Professional Documents
Culture Documents
Relief Valves
Relief Valves
Relief Valves
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Outline
n Introduction
n Hazard Identification
n Process Model for Relieving Conditions
n PRV Calculations: External Fire
n PRV Calculations: Electrical Power Failure
n Sizing and Selecting a Pressure Relief Device
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Protection Layers Emergency Response
in Community
Emergency Response
within the Process Unit
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Managing Process Safety
Maintenance
Inspection Procedures
Process Safety
Management
Permits Training
Managing Change
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Collapsed Fractionating Column
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Failed Pressure Test
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OSHA 1910.119 Process Safety
Management
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OSHA Requirements
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Factors Affecting PHA Methodology
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Factors Affecting PHA Methodology
(continued)
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Approved PHA Methods
n Checklist
n "What if " Analysis
n Failure Modes and Effects Analysis
n Hazard and Operability (HAZOP) Studies
n Fault Tree Analysis
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HAZOP
Methodology
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HAZOP Objectives
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Scope of HAZOP Analyses
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Process Unit
Feed(s) from Other
Process Units
Feed(s) from Storage Interface
Utilities
Injection
Chemicals
Process Unit
Catalysts,
Absorbents
Ancillary
Systems
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Study Node HAZOP
Flowchart
Design Intention
Process Deviation
Causes
Consequences
Safeguards
Risk Ranking
Recommendations
Yes
More Deviations ?
Yes
Other Nodes ?
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Study Nodes
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Design Intent for Process Parameters
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Problem 1B: Process Deviations
Using the P&ID provided, identify the process variables
that apply to the overhead condenser system (node
highlighted in yellow). Construct your process deviation
list based on these process variables.
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Determining the Causes for a Deviation
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Determining the Causes for a Deviation
(continued)
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Problem 1C: Causes
Using the P&ID for the overhead condensing system, list the
causes for two deviations: “High Pressure” and “Low
Pressure”.
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Qualitative Risk Assessment
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Severity Definitions
Level I II III IV
Description Catastrophic Severe Moderate Low
Human Impact Death Injury Minor None
Environmental Damage Major Serious Minor None
Production Loss > 6 Months 1- 6 Months 1- 4 Weeks < 1 week
Damage Value > $10M $1M - $10M $0.1M - $1M < $0.1M
M = Million
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Likelihood Definitions
n Frequent (Level 1)
– Expected to occur frequently (many times a year)
n Occasional (Level 2)
– Expected to occur occasionally (once a year)
n Infrequent (Level 3)
– Expected to occur under unusual circumstances
(once or twice during facility lifetime)
n Unlikely (Level 4)
– Could occur; however, not likely during facility
lifetime
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Risk Ranking Matrix
Severity
I II III IV
1 D D C B
Likelihood
2 D C B A
3 C A A A
4 A A A A
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Response to Risk Ranking
Ranking Action
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Recommendations
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Engineering Review of Recommendations
Assign Priority
Implement or Reject
Recommendation
During After
HAZOP HAZOP Document Decision in
Meeting Meeting Follow-up Report
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Using the Results from a HAZOP Study
List of Overpressure Events
Requiring PRV Protection Enhanced Process Safety
Management Systems
Rationale For
Allocating Resources
HAZOP
Study Results
Operator Training
Documentation
Required by OSHA
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Fire-Heated Boiler
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Process Modeling
for Relief Conditions
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Heat and Mass Balances
In = Out
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Blocked Outlet Transient
RS 31.4-R00-4
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Upstream Control Valve Fails Open
RS 31.4-R00-5
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Relief Model Development
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Codes and Practices
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Simplifying Assumptions
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Instrumentation Response
API recommends that no credit for instrumentation
response should be taken if that response reduces
the relieving requirement.
RS 31.4-R00-7
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Instrumentation Response
RS 31.4-R00-8
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Operator Response
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PSV Calculations:External Fire
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Feed Surge Drum
LLC
RS 31.5-R00-9a
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Fire Case Model
Qfire RS 31.5-R00-9c
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Heat Input Due to External Fire
Q = 2100FA 0.82
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Environmental Factor
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Wetted Surface Area
25 ft.
