: + yp -BASE L para cHusN po. ‘ACID iu 1 MUCT ot mah bay durge nguyén “five hanh duge thao tée pha due fe HC201.2H20 vi dung dich NaOH 0, id - base. OLN tir ic chudin - “ich ‘chwdn HaC204 SA chs jet ry ehdt chi thi tir NaOH Wien. va kt thie @ inh Ix 1, Pha eli Jhudin d6 acid — base trong: Tong by 41. H,C6 - Ung dung duge phuong php chu: gfe, do a6 ¢ bai tip HCI va HsPO., z auge ean CHAT, DUNG Cy THI NGHIEM tht nghigm bd Pha 10 7 Wicks Dyng cu thé 42 PN 90 nl - H2C201.2H20 (chit gé eee au eda ch ioe a ete + Pipet chinh xé¢ 10 ml 64 KBs I “HCI dc ~ Binh dinh mae 100 mt nha Na‘ = FSPOs die - Binh nén 100 ml 6, hoa ta - Ethanol tuyét d6i ~ Céc 66 mé 100 ml condng ¢ - Nude ct - Dia thiiy tinh chuin 44 ~ Phenolphtalein (chi thj) ~ Phéu thiy tinh PI ZS ~ Luc bromocresol (chi thj) ~ Qua bép cao su . HC2041 - Gidy chi thj mau van nang ~ Binh dyng nue ct a ~ Cn ky thuat dign ti, cn phan tich dign tr ¥ va ko k ¢) 3. NOIDUNG THYC HIN a chite ac cH) ~~ Pha 1p dung dich chudn H2C20, 0,1 N tir chit g6c HaC204.2H:0. Khi ch (af4g7 ~Pha 100 ml va dinh Ingng ndng a6 dung dich chudn trung gian NaOH 0,1N ving c tir NaOH vién. aan thé di ~ Dinh Ingng dung dich HCI bing dung dich NaOH O10N, 43.D ~ Dinh Iugng dung dich H3PO, bing dung dich NaOLL 0,10N. 4. NGUYEN TAC sau: Chudn d6 acid-base 1a phuong phap dya trén phan img cho nhn proton phip PI iB gitta acid va base: Acid (1) + base (2) = Base (1) + Acid (2) Trong qué trinh chudn 4, néng bing 46 cde ion H* va OH thay di tite 1a thé, PH ctia dung dich thay déi Tai diém tuong duong 06 Sy bién ddi dot ngdt cia duro DH va ta thu duge m6t dung dich cé. PH nhat dinh 6 va i Ung acid, trung tinh, hodc 4.4. at diém tuong duong khong ob nihting bign di cB thé quan sat duge, vi vay phai cho tl i ph céyy au sie thay di & lan ean ditm tong duong dé Ta duge y an di e 8 AE nhan ra gy 9% 2 oni Hh A ones y gua teinh chin va Ker chinks xe 100 ml dung djch géc vende ein hl wen in pn eh ma see 38 cure une dich chun 6 ndng d6 theo pete 7 7p, pha 100 ml va xB djnh nang 4.cia dung aver na out 8 bi carbonat hod vi fot 8 dich chudn Naor o, fay nhién, kht pha s€ ai dong morgen ae hyd. NB Pha sé sir dung mét lugn, thoa min yéu y thuyét, Néuw NaOH Tan ft carbonat co pb eat 32 Litnuge, NaOH edn Iai coi nhur pone ig céch ria ha Loang bing ruse dn di thé tich 48 duge dune neni ag xép xi OLN, sau d6 ding mot php din Iu luge dung dich NaOH Sdn aa bier dng 0 dé xe din néng 46 cia dung ena eee Phan ting d& xéc djah ndng 40 dung dich NaOH ee H)C:0414 phan ung gitra mot acid yéu va m6t base manh: one ane 2NaOH + HyC;04 = NaC,0, 4 21,0 : PyC,0+ la da acid 06 2 hing sé phan ly pki * 1,25 va pky= pete any knong chen lech nha nhidu nén KhOng. thE eae Penolin se acid v6i sai sO theo yeu cau d6i véi in d6 aa eves che acid vi 0 yeu c di véi phép chuan d6 (trong khoang + 1%). .s Khi chudn 46 HoC20+ bing NaOH chi quan sat r6 chuin 49 née 2 (@inh by nite acid) mg voi bude nhay PH trong khoang 6,5 — 10 cer henolphtalein 48 nhgn biét diém tong duong, 4.3, bjah lwgng dung dich HC 0,1 N bing dung dich NaOH 0,1 N Day 1a phan tmg gitra m6t acid menh va mot base manh dién ra nhw yeu cht cia mot en HOME MOLIhE heen chu oda ebb £6 voi kh6i ORE 4 sOH v6 6, hoa tan V8 PI tdng cong ca 2 cl thé ding chi thi p! sau: NaOH + HCI = NaC! + #0 g, dich chi c6 NaCl, 1,0, pH ciia dung dich dinh lugng trong khoang 4-10 nén cd & nhan biét diém tuong diém tuong duong, dun; bing 7. Bude nhay pH eta phan (mg thé ding chi thj phenolphtalein hoe da cam methyl 4 duong 44, Dinh lugng dung dich HPO. 041 M HPO, 1a da acid c6 c6 ste ac manh yeu ais voi 3 hing 6 phan ly pky = 2,15 pka= 7.2 va pls 12,4. Khi phan tng ¥ mot base, lan gt 6 3 phan img xay ra ting v6i cae igm tuong duong nh sau: oa H;PO, + NaOH = NaH,PO,+ #20 pia = 46 18HC 1 =e UP, +2NaOH = Naso, esPOe+ 2140 HPO, +3NOH= Neos sain Ut Voi sai 96 4196 a ~ Bue ny eb aid 1, pH bign i tr 41> 526 dng ~ Bde ly ; th da cam thyl, do methyl hay lye bromocrezol dé nhén biét diém ty ae fas domed wong daong va ~ Buée nhay ota acid 2, pH bién adi tir 9.2 -> 10, 66 thé ding chi thi /~ phenolphtalein a8 nhgn biét diém twong duong va khi dé Eyyo, = MO», henolphtal 90, = - Buse nhay ea acid 3 qua yéu, trong thye t& khéng thé ding chi thj dB xée dinh duge diém tong duong 3. ___ Khi chufin d9, ding chi thj 1a diém tong auton; Tai sromocresol vA phenolphtal 1, mau sé chuyén-tir_ving sang Iuesing. Tai diém tuong, duong 2, mau sé chuyén tir lye.sing sang xanh rdi sang tim (khéng 48 chuyén sang mau tim sim). Dé dé nhan biét sy chuyén mau cita dung dich o6 thé chudn dung dich dm cé pH 4,6 va 9,6 thém chi thj lye bromocresol