Corrosion Inhibitors

EMEA
NUBIROX RANGE
NUBIROX Range
nubiolaeurope@nubiola.com

LATIN AMERICA
Nubirox N2 Standard Zinc Phosphate nubiolacolombia@nubiola.com
Zinc Based Pigments

Small Particle Size Zinc Phosphate

High Performance

Nubirox SP
NORTH AMERICA
Nubirox 102 Organophilized Zinc Phosphate and Zinc Molybdate
nubiolausa@nubiola.com
Nubirox 106 Organophilized Zinc Phosphate and Zinc Molybdate
APAC
Labeling Free

Nubirox 213 Iron Phosphate and Zinc Phosphate

nubiolajapan@nubiola.com
Nubirox 301 Calcium Strontium Phosphosilicate nubiolachina@nubiola.com
Pigments
Zinc Free

nubiolaindia@nubiola.com
Nubirox 302 Organophillized Calcium Strontium Phosphosilicate

Chromate Based Pigments

Flash Rust Inhibitors

Nubirox FR-10 Nitrite Based Liquid Inhibitor Zinc Chromate Zinc Chromate
Nubirox FR-20 Nitrite Free Liquid Inhibitor Zinc Tetraoxychromate Zinc Tetraoxychromate
Strontium Chromate Strontium Chromate

Product Data Matrix

Non classified as hazardous Anticorrosive Pigments Chromate Pigments

Zinc Zinc Tetraoxy- Strontium

Standard Chromate Chromate Chromate

High Performance Zinc Based Anticorrosive Pigments Zinc Free Anticorrosive Pigments Zinc
Specific
Phosphate gravity, 3.5 3.6 3.9
(g/cm3)
Nubirox SP Nubirox 102 Nubirox 106 Nubirox 213 Nubirox 301 Nubirox 302 Nubirox N2 Chromate 41 - 45 17 - 19 >46
(% CrO3)
Specific gravity
3.4 3.1 3.2 3.0 3.0 2.9 3.3 Zinc (% ZnO) 35.0 - 68.5 - -
(g/cm3)
40.0 72.0
Zn (% ZnO on
64.0- 66.5 60.5 - 64.0 63.0 - 66.0 31.0 - 34.5 - - 62.0 - 64.5 Potassium
calcined product) <13 - -
(% K2O)
Fe (% Fe2O3 on
calcined product)
- - - 32.5 - 36.0 - - - Strontium
(% SrO)
- - >48
NUBIROX

March, 2012
Loss of mass on Conductivity
calcination at 8.5 - 11.0 11.0 - 15.0 10.0 - 14.0 9.5 - 13.5 3.0 - 6.0 3.0 - 6.0 9.0 - 12.5 - - <1100
(µS/cm)
550ºC (%)

Conductivity
Soluble
Chromate,
0.06 -
-
0.04- Labeling Free Corrosion
250 - 400 550 - 800 600 - 950 300 - 550 300 - 550 300 - 550 <154 0.15 0.10
Inhibitors
(µS/cm) (gCrO3 /100ml)

Soluble matter
pH of aqueos - <0.8 -
6.5 - 8.5 5.0 - 7.0 6.0 - 8.0 6.5 - 8.5 8.5 - 10.0 9.0 - 11.0 6.0 - 8.0 (%)
extract
Sulphate
Sieve Residue on <0.2 - -
(%SO42 -)
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
a 45µm, (%)
Chloride,
(% Cl-)
<0.1 - <0.1
www.nubiola.com
Oil absorption
42 - 56 17 - 23 34 - 45 40 - 54 40 - 50 40 - 50 18 - 24
(g/100g)
Nitrate
(% NO3-) - - <0.1 Disclaimer for commercial products
Sum of
<0.02 <0.02 <0.02 <0.05 - - <0.01
Cl- & SO42 -
Insoluble
Nubiola can only guarantee those certified parameters in
matter in
<0.3 - -
the Specification Data Sheet of our products. Nubiola is not
acetic acid
(%)
responsible for any misuse and/or inappropriate handling or
Liquid Corrosion Inhibitors storing conditions that may act to the detriment of certified
Insoluble
matter in
specifications of our products or pose a risk to human health
<0.5 <0.5 -
Nubirox FR-10 Nubirox FR-20 NH4Cl, (%) or the environment.
Due to the fact that there are a multitude of formulations,
3
Specific gravity, (g/cm ) 1.14 - 1.16 1.21 - 1.23 Moisture and
manufacturing processes and end uses, Nubiola strongly
ISO 9001:2008
volatiles at <1.0 <2.0 <1.0
pH 9.5 - 11.0 7.5 - 9.0
105ºC, (%) recommends that customers perform previous tests under their
Sieve residue own testing program and carry out appropriate verifications in
35% minimum 60% minimum <1.0 <1.0 <1.0
Solids by weight, (%) on a 45µm, (%) order to determine the ultimate suitability of our products and
observe existing laws and legislation.
NUBIROX Technology
NUBIROX Labeling Free Modified Zinc Phosphates NUBIROX Zinc Free Pigments
Small Particle Size Zinc Phosphate

NUBIROX 102 Organophilized Zinc Phosphate and Zinc Molybdate Calcium Strontium Phosphosilicate

Standard Zinc Phosphate

• Direct replacement for standard zinc Alkyds
• Excellent performance in water and Alkyds phosphate. Epoxies

