LJ/809 2009 Series B Sooo CHEMISTRY (English & Telugu Versions) Time : 150 Minutes Max. Marks : 300 Shaken : 150 Dddswev Ando Srdyev : 300 INSTRUCTIONS (295s) 1. Please check the Test Booklet and ensure that it contains all the questions. If you find any defect in the Test Booklet or Answer Sheet, please get it replaced immediately. Bh SSSos* wd) She LoGosodss TS Urwseesow. 6% Shiv" wd, Sores Sind Md QBor SHES" ord Qusinc* SH¥Hdd Sood SHS SSS. 2, The Test Booklet contains 150 questions. Each question carries two marks. (OH Sand" 150 Awd. 28.8, WH Tod Srwyo Serovosadsa, 3. ‘The Question Paper is set in English and translated into Telugu language. The English version will be considered as the authentic version for valuation purpose, HS[Sdv aohis® Sovroidosad ort Ass Sede DabodsO. Sirqrs S|Sdv worg Polsine acho SHS Soo Srdrssiorr BHTSaew. 4. The Test Booklet is printed in four (4) Series, viz. [Al] (D). The Series, yr [B] or {D] is printed on the right-hand corner of the cover page of the Test Booklet. Mark your Test Booklet Series {A]or [B] or [C] or [D] in Part © on side 2 of the Answer Sheet by darkening the appropriate circle with HB Pencil.. B% S[Sdo Tort SfSvod* (Series) esr [DD] dgsnoc*® axBounssa. 6: Sgavew [A] md [B] od [G] md D] md BH Sho ans, Sbw bE LBBH Sros* SyGodosss, HEQYS HA Sav oink, Sysw (eries) [B] ma [G] ma DB] ma Bargr BWSw Todd Bh HG C Sot eossstsiin Feronodads Sy siwis WS.O. Bd)SE" SOT GY d08STH. Example to fill up the Booklet Series It your Test Booklet Seriesis A, please fllas shown below @®oOoe If you have not marked the Test Booklet Series at Part C of side 2 of the Answer Sheet or marked in a way that it leads to discrepancy in determining the exact Test Booklet Series, then, in all such cases, your Answer Sheet will be invalidated without any further notice. No correspondence will be entertained in the matter. b (St, SSSx Avs, SYS (Series) Sires HSSv IIHS HF C MQossronw IF GOS SIS [SASS SYSv POSIT BLE Lwoe ISSO 6 Sbor dm) vtvSod od) SodASvod*, A DenSoe Mes and SosQowds SErOS S52 SObDoswsL (invalidated). 529 009 HwSoS af ojshysosver wooo,(2) Lu/809 . Each question is followed by 4 answer choices. Of these, you have to select one correct answer and mark it on the Answer Sheet by darkening the appropriate circle for the question. If more than cone circle is darkened, the answer will not be valued at all. Use HB Pencil. to make heavy black marks to fill the circle completely. Make no other stray marks. 63 BHS wen Sirgrhiner akpodS., woeds* Sabi earn ISD Sdrgrs His WHE Forcnciads Siw Sgr GY DSSS. af crd8or] IKYS Hgiwow dodset, & Bhrgrhdn SOROSASS. Sov HOM Sy GY VoHok WS5.0. BOSS Tssos. wSSSSH Moher BOTS. eg. : If the answer for Question No. 1 is Answer choice (2), it should be marked as follows : ac : Hains Lavong 1 8 waren (2) wandSzpth odd Si (808 Dior MYossow : 11O|@/@|@ Mark Paper Code and Roll No. as given in the Hall Ticket with HB Pencil. by darkening appropriate circles in Part A of side 2 of the Answer Sheet. Incorrect/not encoding will lead to invalidation of your Answer Sheet. BS GSE adgndd Ss SSH swt, S5 Soatiy Hda% 2 GFF sont Sdrqrs SSSn Bob, DoSSBHYS SE A Sot WH.D. BOSS HOM Adve Sor HY HQossoS. wdonginm dda SE ASydoH Sossdtanw Snows Swim SoDossweke. Example : If the Paper Code is 027, and Roll No. is 95640376 fill as shown below : aoede : S55 SE 027 L0av SS So, 95640376 Govss (Sods uirdS Opiivrr Dora : Paper Code Roll No. B85 85 CS 30. 6 © @ @ @ @ © e @ © ©QOOOOOG|* 2 @ @ @ @ @ @ © @ 5 3 © @ @ @Q @ @ @ e @ @ e ® @ © @ @ ® ©! ©©@QOOO000|~ ©OQO@OOHOOOGO|° alo Qe QO @@ @®@ ea Qo @®@ QQ @® QOOOQOOOOOE|> ©QOOOOOOe@OG|» Please get the signature of the Invigilator affixed in the space provided in the Answer Sheet. An Answer Sheet without the signature of the Invigilator is liable for invalidation. BErgS S[SSnd* SeronodS osns* SvgIYLD (Invigilator) dinky, SoS8ivke Hossss. BS S8GALHD SosSan Sarg S Sind" SST oss © SOWosaso.Lu/809 (3) B 8. 10. i. ‘To change an answer, erase completely the already darkened circle-and use HB pencil to make fresh mark. DBer hs Srqrsir ArHySSIHY, aosH Avot Dods Sys (Circle) Sgr Says BODso wS.D. BSS [SFr MQossSSw. ‘The candidate should not do rough work or write any irrelevant matter in the Answer Sheet, Doing so will lead to invalidation. 