va. phenolphtalein lam dung dich so sénh Nhén xét qué trinh chuyén mau ca chi thi, tinh két qué theo V; hoe Vp, gidi thich sur hra chon nay. 5. TRINH TY TIEN HANH 1, Pha chinh xe J0Cinl dung di ‘Cae thao tic fone C,0,.211,0 olin thiét duge,tinh theo céng ey NxExV_0, 1000 x 63,035 x NO 1000 __ ae én an phn th Ki Twang | ma, 7 [Can chinh HyC,042H20\(m0) I Cho HyCz0.21h0 vito cbc c6 mé. Hi AO ml nude “Chuyén dung dich cdc 3.Jan,.méi lan v¢ u vyéo binh dinh mac trén. Thém mde v | Ti Eoin dung dich HC.0s 48 pha chad Tinh Ky, va Cn thy ti | Tinh Kye VACNEE Vio binh dinh myCie thao tie otra pn 100 mi dung dich, NaOH = | “Finh s8 gam NaOH dé pha 100 mi dung dich NaOH = 0,1 N, cn thém khoang. 10% our NaOH vio bc 66 mo. Cin tn clin KY thustkhdi heong Hoa tan trong nude vira dt 700 ml. Khuay déu. NaOH [én buret. Diéu chinh ti vach “0”. Rot dung dich Lay chinh xdc 10,00 cho vao binh nén. Tht imi dung dich gbc H2C20x via pha, ém 2 gigt chi thi phenolphtalein. Lic déu. hd ty tir dang dich NaOH xudng binh nén ti khi dung dich trong binh nén xudt hign mau héng nat. Ghi thé tich dung dich NaOH da ding: Vie Avigent Tinh ndng do Cy cha oye NaOH, Vato. *Cuvco) 2s wb Cu non = o 3 ¥ NW wot Cw son = inh rgng dung djch HCI bang dung dich NaOH 0,1N (6) 5.3. Di TT Cac thao tie Két qua 1 Rot dung dich NaOH can dinh Iugng lén buret. Diéu chinh téi vach “0”, LAy chinh xdc 10,00 ml dung dich HCI 0,10 N, cho vao binh nén. Thém 2 giot chi thj phenolphtalein. Lic déu. _g Nhé tir tir dung dich NaOH xuong binh non t6i khi dung djch trong binh nén xuét hign mau hong nhat. Ghi thé tich dung dich NaOH da ding: V2. Ma. Tinh ndng dé P cua dung dich HCl. Pra= 20 4SPN AM Ut ee " = . a ae - | ai \ » (gi = NE EH wat Peet Ba Stbs 5.4. Dinh lugng dung dich TL M_ cho TT ie thao the - Ache qual Dy T | Rot dung dich NaOH 1én buret. Didw chin i voc "0" 2] Lay chink xée 10,00 mit dung dich MPOg, cho vio binh nén, Thém 1 gigt chi th) IG bromocresol vA 1 plot el thj phenolphtalein, Lic déu, ~ ° 3 [No tir tir dang djeh NaOTi xudng bind nde ti Khi da dich trong binh nén chuyén tir waving seme yy NG, sang. 4] Ghi thé tich dung dich Naw da din BV By. eabing Wt Kit A ah 3 [Tip tue nho tir tir dung dich No‘ dich trong binh nén chuyén tir mau Jue sing #0 a rdi sang tim. hea od : S| Ghi thé tich dung djeh NaOH da din Fink nbng a} Gy cba dung dich ThPOs theo Vs C ae Cr yuo, Eth chou) Wie Varo. Muyo. Vo \ VY wee : ie i trong d6-Eyyro,= Mino. c 4 Hoke J VN ‘ VeXCn won Hint (gol 6. CAU HOL y | 6.1. Tai sao cO thé pha trye tiep HyC,04.2H,0, con. khong pha tryc U NaOH vién?~ — 2204 QIN Ait igp duge dung, dich phe Naot ont duge dung dich goo HI 2 ‘thea 9. Vea hy Wet AM hal ‘un ub nd Via i _< AErea > bigt BALL. CHUAN D9 ACWDMAS 3 dich a L Mueritu én ~ Pha duge dung dich ehudn c6 ndng 49 ohtun Nite Y chMt ado Nase dy, ~ Pha duve dung dich chudn nC BENCH Ae vA inh tigu Has er chun NaxCOy, Mist Ho chy ~ Dinh Inong dine dung dich 4 a 7 cht hate ng dich NH, bang dung ieh chuda HEL ya, UGE wat dng > Dinh luong durge hin hop Nao va NaxCOs bing dung dich chuda HCI, 2. HOA CHAT, DUNG cU Thi NGmeM Héa chit Dung ov thi nghignr - Hel ~ Buret ~ Na2CO; ~ Pipet chinh xe 1om!, som ~ Phenolphtalein ~ Binh djnh mite 1oomt > Methyl da cam ~ Binh nén 100mt ~ Dung dich NHy ~ Cc 66 m8 100m1 ~ Nuse cét ~ Dita thay tinh, ~ Dung dich hén hop ~ Phéu thay tinh NaOH va Na2CO; ~ Qué bép cao su ~ Cn kJ thugt dign ti, cfm phan tich dign ti 3. NOI DUNG THYC HItN ~ Phal00ml dung dich chuiin NazCOs 0,1N trye tiép ti NayCOs khan, - Pha 100ml dung dich chudn HCI tir HCI dic va xéc dink Tai ndng 49 bing dung dich NazCO3 0,1N vita pha. i je dung dich HCI 0,1N. - Djnh hugng dung djch NH; bing om Iugng h6n hop dung dich NaOH va NagCOs bing dung dich HCI 0,1N, - Di { UYEN TAC \ / ; ; ‘ Mi dung-djch HCI 0,1N bing dung dich Nay '030,1N _ ne dich dag oad da base) dya }rén phan img: Dung dich duge chuani'd6 voi NazCOs (Ia mgt da ba Na2CO3 + HCl = eee os o Cl = NaCl + 20+: ; . ee duong(pH = 84) ding chi thi phenolphtalein. Phan tmg (1) cé diem tuonge cf joni pH = 3,7! ditng chi thi methyl da cam. 1, 0,1N bing dung dich HC10,1N duge chuin 46 bing HC! theo phan tng sau: Phan tig (2) £6 diém tone du 4.2. Dinh Iurgng dung dich NE NELOI 1a mot base you T_] NH,OH + HCl = NHAC! + 10 yore Phan ting 66 diém tuong duong pH ~ 5,8 Jduing chi thi hon hop Tashiri Whe re (methyl do va methyl xanh) Uta: in hyp NaOH + Na,CO; bing dung dich HC10,1N 4.3. Dinh lrgng bi d& dinh lugng phai ding mt dung dich acid Vaz tr Day 1a hén hgp cae base, manh la HCI: ols NaOH + HCI = NaCl + 20, (1) 06 pHy=7 ‘Na;COs + HCI = NaHCO; + NaCl (2) co pH y=8,4 Voz % NaHCO; + HCI = NaCl + H,O + COr G) 06 pH q=3,7 Néu dinh Iugng, ding chi thi phenolphtalein chuyén mau (pH = syn te sé thyte hién xong phan ing (1) va (2) (toan bj NaOH va 1/2 Na,CO) phan img); néu thém tiép chi thj methyl da cam va dinh Iwgng tiép cho dén Kkhi chuyén mau (pH = 3,3 — 4,4) thi phan ting (3) ay ra Soe toan (1/2 Na,CO3 con Iai phan img) 4 G® wo & Sdg’ Ww (wag * A Wag, Vv 5. Trinh vt, fin hanh > Tah 5.1. Pha f00ml dung dich géc NazCOs 0,1N. TT ‘Cac thao tie Két qua | 7 | Tinh lvong Na,CO; tinh khiét cin pha, cho ‘| oe 4 sagen 06S ST, 2] Can Iwong Na;CO; tinh khiét trén cn phan tich, hoa tan trong nude dén via di 100 ml (trong binh dinh mite) 3] Tinh K hiéu chinh va ndng d6 Cy thye téctiadung dich | K= Na,CO3 vita pha. He 5 13 0, 048 a5 os 4 24va dink lryng, Hot dune dich Che thao the Tinh wong HCI nbpe 4 C% in iy 46 male sie) , — Ding cdc dong lay TIC 10%. Rot vao che c6 mo. aa) 5A. Syn lyn bbe ON Ffoa tan vi thém mute cht cho di 100 mi. REt dung dich TICI vira pha lén tren puret. Dieu chinh toi vach “0”. 7 3k vie | 3 \ Tay chinh xéc 10 ml NaxCOs D,iN cho vio ‘pinh non, thém 2 giot phenolphtalein, nho HC! ti buret xudng cho dén khi mau hdng nhat. giéng mau fu (b mon chufin bj mau mu), Ghi thé tich HCI da ding: Vil. Tip tue chun 46 én Khi dung dich amit mau hong thi thém vao binh nén 2 gigt methyl da cam. Who tigp HCI xudng cho den Thi miu dung dich trong | V2 = 7 inh nén chuyén tir vang sang dd cam, Ghi thé tich HCL da ding: Va ml. (A 25. —a& [Fink nding d} chinh xée cia dung dich ICI da pha. \ Crma> 5.3, Dinh hirgng dung dich amonineNHG.AN ping dung dich HCLOAN | 1T Cae thao tac \ Ket qui 1 7] Rot dung dich HICK Tén trén buret. Dike chinh ti vach | = Pod es Z| Ey chinh fe 10 mi Ting die NHs_vio Bish non, 6.1. Pt ‘ni_thi. methyl 4d, 1 gigt chi thi, methyl ; vita, chat | 5 | Nho HCI xuéng ‘Binh hon cho t6i Khi mau chuyén tr | Va= os Iyc sang tim. Ghi thé tith HCl 43 dang? V3 ml. e : 63.binh nén, thém 2 gigt phenolphthalein, Nhé TCI xudng cho dén khi eo mau dung dich wong 7 ong | Vee én tén buret. Dib chink p> NaxCO, via | ic 10ml hin hop NaOlt vi binh nén gidng mau cia 6; 6 bj). Ghi thé tieh HCI da dine ee "6 min cua | hém 2 giot chi thj methyl da cam vio binh Giah Tagng, 1 tiép tue nhé HICI xuéng cho dén khi dung dich chuyés | tir mau vang sang d6 cam, Ghi thé tich HCI da diing-V, | ; ml. | Tinh % (KIA) ea NaOH va Na;CO, trong honhop. | Ga en j= ‘ he | 6. CAU HOI 6.1. Phong thi nghiém cé cac logi hoa chat tinh khiét HAC; vign, NayCO} khan, HCI dic, HySO, dic. Trong céc hoa chit nay, chit nio 1k cht géc? Trinh bay céch pha dung dich chuan HCI? Néu céch dinh rong 2H,0, NaOH dung dich NH3? 6.2. Thy té khi chudn 46 HCI voi NaxCOs c6 thé ding mgt chi thi methyl da cam hoic phenolphthalein duge khéng? Tai sao? _ 6.3. Trinh bay cach dinh Iugng hén hop dung dich NaxCOs va NaHCO. Lip céng thitc tinh % cia timg chat trong hén hop? Pndu ny ie { porn 24°09 , ( \ { dul OL Nah «OX ' wok fis1 BAI 4. cn ri UAN DO TAO Prive BANG Py Comrunen + PHUONG PAP 1. MYC TRU é - Trinh bay duge n; fs S guyén the chi i “ a win 49 bing complexon, ‘ Ge dig ee tel dung dich chun gbc MgCl 0,01N, ae Pl ‘p complexon trong chitin TH due ay peal n Ca?*, ion SO bing cde kj nplereptedeetrd P VA trong xe dinh duge a9 cimg ote nue anaes c. 2. HOA CHAT, DUNG CU THI NGHTEM Héa chit ee Dung cy thi nghigm ~ Buret - HCl di rer Nese ee - Binh djnh mie 100 ml ' KOHN ~ Binh nén 100 ml, 250 ml , = Céc c6 mé 100 mi ~ Den eriocrom T (chi thi) - Ong dong 25 ml - paar (chi thi) ~ Dia thiy tinh, phéu thay tinh ~ Gidy loc dinh lugng - Déncdn - Dung dich dém = Qua bép cao su ammoniac pH=10 ~Pipet chinh xéc va pipet chia vgch 5 ml, 10 ml, 20 ml ~ Can ky thugt dign th, can phin tich dign ti 3. NOI DUNG THYC HIEN AC naolt ~ Pha dung dich chuin MgCh0,01N ~ Dinh lugng dung dich EDTA bai tip py Aso? = Dinh lugng dung dich Ca a A . Binh lugng dung dich SO” a G2 4 170% _-Xéc dinh d6 etmg ota nude. / 4, NGUYEN.TAC rc : 4.1. Nguyén tic chung Kha ning tao thinh hop - Phuong phép dinh lugng bang ea ss thir him oo Ia cfc acid ? «. onan jon kimloai vol. nee v chit ngi phic BY es = fichat cla ching tvdng 6 gai ete amin, polycarboxylic, vA of iz complexon nhw: w/ + Aid etyten dia WA a) ki hig AYEDTA ki higu SEY (complexon 111) + Muéi dinatri eta ig EE (com +l ina gta ck on i ~ Psi ng 120 Per + HY ee MYO) + 2H" 6 pHH=4-6 Mee HY eo MYO! +H 8 pHAT-10 han biét diém twong. duon! ‘bing chi thi kim logi nhu: Gen eriocrom im murexid... 