MCA of Hong Kong Christian College

Chapter 18: Separation and Purification Name:

KdhuAer
Class: 2 (2)
Set IX 3
Chapter 18 Homework Separation and Purification

18.1 Making a substance in thelab

1. 0620_s20_qp_22 Q2 [1]
Which piece of apparatus is used to 25.0 cm
measu re of aqueous sodium hydroxide?
A B C

AU2. 0620_m19qp_22 Q:3 [1]

Lead(11) iodide is insoluble in water.

Lead() iodide is made by adding aqueous lead(1l) nitrate to aqueous potassium iodide.

Which pieces of apparatus are needed to obtain solid lead(l1) iodide from 20cm of
aqueous lead(|) nitrate?

1
LY 2 3 4 5

A 1,2 and 4 B 1,3 and 5 1,4 and 5 D 2,4 and 5

Page 1 of 11
F.3 Chemistry
 Christian College
YMCA of Hong
Kong Purification
and
Chapter 18: Separation
solublty
18.2 Solutlon and
3.
Define
these terms:
trougl he g i e prpeg
Fitrate
Ihe liyid thatpusses
remeins an filler pap
Residue: The elM (2
aglailHrateh 11
2uly bo lquid..
Solution: C_Misfure_and cpn neitmya Bpnd
Saturated solution: a
5yiah tha tontaing
Solute het cas he disgolver.
formed.
tetrachloride. A violet coloured liquid is
dissolves in liquid carbon
4 Solid iodine
ldentify the
solvent, solute, and solution Saltd iadi
Solvent: 4vid Cahyn etrn 1 Solute
Solution: auioletchelved lyui
Match the following
[3]: Common salt
5.
Water
Sea water
(a)

Solvent
Solution
Solute

are shown in the table

compounds
The solubility of
some

6 Compound
Solubility
Solubility g/ 100cm water
Compound
g/100 cm water
potassium nitrate 37.9
0.113
calcium hydroxide silver chloride
0.0002
102.1
calcium nitrate 241.3
silver nitrate
0.00003
iron() hydroxide

is very soluble
in water?. nlve hithat
of metal compound ri
What type
are
insoluble in water?_rOI
drozde rh
Which compounds
ii.
is sparingly soluble?
eule(Vhhydvrok id
Which compound
ii.

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F.3 Chemistry
YMCA of Hong Kong Christian College
Chapter 18: Separation and Purification
The graph shows the solubility of two tofmipourds t
different termperatures

.Deduce the solubility,of potasslum nitale at 79 C

156
(ECitrieihs ol0ty Ing
I. Whichcogjpound is m0st solutye (n vwater at 10 "C7
Pota44iUn clod-e (
duulesiburiliilraterivitineaveuuluieuniituiiuiussvady

il. Deduce the maximurn mass of potassiurn nitrate

that dissolves In 100 cm of water at 60 "C
fengaroo6/
uueus iutpssivuiiiuneusururoin

18.3 Separating a sold from a lquld

7. Suggest three ways to separate a solid from a liquid (4)

Separating-a-4olid fusss-a liquis

a b)
FRltorUEou ryslalgali ubtorol

ByremoVing a Byobtaining a
solid from its
Solid
solutíon
the (d) lI

8. Put these statements about crystallisation of zinc sulfate in the corect order
A Filter off the crystals,

BHeat thesolution to concentrate it.

C Dry the crystals with filter paper

D Wash the crystals wíith a small amount of solvent.

E Leave the solution to cool and form crystals

F By seeing if crystals form on a cold surface

G Check that a saturated solution has forrmed.

Order 9 -2E7AD-2C>F

F.3 Chemistry Page 3 df 11

 Christian
College
Kong the dotted lines 31
of Hong
Purifñication

MCA Separation
and
the corect
labels on
apter 18
the diagram
by writing
9 Complete

Suspension of
chalk in water

fUnnel

Cpi'hiCal

separation method you could use to separate

10. Name the

(a) Sand from a mixture of water and sand ilra>h [1

(b) Waterfrom a solution of copper(|) sulfatein water_Custali~arigh
salt using ethanol: Given than sugar is soluble in ethanol, but
(c) Separating sugar and
salt is not. To separate a mixture of sugar and salt, ethanol is added to dissolve sugar.

The undissolved salt is removed b y _ r 1 .Salit is trapped in the filter

paper while the fltrate passes through. Finally, sugar is separated from ethanol by

184 Separating by distillation

11.Pure water can be obtained by distilling the mineral water using the apparatus shown

below. Labelthe diagram of the distillation apparatus to show: B the distillation flask;
C the distillate; D where cold water enters A [3]

flask

mineral
beaker
water

heat

State the name of the piece of apparatus labelled A: AhdnSe [11

(6i) Where does the pure water
collect? beako [1
(ii) Explain why this method can be used to separate mineral from mineral water.

CeAdeacThhe [1
F.3 Chemistry Page 4 of 11
YMCA of Hong Kong Christian College
Chapter 18: Separation and Purification
(v) Explain why this method cannot be used to separate two liquids which have similar

boiling point [1)

ecause @M 1eperclt
12 0620s18 MS 41 Q1 2 hauids
A dent suggested that the apparatus shown could be used to separate the mixture of

alcohols

The bolling points of four differont alcohols, A, B, C and D, are shown.

alcohol A 3 C D

boiling point/°C 56 78 122 160

A student suggested that the apparatus shown could be used to separate the mixture of
alcohols.

fractionating column

mixture of
hot water alcohols
A, B, C and D

electric heater-

) Apparatus X needs to have cold water flowing through it.

