JEE - ADVANCED

SAMPLE TEST PAPER-2

(MATHEMATICS + PHYSICS + CHEMISTRY)

PART : I MATHEMATICS 5. If the axis of a parabola and transverse axis of

rectangular hyperbola is same and the vertex
SECTION – 1 of the parabola is same as center of
 This section contains FIFTEEN questions rectangular hyperbola then if locus of the point
 Each question has FOUR options (A), (B), whose chord of contact with respect to the
(C) and (D). ONE OR MORE THAN ONE of parabola touches the hyperbola is a curve then
these four option(s) is(are) correct (A) curve is ellipse with the same center
(B) curve is ellipse whose axes concide with
2 the axes of the hyperbola
1. A point is moving on the circle (x – 4) + (y – (C) curve is hyperbola with the same center
2
8) = 20, then it broke away from it and moving (D) curve is hyperbola whose axes concide
along a tangent to the circle cut the x-axis at with the axes of the hyperbola
point (–2, 0). The coordinates of the point on
the circle at which the moving point broke 6. For positive real numbers a,b,c such that a + b
away can be + c = p, which of the following hold good ?
 42 36   2 44  8 3
(A)  ,  (B)  ,  (A)  p  a  p  b  p  c   p
 5 5   5 5  27
(C) (6, 4) (D) (2, 4) (B)  p  a  p  b  p  c   8abc
2. If the normal at P to the rectangular hyperbola bc ca ab
2 2
x – y = 4 meets the x,y-axis at G and g (C)    p
respectively. If C is the centre of hyperbola,
a b c
then (D) (p – a) (p – b)(p – c) < 8abc
(A) PG = PC (B) Pg = PC
7. The number of ways of choosing triplet (x,y,z)
(C) PG = Pg (D) Gg = 2PC
such that z  max(x, y) and x,y,z  {1,2,...n,n
3. If the quadratic equation + 1} is
(A) n 1C  n  2C
ax 2  bx  c  0( a  0) has sec2  and 3 3

cos ec 2 as it's roots ( R ), then which of n ( n  1)(2 n  1)

(B)
the following must hold good? 6
(A) b + c = 0 (B) b 2  4 ac  0 (C) 1  2  ........  n 2
2 2

(C) c  4a (D) 4a  b  0 n2

(D) 2. C 3 
n 1
C3
3 2
4. If the roots of equation x + px + qx – 1 = 0 8. Let A denotes the product of values of m, n
form an increasing G.P., where p and q are and p where m = log34, n = log46 and p =
real, then log627, B denotes the value of
(A) p + q = 0
(B) p  (–3, ) log 2
( 42 3 – 4 – 2 3 ) and C denotes
(C) one of the roots is unity the value of 'a' for which the quadratic equation
(D) 1 lies between the roots 2
(a – 1)x – (a + 1)x + (a + 1) = 0, a  R, is such
that sum of the squares of roots is two less
than their product. Then which of the following
is/are correct ?
 (A) A + B = 5 (B) A + B = 6
5 SECTION – 2
(C) (B + C A) = (D) (B + C A) = 3  This section contains FIVE questions
3
9.
p q r
If the divisors of n = 3 . 5 . 7 are of the form  The answer to each question is a SINGLE
DIGIT INTEGER ranging from 0 to 9, both
4k + 1, k  0 . Then
inclusive
(A) p + r is always even
(B) p + q + r is always odd
(C) q can be any integer 16. In a triangle ABC,
(D) if p is odd then r is even
2 if cosA + sinA – = 0,
10. If the product of the roots of the equation 2x +
ax + 4 sina = 0 is 1, then roots will be
imaginary if then the value of is
 7  
(A) a  R (B) a   , 
 6 6
  5   3  17. Number of solutions of
(C) a   ,  (D) a   , – 
6 6  2 2 in
is
11. The least positive solution of
sin  ( x  x )  sin x 2  0 is  The tangent and normal to the parabola y2 =
2
18.
(A) a rational number 8x drawn at (2,4) intersect the line x + y = 3 at
(B) an irrational number of the form  the points A and B respectively. If AB subtend
a right angle at the vertex of the parabola then
 1
(C) an irrational number of the form , absolute sum of all possible values of  is
4
where  is an odd integer
19. If N is the number of ways in which a person
1   1
(D) an irrational number of the form , can walk up a stairway which has 7 steps if he
4 can take 1 or 2 steps up the stairs at a time,
where  is an even integer N
then the value of is?
12. In a ABC , A , B  (1, 2), C  (2, 3), 3

