
V rata-rata = 5,83 mL
Ditanyakan : N KMnO4 . . . ?
Penyelesaian :
W 25
x2 x
N KMnO4 = BM 100
V (mL)
650 mg 25
x2 x
= 126 mg/mmol 100
5 , 8 3 mL
5 ,1 5 mmol x 2 x 0 , 25
=
5 , 8 3 mL
= 0,441 mmol/mL
= 0,441 N
2. Penentuan campuran Ferro (Fe2+) dan Ferri (Fe3+)
a. Kadar ferro
Diketahui:
N KMnO4 = 0,441 N
BM Fe = 56 mg/mmol
V1 = 2,9 mL
V2 = 0,6 mL
V3 = 4,9 mL
V rata-rata = 2,8 mL
Ditanyakan : Kadar Ferro . . ?
 Penyelesaian :
V 1 ( mL ) x N KMnO 4 x BM Fe
Kadar Ferro =
25 mL
mmol
2 ,8 mL x 0 , 441 x 56 mg/mmol
= mL
25 mL
= 2,75 mg/mL
b. Kadar Ferri
Diketahui :
N KMnO4 = 0,441 N
V rata-rata (V1) = 2,8 mL
V1 = 2,2 mL
V2 = 2,4 mL
V3 = 9,0 mL
V rata-rata (V2) = 4,5 mL
BM Fe = 56 mg/mmol
Ditanyakan : Kadar ferri . . . ?
Penyelesaian:
( V 2−V 1 ) x N KMnO4 x BMFe
Kadar ferri =
25 mL
mmol mg
( 4 ,5−2 ,8 ) mLx 0 , 441 x 56
= mL mmol
25 mL
= 1,67 mg/mL