Elev.
RS 31.5-R00-10
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Vaporization Rate
Q
Wfire =
∆Hv
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Latent Heat of Vaporization
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Problem 2: Relief Rate for an External Fire
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Liquid Filled Vessel: Initial Conditions
Qfire Qfire
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Liquid Filled Vessel: Later Conditions
Qfire Qfire
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UOP Design Practice for Liquid Full Vessels
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PSV Calculations:
Debutanizer
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Debutanizer
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Problem 3: Construct a HWB at Normal Conditions
Using the HWB report for normal conditions, construct a heat
and weight balance around two sections of the fractionating
column.
n Draw an envelope around fractionating column,
including the feed -bottoms exchanger and
reboiler, but not the overhead system.
n Draw a second envelope around the overhead
condensing system, including the condenser and
overhead receiver.
n Construct a HWB for each envelope, assigning
positive values to streams entering the envelope
and negative values to streams leaving.
n Sum the heat and mass streams entering/leaving
the envelope, and confirm that the total is zero.
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Summary of Overpressure Events
for the Debutanizer
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Refinery-Wide Electrical Power Failure
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Debutanizer
(Electrical Power Failure Model)
Condenser Duty
(natural convection)
HWB 1 HWB II
Reboiler Duty
(radiation from refractory)
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Power Failure HWB I
Mass Heat
Total 0 0
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HWB I: Power Failure Case
(Working Equations)
QREB
WB =
∆H V
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HWB II: Power Failure Case
Qcond
Wcond =
∆H v
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Problem 4: Construct HWB I at Relief Conditions
Using the working equation for HWB I, determine the amount
of bottoms vapor that must leave the first envelope to obtain a
heat and mass balance during the electrical power failure
case.
n Assume that your process simulator reported the
bubble point temperature of the bottoms liquid
was 435°F at relieving pressure, and that its
specific enthalpy was 230 BTU/lb.
n In addition, assume that your process simulator
reported the specific enthalpy the bottoms vapor
to be 315 BTU/lb for the first bubble.
n Determine the amount of bottoms liquid that must
be vaporized the balance the system during an
electrical power failure.
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Loss of Air-Cooled
Condenser Duty
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Loss of Condenser Duty
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Debutanizer
(Model for Loss of Condenser Duty)
Condenser Duty
(natural convection)
HWB 1
HWB II
Reboiler Duty
(normal)
RS 31.6-R00-17
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Condenser Failure HWB I
Mass Heat
Feed
+ Wf + Wf hf
Net bottoms
− Wnb − Wnbhnb
Reboiler Duty
+ Qreb
− Wno − Wnohno
Net Overhead Vapor
− WT − WThv
Vaporized Tray Liquid
+ WT + WThl
Depleted Tray Liquid
Total 0 0
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Vaporized Tray Liquid
(Working Equation)
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Reflux vs. Liquid Inventory
RS 31.6-R00-18
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Heat Content of Net Bottoms
(Leaving the Envelop)
Before F/B exchanger After F/B exchanger
F/B exchanger
must be rated
regardless of
heat & mass
envelop
RS 31.6-R00-19
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-76
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Feed/Bottoms Exchanger Duty
T hsi
Assumes:
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Problem 5: Construct HWB I at Relief Conditions
Using the working equation for HWB I, determine the amount
of tray material that must leave the first envelope as a vapor to
obtain a heat and mass balance during a condenser failure case
Mass Heat
Overhead Vapor + Wo + Wo h v
Relieving Rate − (Wo - WA) − (Wo - WA) hv
Condenser Duty − Qcond
Accum. Liq. Inventory − WA − WA hl
Total 0 0
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Loss of Condenser Duty Relieving Rate
Qcond
Wcond =
∆Hv
Relieving rate (difference between total vapor rate
leaving debutanizer and residual condensation):
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-80
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Reality Check
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Separator LLC Fails Opened
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-84
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Types of Relief Devices
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Conventional
Pressure Relief Valve
RS 31.7-R00-22
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-86
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Balanced-Bellows
Pressure Relief Valve
RS-31.7-R00-23
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-87
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Opening & Closing
Spring-Loaded PSV
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-88
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Impact on Design
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-89
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Force Balance
Conventional Pressure Relief Valve
RS 31.7.R00- 27
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-90
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Seating Force