88g ‘DESY Rough Work) 9 md ISH eH Ddokimo wd sirors Ssiyp [Prokords, wd» HSS Sirord S[Sdv SOBDossow soderds oro Sassy. Do not mark answer choices on the Test Booklet. Violation of this will be viewed seriously. Sirgrhived SS WSiop HYosords, 609 eaSMoDSS Bporr Soriosas. Before leaving the examination hall, return the Answer Sheet to the Invigilator, failing which, disciplinary action will be taken. SOS HSK SOO SPS Singh SSSwk HS Gh) SIgS{LDS (Invigilator) adysow. SO LHWeo Bog SHS So ho @ 20 (3) ho @) o&) 285 edodS 6D s5)S Starmyop Ke So86SSnkn (1) sp S200% sp? (2) sp® Ss0%0 sp? (8). sp 00% sp” (4) sp, sp? 980% sp? Ber Sosst sgt () ZS HSyighv de esd Q) C=C sodin ans, wie wSESdo HHS Sh) ISYS (3) 0 S00 x wowe dHB1:1 (4) C-N wogdn @4% HCN & @%)083 sotvod S08 Saas Gog aw syooS SEs 1 (808 ad Hg fo 9498 (1) 2878S Bolrzargo Brac Song S0aw FRorSndd oS$ivo song (2) 2873S Ealrargo Bravo . Song Boa how'd sgooho Song, @) Faows'oas Soom — SwgFoas are Song 4) PRE DGS ago Sowg Mov DOSS Sakrades emiyo Somg sgooho song Bosressy10. ue 12, 13. GQ) X>You (2) Y>X>Z (@) Z>X>¥ (4) X>Z>¥ When the azimuthal quantum number (J) is 3, m can have (1) 1 value (2) 3 values (3) 5 values (4) T values Bohr's model can explain (1) the spectrum of hydrogen atom (2) the spectrum of atom or ion containing one electron only (8) the spectrum of hydrogen molecule (4) solar spectrum ‘The structure of [Cu(H,0),J** ion is (2) square planar (2) tetrahedral (3) pyramidal (4) octahedral 15. 16. 17. 1/809* Which has a minimum dipole moment ? (2) Butene-1 (2) cis-butene-2 (8) trans-butene-2 (4) 2-methy! propene During adiabatic expansion of gas (1) internal energy increases, (2) temperature increases (8) temperature decreases (4) entropy decreases A gas expands against vacuum from a ‘volume of one lit to 10 lit at 273 K. The work done during this process is (1) 100 keals (2) 5-0 keals (3) zero (4) 10 keals In a chemical equilibrium A + B = C + D when one mole each of the two reactants are mixed, 0:6 mole each of the products are formed. The equilibrium constant is a 10 (2) 036 (3) 225 4) 0-44un. 12, 13. SF X,Y &doi Z Fro viydo (sido (1) X>YoZ () Y>X>Z (8) Z>X>¥ (4) X>Z>¥ wetandd srgobs> Song @) ded 3 wordings m H ho oso Sows @a (2) 3 @) 5 a 7 86 Sarr __ & dS0iH08. (1) PWSexw Sire S450 Q) 28 dogy& SONY SéSremiy Bor voir& Gok, Sf Soo 8) PEew omy Got, Sg560 (4) 26 S85H0 [Cu(H,0),)"* io8z_ Do~ystbn () ShSo Saospodo Q BEwES (3) SdDad 4) epwsd 14. 15. 16. 17. WSO) Ags ErwSin Sod @) engi Q) BSengdS-2 (3) ErSyeng5.2 28d BSS moby QOYS a gSso BoBsiyer (1) voSOS 48 BHrsH0d 2) AQ PBs Bere0o @B) aX WS SisHoa 4) do Sis0a aS rated) rSg bards Sgadsorr 273 K &% af 5. S08 10 0. & argS'so BoBsO. ds Sobs* wONs SD (2) 10-0 keals (2) 5-0 keals 3) By (4) 1-0 keals A+BEC+D ©& SHO8S SHE ZB WOsS* ays Br Sow Gor ira Semdr 0-6 Srv oS yk, Soir wbdgin D8VSSD. wows Ge Gog dinky SerpB Qorosim Devs a 10 (2) 0:36 (@) 225 (A) 0-4418, 19. a. ( The solubility of a sparingly soluble salt of the type AB, is 20 x 10-6 m lit, The solubility product of this salt is a) 82x 107" (2) 40 x 10"? (a) 80x 107% (4) 40x 1078 In a vessel containing S03, SO, and O, at equilibrium, some helium gas is introduced so that the total pressure increases, while temperature and volume remains constant. According to Le Chatelier’s principle, the dissociation of SO, () increases @ (3) «@ decreases remains unchanged is uncertain ‘The heat capacities of an ideal gas are related by the reaction a =R @ o,+=R @ 2-R W gxqek Calomel electrode is an example of a @ metal-metal ion electrode oxidation-reduction electrode (3) amalgam electrode (4) metal-metal insoluble salt electrode 8) 22. 23, Lu/s09 * ‘The relation between free energy change and equilibrium constant of a reaction is AG ree @ k= 25 G) Esec. @) ke eteRr @ kee AORT ‘The sum of transport numbers of cation and anion of an electrolyte is (1) unity (2) zero @) >1 @) <0 The solubility of a sparingly soluble salt in conductivity experiment is calculated using the formula a) s- aa 2) s= 100A @ s=(s) @ s- 00 If the value of one Binstein of radiation is 72 kcal, the wavelength of light is a) 39724 (2) 79444 (3) 1986 A @) 2A1/809 18. 19. 20. 21. AB, of 28 wo) rSdoss fo obey whdoss 20 x 10% m Tit. od (wddober ogi» a) 32x1077 @ 40x10? (3) 80x10 (4) 40x10 805, SO, 200% 0, w Sergac’ od) 28 DH SoS Ooo maw} Sexsodsd Ss [BSobs* aA 4S How SS S0hrady QSorr aodrr SS00 Sako SrSb BORED. | HYoSS dr[So sso Gs [Eos SO, dinky Deresso GQ) Besrbe @) Sipe 8) debe 4 dHMmMs' BS )Sdo ak vSt) wok dot, of giado Gg ho Boosio @ =R Somd og'gu & ooo. Q) Simin SH war do$'e (2) w8ySde0-$oHsim Ios'oe @) wdr—h dog" 4) Sie Sey Crddoss Td cdm%y DoS 5c 19) 22. 23. 