point A lies on the line y = 2x + 3, where 20. If the eccentricity of the hyperbola
are Integers, and the area of the triangle is S is times the
such that [S] = 2 where [.] denotes the greatest
integer function. Then the possible coordinates eccentricity of the ellipse .
of A can be
(A) (–7, –11) (B) (–6, –9) Then the smallest positive value of  is .
P
(C) (2, 7) (D) (3, 9)
The value of P is?
13. Let N = 2 + 22 + 222 + …. upto 30000 terms.
(A) last four digits of N are 8580
(B) last three digits of N are 580 PART - II : PHYSICS
(C) last four digits of N are 7580
SECTION – 1
(D) last digit of N is 0
 This section contains FIFTEEN questions
14. ABCD is a square of unit area. A circle is  Each question has FOUR options (A), (B),
tangent to two sides of ABCD and passes (C) and (D). ONE OR MORE THAN ONE of
through exactly one of its vertices. The radius these four option(s) is(are) correct
of the circle is less than or equal to
(A) 2  2 (B) 2  1 21. A train is moving with constant speed along a
1 1 circular track. If length of the train is one fourth
(C) (D) of length of circular track then which of the
2 2 following is/are correct options (Assume that
sound source is at engine) :
15. The equation
(A) Frequency observed by a passenger who
is sitting in the middle of train (equidistant from
has front and rear end) will continuously increase.
(A) Four real roots if a > 2 (B) Frequency observed by a passenger who
(B) Four real roots if a < –1 is sitting in the middle of train (equidistant from
(C) Two real roots if 1 < a < 2 front and rear end) will remain constant but
(D) No real root if a < –1 more than actual frequency.
 (C) Frequency observed by a passenger who 24.
is sitting in the middle of train (equidistant from
front and rear end) will remains constant and
equal to actual frequency.
(D) Wavelength observed by the person who is
on the rear end of train is more than the actual
wavelength of sound wave.
22. In a flexible balloon, 2 moles of SO2 having
initial volume of 1kl at a temperature of 270C is
filled (SO2 is a non-linear triatomic gas). The
gas is first expanded to thrice its initial volume
isobarically and then expanded adiabatically so
as to attain its initial temperature. Assuming
25
gas is ideal and R = Jmol-1K-1.
3 25.
Choose the INCORRECT option(s).
(A) Change in internal energy of the gas in the
4
isobaric process is 2.5 × 10 J
(B) Change in internal energy of the gas in the
4
isobaric process is 3 × 10 J
(C) Work done by the gas in the whole process
is 35 kJ
(D) Work done by the gas in the whole process
is 40 kJ
23. Consider one mole of an ideal monoatomic gas
inside a fixed, perfectly insulating cylindrical
vessel at temperature T and piston is at
equilibrium initially as shown in figure. Now a
particle of mass
m strikes horizontally to piston of same mass at
mid–point of piston and sticks to piston. Initially
mv 2
temperature T = , where R is universal gas
R
constant) (Neglect heat loss through piston,
assume that velocity is so small that change in
the temperature of gas due to motion of piston
is simultaneous in whole volume) (Gravity and
26.
friction is absent everywhere) Choose the
correct option(s)
(A) Ratio of maximum temperature and
minimum temperature of gas during motion of
piston is 7 : 5
(B) Ratio of maximum temperature and
minimum temperature of gas during motion of
piston is 6 : 7
(C) If particle strikes elastically then ratio of
maximum temperature to minimum
temperature during motion of piston is 1 : 2
(D) If particle strikes elastically then ratio of
maximum temperature to minimum
temperature during motion of piston is 4 : 3
Choose the correct option(s)
(A) A tight string is fixed at both ends and
sustaining standing wave then at the middle,
antinode is formed in odd harmonic
(B) A tight string is fixed at one end and free at
the other end then at the middle, neither node
nor antinode is formed.
(C) Standing wave is formed in an open organ
pipe and end correction is not negligible, then
phase difference between SHMs of any two
particles will be either  or zero.
(D) Standing wave is formed in a closed organ
pipe and end correction is not negligible. then
at the middle, neither node nor antinode is
formed
An elastic ring of mass 'm' and force constant k
(stiffness) is released from rest in a smooth
cone of semi vertex angle  from horizontal
position as shown in figure. Initially the ring
was in natural length : Choose the correct
option(s)
ring
g
(A) initial acceleration of any point on
circumference of ring is g
(B) initial acceleration of centre of ring is g
2
cos 
(C) maximum vertical displacement of centre of
mg cot 2 
ring is
2 2 k
(D) at the moment of maximum vertical
displacement acceleration of centre of ring is
zero.
A semi circular disc of radius R is placed on a
smooth horizontal surface. Figure shows top
view of this. If temperature is increased by t
then displacement of (coefficient of linear
expansion is ) :
A
y
B
x
C
(A) A along y-axis is Rt
4R
(B) A along x-axis is – t
3
(C) B along x-axis is Rt
(D) B along y-axis is zero
27. An external force 6N is applied on a sphere of 30.
radius R = 10 cm of mass 1 kg and the sphere
moves in a liquid with a constant velocity 5 m/s
making 530 with the horizontal. The coefficient
of viscosity of the liquid is 20/(6), in S.I. units.
(Take g = 10 m/s2). Choose the correct
option(s) :
31.
(A) The viscous force on the body is 10N.
(B) The effective weight (weight – upthrust) of
the body is 8 N
(C) The direction of the external applied force
must be horizontal.
(D) If the external force is suddenly removed
the acceleration of the body just after the
2
removal of the force will be 6 m/s .
28. A particle is subjected to two simple harmonic
motions along x and y axis according to, x = 3
sin 100 t, y = 4 sin 100 t.
(A) The path of the particle will be ellipse and it
is moving in clockwise direction.
(B) Motion of particle will be on a straight line.
(C) Motion will be a simple harmonic motion
with amplitude 5.
(D) Phase difference between two motions is
 2
. bubble then r2 = R
2 5
29. A small ball of mass m is released from rest
from a height h above the liquid surface. The
density of ball is : (assume no splash)
3
32.
(A) If h  H, then the ball will be able to enter
the liquid of higher density
7H
(B) If h  , then the ball will be able to strike
2
the bottom of the vessel
(C) If h = 2H, then the ball will cross the
interface of two liquids with kinetic energy =
mgH
(D) If h = 0 then ball will float on the surface
An experiment measures quantities a, b, c and
ab2
x is calculated from x = 3 . If the percentage
c
errors in a, b, c are ± 1%, ± 3% and ± 2%
respectively.
(A) The percentage error in x can be ± 13%
(B) The percentage error in x can be ± 7%
(C) The percentage error in x can be ± 20%
(D) The percentage error in x can be ± 26%
Two spherical soap bubbles in vaccum are
connected through a narrow tube. Radius of
left bubble is R and that of other is slightly
smaller than R. Air flows from right to left very
slowly. At any instant r1, A1, V1, n1 are radius,
surface area, volume and number of moles of
gas in the left bubble and
r2, A2, V2, n2 are same for right bubble. Assume
that temperature remains constant : Choose
the correct option(s)
(A) The rate of change of " n1 + n2 " with
respect to time is zero
(B) The rate of change of " A1 + A2 " with
respect to time is zero
(C) If at an instant number of moles in left
bubble is 4 times of number of moles in right
(D) If at an instant number of moles in left
bubble is 4 times of number of moles in right
8
bubble then r1 = R
5