Spring-Loaded Pressure Relief Valve
RS 31.7.R00-26
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-91
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Valve Leakage
Set Pressure
Operating Pressure
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Design Options for Leakage
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Inlet Pressure Loss
Set Pressure
Minimum Inlet Pressure
95
} Blowdown Pressure
90 93
Operating Pressure
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Inlet Line Sizing
Pressure Drop Calculated Using
Rated Capacity of Valve
Equivalent length
includes:
Sudden contraction
Elbows
Tee
Reducer
Length of piping
RS 31.7.R00- 40
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-95
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Design Options for Meeting 3% Inlet ∆P
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-96
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Force Balance
Conventional Pressure Relief Valve
RS 31.7.R00- 25
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-97
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Effect of Back Pressure
RS 31.7.R00-29
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Force Balance
Balanced Pressure Relief Valve
RS 31.7-R00-30
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-99
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Effect of Back Pressure
Balanced Relief Valve
16 %
RS 31.7-.R00-31
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-100
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Design Options for High Back Pressure
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Summary
Spring-Loaded Pressure Relief Valves
110
% of Set Pressure Accumulated Pressure
97 100
Significant Leakage
Operating Pressure
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Sizing for Vapor
Spring Loaded Relief Valve
W TZ
RA = If heat capacity ratio is
CKPacc K b MW unknown, assume CK = 306
Q SpGr
RA =
38 K Pacc − Pb
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Sizing for Flashing Flow
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Pop-Action Pilot-Operated Valve
(Flowing Type)
RS 31.7-.R00 -34
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-106
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Flow Characteristic
Open and Closing
% Capacity
No Blowdown
Modulating Pilot
No Leakage
RS 31.7-R00-36
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-108
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Seating Force
Pilot Operated Pressure Relief Valve
RS 31.7-R00-37
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-109
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Unique Considerations
Pilot Operated Relief Valves
n Backflow Preventer
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Backflow Through a PORV
RS 31.7-R00-36
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-111
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Backflow Preventer
RS 31.7-R00-39
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-112
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Remote Sensing
Applying the 3% Pressure Loss Constraint
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
PORV Advantages
n Seat Tightness
n Remote Pressure Sensing
n Less Sensitive to Back Pressure
n Field Testing of Pilot Set Point
n Remote Depressuring
n Ability to Modulate Flow
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-114
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
PORV Disadvantages
n Difficult to Specify
n Temperature Constraint
n Elastomeric Compatibility
n Limited Metallurgy Selection
n Unfamiliar Technology
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-115
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
PORV Applications
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-116
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
PORV Sizing for Vapor
W TZ
RA =
CKPacc MW
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-117
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
PORV Sizing for Liquid
Q SpGr
RA =
38 K Pacc − Pb
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-118
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Multiple Valves
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-119
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Example
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Spare Valves
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Isolating Block Valves
Design Considerations
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Rupture Discs
Safety Head
Process Process
Pressure Pressure
RS 31.7-R00-41
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-123
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Rupture Disc Applications
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-124
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
In Combination With PSV
RS-31.7-R00-42
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nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Rupture Disc Sizing
RS 31.7-R00-43
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-126
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Critical Flow
(Critical Flow Equation for a Rupture Disc)
Qm S g T
RA =
260 Pacc
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-127
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.
Piping Systems
Atmosphere
Po
P2
Rupture Disc P1
P4
P3
From Reactor To Reactor
Section Section
P5
RS 31.7-R00-44
2003 ENGINEERING DESIGN SEMINAR – LIMITED DISTRIBUTION: This material is UOP LLC technical information of a confidential EDS 2003/RV-128
nature for use only by personnel within your organization requiring the information. The material shall not be reproduced in any manner or
distributed for any purpose whatsoever except by written permission of UOP LLC and except as authorized under agreements with UOP LLC.