SDS - Stikwel 469L-LV

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Safety Data Sheet

Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

1. Product and company identification


1.1 Identification of the substance or preparation:
Commercial product name: STIKWEL 469L-LV
Use of substance / preparation STIKWEL 469L-LV is a high-performance water-based Ethylene Vinyl
Acetate Copolymer Emulsion for OPP lamination to solid printed white
paper board.

1.2 Company/undertaking identification:


Manufacturer/distributor: Consolidated Adhesives, Inc.
139 D Aurora Boulevard
San Juan City, Metro Manila
Philippines
Info Line:
Tel (02) 8872-8797, Fax (02) 8874-1486
Hours of operation:
Monday - Saturday, 8 am to 5 pm
Corporate website: www.stikwel.com

Contact person: Mateo Chan, Jr.


(02) 8872-8797 (Manila)
Carmela Chan
(046) 430-2035 (Cavite)
Emergency telephone nos: (02) 8872-8014 (Manila)
(046) 430-2035 (Cavite)
(02) 8359-5595 (Wireless landline)

2. Hazards identification
2.1 Classification of the substance or mixture
Classification (GHS):
Not a hazardous substance or mixture.
2.2 Label elements
Labelling (GHS):
No labeling according to GHS required.
2.3 Other hazards
No data available.

3. Composition/information on ingredients
3.1 Chemical characterization (preparation)
COMPONENT CAS NO. CONCENTRATION
Ethylene Vinyl Acetate Copolymer - 48 – 52%
Water 7732-18-15 48 – 52%
Additives - < 1.50%
Preservatives - < 0.40%
Information on ingredients:
This material does not contain any reportable hazardous ingredients.
Component CAS No. Concentration Acrylic polymer - 51 – 53% Water 7732-18-5 51 – 53% Additives - <
Substances listed in the Subsections
1.50% Preservatives - < 0.40%"HAPS" and "California Proposition 65 Carcinogens / Reproductive Toxins" that are not
listed in this section are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non-
carcinogenic HAPS or they are inextricably bound in the product.

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

4. First-aid measures
4.1 General information:
In cases of sickness seek medical advice (show label or SDS if possible).
4.2 After inhalation
No special treatment required.
4.3 After contact with the skin
If contact with skin, wash skin with plenty of water or with water and soap.
4.4 After contact with the eyes
If contact with eyes, immediately flush eyes with plenty of water. Get medical attention if irritation occurs.
4.5 After swallowing
If swallowed, induce vomiting. Get medical attention if symptoms occur. Show label if possible.

5. Fire-fighting measures
5.1 Flammable properties:
Property: Value: Method:
Flash point...............................................................: not applicable
Boiling point / boiling range .....................................: approx. 100 °C (212 °F) at 1013 hPa
Lower explosion limit (LEL) .....................................: not applicable
Ignition temperature ................................................: not applicable
5.2 Fire and explosion hazards:
Dried up material is combustible. This material does not present any unusual fire or explosion hazards.
5.3 Recommended extinguishing media:
Use extinguishing measures appropriate to the source of fire. Water may be used to cool tanks and structures adjacent to the fire.
5.4 Unsuitable extinguishing media:
not applicable
5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
At low oxygen level: acetic acid.
5.6 Fire fighting procedures:
Fire fighters should wear full protective clothing including a self-contained breathing apparatus.

6. Accidental release measures


6.1 Precautions:
Wear personal protection equipment (see section 8). If material is released indicate risk of slipping.
HAZWOPER PPE Level: D
6.2 Containment:
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
Spills of material which could reach surface waters must be reported to the Philippine Coast Guard phone number (02) 527-8482
to 89.
6.3 Methods for cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. For small amounts: Absorb with a liquid binding
material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and
pump up into suitable containers. Clean up with plenty of water. Dispose of cleansing water in accordance with local/state/federal
regulations.

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

7. Handling and storage


7.1 General information:
No special protective measures required.
7.2 Handling
Precautions for safe handling:
Spilled substance increases risk of slipping.
Precautions against fire and explosion:
No special precautions against fire and explosion required.
7.3 Storage
Conditions for storage rooms and vessels:
Protect against frost.
Advice for storage of incompatible materials:
not applicable.
Further information for storage:
not applicable.
Minimum temperature allowed during storage and transportation: 0 °C (32 °F)

8. Exposure controls and personal protection


8.1 Engineering controls
Ventilation:
Use with adequate ventilation.
Local exhaust:
not necessary
8.2 Personal protection equipment (PPE)
Respiratory protection:
not necessary
Hand protection:
Recommendation: rubber gloves.
Eye protection:
chemical safety goggles
Other protective clothing or equipment:
not necessary
8.3 General hygiene and protection measures:
Do not eat or drink when handling. Wash thoroughly after handling.

