VELAMMAL IIT & NEET ACADEMY

XII IIT RPTM – 16 PHYSCIS DATE: 17.12.22

TOPIC: KTG and Thermodynamics
SECTION - I
1. Suppose ideal gas equation follows VP3 = constant. Initial
temperature and volume of the gas are T and V respectively. If
gas expand to 27V then its temperature will be come
(a) T (b) 9T (c) 27T (d) T / 9
2. A gas is enclosed in a closed pot. On keeping this pot in a train
moving with high speed, the temperature of the gas
(a) Will increase
(b) Will decrease
(c) Will remain the same
(d) Will change according to the nature of the gas
3. Two spherical vessel of equal volume, are connected by a n arrow
tube. The apparatus contains an ideal gas at one atmosphere
and 300K. Now if one vessel is immersed in a bath of constant
temperature 600K and the other in a bath of constant
temperature 300K. Then the common pressure will be

A B

4 4 3
(a) 1 atm (b) atm (c) atm (d) atm
5 3 4
4. At what temperature, the mean kinetic energy of O2 will be the
same for H 2 molecules at – 73°C
(a) 127°C (b) 527°C (c) – 73°C (d) – 173°C
5. If the r.m.s. velocity of a gas at a given temperature (Kelvin scale)
is 300 m/sec. What will be the r.m.s. velocity of a gas having
twice the molecular weight and half the temperature on Kelvin
scale =
(a) 300 m/sec (b) 600 m/sec
(c) 75 m/sec (d) 150 m/sec
CP
6. The ratio of two specific heats of CO is
CV
(a) 1.33 (b) 1.40 (c) 1.29 (d) 1.66
7. A partition divides a container having insulated walls into two
compartments I and II. the same gas fills the two compartments.
The ratio of the number of molecules in compartments I and II is
(a) 1 : 6
(b) 6 : 1 P, V, T 2P, 2V, T

(c) 4 : 1 I II
(d) 1 : 4
C
8. Considering the gases to be ideal, the value of   P for a
CV
gaseous mixture consisting of = 3 moles of carbon dioxide and 2
moles of oxygen will be ( O2  1.4,  CO2  1.3)
(a) 1.37 (b) 1.34 (c) 1.55 (d) 1.63
9. A jar has a mixture of hydrogen and oxygen gas in the ratio of 1 :
5. The ratio of mean kinetic energies of hydrogen and oxygen
molecules is
(a) 1 : 16 (b) 1 : 4 (c) 1 : 5 (d) 1 : 1
10. Graph between volume and temperature for a gas is shown in
1
figure. If   volume coefficient of gas = per °C, then what is
273
the volume of gas at a temperature of 819°C
(a) 1103 m3 (b) 2 103 m3 (c) 3 103 m3 (d) 1103 m3
11. The P-V diagram of 2 gm of helium gas for a certain process
A  B is shown in the figure. what is the heat given to the gas
during the process A  B P

(a) 4PVo o
2P0
B

(b) 6PV
o o
P0
(c) 4.5PV
o o
A

(d) 2PV
o o V0 2V0 V

12. A certain mass of gas at 273 K is expanded to 81 times its

volume under adiabatic condition. If   1.25 for the gas, then its
final temperature is
(a) – 235°C (b) – 182°C (c) – 91°C (d) 0°C
13. In the case of diatomic gas, the heat given at constant pressure
is that part of energy which is used for the expansion of gas, is
2 3 2 5
(a) (b) (c) (d)
5 7 7 7
14. A tyre filled with air (27 C, and 2 atm) bursts, then what is
o

temperature of air (  1.5)

(a) 33o C (b) 0o C (c) 27o C (d) 240o C
15. P-V diagram of an ideal gas is as shown in figure. Work done by
the gas in process ABCD is
P
(a) 4 PV
0 0
C D
2P0
(b) 2 PV
0 0
P0
B A
(c) 3PV
0 0 V
V0 2V0 3V0
(d) PV
0 0