7 a Chit chi thi 1 nbimg chat hou co Pp yi ion kim logi va mau eta chi thi & dang do (dang chua t20 phic) le alltel Mind" (Maul) (Mau 2) Vi pH cia dung dich chudn dé anh huéng dén mau cia chi thi 6 dang vs do va agri tpis hinge dng ich Gem 38 dy PH a Gone eh chuin do. «anh trank tg0 phite cia kim loai véi chi thi va voi complexon: Do phite cia kim logi véi chi thj khong bén bing phic cia kim loai voi ‘complexon: Mind)" +HY*<> MY@4" 4 Ind™ +H Chit y: Vi dung dich nude cia chi thi chong hong nén thudmg ding hon hop chi thi rin voi NaCl v6i ti @ chi this NaCl = 1:200 (hay 1:500) 42. Dink lngng dung djch EDTA 0,01 N bing dung djch Mg’ 0,01N - Trong binh dinh nén c6 ‘Mg** va chi thj den eriocrom T, trong méi trudng dém ammoniac pH= 9-10 pén-dung jeh.co mau dé yang: . ‘Mg + Ind™ -Khi nhé EDTA tir trén buret xudng: +EDTA sé phan ung voi Mg** ty do (Mgt HY ‘o> Mey * Ht + Dén diém tuong duong: o6 sy canh tranh tgo phire /Mgind"+ HY MgY?*+ HInd™ (@é vang) gee (Kant) + Dimg chudn 6 khi dung djch chuan 49 chuyén sang mau xanh hoan toan (phan tmg hét Mg") . 4.3, Dinh wong dung dich Ca** bing dung djch EDTA 0,01N - Trong bith nén c6 Ca* va chi thj murexid (trn murexid véi natri clorid tilé 1:100), méi trudng kiém pH= 10-11 nén dung dich 6 mau 46: 28 My %, at uw ow Ki nis BAITS + EDTA + bine + Ditn Wan (pede te 44. Dinh bu - BE chmdn haan xée dip tt chénh lech complexon chi thi der - Trong bi phic Mg chi th de pH= 9-1 -Khinl IgBaar: wong) toamT, chich hie x ich 3 li. ~~ ce eee Ce [Ca¥ + Hand” <> Cabfaln = Khi nhd EDTA tir trén buret xuéng: + EDTA sé phin img voi Ca®* ty do Cat + HY* @ Ca¥? * Ht + Dén diém twong duong: c6 sy canh tranh tao phite CaHlsind’ + HYe2'Ca¥® + Hslnd™ ace @o) (tim) Soe, + Dimg chudn d@ khi dung dich chuan 49 chuyén sang mau tip, tea ~ Dinh lugng toan (phan tng hét Ca®*) 4.6. Xée din 4.4. Dinh lgng dung dich Ba®* bing dung dich EDTA 0,01N te ‘Nude = Bé chun 49 trye tiép Ba?* bing complexon Whing-AbnE-CampESh " Biers crideramaERaruedd; nén cin cho thém Mg” vio dung dich chudn gg @ hhydrocarbe xde dinh thoi diém chudn ¢0 xong Mg®* va Ba”* (do_188,,3.=7,16 dun s6i vi chénh Igch nhidu so véi Ig Byyys. = 8,70). Khi 46, qué trinh chun 49 Bay erat complexon hoan toan tuong ty nhu chudn 46 trye tiép Me™ bing EDTA 4, Ta do cdc chi thj den eriocrom T. : nude hau - Trong binh nén cé hon nbp Ba* va Mg** cling véi chi thi den eriocrom, - D6 ctr phtte Mg?* véi chi thj den eriocrom T (1g Bygias- = 70) ban hon cita By Wi trong nu . - Dé xd chi thj den eriocrom T (Ig Brune 3,0) trong THE trudmg dém ammorsg lugng t pH= 9-10 dung dich 6 mau dé vang do: .) . Cat yi Mg** +Ind™ <> Mgind +H" tee @ovang) / a -Khi nhé EDTA tir trén buret xudng: / : + EDTA 3é phan img voi Mg" ty-do-trirse Ba? ty do, nhung & ea IgBeav2-=7,76 kh6ng chénh Iéch nhiéu so v6i lgBugv2-=8,70, nén Khichulad : xong Mg” thi chép nhan Ba® da duge chun d9 hét: hoa Mg* + HY® <> MgY* * Ht : Ba** + HY* <> BaY? * Ht + pén diém tuong duong: c6 sy canh tranh tao phirc : Mglnd: + HY<> MgY* + Hind™ (6 vang) * Kan) + Dimg chudn d6 khi dung dich chudn d@ chuyén sang mau xan holt ton (phan img hét Mg”*) 2 29 __SB crv Vo GAs Mi’ mM Wu ) HNO baa EDTA 0018 an ta wi del eho le ettat Ae HAC, A BAL Hn fue " enn hes tee rat thn Se qs Ha ar theo numyen the 6H (nye 4.4), acca 1g exkngt ela nese 40 8 Day nto evi, Hine eo) midi enlel vA magnon hom tn, 196 ef et guy pita thidah 2 tol: dQ ect (gin thea vA Ad eCany vind eden 11h do che: muhi me Esto jycwarbonat ena catol vA nianonl, DO eitmg eb nds smb hes kis wh dea edt v1 KhEdS hydtrocarbonat bj phi huy vi rhonat . Sie CaCO = CaCOs + CO HO - pp cing Vinh ciku cia mde: (hay cdn ggi Ih dd eting khong, phi carbonaty 14 do cde mudi sulfat vi clorid cia call va magnesi, DO cing Vinh cin ea ng nude hdu nhur khong thay di khi dun s6i, = Dp cing toan phdn cia mede: ng him lugng mubi calc va magynesi van trong nude. vi - dé xie dinh dp citng todn phn citu nude: twatng ding phuong, ph4p dinh huyng bing complexon III v6i chi thj den eriocrom TT d& xée dinh thng Iugng Ca®* va Mg”*dya trén nguyén tie: ¢ Lay mau nude cin dinh lugng, thém dung dich dm pH=8-9 va chi thi den eriocrom T vi m@t phin nhé Mg s8 tao phite véi chi thi & dang Mglnd” dung djch sé cé mau dd vang. \ ¢ Khinhé complexon III vao miu dinh long, HY* sé phan img véi Ca tr do, sau dé v6i Mg tyr do (vi phite Ca¥* bén hon phite Mg), © Dig chufn dé khi mau dung dich tir mau dé vang chuyén sang xanh hoan toan, do phan tmg canh tranh tao phic; HY* + Mgind: = MgY? + HInd™ (xanh) © Bang giéi han d6 cing cia nwéc theo TCVN 5502-2003 ing Mite DO cig (mg CaCOs/) | Phin logi T 0-50 Nude mém IL 50-150 Nuéc hoi cimg It 150-300 | ——TNuée cimg IV >300 : Nuc rat cimg 30°Aue donk d? recy ph ed? euler Plier cle cay Guu lied yes Uwe 2 CU ry chin , CAG ne Me LAL, cel Ay scyg O° VON HANI : “At wn Heh chad be MBCL ONIN Wy oe ethan the nh Can chinh xde khodng 040124 MnO, Hin Kev gqna (SIME HCI die. Lae cho Won teens Saat | Dinh mic vita dh ww lt ih _ 100,0rl bangs made Pha loaing 10 tn diet HH WA ‘ hing diol Won cage: lunge ich Napa |! uy Ghi Iai ndng 46 dung dich go MECH da pha Tang ‘ Try 5.2, Djnh hrgng dung dich EDTA 0,0UN bany ‘aun het Mg" 0,00! 