A boat crosses a river at a velocity v (relative
to water) that is constant relative to water and
perpendicular to the banks. The magnitude of

the velocity v is 0.3 m/s. Width of the river is
b = 63 m. Speed of the current varies
according to the parabolic law.
2
4u0  b
u = u0 – 2
x – 
b  2
where x is distance from the banks and u0 is
constant equal to 5m/s. Choose the correct
options.
(A) Drift of the boat during the time it crosses
the river is 1050m.
(B) Drift of the boat during the time it crosses
the river is 700m
(C) Time taken by the boat to crosses the river
is 210 sec.
(D) Time taken by the boat to crosses the river
is 12.6 sec.
33. Position verses time graph for a particle is SECTION – 2
shown in figure then select correct  This section contains FIVE questions
alternative(s)  The answer to each question is a SINGLE DIGIT
INTEGER ranging from 0 to 9, both inclusive

36. A ball collides elastically with a massive wall

moving towards it with a velocity of v as
shown. The collision occurs at a height of h
above ground level and the velocity of the ball
just before collision is 2v in horizontal direction.
Then the distance between the foot of the wall
and the point on the ground where the ball
lands (at the instant the ball lands) is
2h
n v , where n is :
(A) Particle does not change its direction of g
motion during the motion from t = 0 to t = T
(B) Particle changes its direction twice during v 2v
the motion from t = 0 to t = T
(C) Acceleration of particle changes its h
direction once during the motion from t = 0 to
t=T
T 37. A particle is suspended by a light vertical
(D) Direction of force is reversed at t = inelastic string of length  from a fixed support.
2
At its equilibrium position it is projected
34. Heat is supplied to a certain homogeneous
sample of matter at a uniform rate. Its horizontally with a speed 6g . The ratio of the
temperature is plotted against time as shown in tension in the string when the string is in its
the figure. Which of the following conclusions horizontal position to that in the string when the
can be drawn? particle is vertically above the point of support
is x : 1. Find 'x'.
38. A thin rod of length 1 m is kept vertical and is
hinged from the lower end ‘H’. Its linear mass
density varies with the distance (x) from the
end ‘H’ as  = (12 x) kg/m, where x is distance
(A) its specific heat capacity is greater in the along rod from point H. The potential energy
solid state than in the liquid state. (in Joules) of the rod is 5N. Find N (at H the
(B) its specific heat capacity is greater in the potential energy is zero) (g = 10 m/s2)
liquid state than in the solid state.
(C) its latent heat of vaporization is greater
than its latent heat of fusion.
(D) its latent heat of vaporization is smaller
than its latent heat of fusion.
35. The ring shown in figure is performing pure
rolling on a rigid surface. Radius of ring is 'R'
and angular velocity of ring is ''. There are H
four points marked on the ring as shown. After 39. A uniform rectangular plate of mass 1 kg is
 performing combined rotational motion and
time t = , choose the correct option(s)
 translational motion with constant angular
regarding displacement of points. speed 2 rad./sec (as shown in figure). Speed
C of centre of mass of plate is 1m/sec. If the
kinetic energy of plate with respect to a point A
B K
D (point A is on the plate) is Joule then 'K' is :
R 3