16. An engineer claims to have made an engine delivering 10 kW

power with fuel consumption of 1g s 1 . The calorific value of fuel
is 2k cal/g. His claim
(a) Is non-valid (b) Is valid
(c) Depends on engine (d) Depends on load
17. An ideal gas heat engine operates in a Carnot cycle between 27°C
and 127°C. It absorbs 6 kcal at the higher temperature. The
amount of heat (in kcal) converted into work is equal to
(a) 3.5 (b) 1.6 (c) 1.2 (d) 4.8
18. An ideal gas (  1.5) is expanded adiabatically. How many times
has the gas to be expanded to reduce the root mean square
velocity of molecules 2.0 times
(a) 4 times (b) 16 times (c) 8 times (d) 2 times
19. Heat is supplied to a diatomic gas at constant pressure. The
ratio of Q: U : W is
(a) 5 : 3 : 2 (b) 5 : 2 : 3 (c) 7 : 5 : 2 (d) 7 : 2 : 5
20. A cylinder of mass 1kg is given heat of 20000 J at atmospheric
pressure. If initially temperature of cylinder is 20°C, then work
done by the cylinder will be (Given that Specific heat of cylinder
= 400 J kg–1, Coefficient of volume expansion = 9  10–5 °C–1,
Atmospheric pressure = 105 N/m2 and density of cylinder 9000
kg/m3)
(a) 0.02 J (b) 0.05 J (c) 0.08 J (d) 0.1 J
SECTION - II
NUMERICALS:
21. One mole of a monoatomic ideal gas is mixed with one mole of a
diatomic ideal gas. The molar specific heat of the mixture at
constant volume is ___ R
22. When the temperature of a gas is raised from 27°C to 90°C, the
percentage increase in the r.m.s. velocity of the molecules will
be______%
23. The volume of a gas at pressure 21104 N / m2 and temperature
27°C is 83 litres. If R = 8.3 J/mol/K, then the quantity of gas in
gm-mole will be ______
24. The pressure and temperature of an ideal gas in a closed vessel
1
are 720 kPa and 40C respectively. If th of the gas is released
4
from the vessel and the temperature of the remaining gas is
raised to 353C, the final pressure of the gas is ___ kPa
25. One mole of an ideal monatomic gas requires 210 J heat to raise
the temperature by 10 K, when heated at constant temperature.
If the same gas is heated at constant volume to raise the
temperature by 10 K then heat required is____J
26. If a Carnot’s engine functions at source temperature 127°C and
at sink temperature 87°C, what is its efficiency______%
27. A gas expands adiabatically at constant pressure such that its
1
temperature T  , the value of CP / CV of gas is____
V
28. An ideal gas heat engine operates in a Carnot cycle between 27°C
and 127°C. It absorbs 6 kcal at the higher temperature. The
amount of heat (in kcal) converted into work is equal to ______
29. A gas expands with temperature according to the relation
V  kT 2/3. What is the work done when the temperature changes
by 30o C ____ R
30. A gas undergoes a change of state during which 100 J of heat is
supplied to it and it does 20 J of work. The system is brought
back to its original state through a process during which 20 J of
heat is released by the gas. The work done by the gas in the
second process is ____J
 VELAMMAL IIT & NEET ACADEMY
XII IIT RPTM – 16 CHEMISTRY DATE: 17.12.22

SECTION - I
31. Among the given compounds, the most susceptible to
nucleophilic attack at the carbonyl carbon is:
(1) MeCOCl (2) MeCHO
(3) MeCOOMe (4) MeCOOCOMe
32. Under Wolf Kishner reduction conditions, the conversion which
may be brought about is ?
(1) Benzaldehyde into Benzyl alcohol
(2) Cyclohexanol into Cyclohexane
(3) Cyclohexanone into Cyclohexanol
(4) Benzophenone into Diphenylmethane
33. An organic compound C3H6O does not give a precipitate with
2,4-dinitrophenyl hydrazine reagent and also does not react with
metallic sodium it could be :
(1) CH3–CH2–CHO (2) CH3–COCH3
(3) CH2=CH–CH2–OH (4) CH2=CH–OCH3
34.

35. Among the following compounds which one will react with
acetone to give a product that contains carbon-nitrogen double
bond ?

36.
37.

38.

39.

40.

41.

42.

43.
44.

45.

46.

47. An amine C3H9 N reacts with Hinsberg’s reagent to give a product

which is insoluble in aqueous KOH. The amine is
(A) C2 H5 — CH2 — NH2 (B) CH3 — HC — CH 2 — NH 2
|
CH3

(C) C2 H5 — NH — CH3 (D)  CH3 3 N

48. Observe the following product

It can be formed from which reactants pair given below by

diazotisation & coupling ?

A) B)

C) D) All The Above

49. Ethylamine and diethylamine cannot be differentiated by
a) Hinsberg test b) Carbylamine test
c) iodoform test d) both (a) and (b)
50. Which of the following compound gives N-nitrosoamine on
reaction with nitrous acid

(A) CH2 NH2 (B) H3C NH2

(C) N (D) NH CH3

SECTION - B
O O O

51. NH
KOH
N K+
RX/DMF N R
Ethanol
RNH2
reflux

O O O
Out of the given amines, how many cannot be prepare by this
method
1) CH3CH2NH2 2) CH3NHCH3 3) CH2  CH  NH2
NH2
NH2

4) 5)
52. How many of the following compound/(s) exist as a dipolar ion
among the following, P-amino benzoic acid, sulphanilic acid, P-
amino phenol
53. How many of the below listed compounds on treatment with
HNO2 would go for ring expansion?
NH2
CH2 NH2 NH2 CH2 NH2
, , , ,

CH2NH2
H2C NH2

OH , , NH,
 CN
H3O 
54. CN Final product ' P '
CN 
CN
Number of oxygen atoms in the final product P are
55. The number of compounds undergo H.V.Z reaction is

I. CH3-COOH II. CH3-CH2-COOH

III. Ph-CH2-COOH IV. PhCOCl
COCl
V.
56.

57.

58.

59.

60.
 VELAMMAL IIT & NEET ACADEMY
XII IIT RPTM – 16 MATHS DATE: 17.12.22
TOPIC: Definite Integrals, Areas, Sequence and Series
SECTION - I
Single Correct Choice Type
Numerical Type