7 \y KA qua R6t dung dich EDTA 1én Tat chinh xéc 10,00 mi M, Tinh ndng do Cy cua dung dich ding: Vi. OH ea SS 2 ah Vat Yooy\ ng djoh EDTA 0,01N . 0 tite inh lwgng dung djeh Ca Kat quis ADTA len buret, Didw chinh vi vac "0", Rot dung dich Lu chin Wi cho vito bint nén, ‘Them | Hat chinh xée 10,00 ml Ca" ml KOH 2N, 0,2 gcht thj murexit: gchith nx. ia Nho dung dich EDTA tir trén buret xu oe %n tiv mau hdng sang | V2~ DTA dit ding: Va. 3 4 | Dang chudn d6 khi dung dich chuy! tim hoa cd. Ghi thé tich dung dich EI 3} Tinh nong do Cy cia dung dich Ca .WEPEA O0It Cae thane the ave ton won, Dib lal 10 vas jew" soo ant Hae? va 2,00, nk de jobs | ch vio Dl nude eft, 9 at hl th] den erlocto EDTA tel ug diel € agen a! bat sng, dich gun, arninoniae 1 vio binh nén. <0 Mych ot rem 20 mh plt-10 vi OL et Nid dng: diel Dang chula do khi d xanh hodn (On txudng. Jnuydn tie mii ands 40 | Vy = vang sat Rot dung di Flat chinh xde 10,00 ml SO,” cho vio binh non. Tt chinh xdc 20,00 ml dung dich Ba” & trén nho tir tir 4 loc, rita tiia biing nude ct nhiéu lan. Kiém tra con Ba” : Lay Iml dich rita vao éng nghiém, nhé tir 4 | bing SOs": tir SO,? vao thanh dng; quan sat éng nghiém khong co két tia 1a duge. Gop dich Igc vao dich nta trén vao binh nén 250 ml. vo binh dn teén. Dun séi binh nén én 5 phit, dé ngudi. Loe ly dich dich ado. 3] Thém 5,00 mi dung dich MgCl, @ trén va 5 ml dung dich dém ammoniac pH.'10 va 0,1 g chi thj den eriocrom T vao binh non trén. Nho dung dich EDTA tir trén buret xuong. Va= Dimg chudn do khi dung dich chuyén tir mau 46 vang sang xanh hoan toan. Ghi thé tich dung dich EDTA 4a ding: V4. ¥ 8 | Tinh ndng 46 % cia dung dich SO,” (kI/tt) C% so = 32mae yp ht qua ve annie eave ttn Oe uy Lael, OO co Nate atte at atte ww {jaan clung adit KOEN \ Aue oltale vgel) “y AE ebih sae AOU rgd annteie € An ade dint eho yao binh Wont vod Suh dug, ayely dQ sean Tyo lah non, ammonite pts10 vi 0,1 & ehi thi don erloe 4 [Nt any ajoty MOEA AE We HULL NB: SP dag ehudy fg Kat tung, aijoly cluydn Ke mie miu 40 1G thd leh dung, dich | yang, sayy Aan fodn tod WDTA da ddage Vs: _— ° | Tints Kat qua theo da ny Ne cacOs re! DD Jing, cttw nie hee him phap Complexon. exid trong yen the chun dg kim Jogi bing phuons aa chi thi den eriocrom T, mur chuyén miu ct 6. CAU NOL 6.1, Trinh bay ne 6.2. Giai thich co ed ede thi nghigm tren. 6.3. Tai sao trong th biet nong dO yao binh non. 6.4. Xay dumg céng thite tinh % 5.5. { nghigm 5.4, phai cho thém’5,00 mil dung dich MeCh dé (kiitt) ob dung dich SO” trong thi nghiém. si a fi / (sem -" atm L. VEDA SM wy") 7OXY HOA Kay ‘AU PERMANGANAT iyén the chubn ag 19 Oxy héa Khir bik ioe phurome phi ” p “pha va xe dinh duge ndog dd dung dich ehuty etudn KMnO¢ win gbe 1c . dung dirge phuong phép permanganat a 204 9,1, dung dich hThO,, inh Weng cée dung dich 2 |AT, DUNG CY THE NGHIEM 4 Méa chat Dung cy = Mudéi Morh ~ Pipet chinh xéc_ a (NI)2Fe(SO,)2.610 nee "Om SO ml pipet chia vhs mi = KMn0x = Binh dinh mite 100ml = HyC,04.2H,0 - Binh nén 100 mi - H,02 - Cc 66 mé 100 = HSO4 5% ~ Bila thay tinh, phéu thy tinh, qua bép cao su Nude cdt ~ CAn ky thuat dign ti, cén phan tich, 3. NQI DUNG THYC BIEN ~ Pha dung dich chudn H,C,O, 0,1 N tir chit g6c H,C,0,.2H,0 . ~ Pha dung dich chun 4 KMnO, xp xi 0,1N va xée dinh lai ndng 6 bing, dung dich HzC204 0,1 N. = Dinh lugng dung dich mudi Mohr bing dung dich KMnO;0,1 N = Dinh lugng dung dich H,0> bing dung dich KMnO, 0,1.N 4. NGUYEN TAC én tie chun; ‘ en vine: permanganat 18 phurong phép dinh leon, dya ve va ning oxy héa cia permanganat ca 6 trong | tnvingacid, trung tinh, em: - Trong méi trudng acid manh, MnOs bi khir dén Mn": MnO, +8H'+5e = Mn” + 41,0 (mau héng) (Khong aay . i 0,’ bj khtr dén Mino : 6i trudng trung tinh, kiém, MnO, Trong mdi iB MnO, + 21,0 + 3e = MnO,| + 40H" 3 fi (mau hdng) (au) 34 © haa ne "08 dong BM ea a tr one Hn te be an Phin de . fom, SY ch, sang 3. Dishtengdsegag Dinh leyag dung a Bs “rong. pin ng oxy duge tn Ving 6 tink nhs sau: w ‘Nhu viy tmot Veicy, =4 2 ‘wong img thé tich c 5. TRINETY TI Sal, Pha dung djM/, 4.2, Dinh lrgng dung dich KMnO, 0,1 N bing dung dich 12C:04 0,1 N 2KMnOy + SH2C204 + 3H2$04 = 2MnSO4 + 10CO2 + K2SO4 + 820 Trong phan ting dinh lugng nay ngudi ta phai dun néng t6i70-80°C a& ting téc 46 phin img. Mitt khic ion Mn** xic tac cho phan (mg, vi thé Iie dau. phan img xiy ra chim, sau dé do c6 Mn?" xtc tic phan img sé xAy ra nhanh hon. 4.3. Dinh hrgng dung dich mudi Mohr bing dung dich KMnQ,0,1 N 2KMnOy + 10FeSO, + 8H2SO1 = 2MnSO4 + SFex(SO4)s + K28O4+ 820 4.4. Dinh long dung djch 1202 bing dung dich KMnO. 0,1 N 2MnO¢ + 6" + 5H202 = 2Mn?