24, B| a BiSos odo, Leer) WBS'D Srv) @ She QB gross Aog fo Doogie ac a) k= 46 @) k= ae Oekeecs @) k= ete /Rr (4) k=e40RT eS DegOogdtgod*D Shotrio HOawy whoiriho SOAS Somgo Svgav ami @ wy @) >1 a) <0 28 voy rddoss Ko omy rddoss wri Srdso ago Bs0smds od diye a gs = 10K @ gs = 10004 @ S= (A) (4) s = 1000 aS S08 Gnky af oSHe Dev 72 kcal word oD SSoABggoo a 3972 A (@) 79444 (a) 1986 A ® 2A26. 27. (10) ‘The rate constant of a first order reaction at |$1. 300 K is 6-93 x 10 s~¥, Its half life period is () 100 min @ 1008 (3) 1000 min (4) 1000 5 32. ‘An important characteristic of enzyme catalysis is (1) high specificity (2) occurs in presence of light (3) rate increases with temperature 3. (4) rate increases with pressure 7 Which of the following compounds show cis-trans isomerism ? (1) 2-Butene (2) 2-Butyne (3) 2-Butanol (4) 1-Butanol Mesotartaric acid is optically inactive due to (1) two chiral carbon atoms (2) molecular unsymmetry (3) molecular symmetry (4) absence of centre of symmetry ‘The reagent used for separation of amino acids is (2) © phenolphthalein (2) ninhydrin 35. (3) methyl orange (4) methyl blue Lu/803 ‘The critical temperature for H is q@ src (2) ~ 240°C (3) 120°C (4) 100° ‘The constant ‘a’ in Van der Waals equation of state is maximum in (1) He @) H, @) 0, (4) NH; In the reaction AB, if the concentration of A is increased by four times and the rate of the reaction becomes double, the order of the reaction is (Q) zero @ 1 1 @ 3 4 2 ‘A chemical reaction A + 2B — AB, follows in two steps. A+B AB(slow) AB +B AB, (fast) ‘Then the order of the reaction is @ 3 @ 2 @ 1 @ o ‘The molecularity of a reaction is (1) can be zero (2) only a fraction (3) can be zero or a fraction (4) only a whole number1/809 26, 27. 28, 29. 30. aS BG [Shros og porosiy 300 K 3g 6-93 x 10° s” eogrosigy @ 1009 (2) 100% (3) 1000 9 (4) 1000 ® ans, do 1 wd DoBH a3y,68 WWgo dong of ato () eSg08 DAQS Q) S08 SFOS" wdsrbsod (8) ABS S8gSi0 Dotod0d (4) $8808 dem Uy Stho Dodra00 [> Si (80 HDS! BSS) SSyT "A (Sa070HS9 (1) Regd 2) 2engsS @) 2agord 4) Lexgord 34. hetirges vit = Go Be orirergdy [SGOVOSADE sSadw () Gok Z6S swyS Sordrmiymodo S08 Q) e&¥S ems voudosss (3) BS emi vd6o sod (4) 2H Solo Ssoesos 35. ePS vdrow SHSdaIS TI srdsS GQ) 9rd5Hd% 2) aSp am (8) 2BS woe ) b3S ar (4) 31. 32. H, Gio8y, SoOS SAWS @ sire @ 240°C (3) 120°C (4) 100°C w05 TS QB SH¥ImOS'D QrossHs ‘a’ Dos 61 BOO way’ vssosin @ He @) Hy (@) 0, @) NH, A 3 B e& Sogo! A aot, mgsw aoste Be» Bodsige (SA(So% (reaction) 3m Beodysod. word S Sy (WSrossn @ S& @ @ win + (4) A+ 2B > AB, 6% S8g Doc Siombr edotoeood A+ BAB (8&QO~), AB + B > AB, (&g0Sorr) word St Sos Warotiiy @ 3 @ 2 @) 1 a 0 28 88g ocd ) Wa) wow soddeey @ 3 (ay Daro%ov dotvod ey) TE Nmor*boriyossyy Sry Sows wav aom0d36. 37. 38, 39. (12) In a first order reaction, the concentration of product ‘x’ at time t is given by the expression a) x=a(1-e**) @ @) (4) In a zero order reaction the rate (R), rate constant (k) and the initial concentration of the reactant (a) are related by @) Reak @ @) “) ‘The half life period of a second order reaction is given by ay 988 @d @ & w * ‘The rate constant of a certain reaction is 1-25 x 10° lit mol”! s“). This information suggests that the reaction is (1) a fast reaction (2) a slow reaction (3) a first order reaction (4) a second order reaction 40. 41. 42, 44. Lu/809 . ‘The activation energy of a reaction is a @ the energy of the activated complex the energy difference between the reactants and products the energy difference between the activated complex and products the energy difference between the activated complex and reactants @) «) When pressure is applied to the equilibrium system ice * water, which of the following phenomena will happen ? a) @) 3) 4) More ice will be formed Water will evaporate More water will be formed Equilibrium will not be formed In which of the equilibria; does the position of the equilibrium shifts towards products, if the total pressure is increased ? QM b@+H,@=2HI@ (2) Ny (g) + 0, (@) = 2NO &) (3) Ny (g) + 3H, (g) & 2NH, (g) (NAO, (g) = 2NO, (g) In the equilibrium, 41,0 (g) + 3 Fe (s) = Fe,0, (6) + 4 Hy (@) the yield of H, can be increased by @ @ @) @ increasing the pressure passing more steam increasing the mass of iron decreasing the pressure Law of mass action cannot be applied to @) 2HIe H+ I, @ PCL, = PCI, + Cl, (3) water + ice (4) CaCO, + CaO + CO,1/809 36. 37. 39. 2S hm LSro$ sigs 1 srodesy [Boi adgty mgs ord GQ) xsa(1-e? 2) @) @ Arby SSroS Shs cat, de (R), do Qoosi (k) Haw Sar assy FD Bd (a) © BBs Sonos (@) R=ak (2) Reatk @ R=? @ R=* Ogboh [Sdrok Shs cht, epowoy Bsyosards wd Sbssadv 0693 a > 1 @ = re) sie wis @ aSSS Woy aot, doo Qrosso 125 x 10° 8 ard! wl ao & [80 Dhasrd Bexsyeood (1) 28 28 ShbosMSs Seg 2) 2B Syd aot svg (3) ab Sho Bros Woy (4) 20 OgBos Whos og (3) 40. a1. 