9. Physical and chemical properties


9.1 Appearance
Physical state / form ................................................: Liquid
Color .....................................................................: Milky white
Odor ......................................................................: Faint

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

9.2 Safety parameters


Property: Value: Method:
Melting point / melting range ...................................: Not applicable
Boiling point / boiling range .....................................: approx. 100 °C (212 °F) at 1013 hPa
Flash point...............................................................: not applicable
Ignition temperature ................................................: not applicable
Lower explosion limit (LEL) .....................................: not applicable
Vapor pressure......................................................: 23 hPa at 20 °C (68 °F)
Density ....................................................................: 1 - 1.05 g/cm³ at 20 °C (68 °F) (Specific method)
Water solubility / miscibility......................................: Highly miscible
pH-Value .................................................................: 4.0 – 6.0 (Specific method)
Viscosity (dynamic) .................................................: 500 + 100 cps at 25 °C (77 °F) (Specific method)

10. Stability and reactivity


10.1 General information:
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
10.2 Conditions to avoid
none known.
10.3 Materials to avoid
Use clean receptacle in handling to avoid microbial contamination. Keep container tightly closed when not in use.
10.4 Hazardous decomposition products
If stored and handled properly: none known. At increased temperature: acetic acid.
10.5 Further information:
Hazardous polymerization cannot occur.

11. Toxicological information

11.1 Information on toxicological effects


11.1.1 Acute toxicity
Assessment:
Based on the available data acute toxic effects are not expected after single oral exposure.
Product details:
Route of exposure Result/Effect Source
Oral Not applicable Materials are
Dermal Not applicable not of
Inhalation Not applicable hazardous
nature
11.1.2 Skin corrosion/irritation
Assessment:
Based on the available data a clinically relevant skin irritation hazard is not expected.
Product details:
11.1.3 Serious eye damage / eye irritation
Assessment:
Based on the available data a clinically relevant eye irritation hazard is not expected.

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

11.1.4 Germ cell mutagenicity


Assessment:
Based on known data a significant mutagenic potential may be excluded.
Product details:
Result/Effect Species/Test system Source
Not applicable Not applicable Materials are
not hazardous
in nature
11.1.5 Carcinogenicity
Assessment:
For this endpoint no toxicological test data is available for the whole product.

11.1.6 Reproductive toxicity


Assessment:
For this endpoint no toxicological test data is available for the whole product.

11.1.7 Specific target organ toxicity (single exposure)


Assessment:
For this endpoint no toxicological test data is available for the whole product.

11.1.8 Specific target organ toxicity (repeated exposure)


Assessment:
For this endpoint no toxicological test data is available for the whole product.

11.1.9 Aspiration hazard


Assessment:
Based on the physical-chemical properties of the product no aspiration hazard must be expected.

11.1.10 Further toxicological information


No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Other information: No information on damage to health during manufacture and use.

12. Ecological information

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

12.1 Toxicity
Assessment:
No expected damaging effects to aquatic organisms. According to current knowledge adverse effects on water purification plants
are not expected.
Product details:
Result/Effect Species/Test system Source
Not applicable Not tested Materials are
not hazardous
in nature
Not applicable Not tested Conclusion by
analogy
12.2 Persistence and degradability
Assessment:
Polymer component: Not readily biodegradable. Elimination by adsorption to activated sludge. Separation by flocculation is
possible.
12.3 Bio accumulative potential
Assessment:
No adverse effects expected.
12.4 Mobility in soil
Assessment:
No adverse effects expected.
12.5 Other adverse effects
None known
12.6 Additional information
According to present knowledge no adverse influence to environment expected.

13. Disposal considerations


13.1 Product disposal
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Small quantities may be disposed of by
incineration in an approved facility. Observe local/state/federal regulations.
13.2 Packaging disposal
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Recommended cleaning agent:
water

14. Transport information


14.1 US DOT & CANADA TDG SURFACE
Valuation ................................................: Not regulated for transport
Other Information ...................................: Protect from freezing, when exposed to cold temperatures approaching 0 °C (32 °F) or
below.
14.2 Transport by sea IMDG-Code
Valuation ................................................: Not regulated for transport

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Safety Data Sheet
Stikwel 469L-LV Date of print: 10/21/2023 Date of last alteration: 10/21/2023

14.3 Air transport ICAO-TI/IATA-DGR


Valuation ................................................: Not regulated for transport

15. Regulatory information


This safety data sheet (SDS) has been prepared in accordance to the hazard communication requirements of DENR
Administrative Order No. 2015- 09 on the implementation of Globally Harmonized System (GHS) of Classification and
Labelling of Chemicals.

16. Other information

Date of issuance : 10.21.2023


Revision details : Fulfillment of minimum information requirements in all sections

Key to abbreviations and acronyms:

PPE Personal Protective Equipment


LD50 Lethal Dose which causes the death of 50% of a group of test animals
LC50 Lethal Concentration which causes the death of 50% of a group of test animals
DOT United States Department of Transportation
IMDG International Maritime Code for Dangerous Goods
IATA International Air Transport Association
UN United Nations Dangerous Goods List
SDS Safety Data Sheet
DENR Philippine Department of Environment and Natural Resources
GHS United Nations Globally Harmonized System of Classification and Labelling of Chemicals

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