SEMS Academy

Chemistry (TEST -11)

Test Session-2021
Name: Class: 2nd Year, Time: 1.Hrs, Marks:, Date:
Q No. 1 2 3 4 Total
Marks 30

Q.1 Four possible options have been given. Tick () mark the correct option. (08)

i. Which of the following will have highest boiling point

(a) Methanol (b) Ethanol (c) Propanol (d) Hexanone
ii. A cyanohydrins carboxyl adduct contains
(a) All single bonds (b) single & double bonds
(c) double & triple bonds (d) single & triple bonds
iii. Which of the following reacts with HCN to form an addition product?
(a) CH3CHO (b) CH3CH2-OH (c) CH3COOH (d) CH3-CONH2
iv. Calcium format on dry heating yields
(a) HCHO (b) CH3CHO (c) CH3COCH3 (d) CH3COOH
v. A mixture of calcium formate& calcium acetate on heating yields
(a) HCHO (b) CH3CHO (c) CH3COCH3 (d) CH3COOH
vi. Acetaldehyde reacts normally with
(a) Electrophiles only (b) Nucleophiles only
(c) Electrophiles & Nucleophiles (d) Free radicals only

vii. Aldol compound consist of

(a) Aldehyde (b) Hydroxyl group (c) Carboxylic acid (d) a + b
viii. The carbon atom of a carbonyl group is:
(a) sp2 hybridized (b) sp hybridized (c) sp3 hybridized (d) none of these

Note: Attempt any six questions: 7x2=14

i. Covert calcium acetate into acetone?

ii. What is formalin?
iii. How acetaldehyde is prepared on industrial state?
iv. What is the reactivity of carbonyl group?
v. Covert acetaldehyde into lactic acid?
vi. Give the generalized mechanism of base catalyzed reaction?
vii. What are symmetrical and unsymmetrical ketones?
Long Questions: 4x2 = 8
(a) Discuss the mechanism of sodium bisulphite with carbonyl compound
(b) Discuss the mechanism of aldol condensation.