.Draw an arrow on the diagram to show where the cold water enters apparatus X.
[1

(ii) Part of the fractionating column is missing. This means that the experiment will not work.

Draw on the diagram the part of the fractionating column which is missing.
Explain why the experiment will not work with this part of the fractionating column
missing.

w. e ******

**********
******************s***************************************.**.*.so*e**o**anne***oopoeo*...
2
F.3 Chemistry Page 5 of 11
 MCA of Hong Kong Christian College
Chadpter 18: Separation and Purification
ii)
A hot water bath cannot bo used to soparato alcohols C and
D

Explain why.
c.c.a halh cghos i. ****** ***

Y********************* *****"***** Y ** *******

wwabass*sesakue***ea sean***seeunv************s*epe*****esep******* Y Y . . * . . e e s e g ******************************

(2

18.5 Paper chromatography(part)

186 Paper.chromatog.raphy(partl)
13. The diagram shows a chromatogram

solvent front
4.0cm spot A
3.5 cm

spot B
2.2 cm spottC
| 1.8 cm

original spot
baseline

Which spot is the most soluble in the development solvent? Explain?

kiehes
(21
(i) Calculate the R value of spots A, B, and C.

[3
F.3 Chemistry Page 6 of 11
 YMCA of Hong Kong Christian
Chapter 18: Collegee
Separation and Purification
14.

a. Give three of
uses chromatography.
e ******************
****

-.chuMAAtetzasp.AM Paalc0icdeubisatie
.NRpailg.kolznd. ****************sa oono 3)

b. A paper chromatogram of some amino acids from a mixture

of amino acids is shown. Two pure amino acids, Ser and Gly solvent front
were also run on the same piece of paper.
Leu
i. Why was the baseline drawn in pencil and not in ink?
Val- -

N£il... A..Ld.
ii. How many amino acids have been completely
sola
Ser
Gly
separated? Ser
Gly
**one~e***************************** [1
Cys -baseline

ii. Which amino acids have not been separated?

Se n. 1
iv. Suggest how you could you separate these amin0 acids?
ninhydk.iA.. ***we*****a*****-***** aeee** [11

V. Calculate the R, value of Val. .. ****eet**a*ae

[1

vi. Lysine has an R, value of 0.14. On the diagram above, draw the approximate position of Lys. Label it Lys. (1]

C. State two factors which determine the distance an amino acid travels up the paper.

.depad ** *****

****oo*94bru 2

d. Amino acids are colourless. How can you make the spots show up?

..Ja.
* * * * e **soe 2

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F.3 Chemistry
 TMCA of Hong Kong Christian College
and Purification
Chapter 18: Separation
15.

of substance X.
Diagram 1 shows the paper chromatogram

diagram 1

Diagram 2 shows the cooling curve for substance Y.

temperature/C

147

time

diagram 2

Which statement about X and Y is correct?

A Xis amixture and Y is a pure substan oe

(BXis a pure substa nce and Yis a mixture.
C Xand Y are mixtures.

D X and Y are pure su bstances.

[1]

F.3 Chem istry Page 8 of 11

YMCA of Hong Kong Christian College
Chapter 18: Separation and Purification
18.7 Checking purity

16.

0620_s17-qp.22 Q: 2

Impurities change the melting and boiling points of substances.

Sodium chloride is added to a sample of pure water.

How does the addition of sodium chloride affect the melting point and boiling point of the water?

melting point boiling point

increases increases
B increases decreases
C decreases increases
D decreases decreases

17.Seawater is a mixture
What is the meaning ,of the term mixture?
n made Up _D he Y_ore_hemod]
Suggest a value for the melting point of seawater?

[11

18.Sulfur melts at 119°C and boils at 445°C.

Draw lines between the boxes on the left and the boxes the
on right to complete the
sentences.

.melts over a 4°C temperature range.

Pure sulfur.. ...turns to a vapour at 450 °C.

Impure sulfur.. Solidifies at 119 °C.

..has a sharp boiling point

2]

F.3 Chemistry Page 9 of 11

CA of Hong Kong Christian College
and Purification
Chapter 18: Separation
Chapter Questions
19. Use the correct words from
the list to complete the sertences (6

Eiltration ETaporation gptallizzion

Stmple distmstion Fractonat distiiation Paper chromatography

P T o obtain a solvent from a solution. (t is also used to separateea

misture of two or more liquids with a great diference in boiing points)

fitltreith To remove an insoluble solid froma Equid / solution

POyer ch aJepahes solute of solid powders fom
Lrgtallizatefo separate a solute of solid crystais from a soluion.
Simple distila,To separate the solutes in a solution.
FradioAL To separate two miscible iquids (iquids that mix completely) wi
dose boiling points.
(SHilateon
20.Drawa labelled set-up of filtration for separating water and chalk [4

wte
funrel chalk
Mixtore

benke

Page 10 of 11
F.3 Chemistry
 YMCA of Hong Kong Christian College
Chapter 18: Separation and Purification
and
for separating a mixture of ethanol
21.DraWa labelled set-up of fractional distillation

in" and "water out" openings |5].

water. Indicate the "water
hepomhreEr

condeh Se
glass
beads
Lot ro
ro n d -
Fusk

heat Slaz

chromatography [4]
setup for paper
22.Drawa labelled

-6 eaky
chronut
Parer
v?u warr

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F 3Chemistry