42. 43. 44. as a (2) Sg odes 48 edad edioky obs, 48 Bor aks Hoa ar argo io kbs dor @) e828 adoss Sa Golraarzo the &bg dar () @828 aBodn Hdat Bakr adsro Abo &dg dar ho = bh Shep bewd) Barrnoasyew bBo Sry etorodood GQ) Sow waSorr D8ygoeod 2) Dt shygsso Bocosvos (3) S& wOSorr Idjesod 4) SHeHs Ose St (80D HOS D Ber pad’ dowd) DodSnto D Sy6$5* Sheys Bole Barge BH wdorowod 7 @ 1,@+H, @ #21 @ (2) Ny (g) + 0, (g) = 2NO@) (3) _N,(@ +3H, @) * 2NH, (@) (4) _N,O, (@) # 2NO, (g) SHERI 4 1,0) +3 Fe GS) Fe,0, ($08) + 4H, @) Bogs" H, awk Stood Dowsee () Sado Bord (2) 0% SxSod* O48 wd0D Sodd (3) adsby Boky grord) Domrd (@) bebo Showd Si Bod GDS Gdgrs Farr dosindw SQosdosdion @ 2HleH, +1, Q POL, = PCI, +Cl, @) do + sow (4) CaCO, # Cad +60,45. 46, 4. 48. 49. (14) ‘According to first law of thermodynamics, |51. q) aB=q-W (2) aB=qxW (3) AB =Aq+ Aw (4) AB =Aq+W ‘According to Kirchhoff’s equation, the following factor affects the heat of reaction : (1) Pressure 52. (2) Temperature (3) Volume (4) Molecularity ‘The reaction between AE and AH is (1) AH = AE ~ VaP (2) aH (3) AH = AE + VaP (4) AB = AH + PAV For the reaction, Ny + 3 Hy > 2NHg, AH = Q) aE + 2RT (2) AE-2RT () aB+R? (4) 4 be For an irreversible process AS is (1) zero @ <0 @ >0 (4) cannot be predicted 55. During isothermal expansion of ideal gas, its (1) internal energy increases (2) enthalpy decreases (3) internal energy remains unaffected (4) enthalpy reduces to zero AE + PAV 53, 1/809 ‘The Joule—'Thomson expansion of an ideal gas is an (2) isothermal process (2) isoentropic process (3) isoenthalpic process (4) isobaric process When ice melts into water, entropy (2) becomes zero (2) decreases (3) increases (4) remains same For a spontaneous chemical process, the free energy change is (1) positive (2) negative (3) positive or negative (4) zero ( ‘The relation AG = AH - TAS is given by (1) Boltzmann (2) Faraday (3) Gibbs (4) Thomson Hi, (g) + I, (g) = 2 HI (g); AH = ~ 12-40 keal According to this equation the heat of formation of HI is (1) 12-4 keal (2) = 12-4 keal (8) ~ 620 keal (4) 620 keal7809 45: GQHB why Bi Dos\iv [Ss-Ssw @ (2) @ CO 85 sh SbSdersHywsO0d 6 [E08 worn SOQ Ber dSo Tipod () bess @ egs @) SeSS0Src%9 @) ems AB S00% AH SBg fo Somos a @ 47. AH = AE - VAP SH = AE + PAV (3) AH =AE+ VAP (@) AB =AH+ PAV Ng + 3H, > 2NH, w& Sdgs* aH = a (2) @ (4) 48. AE +2RT AB -2RT AE +RT aE 49. vibdzyiordos WasS* AS Devs @ @ <0 @ >0 4) earostio 50. 85d) woke Sr} arg8'so Boasiys o @ @ ® ) wodOS 48 BYre08 oS4S Axo Sid odes 486 Srthy Godds w0S$S axin Lod) viydood (15) 51. 52. 53. 54. BI 55) sory FS-grodS aryS'siv Bods SSo% (1) Sarg BBs Q) 8% doS'DE Has (3) S%dogrODE [S|S0% (4) 3h Sab [SoH ow SA Storr Ars [SSo%S* 2016" () B%y whsod 2 Sioa (8) De&rbéod (4) 3Borr dod08 BySos GroHDS Bohs gory 4G arty GQ) Sry (2) ener dysio (8) GardySSo Bor aver dy8in oS) aG = AH - Sr dose CQ) SSeS @ eed (3) Ady ) @&yS TaS — w& Sowogrd H, (@) + 1, @) & 2 HI); AH = ~ 12-40 keal Si _ SESSersH Hood Sosostgen HI Gb, a @ (a) a) 12-4 keal = 12-4 keal = 6-20 keal 6-20 keal57. 58. 59. 60. (16) In an electrolytic conductor @ (2) @) co) electrons move ions move neutral particles move H,0 molecules move An aqueous solution of which of the following substances has a pH > 7? aM @ @ @) NaCl CH,COONa NCI KCI pH of the solution obtained after the electrolysis of aqueous NaCl using inert electrodes is, @ o (2) between 0-7 @) 7 ) >7 In potentiometric acid base titration, the potential of the following electrode changes : a) (2) @) @ quinhydrone electrode platinum electrode calomel electrode silver electrode Debye ~Huckel~Onsager equation is applicable to a) @ @) @) weak electrolytes strong electrolytes organie acids organic bases 61. 62, Lu/e03 The size of the ion decreases in f-block elements. This is explained as due to (Q) increase in atomic number (2) increase in mass number (3) lanthanide contraction (4) clectronegativity ‘The most important oxidation state of f-block elements is a) +4 2) +3 (3) 41 (4) 42. Which of the following is a polynuclear compound ? (1) (Co(NH,)4Cly] C1 (2) NaFe(Fe(CN),] (3) [CrH,0), CCL, (4) [(CO)g Fe(CO), Fe(CO),] Which does not obey EAN rule ? @) K,0Fe(CN),) (2) Ky [Fe(CN),! (8) [Co(NH,)g) Cl, (4) PNKCO),) Optimal isomers have A. property of chirality. B, almost identical chemical properties. C. almost identical physical properties. D. similar rotation of plane polarised light. o @ @) w A,B, C are correct B,C, D are correct A, C, D are correct A,B, D are correctLu/809 56. 