A
(A) Displacement of A is R  2  4
(B) Displacement of B is ( – 2) R
(C) Displacement of C is R  2  4
(D) Displacement of D is ( + 2) R
40. Figure shows a particle of mass m attached
with 4 identical springs each of spring constant
K and each of which are initially in their natural
length L. The gravitational force is neglected. If
the mass is slightly displaced by distance x
along a line perpendicular to the plane of the
figure and released then the force acting on
particle just when it is released is proportional
to xn, find n.
43. Which of the following statement(s) is/are
incorrect ?
(A) Molar volume of every gas at STP is 22.4 L
(B) Under critical conditions compressibility
factor is 1.
(C) For any gas Boyle's temperature (TB) is
greater than critical temperature(TC).
(D) At absolute zero temperature kinetic
energy of gas is R.
3
8

44. Which of the following is/are exothermic

process?
(A) Combustion of C6H6.
(B) Formation of CO from elements in their
standard state.
(C) Solubility of gas in liquid.
(D) Atomisation of I2 (s).

45. Salt AB undergoes anionic hydrolysis and its

0.1 M solution has pOH as 5 then select
correct statement(s):
–
(A) Kh is equal to Kb of B
(B) pKa of HB is 5
PART - III : CHEMISTRY (C) h is 0.01%
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, (D) pH of 0.1 M HB is 3
O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, 46. Select the incorrect statement(s) :
Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75, (A) The PV work in a mechanically reversible
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207] process in a closed system is always equal to
– PV.
SECTION – 1 (B) The infinitesimal PV work in a mechanically
 This section contains FIFTEEN questions reversible process in a closed system is
 Each question has FOUR options (A), (B), always equal to – PdV.
(C) and (D). ONE OR MORE THAN ONE of (C) The value of the work W in a reversible
these four option(s) is(are) correct process in a closed system can be found so
long as we know the initial state and the final
41. Which of the following expression(s) for the state of the system.
2
degree of dissociation of weak monobasic acid
(D) The value of the integral  Pdv is fixed once
(HA) in aqueous solution is/are correct? 1
the initial and final state 1 and 2 and the
1 Ka equation of state are known.
(A) (B)
1  10pK a  pH K a  [H ]
47. In the nuclear transmutation :
[H ] 1  10pK a  pH
(C) (D)
K a  [H ] 1 8
9
4 Be  x 4 Be  y ,
42. Select the incorrect statement(s) : (x, y) is/are :
(A) At equilibrium, concentration of reactant (A) (, n) (B) (p, d)
always become equal to concentration of (C) (n, d) (D) (, p)
product.
(B) In presence of catalyst, rate of forward 48. The wave functions of 3s and 3pz orbitals are
reaction increases and rate of backward given by
reaction decreases by same amount.
(C) Keq (equilibrium constant) may have zero or 3/2
1  1 
1/2
 z   4zr 4 z2r 2   zr/3a
–ve value.  3s      6   e 0
9 3  4   a0   a0 9 a02 
(D) As pressure increases Keq increases for the  
reaction N2(g) + 3H2(g) 2NH3(g) at given
temperature. 1/2
 z 
3/2

1  3  2zr   2zr   zr /3a0
 3p      4   e cos 
9 3  4   a0   3a0   3a0 
 From these we can conclude : 53. Select the incorrect statement :
(A) Number of nodal surface for 3pz & 3s (A) H2SO5 acid has one S–OH linkage.
orbitals is equal. (B) Number of B–O–B linkage in borax is equal
(B) The equation of angular nodal surface of to number of P–O–P linkage in P4O10.
3pz orbital has  =  /2. (C) Hybridization of both sulphur in H2S2O5 is
(C) The radial nodal surfaces of 3s orbital same but oxidation state of both sulphur are
and 3pz orbital are at equal distance from the different.
nucleus. (D) Basicity of phosphorus acid is three.
(D) 3s electron have greater penetrating power
into the nucleus in comparison to 3p electrons. 54. Which of the following statement is/are true for
P4S3 molecule?
49. In the following options which is/are correctly (A) It contains six P–S bonds and three P–P
arranged in decreasing order of C–N bond bonds.
length? (B) It contains six P–S bonds and ten lone
NH2 NH2 NH2 pairs.
3
(C) It has all P atoms are sp hybridised.
(D) It is a non planar compound.
(A)

55. Ca2B6O11 + Na2CO3  [x] + CaCO3 +
O NaBO2
NH (unbalanced equation)
Correct choice for [X] is/are.
(A) Structure of anion of crystalline [X] has one
(B) CH3 – CH2 – NH2 CH2 = NH 3
boron atom sp hybridised and other three
2
boron atoms are sp hybridised.
(C) CH3–NH2 CH2=CH–NH2 NH2 (B) Aqueous solutions of [X] is alkaline.
(C) In the structure of [X] anion B–O–B bonds
NH2 NH2 NH2 are presents.
(D) [X] on heating with chromium salts in
(D) oxidizing flame gives green coloured bead.