* +502-+ 8E20 Trong phn img nay, ngudi ta ding khéi nigm ndng a theo thé tich oxy duge tinh bing “s6 lit oxy ma 1 lit dung dich HaO> ty phan hay ra”. Cach tinh nhu sau: tuong tmg thé tich oxy sé Ia: Voxy = V6i Cio, =5Cstn = 21202 — 220 + O2 Nhu vay Imol HO2 sé gidi phéng ra % mol O2, 1 1 GO Chino, =ZCtine) Licy,, «22,4 ()=5,6xCy, , (lit). a ‘Muyo, ‘Nuno, ‘5, TRINH TY TUtN HANH - { 5.1, Pha dung dich chudn géc H2C20x 0,1 N 1T Cie thao tie Kt qui 1 | Tinh sd gam chat gbc HzC204.2hh0 edn thiét d& pha| 100 ml dung dich chudin H2C204 0,1 N. 2 | Can chinh xdc trén cin phin tich lugng H2C20, cin lay. N 3 | Ha tan hoan toan chit gc vio nude c&t; chuyén vao 7 binh djnh mic 100 ml, thém vira di thé tich bing, nude |_ 7 cit, lic déu. 4 | Tinh Kne va Cnthye té ciia dung dich da pha. K= 35a xh xi 05 MnO. aK tat HST TH trong ob 08 TO cay, gan My pi | ong, khuay, gan lay Pl me Bl be ob ‘md 100ral. Lap lai cho 0 Be ae eM, dé ngudi ve niet 46 pg, a ‘aude eft toi thé tich khodne 100 ml, khudy dew ii tinh. on a RMnOr én buret. Diéu chinh ti vach _____—, sis i,G,0, vio t |__| <ée To ml dang dich g8e H2C,0« vao binh thém 30 ml HO, 5 ml HaSO, 50 %. Bun néng t6i khoang 70°C tren cach thiy hoae dén cbn. iho fir dung dich KMnO, tn buret xuéng binh non ——| cho t6i khi dung dich trong binh nén 6 miu hdng nhat. dung dic! Ghi thé tich V; cia dung dich KMnOs doe duge trén | V\= buret. [ r Tinh nong do chinh xdc cla dung dich KMn0,. Cyrawo, = 5.3. Dinh lwoug dung djch mudi Mohr bing dung dich KMnO, 0,1 N Cac thao tac Két qua ma Rot dung dich KMnO, [én buret. Bigu chinh tdi vach “0” Lay chinh xéc 10 ml dung dich mudi Mohr vao binh 2 nén, thém 30 ml H,O, 5 ml H,SO, 50 %. 3 | Nho tir tir dung dich KMnO, xudng t6i khi dung dich trong binh nén cé mau hong nhat. 4 | Ghi thé tich V2 cla dung dich KMnO, doc duge trén | V2. = L buret. 5 | Tinh nong d6 (g/l) ctia dung dich mudi Mohr. Pel anin= 362 | ndng d6 cua g 1-1,5%- Betonul 2 ‘| Lay ch a ml aioe dich ea 2 vira aman ve ~ . Myo THe binh non da chia sin 20 mi nu , them 20 ™ jung dich pag os H,SO, 10%. Tava 3 | Nhé tir tir dung dich 10. buret ~ - Ung dung toi khi dung dich tron pinh non cd mau hong, at. AsOa vi! Ghi thé tich Vs cl@ dung dich KMn0« doe duge tren 2HOAC buret. - 4 | Tinh nong 46 dung dich H202 ban ° f ~ NaS; cho Ey,o, —M 217,005 \ lod 7 \ -KL \ - HC =i; -G -N “I 6. CAU HO! 6.1. Trinh bay cac nguyén tic dinh luong, cia cac phuong phap permangaral 6.2. Tai sao khi chuan 46 KMnO« bing HyC204 lie dau phai dun nong? 6.3. Chat chi thj trong phuong phap permanganat la ai? 6.4. So sanh digu kién phan img gitta KMn0O, voi mudi Moth va voi HyCi0+ 6.5. Xay dung céng thie tinh két qua trong thi nghigém 5.3 va 5.4.wv ow wp Met Meee DAN DO ONY HOA KID BANG PHUONG wo, ei, 4. Myc TIEU A ran the eda chudn dd bing phony, php tod, = Trinh bay duve nsuy' ya xe dinh dirge ndng dé dung dich lod theo you elu, 6 tan 4 - Pha - Ung dung durge phurong phap do iod A dinb trgng ding deh Nays,0),10, ‘As 03 vi Glucose 5%. ne “Kid 2, HOA CHAT, DUNG cy THENGHIEM minty Hoa chat Dyng, cw ~ Chat géc K2Cr207 = Co cd md 100 nt ~ Na2S203 = Binh nén c6 not mai Sa‘ - lod = Buret -KI = Quit bop cao stt - HCI dac = Cin ky huge dign tit, ~ H,SO, die = Clin phiin tich dign tir - Glucose = Pipet chink xée 5 ml, 10 ml - NaOH ~ pipet chia vach 5 ml, 10 ml 7 - Hé tinh bét (chi thi) - Binh dinh mie 100 ml : - Amoni molypdat (chi thi) . 3, NOI DUNG THYC BIEN ‘ - Dinh lugng nong 46 dung dich Na2S703 0,1 N. - Dinh hrgng nng 46 % dung dich H,02, - Pha 100ml va xdc dinh lai ndng d6 dung dich iod 0,1N. - Dinh long ndng 46 % dung dich As,03 . ~ Dinh lugng dung dich'glucose 5%. pIRU KIRN CUA PHUONG PHAP 4. NGUYEN TAC, DAC pItM, 4.1. Nguyén tic dinh lugng Chudn d6 oxy héa kh oxy héa khir: ir bing phwrong phap do iod 1a dya trén phan ing =0,54V. dung dich iod hode iodid c chat khir cia cdc clip oxY ht2eoW vi Eo, n- Dua trén thé oxy héa khtr tiéu chun nay, duoc str dung dé xdc dinh néng d6 chit oxy héa ho’ héa khit khac. Vi du: 2MnO, + lor +164" = 5]y +2Mn™ + 8HL0 AsO; +h + #20 = ‘AsOg” + 20 +70" 1oy + sr + = 3h, + 310 38Sec BANG PHUONG FRAP DO BSS ALT. CHUAN BO RET TTA 1 DUNG CY THE NGHTESE + AgNO: _XSCN bows NHSCN -Kl + HNO: de = CHCOOH ~ Pha 50 ml dung dich chads - Dinh vung dung dich cleri 4. NGUYEN 4.1. Nguyén tie chung os Phuong phép dink Ineng ing do bee da tra ins tho x g musi bac ket tia. Thunng str dung dung dich AgNOs cho t can dinh luong 6 kha ning tao két ta vii bee (thutey Ag+ X= Ack! 4.2. Di i , 5 ao dich clorid theo phuung phip Moar ng méi tudng trung tinh, két tia Cl bing dung dich AgNOsagi pet Agcll rag ot Kara, HOE BIOL AN | Chi thy) yg La Agt 88 cho kb iy | nvdusdid eda ApsCtOe 2Ag' b C10? AgacrOa} tinh nen; Néu dung dich acid phi trang kid phai trang hda bling dung toa ‘Cin chinh xg Vi yan ede mdi traning (rang, Ingr bdng change jot NalTCO,. Néu dung diet © dich INOS. Pha vio ng 4,3. Dinh hegng dung dich KT bing phuong phiip Fajans. inh mite aé Phuong phip ndy da ten tinh cht eda Kt tia Nd phy mgt sb ete 4 [Tinh Kiva snd vd laa cho ede cht maw nay thay dBi mau, KC ta T bang dung dich AEE ha Crinscr ri cozinat, ‘Trong dimg dich, anion eozinnt (E) ¥8 moe base ‘neu -—_t—_ voi chi thin co, ¢6 mau hdng. > Agh += Agtt Khi chtra dén didm trong durong, két tha A\ 5.2. Dinh long ai a gl trong dung dich s€ hip } | phy I, Ie ndy meng tinh thd Agl s® 06 din thch im, khong x8 To ign tugng hip phy do cing dign tfch Am. Khi thira 1 gigt AgNOs, mang tinh thd Agi | Rot dung sé hfp phy Ag* va mang dign tich dong, xay ra hign tugng hap phy Ey im Didu chin mau ctia cia dung dich chuyén tir hdng sang do tim. 20 | Lay chink 4.4, Dinh lugng dung dich KSCN binh nén 5%, .CN bing dung dich AgNOs = Trong méi trudng acid, két tha KS Ag +SCN’= AgSCN | | | 30 | Nho tirt Af Chi thi ding la dung dich Fe (thuéng ding phén sit/amoni). Ki de dung dic | \ \ mot giot SCN" sé lim dé dung dich do t20 phitc Fe(SCN)2". Ghi thé K Fe?* + SCN’ = Fe(SCN)2" 4” \Tinhnd 4,5. Dinh lrgng dung dich clorid 0,9% bing phuong phap Volhard, Faw, = Dang mét lung AgNOs dur va chinh xéc két tia hét Cl. Agt +Cl= AgCl | | 5.3. Dinh Ign, Sau khi phan tg xong, din lugng Ag’ thira bing dunk dich kscy | 2E véi chi thj la Fe": Ag* + SCN'= AgSCNI 1 Rot au Khithira 1 gigt SCN’: : bat Fe}! +SCN'=Fe(SCN)* (mau dd) on hon . 5, TRINH TY TIEN HANH eozin 5.1. Pha 50 ml dung djeh goe NaCl0,0SN__ 7 al 3 NnO [ TT Ci thao tae Ket qui | mau! 1 | Tinh sé gam NaC! de pha 50,00 ml dung dich goc m= J Ghit VeEV 4 | Tinh oe 45 {0mh alata mie dén vach bing nude ck “Tinh Kre va nding d9 thy Wwe chia dui lung dich NaCl vi ira sent | pha Cw nect AB sou | Mp nh long dung dich AgNOs theo phuong phap Mi eas [Toa Cac thao the re T 1 dung dich AgNOs clin xae dj | n “ et | Diéu chinh téi vach “0”. nes ie |__| 2 2 | Lay chinh xéc 10 ml NaCl 0,05N via pha, cho vi cho vio | binh nén. Thé i | i 1m 20 ml nude cdt, 5 giot chi thi K2CrOs | aoc Ka yi 5] No ti dung dich AgNO; wing tinh moe dung dich trong binh nén cé mau hing nhet, Ghi thé tich doc duge trén buret: Vi ml. | 7 | Tinh ndng a6 Cy cita dung dich AgNO. Cho Egg, = = 169,87 TT Cac thao tic 5,3, Dinh lugng dung dich XI theo phuong php Fajans . T | Rot dung dich AgNOs vira xéc dinh nong 4 len buret, Diéu chinh téi vach “0”. 2 | Lay chifih xae 10,00 ml KI can dinh Iugng cho vao | binh non, thém Im! acid acetic dic, 2 git chi thi, ‘ eozinat 0,5%. | Fa hiino tert dung dich AgNOs suing dén koi Ket tha c6 mau hdng tim. | Ghi thé tich doc duge trén buret V2 mi. 4 | Tinh két qua P g/l cia dung dich KI.a y __ [Re qua cin xde dik nina ae Kaeo | a dung dich xult hign mau ao, Ghi thé teh doe duge trén buret Tinh ning 46 Cy cha dung dich KSCN, wyng dung dich clorid 09% bing Phuong php Volbard =~ Cie thao tae Ket qui Rot dung dich KSCN via xk burt | ic dinh néng 49 len bare, Didu chinh 161 vach “0”, Ht 20,00 mi dung dich NaCl09% vio Dak inh mite 100 ml, Thém nude dén vach. Lic déu. Hilt chinh Ye 10,00 ml ding dich NaCl win pha} . Joang trén binh dink mite 100 ml, thém vao chinks (ee 20,00 ml dung dich AgNOs vita dinh Iugng mye * | them 1 mLHNOs de, cho nude edt vita di 100 sal fe dau Ay de if ; Le déuy db ling LE qua gidy Ige (dich loc phai trong). Lay dich loc. Ly chinh xde 50,00 mal dich Ipe cho vio binh nbn, tha $m INOS chi th phn sit amon 10%. ty Won f Nho tir tir dung dich KSCN xudng binh non tGikhi | Vigo, = xudt hién mau dé nhat. Ghi thé tich trén buret. Tinh két qua ndng d6 % cita dung dich NaCl etki n= ew- Pipet chin _ pen cén, das thoy = NH«NOs 1% _ Gidy loc bang xanh r - Bép di _ Can phin dich diéa Sr 3. NOI DUNG THYC HIEN os 4 - Tao tia, Foe va rim tia, fy ta vi mung toa dén Kes tugng khing 455 ak, tates dinh khéi long ta. : - Lap c6ng. thite tinh todn C26 (Kl/t) NaxSOu trong mS. = 4, NGUYEN TAC ‘| Khi thém mot dung dich BaClz dur vio dung dich sulfat cdn xic Sh 6 tia