woo reqigmye wnnycciny [http://www.akubihar.com Code : 100103 B.Tech ist Semester Exam., 2019 Time : 3 hours (New Course) CHEMISTRY ull Marks : 70 Instructions: The marks are indicated in the right-hand margin (8) There are NINE questions in this paper. (ii) Attempt FIVE questions in all (fv) Question No. 4 is compulsory (a) oe o @ + Answer any seven questions (answer in brief): 2x ‘What is the designation of the orbital having n=4 and 1=3? Which quantum number specifies the shape of an orbital? What are the shapes of NF5 and CIF, molecules? ‘Arrange 0,03, OF" and O§ in order of increasing bond length, 20aK/270 (Turn Over } bitp:/www.akubihar com woo reqigmye wnnycchny @ my @ o % |http://www-akubihar.com (2) Out of Cr? and Cr", which one is stable in aqueous solution? Write the electronic configuration of Zn®* and comment on its magnetic behaviour What is selection rule? A reaction has AH 082 L atm K" ‘mol, Compare the above result with the pressure caloulated using ideal gas equation. 4 043 L mol", R 6. (a) The boiling point of water is 373 K at 1 atm. Calculate w, q, BU, BF, 8G, OA and AS when 1 mole of steam is ‘compressed igothermally and reversibly. Given, latent heat of vaporization of water is 40-67 kel mol”, 7 20aK/270 ( Continued } bitp:/www.akubihar.comwoo reqigmye wnnycchny |http://wwayakeubihar.com Cs) (b) Consider the reactions P02(0) +41" (aq) +502 fq) +2 + P0804 6) following —half-cell 42H,0, B°=170 V PUSO« 6) +2e 4 Po(9 +807" faq E*= -031 V ‘Write the cell in proper cell notation and ‘also write the cell reaction. Calculate the value of E* for the cell and the EMP a 3 ‘http://www akeubihar.com i) ‘and same volume of hard water sample, after boiling and filtering, required 10 mL of EDTA solution. Calculate total hardness ané carbonate hardness. for the hard water sample. 3 Give the theory of zeolite method, its Limitations ané advantages. 6 Write notes on the following 3xd12 coed =f Glso1m and = ( Geomesrcalisomeriem = (80% ]=224. bups/iwwwakubiharcom 7 = § (@) Open womerian g Z : (3) naniomers : + fa) Calculate the amount of time 4% = BE fo) meneecanas = pry) and toda (82% puri) renuired = eso-comp E for the ueatment of « milion yes of «FE which among the following molecules water per day for a week having 3 g ‘shows geometrical isomerism? 2 3 folowing constituents s 3 g ae a -butene Ca(HCOs} =40ppm, Mg(HCO,}, =36 ppm aS0, =34 ppm, MgSO, = 30 ppm, CaCl, =27-75 ppm, NaCl =10 ppm (2 2-pentene 2 a 8) 05 g of CaCO, was dssclved in HCL (eo) 1, 2chlropropane and the solution made up t0 500 mL with distled water, 50 ml of this 9. (@) Explain the flown solution required 48 mL of EDTA Expl lowing 9 Solution for titration. 50 mL of hard © Heoatkanes on reaction with KCN rater sample required 15 mL of EDTA give cyanide and with AECN ive isocyanies. Ps 20AK/270 (Tum Over } oaKs270 ( Continued ) bitp:/www.akubihar.com bitp:/www.akubihar comwoo reqigmye wnnycchny ppg com (6) dition oF a, follow “Maou sae Presence of persie, (ts, 1 kd scenic oe whereas 83.2 gives inverted ett Products, 7 1) How do you ese waste ain CtlBev on -scHyom proceeds by Sy) 82 wet? Give proper explanation, 3 (0) Comment on the stability of carbocations. 2 apse akbar com Whatsapp @ 9300930012 Your olé paper & get 10 sy ee A ae 10 Pim or Gog Pos cade 00108 270 200900 ovr akubiharcom