SECTION – 2
CH=O  This section contains FIVE questions
 The answer to each question is a SINGLE
50. Which of the following species will be DIGIT INTEGER ranging from 0 to 9, both
diamagnetic in nature, if Hund's rule is violated inclusive
while writing their molecular orbital
configuration? 56. Given is an equation of state for real gas,
(A) O2 (B) N22  where A and B are constants. P : Pressure
(C) He2 (D) B2 and V : Molar volume
A 2B
PV = RT – 
51. Which of the following contain same number of V V2
linearly arranged carbon atoms in their 1
Find at critical point.
respective molecules ? Z
(A) CH2 = CH – C  CH
(B) HC  C – C  CH 57. A magnesium ribbon, when burnt in air, left an
(C) CH2 = CH – CH = CH2 ash containing MgO and Mg3N2. The ash was
(D) CH3 – C  C – CH3 found to consume 0.6 mol of HCl according to
the reactions :
52. Which of the following statement(s) is/are MgO + 2HCl  MgCl2 + H2O.
correct : Mg3N2 + 8HCl  3MgCl2 + 2NH4Cl.
(A) CH4 cannot be prepared by Wurtz reaction The solution so obtained is treated with excess
method. of NaOH, then 0.1 mol of NH3 is evolved
(B) Wolft-Kishner reduction is used to prepare (NaOH + NH4Cl  NH3 + H2O + NaCl). The
alkanes from carboxylic acid mass (in g) of magnesium burnt is.
(C) Lindlar's catalyst is used to prepare alkene
from alkyne. 58. How many structural alcohol of formula C5H12O
(D) Oxymercuration–demercuration process can give instant turbidity with Lucas reagent
gives alcohols corresponding to Markovnikov (HCl + ZnCl2)
addition of water to carbon carbon double
bond.
59. How many functional groups are present in the
following compound:
H2N O O
H
NH OH
O O O O
H
O O

60. How many of the following compound have

correct common name.
COOH

neo-pentane COOH
(I)
Maleic acid
(II)

OH
COOH

COOH
Succinic acid Carbolic acid
(III) (IV)

COOH O
O–C–CH3

Aspirin Styrene
(V) (VI)

CH=CH–COOH

Cumene Cinnamic acid

(VII) (VIII)

OH
COOH

Salicylic acid
(IX)
 SOLUTIONS & ANSWER KEY
PART : I MATHEMATICS  2p 1

1. A point is moving......................    p  a  p  b  p  c   3
3
Sol. Equation of chord of contact from (-2, 0) is 3x +
4y -34 = 0 7. The number ......................
2 Sol. When z = n + 1, we can choose x, y from
Solving this with circle we get x = 6 ,  2
5 {1,2,........,n}  n ways
total no. of ways = n   n  1  ..........  1
2 2
2. If the normal at......................
Sol. Equation of normal at P (2 sec  , 2 tan  )

is 2x 2x 8. Let A denotes ......................

 8
sec  tan  Sol. A = 3
then G (4 sec  , 0) and g (0, 4 tan  ) B = log 2 (( 3 + 1) – ( 3 –1)) = 2
3. If the quadratic ...................... 2

Sol. sum of roots = product of roots and roots are real (a – 1)x – (a + 1)x + (a + 1) = 0

4. If the roots of ...................... such that
2 2
Sol. roots are a/r, a, ar where a > 0 and r > 1   +  =  – 2
2
a/r + a + ar = –p ............(1) ( + ) – 3 + 2 = 0
2
(a/r)a + a(ar) + (a/r)ar = q ............(2)  a  1  a  1
(a/r)a(ar) = 1  a=1    –3   +2=0
 a – 1  a – 1
since r + 1/r > 2 from (1) p < – 3
2 a 1
5. If the axis of ...................... t – 3t + 2 = 0, where t =
a –1
Sol : Let parabola be y 2 4ax and let hyperbola be t = 1, t = 2
x2 y2 a 1 a 1
1  = 1 (not possible) and =2
a2 b2 a –1 a –1
Then chord of contact for (h, k) is ky 2a x h
a=3 C=3
And it touches the hyperbola so applying Hence A + B = 5; (B + C  A) = 2 + 3  3 = 3
condition of tangency, we get equation of ellipse.
9. If the divisors ......................
6. For positive ...................... Sol. 3 p   4  1  4l   1
p p

Sol. Using A.M  G .M q q

5 = (4 + 1) = 4m + 1
  b  c  c  a  a  b   8abc 7r = (7 – 1)r = 8n + (–1)r
  p  a  p  b  p  c   8abc
10. If the product ......................
Also  p  a    p  b    p  c  1
Sol. Since product of roots is 2 sin a = 1
   p  a  p  b  p  c   3
3 n
or a = n  + (–1) /6, n  I.