57. 59. aigoghas assos* @ ® ®) ® dogryioer Sdooreron watr&ser Sbereron So% Sere SSeeron H,0 wmiyen Sdeoeron & (800 Sag eo[rsn’ pH > 7 vo» #08008 (1) Nac (2) CH,COONa (3) NH,CI (4) KCI NaCl 20 Sed, ad doFgtood BdaIrAOD Dergagdie arr 28a (whos pH Ded @o @) 0-7 © Sg domed @ 7 ) >7 PaQcrivod Lscinhod Tb segs 0% SrSrod! & [S08 dog gt dinky, ASD SrB\od A) 8g837 BH dose 2) PBSo doSyeh @) 26S 208 (A) BEg5 dose BB-HBTOS IKE SbSdaso 8% Sgioo. () webs Ddgogdangen 2) weBs dogoedargen @) spas vérw 4) eas sore a7) 61. 62. 65. 8 fapts Brose soiree Sonne SHSOH srdea0 (1) Shire Sows BH (2) (BSgorR Hows Beste (3) P0685 So8'sso A) amnddogersgys fers Srosedt 8S 9B M4 @ +3 (@) 41 (4) 42 edgoS Songs Ss [808 DIS wire Foss Sayesin () (Co(NH,),Cl,]Cl (2) NaFe[Fe(CN),] (8) (Crd, 0), CCI, (4) (CO), Fe(CO), Fe(CO),} EAN doiirdy wd YD0So @ (2) @ a K,{Fe(CN),l K, [Fe(CN),] [CotNH,),} Cl, {Ni(CO),] (Se Sdyrgo osso A. Brod. B, Go) BSrS dows Soyo) On aodbo. C. way Sirs TBS Soyow son Bodo. D. Sho g)dBs soBd ef d¥or (S00 Bodzrov. @ @ @) (4) A, B, C are correct B, C, D are correct A, G, D are correct A, B, D are correct67. 68. 69. ‘70. (18) ‘The conjugate acid of a strong base is a 71. (1) strong acid (2) weak acid (8) strong base (4) weak base Which of the following is an acid and also a conjugate base of another acid ? 72, (@) HSO; @ 1,80, (@) NO; HO" According to Pearson concept, the soft base among the following is 73. ke @ Br @ HO (NH, Hard acid among the following is 74. @ BH, @ (3) Os** @ Ht The transition metal present in the alloy gun metal is 75. @) Ca @ Ag @) Au () Fe 1/808 ‘The bonding molecular orbital has energy as compared to atomic orbital from which it is formed, (1) lower (2) higher (3) same (4) higher or lower In the area of H, molecule, the number of resulting molecular orbitals is the same as, (1) number of atomic orbitals (2) antibonding orbitals (3) bonding orbitals (4) non-bonding orbitals If an electron is removed from the antibonding orbital of a molecule its stability (2) increases (2) decreases (3) remains same (4) may increase or decrease Elements of zine group (Zn, Cd, Hg) are called (1) noble metals (2) coinage metals (3) volatile metals (4) precious metals Amongst LiCl, RbCl, BeCl, MgCl, the compounds with the greatest and least ionic character are () LiCl, Rect (2) RbCl, BeCl, (3) RbCl, MgCl, (4) MgCly, BeCl,Lu/809 66. 28 a @) @) w BOBS SY Sooty vdeo Bes vido wolrs edgy Dogs goin wold sod 67. & [S08 TAS DB wid Hook STS why Hooker, gvS Corso (@) HSO; 2) H,S0, (3) NO; () HO" 68, DBESS orbs Bsn se God rds" ayoessy eee @ Br ® (a) H NH, 69. & (808 EDS S08 wisn (BH, @ hb @) w os** Ht 10. Wists SSHOSSD SSG Sarosén a) Cu (2) Ag 3) Aw (4) Fe (alloy) (19) 71. 72, 73. 74. 75. a Shrew “GOSS 48 Sh) dD Lod D87aS om ODES 4B 8s @) 28 @) Sérsbv (4) dy BE S8yS H, ems" D088 ve wOyere) Sows & Sordén, a @ oo) @ Stow woyErsy Sowg wdn0g wOyirvy Song Do wdyirey Song wns GO a Sony emysD vdnos v5 0d af dopey Sonodsint ord gssgin (1) BerH0B 2) Sie08 @) Sr8e (8) BENS Sar SHSsyy 20 jw tarosro (én, Cd, Hg) & woth, 6828 Sete wai Sten wayto Sse Dass Sse a @ @ ) Lil, RbCl, BeCl,, MgCl, od we&go¥ Boo edso) CARDS ofa fo Saigeerer @ @ ® w LiCl, RbCl RbCl, BeCl, RbCI, MgCl, MgCly, BeCly76. 71. 78. 2. 80. (20) A real.gas obeys ideally at 81. (2) low pressure and high temperature (2) low pressure and low temperature (3) high pressure and high temperature (4) high pressure and low temperature Tonic solids are characterised by (1) good electrical conductivity 82. (2) high vapour pressure (3) low melting point (4) solubility in non-polar solvents Geometrical isomerism in square planar 83. complexes is given by (2) Ma, complexes : (2) Magb complexes (8) Magb, complexes (4) Mb, complexes [Co(NH,), Br) SO, and (Co(NH,), $0,] Br are examples of which type of isomerism ? (2) Linkage (2) Geometrical (3) Tonisation (4) Optical The number of ions formed when [Cr(H1,0), Cl)Cl, ionises in solution is, ay @ 2 @) 3 w 4 84. Lu/809 ‘The uranium (mass nuniber 238 and atomic number 92) emits an a particle; the product has the mass number and atomic number (1) 236 and 92 (2) 234 and 90 (3) 238 and 90 (4) 236 and 90 Gamma rays are () high energy electrons (2) low energy electrons (8) high energy electromagnetic waves (4) high energy positrons In a certain radioactive decay, an electron is emitted. It comes out from (1) outermost orbit of the atom (2) inner shells of the atom (3) nucleus of the atom (4) penultimate orbit of the atom 2/Al is a stable isotope. {3Al is expected to disintegrate by (1) a-emission (2) fremission (8) positron emission (4) proton emission A. radioactive sample has half life of 1500 years. A sealed tube containing 1g of the sample will contain after 3000 years @ 10g @) 05¢ 8) 025 ¢ (4) 000g1/809 76. Dewos% ord) [SSO7VOB. (2) wey SBSH Sak VOY aRKS 2) wey SSSsiw How voy aA WKS 8) 9G8 Sosdv HOow vos agQyNs (4) ©88 Bis HOow voy aRiss SB B58) ro 11. eo d8 Hd Sarre ofan (1) Hod Déogorginys (2) OE eripPos 3) vey BdSSS SAIS (4) wdyb wddod whdoss 8. swdo SHSssy Sood. Fs dSyergdy SSO (2) Ma, SoRe (2) Mab SoRgres (3) Magb, Soares (4) Mb, So8gren [Co(NH,), Br] SO, 00% (Co(NH); 80] Br SSywgh8 aorvIoo. (20g @ 3s 8) eohdsto @) &8- [Cr(H,0), Cl Cl, vososdasy Sodsspyso AIH worry Sows. @i @ 2 @) 3 w 4 (21) 81. 82. 84, 85. B Sehr Sows 92 eS dowg 238 Ho oieddoho o-terd dddo adie Doyh Sorys rd Bong Loos Soir Song (1) 236 Sox 92 (2) 234 & 00% 90 (3) 238 ¥0ox» 90 (4) 236 S:0% 90 mar Bore a @) 888 48 Ho dogo v0) %8 Ko dogyien (@) eO8 48 Ho Bhgtosdyos sdorred A) 808 48 fo Haire : 28 8BEIrGDE Sobos* dogyyf BerSaso. 6d 0d Sehyss. (1) S8hreak aod, orig 88g (2) S8érmiy Anky ods SSrH @) SdSrmiy Solsssn (A) Boreas aww, adosy 85 Hal aS QS Shpdoviy word Al 3 2 33 od Sesto () wagrie @ pagss (8) daerS-agsso (4) Biers agrody aS dadir crops Bros egomy 1500 So. e. 2S rdw St Sorgrdy 28 MOSS HOD be Sosgs 3000 So.0 Shards DAS Sorgen @ 10¢ @ 058 8) 025 g @ 0:00 g86. 87. 88, 89. (22) ‘The number of a and particles emitted in [91. the nucleon reaction 723Th > 712 Bi are @) 4a and 1p @) 3a and 7p (3) 8a and 1p (4a and 7p According to kinetic energy of gases, (2) there are no intermolecular attractions between gas molecules 92. (2) there are intermolecular attractions between gas molecules (3) the velocity of molecules decreases for each collision (4) molecules have no volume ‘The molecular velocity of any gas is (Q) proportional to absolute temperature (2) proportional to the square of absolute |93. temperature (3) proportional to the square root of absolute temperature (4) independent of absolute temperature In Van der Waals equation of state for non-ideal gas, the term that accounts for intermolecular forces is @ v-b @ RT a @ P+ te @ Ty ‘The units of Van der Waals constant ‘a’ are a) @ @ a atm lit mol” atm lit? mol atm? tit? mol" lit atm mol Luisog Rutherford's alpha particle scattering experiment led to the conclusion that (1) mass and energy are related (2) electrons occupy space around the nucleus (8) neutrons are buried deep in the nucleus (4) the point of impact with matter can be precisely determined When alpha particles are sent through a thin metal foil, most of them go straight through the foil because (1) a-particles much heavier than electrons are (2) @) a) o-particles are positively charged most part of the atom is filled a-particles move with high velocity The half life period of a radioactive element is 140 days. After 560 days, one gram of the element reduces to m de. @ J (3) ie w te ‘The ratio of the energy of a photon of 2000 A wavelength radiation to’ that of 4000 A radiation is i aM 4 @ 4 1 3) 2 @ 5 @ 2Lu/809 86. 87. 88. 89. 90. 2th > *2Bi de Soss soge* Sordd a Bom B Soro Sows (1) 4a SOo% 18 Q) 3a Sa 7B @) Soa 1p “ Soa 7B So ayow aposin (Soro () arate wmiyo dog vost vSYs aeore dH wots emo Ogg vost wks weren dotran G8 aS eds S0Sor emyo Siho Sid (4) emvot ossoirate deo woh emyo Sito () 88 SSE sAYVSH chdEro Sos Got0d 8a, 40, @) @ 2) 88 «SE AIS HPPDB eH ErHISoS* Goov0d (8) S08 SSE aQYiS Symrords SMSF SOS* Gotvod B6h GSE aBUSp ead dsc moi sgod sr0t5 oF 98 eosin aro Sys @ De SeosSm05%, BHLS Soo a) v-b @) RT oa @) v @ ant BodS oS Prosss ‘a’ oky Shrew (@) vty 5 ars? @) very 0? ard? (8) etry? 8? ard? @ d ey ad (23) 91. 192. 94. 8] SrSENG very So So8so [Sairisin DDS Heroin GQ) Ggr8 — S0a = Ho Say Sowogainsye 2) dogyes Fowso wy ad Sera) wEBQon 3) @ SrgirH SoSsos* krHWO aoerav Sogou wePSrso wOAs Dossy Bd)Sor SHITSifoso wer) Serd) Sor Sy dH toa Sods wOS Somgs* Sore Storr Stow Sorrdosard$ sSesn () aera dogryivo BOBSD akoe Sordi $08 SShrayso wo ariiio D048 Bot08 Serer 66S SxoS' Séomeron a Baar GOS Sosy egrosniy 140 Sew, 560 Seos* of "rio Sogo & §cdipod. Cy) sey oe @ @ ) g wie @) @) CO) 2000 A &:Bo% 4000 A S6oNBsginen Ko Beh AHo Logg NB a (2) @) © wie @95. 97. 98. 