SB
solvent based systems. Epoxies (mainly nano-particles) Epoxy Esthers
over zinc phosphate • Suitable for solvent and water based

SB
Epoxy Esthers Urethanes
• Direct replacement for zinc phosphate systems.
Urethanes Alkyd Emulsion
giving improved anticorrosion protection. Nubirox Alkyd Emulsion • Excellent stability in most resins where Soluble Alkyds
102 Soluble Alkyds zinc based corrosion inhibitors are too Epoxies

WB
• Suitable for high film thickness ( >50μ DFT) Epoxies reactive (i.e., urethanes, polyesters). Vinylidene Chloride

WB
single coat medium-gloss systems. Vinylidene Chloride
• Good protection on multisubstrates.
Urethanes

Application Map
Urethanes Acrylic Emulsions

Acrylic Emulsions • Excellent performance in thin

n Wash & Shop Primers

APPLICATION
Wash & Shop Primers film thickness (<25μ DFT) Powder Coating

APPLICATION
Powder Coating
applications such as Coil Coating
Standard Zinc etch/wash primer systems. DTM Gloss
Coil Coating
Phosphate
DTM Gloss

NUBIROX 302 Organophilized Calcium Strontium Phosphosilicate

• Direct replacement for standard zinc Alkyds

NUBIROX 106 Organophilized Zinc Phosphate and Zinc Molybdate
phosphate.
Organic Surface Treatment
Epoxies

SB
HIGH PERFORMANCE: Fast activity COST REDUCTION: Efficiency at low concentration • Excellent zinc-free performance in water
Epoxy Esthers
Urethanes
• Excellent performance in water and solvent Excellent Performance Alkyds and solvent based systems. Alkyd Emulsion
Interphase
8% Zinc Phosphate 6% Nubirox SP based systems. Epoxies Soluble Alkyds
in water & solvent based systems • Good protection on multi-substrates.

SB
1,3
Nubirox 106 Epoxy Esthers Wetting Epoxies

WB
• Excellent corrosion resistance at very low Urethanes
• Excellent stability in most resins where Compatibility Vinylidene Chloride

Application Mao
Anticorrosive performance

concentrations. Alkyd Emulsion zinc based corrosion inhibitors are too Urethanes
5
Zinc Phosphate Soluble Alkyds reactive (i.e., urethanes, polyesters). Performance Acrylic Emulsions
• Suitable for all thin film thickness (<25μ DFT) Epoxies Wash & Shop Primers

WB

APPLICATION
Anticorrosive performance
applications such as coil coatings. Vinylidene Chloride Powder Coating
Urethanes Coil Coating
Acrylic Emulsions DTM Gloss
Wash & Shop Primers
1 2 3 4 5 6 % Anticorrosive pigment
Powder Coating
% anticorrosive pigment
Coil Coating
1,3% Nubirox 106 5% Zinc Phosphate DTM Gloss NUBIROX Flash Rust Inhibitors
NUBIROX FR-10 Nitrite Based liquid Flash Rust inhibitor
NUBIROX 213 Iron Phosphate and Zinc Phosphate
• Prevents Flash Rust and In-Can Rust. Applications
• Especially suitable for most solvent and Excellent Cost-Performance Alkyds • Useful as a short-term temporary protective wash.
water based alkyd and epoxy systems. Epoxies
• Effective in the liquid and in the vapor phase at low loading
unique dual metal cation complex

SB
Epoxy Esthers
• Improved cost effective performance over on a variety of metal substrates.
Urethanes
Styrene-acrylic primer Short oil alkyd primer standard zinc phosphate. • Can be incorporated at any stage in the coating
WB SB
192 hours in Salt Spray 525 hours in Salt Spray Alkyd Emulsion
(ASTM B-117) (ASTM B-117) Soluble Alkyds
Cold rolled steel panels DFT ~ 35μ Cold rolled steel panels DFT~ 35μ manufacturing process, even post added.
• Good replacement for zinc phosphate in Epoxies

WB
one and two-component etch/wash primer Vinylidene Chloride
In-can rusting Flash rusting

Application Map
Urethanes
systems. Zn Fe Acrylic Emulsions

NUBIROX Range Wash & Shop Primers

APPLICATION
Powder Coating
Coil Coating

NUBIROX SP Zinc Phosphate Zn3 (PO4)2·2H2O

DTM Gloss
NUBIROX FR-20 Nitrite Free liquid Flash Rust inhibitor

• Similar properties, applications and performance to

• Efficiency at low concentration. Small spherical particle size Alkyds
Epoxies Nubirox FR-10.
• Efficient replacement for standard zinc phosphate. with high specific surface area
SB

Epoxy Esthers
• Metals protected by Nubirox FR-20 can be welded.
Urethanes
• Suitable for solvent and water based systems. The fumes generated are non toxic as nitrosamines are not
Alkyd Emulsion
• High binder compatibility. Soluble Alkyds produced.
Epoxies
WB

• Applicable in thin film systems. Vinylidene Chloride

Application Map

Urethanes
Acrylic Emulsions
Nubirox non classified as hazardous In-can rusting Flash rusting Water-blast
Wash & Shop Primers cleaning
Anticorrosive pigments
APPLICATION

Powder Coating
Coil Coating
DTM Gloss