2
Again since roots are imaginary, a < 16  2 x 2  x  ( 2m  1)  0
i.e., –4 < a < 4. Therefore
7   5  1 1  8 ( 2m  1)
a   , , . Hence choices (B) and (C)  x
6 6 6 4
are correct.  1 
 x
4
11. The least positive ...................... Where   8 ( 2m  1)  1 is an odd integer.
Sol. We have sin  ( x 2  x )  sin  x 2
  ( x 2  x )  n   ( 1)n  x 2 , n  Z 12. In a ABC , ......................
 x 2  x  n  ( 1)n x 2 Sol. The point lies on y = 2x + 3
Now, two cases arise.  = 2 + 3
Case 1 When n is an even integer say n = Area of triangle ABC
2 m, m  Z In this case, Eq. (i) reduces to
=
x 2  x  2m  x 2  x  2m, m  Z
Case 2 When n is an odd integer say n =   = -7, -6, 2, 3.
2m + 1, m  Z In this case, Eq. (i) reduces
to x 2  x  ( 2m  1)  x 2

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13. Let N = 2 + ......................  x  y   x  y 
Sol. N  2  22  222   2222    2997   10,000 m x2 – y2 – 4x   + 8y   – 12
 3   3 
2
 x  y 
2
= [9 + 99 + 999......]
9   =0
 3 
2
cofficient of x2 + coefficient of y2 = 0
2 3
= [10 + 10 + 10 .... – 30000]
9
122 + 12 – 12 = 0
Where m is a positive integer
2 +  – 1 = 0
14. ABCD is a square......................
Sum of values of  = –1
Sol. 

19. If N is the ......................

Sol. If x and y denote the no. of ways to take unit
and 2 steps respectively, then x + 2y = 7.
X = 1, 3, 5.
If x = 1, then steps will be 1 2 2 2
In ABO, 2 1  r  r No. of ways =
2 (1 – r) = r, 4(1  r)  r 2
If x = 3, the steps will be 1 1 1 2 2

2 = r (1 + 2) No. of ways =
2
=r If x = 5, the steps will be 1 1 1 1 1 2  no.
2 1 of ways = 6
2  
2 1 = r If x = 7, the steps will be 1 1 1 1 1 1 1 
no. of ways = 1
r = 2 2
20. If the eccentricity......................
15. The equation ......................
Sol. . Sol. and

Let t = PART : II PHYSICS

t = a or 1 – a 21. A train is ..............................
Sol.
16. In a triangle ......................
Sol. cosA.cosB + sinA.sinB + cosA.sinB +
sinA.cosB = 2
 cos(A – B) + sin(A + B) = 2
 cos(A – B) = sin(A + B) = 1  A = B
 a = b and sin2A = 1
 A = 45° or 135º ( not possible)

 f [v s  v cos ]
fobs = =f
[v s  v cos ]
17. Number of ...................... v s  v cos 
obs =
Sol. f
For any observer in train frequency
 observed is equal to original frequency but
observed wavelength is more.
 sinx = 0, where x = 0, , 2, 3
22. In a flexible ..............................
18. The tangent ...................... Sol. The V-T diagram for the process would be :
Sol. (x – y + 2)(x + y – 6) = 0
x2 – y2 – 4x + 8y – 12 = 0

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 24. Choose the ..............................
Sol. (A) Number of loops (of length /2) will be
even or odd and node or antinode will
respectively be formed at the middle.
Phase of difference between two particle in
same loop will be zero and that between two
particles in adjacent loops will be .
(B) and (D) Number of loops will not be
integral. Hence neither a node nor an
antinode will be formed in the middle.
Phase of difference between two particle in
V1 V2 same loop will be zero and that between two
A)  (for process AB )
particles in adjacent loops will be .
T1 T2
1 3 25. An elastic ..............................
  T2 = 900 K Sol. (A) initial acceleration of any point on
300 T2
circumference of ring is g cos 
 6R  (B*) initial acceleration of centre of ring is g
dU  nC v dT  2    600  3 104 J sin cos
 2 
P V  P2 V2
C) dW  Wab  Wbc  Pdv  1 1
 1
radius = a
nRdT h
= nRdT   40kJ (C)
 1 radius = b
23. Consider one ..............................
Sol. After collision velocity of (particle + piston) =
b a
v tan =
h
2
h = (b – a) cot
1 v2 mv 2
So, K.E. = (2m) = 1 2
2 4 4 mg (b – a) cot = k(2b – 2a)
As, Q = 0, U = –W 2
mv 2 3R 1 2 2
So, = T  T = mg (b – a) cot = 4 k(b – a)
4 2 2
mv 2 mg cot 
b–a=
6R 22k
mv 2 mv 2 7 mv 2 (D) at the moment maximum vertical
So, Tmax =  = displacement acceleration of centre of ring
R 6R 6 R
is upward.
mv 2 mv 2 5 mv 2
and Tmin =  =
R 6R 6 R
26. A semi circular ..............................
Tmax 7 Sol. Displacement of centre of mass is zero. So
So, = .
Tmin 5 take centre of mass as origin then find
D) When particle strikes elastically, particle displacement of all points.
comes to rest instantaneously and piston
moves with velocity v. 27. An external ..............................
1 3
So, mv2 = RT Sol. Fdrag = 6RV = 6
20
× 0.1 × 5 = 10 N
2 2 6
2
mv
T =
3R
4 mv 2
So, Tmax =
3 R
mv 2
and Tmin =
R
Tmax 4
So, =
Tmin 3