99, (24) Which of the following docs not characterise Xerays? (Q) The radiation can ionise gases (2) It causes ZnS to fluoresce (8) Deflected by electric and magnetic fields (4) Have wavelengths shorter than ultraviolet rays Potassium erystallises in a BCC lattice, hence the coordination number of potassium in potassium metal is Mo @ 4 @) 6 8 The positions of CI” ions in NaCl structure are (2) corners of the cube @ (3) centres of faces of the cube corners as well as centres of the faces of the cube (4) edge centres of the cube Space lattice of CaF, is (Feo (2) BCC (3) Simple cubic (4) HOP. Solid CO, is an example of @ @) (3) ionic erystal covalent erystal metallic crystal 100. 101. 102. 103. 104, (4) molecular erystal Lu/809, An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the centres of the faces of the cube. The empirical formula for this compound is (1) ABs @) AB @) AB @) AB ‘The elements on the right side of the periodié table are (2) metals (2) metalloids (3) non-metal (4) transition elements ‘The element Californium belongs to a family of (1) Actinide series (2) Alkali metal family @) “ Alkaline earth family Lanthanide series Which one is the correct order of the size of iodine species ? @ @) @ 1 @) I>Tor I>Dor >Dot >ist Which of the following elements have the lowest first ionisation potential ? @ Mg @ Rb @) Li @) CaLu/g09 95. 97. 98. 99. Si (80d PDS X-Biaino ofesn H8 (1) ad waged — wobdEdeato Bodosrtesy ZnS 0d BHR Serddogp DZrav DogS HOt wobayos Ysos* wSSGSo Boderon wado SS BWero 8 SsRs Sot Borgdy SON oswotron @ @) w Serhoso BCC eos Ss ywipod sus Pernosod® Sod! FerRoo divsy, SSrhgow Sows @o @ 4 @ 6 w 8 NaCl doywos* Cl wairo Faren GQ) HsSn ow, teroe 2) Sy Soro Sores (3) 88> ok, roe Hoa sero doe (A) Sk wore AeSgdoeiger CaF, Gok, |aSe erossn a @ @) Oy FCC Bcc drhrbs Sosso HOP $8 CO, & [S08 D8 aarérdea (1) eathds Sys8So 2) SEO SyBso @) Se SySsoo A) oem SyS8hm (28) 100. 101. 102. 103. 104. 8] aS wolhds Soryiy (sre DSS A wore Shin oie roo 6 B Core HS Ak, doo Zocro ss Bayo. words 8 Sogn wierd¥ Poe @) AB, @ AB @) AB @) AB wSGS BYSH HIBY oh Srosn Q) SéFen Q Siren @) edtiten $085 Srosres SdZ0)a%0 Awro¥o Boeoaod Q) 638 Ge @ 2d Se Semon (8) 2 BAKS*Ho Seow» 4) rogses fied I &0om GD varwe Sdhrore & {808 Si0d* Gosran Si (80B aS Oeie eis @ 1>r>r @ orm>t @ Geter SSO TNS BSEYS = HSH. wobhsde 45ry2) HORS rosso a) Mg (2) Rb @) Li (4) Ca105. 106. 107. 108. 109. (26) ‘As one moves along a given row in the periodic table, electronegativity (2) remains same (2) increases (3) first increases, then decreases (4) decreases when we move from left to right. ‘The types of bonds present in CuSO, . 5 H,O are (1) electrovalent and covalent (2) electrovalent and coordinate covalent, (8) electrovalent, covalent and coordinate covalent, (4) covalent and coordinate covalent Which of the following cannot exist on the basis of molecular orbital theory ? @ (2) He} (3) Hey 4) 0, The bond order of a bond according to molecular orbital theory a) @) @) Oy cannot have a negative value always has an integral value is a non zero quantity can assume any value including zero ‘The second order Bragg diffraction of X-rays with 4= 1-00 A from a set of parallel planes in a metal occurs at an angle of 60°. The distance between the scattering planes in the crystal is @ 0575 A @) 100A (3) 200A @ 116A 110. a1. 112. 113, 114, Lu/809 A transition metal X has the configuration [Ar] 3d* in its +3 oxidation state. The element. is Q) Mn @ Fe @ 1 @ K Which of the following ions has the same number of unpaired electrons as that of V3+ fon? a @) @) w os Mn2* Ne Fe? Which of the following statements regarding transition elements is false ? (1) Their atoms contain partially filled orbitals (2) They are capable of showing variable valencii @) w Alll of their ions are colourless ‘They form complexes readily ‘The transition metal that has stable configuration in +1 oxidation state is a Cu (2) an (3) Se 4) Ca ‘The highest oxidation state is achieved by transition elements with the electronic configuration a) d's? (2) dst (3) ® as? abs?Lu/e09 105. 88S S8SS'D Glmod® adys Swss* 26H Mod G48 Shdros ova Rhgorayys @) gor dos08 2) Xs 08 HAE Dés*oeoB (8) Axo BON Stars Sreod (1) 2th H08 HAE SHH0d 106. CuS0,. 5H,0 6 fo woe GQ) RogS Sodirak Moa Swoiradas 2) 2gS Soctras Look Srsgow SHorrados (3) dtogS Sodras, Swairados LOaxo Bhrvgos sirerredos (4) Skdirados — Look + sirsgows sharedos 107. & (808 TIS, em wojwro Spossv [Osrdw, 289400 @ HY @) He} (3) He, @ 0, 108. om voy dposin [Ssdan at nogén ain, vod (Sévio (1) ane doxd wonsyotiess 2) dgdpe aS SY Sows (8) && vaxsyouids (4) Sms SoD Ows Botbeoys a Simty ShroSS Soro S8 = 100A SSorBYgso fo X-BGrer eri Ogos [8H BSG BoBs Seiv ders 60° wos © SySH SoESo Sore Hggeirvion a) 0575 A (2) 100A (8) 200A @) 115A wos 109. (27) 110, 11. 