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Uranium - Metal, Production, Uses, Compoundsاصلی مقاله
Uranium - Metal, Production, Uses, Compoundsاصلی مقاله
Uranium
What is uranium?
Uranium uses mainly for nuclear energy production in nuclear power reactors. Ordinary
uranium contains mostly U-238. It can be enriched in U-235 for the production of nuclear
energy.
Naturally occurring uranium contains only one percent fissionable U-235 and 99 percent
U-238. It can decays slowly by emitting an alpha particle.
Uranium-235 is the only naturally occurring fissionable fuel that can participate in a
chain reaction. It can be used mainly in nuclear power plants and the production of
nuclear weapons.
U-238 is fissionable by fast neutrons. Therefore, it can be transmuted to fissile
plutonium-239 by a nuclear reaction.
The half-life of U-238 is about 4.47 billion years and that of U-235 is 704 million years.
The metal is very useful for calculating the age of the earth.
The most important source of uranium is pitchblende (U3O8). Pitchblende is found mostly
in the Great Bear Lake in Canada. A significant amount of uranium ores like Carnotite is
found in Siberia in Russia and the United States.
1. Low-grade uranium ore mined from various countries contains 0.01 to 0.25%
uranium oxides.
2. High-grade ores found in Athabasca Basin deposits in Saskatchewan, Canada can
contain up to 23% uranium oxides.
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Uranium production
The world production of uranium increased in present day because it is an important
metal for energy generation. Worldwide production of uranium mines in the world in 2013
was obtained from three countries such as Kazakhstan, Canada, and Australia.
Production process
The production or extraction of uranium from pitchblende contains the following main
steps,
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Properties
Uranium is a silvery-white malleable, ductile, slightly paramagnetic, radioactive metal that
has strongly electropositive properties. Uranium metal is denser than lead but slightly less
dense than tungsten and gold.
Properties of uranium
Name Uranium
Symbol U
Naming after planet Uranus
Discovery Martin Heinrich Klaproth in 1789
First isolation Eugène-Melchior Péligot in 1841
Appearance Silvery-white radioactive element
Standard atomic weight 238.029
234
Main isotopes U, 235U, 238U
Periodic properties
Atomic number 92
Group Actinides
Period period 7
Block f-block
Electrons per shell 2, 8, 18, 32, 21, 9, 2
Electron configuration [Rn] 5f3 6d1 7s2
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The uranium atom has 92 electrons and 92 protons with electronic configuration [Rn] 5f3
6d1 7s2. It has an incomplete f-orbital. Therefore, uranium is placed in period 7 in the
periodic table within the f-block elements or actinides.
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Physical properties
State at 20°C Solid
Melting point 1132.2 °C
Boiling point 4131 °C
Density 19.1 g/cm3
Heat of fusion 9.14 kJ/mol
Heat of vaporization 417.1 kJ/mol
Molar heat capacity 27.665 J mol−1 K−1
Crystal structure Orthorhombic crystal lattice
Chemical properties
Common oxidation states +6, +5, +4, +3
Electronegativity 1.38 (Pauling scale)
1st ionization energy: 597.6 kJ/mol
Ionization energies
2nd ionization energy: 1420 kJ/mol
Atomic radius 156 pm (empirical)
Covalent radius 196±7 pm
Van der Waals radius 186 pm
Magnetic ordering paramagnetic
Thermal conductivity 27.5 W m−1 K−1
CAS Number 7440-61-1
Uranium shows mainly four oxidation states III, IV, VI, and VI. The VI state is the most
stable oxidation state of the metal.
It reacts with almost all non-metal elements and their compounds. The reactivity of metal
increases with the increasing temperature.
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It can be dissolved by hydrochloric acid and nitric acid but react slowly with non-oxidizing
acid. The finely divided metal reacts with cold water. In the air, it becomes coated with a
dark layer of UO2.