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 Fb + 8 = 10 32. A boat crosses ..............................
Fb = 2 Sol.
B

28. A particle is .............................. v

x 3
Sol. =
y 4
s u
4
y= x x
3
 2
and a = – (100 ) r A
means SHM. ds
u
dt
29. A small ball ..............................
dx
H H v
Sol. mg h = [vg] dt
2 2
h=H ds u

H H H H dx v
mg h = [vg] + [v2g] S b
2 2 2 2 u
7H

O
ds 
v 
dx 
O
s = 700m
h=
2
H H 33. Position verses ..............................
mg h – [vg] = K.E. Sol. It can be interpreted with the help of slope
2 2
Alternate :
5H 3 x = x0 + A sint
mg mgH = K.E.
2 2
dx
K.E. = mgH.. = A cost
dt
dx
30. An experiment .............................. = – A2 sint
ab2 dt
Sol. x =
c3 34. Heat is supplied ..............................
lnx = lna + 2lnb –3lnc Sol. Slope of graph is greater in the solid state
1 1 2 3dc i.e., temperature is rising faster, hence lower
dx = da + db – × 100
x a b c heat capacity.
dx da 2db 3dc The transition from solid to liquid state takes
× 100 = × 100 + × 100– × lesser time, hence latent heat is smaller.
x a b c
100
= 1 + 2 × 3 – 3 (–2) 35. The ring shown ..............................
C A
Maximum error =  13 %

31. Two spherical .............................. D B B D

4s Sol.
Sol. Pressure in left bubble =
r1 A C
t=0
4 3
Volume of left bubble = r1
3 36. A ball collides ..............................
4s 4 3 Sol. Solve in the reference frame fixed to the
Pressure in right bubble = = r2
r 3 wall.
n1 + n2 = 2n Before collision, velocity of ball = 3v towards
2 2 2
r1 + r2 = 2R it.
A1 + A2 and n1 + n2 are constant
 After elastic collision of ball = 3v away
n1 r12 4 2 2R2 from it (here we have used the result that a
r2
n2 r22 1 5 light mass is reversed by a heavy body at
2 rest).
r2 R 2h
5 Time of flight =
g
8
r1  R 2h
5 Distance between wall and ball = 3v. .
g

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37 A particle is .............................. 40. Figure shows ..............................
Sol. Sol.

Fnet = 4F cos
x
Apply conservation of energy = 4K  L2  x 2  L  .
  L2  x 2
1 1
m (6gL) = mgL + mVB2
2 2
1  L 
3 mgL = mgL + mVB2 = 4Kx 1  
2  L  x2
2

VB= 4gL
  x2  
1/ 2

mVB2 = 4Kx 1   1  2  
TB = = 4 mg   L  
L 
1 1  x2  2K
m (6 gL) = 2 mgL + mVC2 = 4Kx  2  = 2 x 3
2 2 L
 2L 
1
mgL = mVC2
2 PART : III CHEMISTRY
VC = 2gL
41. Which of the following ..........
mVC2 + –
TC + mg = Sol. HA H + A
L C O O
TC = 2 mg – mg = mg C(1-) C C
 
TB 4mg [H ] [A ] c2
 =4 Ka = 
=
TC mg [HA ] 1 
+ [HA]
[H ] = Ka
38. A thin rod .............................. [A  ]
Sol. Lets take an element of dx width at a
distance x from the lowest end. [A  ]
pH = pka + log
x 1 [HA]
dU = (dm) g x x 2 dx 40J c
x 0 pH = pka + log
c (1   )

pH = pka + log
1 
dx
1 
log = pka – pH

x 1 
 10pka pH

1

1  10pka  pH
39. A uniform ..............................
c. 
1 ka =
Sol. (K.E.) of plate w.r.to A = I 2 1 
2 A
4 [H ]
A = kg m2 ka =
3 1 
1 4 8
(K.E.)A = × × 4 = J. 43. Which of the following ..........
2 3 3
Sol. (A) Molar volume of ideal gas at STP is 22.4 L
3
(B) Under critical conditions Z = .
8