112. 113. 114, BI 28 S0SSS Serodin X od +3 whysto QOc* [Arlsdt Darged) SOA ama. vont 8 arose () Mn @ Fe (3) Ti (4) K & Bod ads! JdS‘D 2080 Dogywo Song V* 51 2068 Dogyiro Somge Sarsh> (cr (2) Mn** @) Ni (4) Fe S08IS Srosros Son09005 ssp DSoe GQ) SE Sthrmbos* HZsorr Dds d-woyereopotron DDE SByo%\ [Sd0705 Koy BE woiriody Sor 3dd ©d BOS SoFPoH IyHZ-ov @ @) w +1 088d QBST QS Dogma) sons SOSGS Srosso @ @ @) @ Cu Zn Se ca Si God Dogiin So SOSYS Srosm eSsO8 8ySOm QOD SCZ a) as? @ ast @ w ds? abs?B 115. 116. 117. 118. 119. 120, (28) For the first row transition metal ions, the magnetic moment in Bohr magnetons is calculated by the formula a) ya@+D (2) J4s+D (3) yn?(n +2) no? +) Which of the following is an alloy of a metal and a non-metal ? (2) Bronze (2) Electron (3) Nichrome (4) Steel Which of the following compounds is coloured and paramagnetic ? @) ScCl, @ Tcl, (3) CrCl, (4) CuCl In complexes, the primary valency of metal is always equal t a Oxidation number (2) Coordination number (3) Atomic number (4) Mass number The ligand in K, {Fe(CN)g] is @ K (2) Fe (3) Fe* @ cn” The effective atomic number of iron in [Fe(CN),I* is a 34 @) 36 (@) 37 (4) 35 121. 122, 123, 124, 125, Lu/809" According to Freundlich's isotherm x v0 a X= hp @ Bat” (3) xm = kp!” = or @ =. m~ pu ‘The extent of adsorption from solution decreases with (1) decrease of temperature (2) increase of surface area (3) increase of temperature (4) increasing the concentration of solute Hy ~ Cl, reaction is @ @ @) “ molecular reaction catalytic reaction oxidation reaction chain reaction According to Beer—~Lambert’s__ law, absorbance is proportional to qa @ co) «) (concentration)" (concentration)! (concentration)® (concentration) An acidic buffer is () NH, + NH,CI (2) Na,PO, + HPO, (3) CH,COOH + CH,COONa (4) NaOH + NaClLu/809 115. Svs ied FOSS Larose woh yos rosary SE Dihergo* Ss, oes BH HIYO yard (2) J4s6+D 3) yn'a+2) Ya? 116. 6 (S08 wad 2 Stértn Ooty af SSivkno 08 Iyd Se Mpho GQ) Sow 2) dog @) aS @) ge 117. [808 2lXSSgvo5* (compounds) Sor Hoa Srasayzos o¥erdy (5070S (1) SeCly 2) TiC, (3) CrCl, (@ CuCl 118. SoRFOS* Sto | GN, |HHDE SodirakS & Bod ods sardin () B8)d45 Sows (2) S&Sg0% Song (8) Sire Somg (4) Wager? Somg 119. K, [Fe(CN),] 5 Sioes ee: (2) Fe (3) Fe (4) CN" 120. [Fe(CN),]* 6 BSS ok, GBerawrdys Sire Sowg @ 34 2 36 (3) 37 (4) 35 (29) 121. 122. 123, 124, 125. (P0598 Sarg dp Bsrvo a) Xai 2) Ba kp” (3) xm =kp"™ x k © ao Ge [Sako Lod zt woo s Siosoo. GQ aYPISS* Seo 2) 8080 Srogind Dinihso 8) ag WSS" Berdo (4) (PY MESS DMSO Hy-Cl, 58 () emo Sig addr og 2) G87 88 og (8) w8y8d00 Seg (4) Howe svg DE - roof Dosiodo Bessy aor oss % ehSEro Sdod* dosv0d. a) res" (2) (mgs)? 3) (ngs)? @ «res? & (S08 TIS v o$F @ @ @) NH, + NH,Cl Na,PO, + HPO, CH,COOH + CH,COONa (4) NaOH + NaCl5 126. Enzyme catalysis is studied by a @ @) @ 127, In conductometric titrations, Gibbs Arrhenius Michaelis ~ Menten Bohr varies with wo @ a) “ resistance current concentration potential 130) conductance 128, The ionic conductance is maximum for @ @ @) «@ H? ions OH” ions Cr ions Na* ions 129. K,, for the reaction CaCO, (s) = CaO (8) + CO, (g) is a) 8) a) [cao][co, " [eaco,| [caco,] [cao][co,] [c0.] 130. 131. 132. 133. 134, Ly/809- For the reaction 280, + 0, * 250, the units of K, are (1) molefiitre 2) litrefmole (3) mole*Aitre” (4) litre®/mole” Methane can be prepared by (1) Wurtz reaction (2) Decarboxylation (3) Hydrogenation reaction (4) Alkyl magnesium bromide ‘The most strained cycloalkane is (1) cyclopropane (2) cyclobutane (3) cyclopentane (4) cyclohexane How many types of carbon atoms are present in 2,2,3-trimethyl pentane ? (1) One (2) Two (3) Three 4) Four Which reaction represents an example of Friedel - Crafts reaction ? + CyH,Cl Ah, C,H, - C,H, +HCl MM @ oH 0H + Ho 2°, o,H,01 + H,0 (9) CgAol + cHcoc1 “1s, CgHsCOCH, + Cly (4) CyHgBr + Mg thet CH,MgBr ally HyLy/809 126. DoBS-as SS Sogop SOPs s*DOOSD ay Ady (2) edd0b5 (3) BEOSHooS wr SPSS wokirSwod? Tess BF Se Sr*1D @ <1D Microwave active substance among the following is q@) HCl @® a, (3) CO, 4) 0,14/809 145. DDH a @ @) “ 146. a @ @) @ 147. @ @ @) @ $08 Dvy theron. emiver emma Soy don eagdeo DbBS C esr S8QOS wiyho og dS vito wd7008 vio edYS who woyorondoe #8 ofsds fod e& ofesm Kod So dgerbiw Sod wogiiene (38) 148, 149, 150. a (2) @) a) woyeronthh 2S acrérS, wases fr Stor oe rh CCl, v8, Og\S95 erbdo a) (2) @) @ oD 1D >1D <1D G08 PIS BESS Foirho Sogn a (2) 3) @ HCI cl, co, 0%(36) SPACE FOR ROUGH WORK Lu/g03