BaSO+ theo phuong trinh phan ung: Na:SO:+ BaCl > BaSOs] +2 NaCl | Loc liy ta, rita tia, sdy kh, nung tia d&n Khoi lugng khong iden | can trén cn phan tich, tir d6 tinh ra ham lung sulfat cd Rong miu. \ Chii ¥ ring BaSOs ¢6 tan mot it trong acid dic vi thé néakéttoma | trrong acid nhe. BE lim cho hat tia to, khéng bj lot qua gidy lee, edn phai kk Ly tia trong diéu kign dun néng, dung dich lodng va ngém tha liu trong ose dich me (qua trinh lam mudi ta). Khi nung tia khong durge dé nhigt 8 x vugt qué 800°C vi é 1400°C BaSOs bi phan hy theo phirong tinh: BaSO, "5 Bad + SO, 5. TRINH TY’ TIEN HANH TT g aa Cac thao tic Ket qui, a Nac djnh khdi lugng chén nung | , 4g EEphp phn tich Kh8i hagng, rev a phone : | 1.Mye ae nguyen te ou oe Spee ia ta, s8y, mang vo Trinh bay ar ee dO Ce tinh KEL aU nd [ ane hah doe gp drge COM du phn tich, 5 oem ron Sulfa trong mau pl . nbc dG CY THE NGHIEN ; un Dung cu thi nghigm eee _ Chén ean - Céc c6 mé 250ml «pipet chinh xéc 10ml, pipet paste, = BaClh oe - pen edn, dia thay tinh, ph&u thay tiny rte “Ta sdy, ti: nung, binh hit im - Gidy loc bang Oily te bane ea - Can phan tich dign tir 3, NOI DUNG THYC WIEN rae - Tao tia, Ioe va nia tia, sy ta va nung tia den khdi lurgng khong 48 aa He dinh khéi lung tha. - Lap dng thite tinh tod C% (K/tt) NazSOs trong mat _ 4, NGUYEN TAC Khi thém mét dung dich BaCh dur vao dung dich sulfit can xd c6 tia BaSOx theo phuong trinh phan tny 4 NazSOs+ BaCl + BaSOs| + 2NaCl Loc ly tit, ria tia, sdy kh6, nung tia dén khdi long khong di, dem cn trén cn phan tich, tir d6 tinh ra him lugng sulfat co tong miu, Chi ¥ ring BaSOs 6 tan mét it trong acid dic vi thé nén két tia 6 msi | tnrong acid nhe. Dé lam cho hat tia to, khong bi lot qua gidy loc, cdn phat ke tia trong diéu kign dun néng, dung dich lofing va ngdm tia lau trong dung dich me (qué trinh Lim mudi tia). Khi nung tia khong duge dé nhigt 49 cao vuot qué 800°C vi 6 1400®C BaSOs bj phin hity theo phuong trinh: BaSO, "> Bad + SO, 5. TRINH TY’ TIEN HANH [ Cae thao tac jinh khoi lugng chén nung 49 Den avery PMG LS een ta 600 60, Lah ni 96 ¥i6 Wi any. 6 Chuko i 9 Vy chin ncn Nin Tlie Dun s6i. Yue vio bn dur vu phat, pe 4 \ Tae vi rita 1 Gan nude tr khong tro (yi eft, sau 46 _| wen pits Shy tia DE gidy toe loc 6 Wa (khoang 1: wap Iai th dén khdi | Nu Dat chén thanh th: dem nur 25 phit sau dé khdng ¢ 7 \C&n\d Can ctCann mmm Dem eben 00 pit. Hy eh bj mit Ldy ehinh xéc 10,00 mnt dung dich NaxSOs ~ 2% vio ‘ede 250ml, thém 100 mi nude eft, 0SmT ACTA Dat con hay bép dign (c6 16t ludi). tren den Kats Dun s6i. Vira khudy vira cho tir tir dung dich BaCh 0,5N. vao dén dir khoting 10% so v6i sulfat. Dun sdi lai vai phat, Dé ling, kiém tra xem tha hoan toan chua. Dun eéch thiy (think thoang Khudy déu) 1 git (¢6 thé rat ngan thoi gian), dé ling. 4] Lge vA nia tia Gan nuéc trong 6 trén tia qua mot phéu c6 gidy loc kh6ng tro (gidy bang xanh). Rira gan vai Jan bang nuée . cfit, sau dé chuyén hoan toan tia sang, phéu, Rita tiép tha trén phéu 2 lan bing dung dich NHsNOs 1%. “| _|— 3 _| Sy tia - Dé gilly loc va tha chdy nét nuéc, dem cd phéu va gidy loc c6 tha sly & 100°C dén Khi gidy Igc con hoi Am (khodng 15- 20 pht), nhite gidy loc c6 tia ra Khoi phéu, pip lai theo hinh chép va dat vio chén nung 43 nung dén khdi luong khéng déi 6 tren, a Khoi lwrgng khong doi dign va di hay think ngon Ira), sau 4 [6 | Nung tia dé pat chén nghiéng & bép thanh than (nhung khéng cl dem nung chén nung c6 tia & 600-700°C trong khoang 25 phat. Lay chén nung ra dé ngudi trong binh hit Am, ng tigp va can den khéi lwong Jt cho gidy loc chéy sau d6 dem cAn. Lai nu khdng d6i. = 7 [Cain khdi lwong tia ; Can chinh xae khdi lygng cla chén nung co tia duge nas khdi long m2. Xac dinh khdi lung BaSOs. . ‘ 50‘Tinh k&t qua Lp cOng thite tinh C% (kt) NaxSOs trong mau. iw \ Bao cio két qua. 6. CAU HOI 6.1. Trinh bay . Ly duge cée bude ti i i ihdt luge? tién hanh dinh long SO2 bing phuong phép 6.2. Tai sao khi két tia phai thye hién cdc bude sau: - Dun néng dung dich? ~ Cho thuéc thir thira? ~ Dun cach thity, khudy déu thém mét thoi gian? 6.3. Lam thé nado dé biét SO¢* da tha hodn toan? 6.4. Thé nao la sy va nung dén khéi lugng khong abi 6.5. Tai sao phai dé ngudi trong binh hat Am truée khi cin? nén rita lam nhigu an hay it lan? 6.6. Khi rita ‘tia, cling voi thé tich nuéc rita, Tai sao? 6.7, DS dinb lwgng Ca trong 4 véi, news te cn 0,41 16g da voi, hda tan bing, HCI réi kigm héa bing NH.OH. Kat tha Ca duéi dang CaCrOa bing, (NHa)2C204. Loe, rita tia, nung thinh CaO cin durge 0.2302g. Viet phurong, trinh phan tmg xay Ta. ‘Tinh thira s6 chuyén F vA % Ca trong da voi.