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44. Which of the following .......... 51. Which of the following..........
Sol. Formation of CO from constituent elements Sol.Structure Linearly arranged carbon atoms
involves combustion. H H
(A) C=C 3
H C–CC–H
45. Salt AB undergoes anionic .......... (B) H–CC–CC–H 4
– –
Sol. B + H2O  HB + OH H
H
c(1–h) ch ch (C) C=C H 2
c = 0.1 M H C=C
–5 H H
ch = 10
–4 H
h = 10 H
2 –9
Kh = ch = 10 C
Ka(HB) = 10
–5 (D) H CC–C–H 4
– –9 H
Kb of B = 10 H
1
pH = (5 – (–1)) = 3
2 52. Which of the following ..........
dry ether
Sol. (A) 2 R  X  2Na R  R  2 NaX
48. The wave functions ..........
Sol. (A) Total nodal surfaces in 3s = 2 (B)
CH3 – C – CH3 NH2NH2 / KOH CH3 – CH2 – CH3
Total nodal surfaces in 3p = 2
Alkane
(B) Angular node in 3p, cos  = 0 O
 = /2 Carbonyl compound
zr (C) R R
(C) Let =x R–CC–R
Lindlar's
C=C
a0 Catalyst H H
4 2 cis
Radial nodes in 3s, (6 – 4x + x )=0
9
53. Select the incorrect ..........
2 2 2 O
 (3 – 2x + x ) = 0 27 – 18x + 2x = 0
9
Sol. H–O–O–S–OH
18  324 – 216 18  108
 x= = O
22 4 O

93 3 9–3 3 2
–
P
x= ,x= OH
2 2 O O
O—B—O
2 Borax 2Na +
HO—B B—OH O=P
O
P=O
Radial nodes in 3p. 4 – x = 0 O
O
3 O—B—O O O

 x=6 OH P
Hence their radial nodes are not same. O
(D) It is a fact. H2S2O5 (Pyrosulphurous acid)
O O
49. In the following options .......... H–O–S–S–OH
Sol. As bond order between carbon and nitrogen O
increases, bond length decreases.
54. Which of the following ..........
50. Which of the following .......... P
Sol. (A) O2 :- 2
1s *2
1s 2s2 *2s2 22pz Sol. S S

S
2p2x  22py * 2p2x  * 2p y (diamagnetic)
P P
(B) N22  :- 1s
2 *
1s 2  22s *2s2 2p2x  22py P

22pz * 2p2x  * 2p y (paramagnetic) 55. Ca2B6O11 + Na2CO3 ..........
Sol. Compound [X] is Na2B4O7.
(C) He2 :- 1s
2 *
1s1 (paramagnetic) (A) In anion of borax two boron is sp
3
2
 hybridised and two boron are sp
2 *
(D) B2 :- 1s 1s 2  22s *2p2 2px 2  2p y hybridised.
(B) Aqueous solutions of [X] is alkaline.
(C) In the structure of [X] anion B–O–B
bonds.
(D) [X] on heating with chromium salts in
oxidizing flame gives green coloured bead.

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56. Given is an equation of .......... 57. A magnesium ribbon..........
A 2B Sol. Mg + air  MgO + Mg3N2
Sol. PV = RT – 
V V2 0.25 mol 0.1 0.05
RT A 2B MgO + 2HCl   MgCl2 + H2O.
P=  2  3 0.1 0.2mol
V V V
dP
At critical point 0 Mg3N2 + 8HCl   3MgCl2 + 2NH4Cl.
dV 0.05 mol 0.4 mol 0.1 mol
dP RT 2A 6B
 2  3  4 NaOH
dV V V V
1  2A 6B  NH3
0= 2 
RT   2
V  V V  0.1 mol
2
RTV –2AV + 6B = 0 58. How many structural ..........
2
D = 4A – 4 × RT × 6B = 0 Sol. 2-methylbutan-2-ol.
A2 6B A3
TC = VC = PC = ; 59. How many functional ..........
6RB A 108B2 Sol. Functional group present are : aldehyde,
P V 1 alcohol, primary amine, ketone, secondary
Z= C C  =3
RTC Z amide, carboxylic acid and anhydride.

60. How many of the following ..........

Sol. (I), (II), (III), (IV), (V), (VIII), (IX)

ANSWER KEY

PART : I MATHEMATICS

1. (BC) 2. (ABCD) 3. (ABC) 4. (ACD) 5. (AB) 6. (AB) 7. (ABC)

8. (AD) 9. (AC) 10. (BC) 11. (CD) 12. (ABCD) 13. (BD) 14. (AD)

15. (ABC) 16. (4) 17. (4) 18. (1) 19. (7) 20. (4)

PART : II PHYSICS

21. (CD) 22. (AC) 23. (AD) 24. (ABCD) 25. (BC) 26. (ABD) 27. (ABCD)

28. (BC) 29. (ABCD) 30. (AB) 31. (ABCD) 32. (BC) 33. (BCD) 34. (AC)

35. (ABCD) 36. (3) 37. (4) 38. (8) 39. (8) 40. (3)

PART : III CHEMISTRY

41. (AB) 42. (ABCD) 43. (ABD) 44. (ABC) 45. (ABCD) 46. (ACD) 47. (AB)

48. (ABD) 49. (ABCD) 50. (ABD) 51. (BD) 52. (ACD) 53. (B) 54. (ABCD)

55. (BCD) 56. (3) 57. (6) 58. (1) 59. (7) 60. (7)

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