Uranium compounds
Uranium shows mainly four oxidation states III, IV, VI, and VI. Of these four oxidation
states, VI is the common and most stable oxidation state of uranium. The main uranium
compounds formed by these different oxidation states are given below,
Oxides
Uranium formed three main oxide compounds UO3, UO2, and U3O8. Two other less
familiar oxides are U3O7 and U4O9.
The yellow trioxide (UO3) may be obtained by heating uranyl nitrate, hydroxide, or
peroxide to 350 °C. It is also produced from ammonium diuranate when heated below
580 °C.
Black dioxide (UO2) is formed by the reduction of UO3 with hydrogen or carbon
monoxide at 350 °C.
Green black U3O8 is formed by heating UO3 to 700 °C.
All these four oxides dissolved in nitric acid to form a solution containing uranyl ion.
Fusion of uranium oxides with alkali and alkaline earth metal carbonates produces
uranates and diuranates.
Sodium diuranate
A yellow precipitate of sodium diuranate (chemical formula Na2U2O7, 6H2O) is obtained
by adding sodium hydroxide solution to a solution of uranyl salt.
2 UO2(NO3)2 + 6 NaOH → Na2U2O7 + 4 NaNO3 + 3 H2O
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Ammonium diuranate
Ammonium diuranate is obtained by the addition of aqueous ammonia to a solution
containing uranyl nitrate
Halides
Uranium forms a number of stable halide compounds in different oxidation states. The
halide compounds of uranium are given below the table,
Oxidation states
VI V IV III
UF6 UF5 UF4 UF3
colorless pale blue white green green
UCl6 U2Cl10 UCl4 UCl3
green red green red
UBr4 UBr3
brown red
UI4 UI3
black black
Uranyl nitrate
Uranyl nitrate has the chemical formula UO2(NO3)2. It is obtained when UO3 or any other
oxide of uranium metal dissolves in nitric acid.
Uranyl nitrate is freely soluble in water, alcohol, and ether. the crystalline forms which
contain three and two molecules of water may be obtained from the concentrated and
fuming nitric acid solution respectively.
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Uranyl sulfate
Uranyl sulfate (chemical formula UO2SO4, 3H2O) may be prepared by evaporating uranyl
nitrate with concentrated sulfuric acid followed by leaching with water. Yellowish green
crystals may be isolated from the concentrated solution.
Conductivity measurement shows that the concentrated solution of uranyl sulfate contains
the complex ion [UO2(SO4)2]−2.
Uranyl chloride
Anhydrous uranyl chloride (UO2Cl2) may be prepared by the action of chlorine on UO2 at
500 °C or the action of oxygen on UCl4 at 300 °C. A solution of UO3 in HCl yields yellow-
green crystals of UO2Cl2, 3H2O.
Uranyl carbonate
Uranyl carbonate (UO2CO3) is present in the mineral rutherfordine. It may be precipitated
from solutions containing the uranyl ion with ammonium or sodium carbonate.
Uranyl acetate
Uranyl acetate has the chemical formula UO2(CH3COO)2, 2H2O. It may be prepared by
dissolving UO3 in acetic acid and crystallizing.
Isotopes
Naturally occurring uranium metal contains the three most common isotopes 234U, 235U,
and 238U. All these three isotopes are radioactive. They emit alpha particles and they have
a small probability of undergoing spontaneous fission reactions. It has also four trace
isotopes U-239, U-237, U-236, and U-233.
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238
Spontaneous
U 99.274% 238.051 4.468×109 years
fission (SF)
β– β– 238
Pu
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Most of the uranium mined from Kazakhstan, the United States, Canada, Australia, and
Russia has to be enriched in U-235 for nuclear fission reaction. It is achieved by a
multistage diffusion process and a gas centrifuge process.
Nearly fifty percent of the total reactor requirement of uranium comes from reprocessing
of nuclear fuels. Many of the fission products in a nuclear power rector strongly absorbed
neutrons. They have to clear from time to time for the smooth running of the nuclear
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reactor. These fission products are separated from the unchanged uranium for further use
in energy generation.
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